CN110066505B - 哑光pc-abs合金材料及其制备方法 - Google Patents
哑光pc-abs合金材料及其制备方法 Download PDFInfo
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- CN110066505B CN110066505B CN201910443918.6A CN201910443918A CN110066505B CN 110066505 B CN110066505 B CN 110066505B CN 201910443918 A CN201910443918 A CN 201910443918A CN 110066505 B CN110066505 B CN 110066505B
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- 239000000956 alloy Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000000835 fiber Substances 0.000 claims abstract description 99
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 94
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 55
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000004417 polycarbonate Substances 0.000 claims abstract description 45
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 39
- 238000002156 mixing Methods 0.000 claims abstract description 23
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 claims description 60
- 239000004642 Polyimide Substances 0.000 claims description 39
- 229920001721 polyimide Polymers 0.000 claims description 39
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical compound Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 claims description 32
- 239000007853 buffer solution Substances 0.000 claims description 31
- 229960003638 dopamine Drugs 0.000 claims description 30
- 238000001035 drying Methods 0.000 claims description 28
- 229920001709 polysilazane Polymers 0.000 claims description 21
- 239000002048 multi walled nanotube Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 238000001914 filtration Methods 0.000 claims description 19
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 18
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 229910021389 graphene Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims description 12
- 229910003472 fullerene Inorganic materials 0.000 claims description 12
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 11
- 229960001149 dopamine hydrochloride Drugs 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
- 229920007019 PC/ABS Polymers 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 15
- 238000002844 melting Methods 0.000 abstract description 13
- 230000008018 melting Effects 0.000 abstract description 13
- 238000005452 bending Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 30
- 238000001746 injection moulding Methods 0.000 description 21
- 238000002347 injection Methods 0.000 description 10
- 239000007924 injection Substances 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- 239000004744 fabric Substances 0.000 description 8
- 239000003365 glass fiber Substances 0.000 description 8
- 239000002109 single walled nanotube Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- VXZBYIWNGKSFOJ-UHFFFAOYSA-N 2-[4-[5-(2,3-dihydro-1H-inden-2-ylamino)pyrazin-2-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC=1N=CC(=NC=1)C=1C=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2 VXZBYIWNGKSFOJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002748 Basalt fiber Polymers 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229920006150 hyperbranched polyester Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
拉伸强度/MPa | 弯曲强度/MPa | 冲击强度(KJ/m<sup>2</sup>) | |
实施例1 | 42.8 | 60.4 | 28.4 |
实施例2 | 50.3 | 73.8 | 33.2 |
实施例3 | 51.8 | 75.4 | 33.9 |
实施例4 | 52.6 | 75.9 | 35.0 |
实施例5 | 55.3 | 77.3 | 38.4 |
实施例6 | 57.5 | 88.7 | 41.9 |
实施例7 | 60.8 | 92.0 | 48.7 |
实施例8 | 61.4 | 90.5 | 48.5 |
实施例9 | 62.5 | 91.5 | 50.1 |
60°光泽度(°) | |
实施例1 | 16 |
实施例2 | 13 |
实施例3 | 13 |
实施例4 | 14 |
实施例5 | 13 |
实施例6 | 9 |
实施例7 | 8 |
实施例8 | 4 |
Claims (2)
Priority Applications (1)
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CN201910443918.6A CN110066505B (zh) | 2019-05-27 | 2019-05-27 | 哑光pc-abs合金材料及其制备方法 |
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CN201910443918.6A CN110066505B (zh) | 2019-05-27 | 2019-05-27 | 哑光pc-abs合金材料及其制备方法 |
Publications (2)
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CN110066505A CN110066505A (zh) | 2019-07-30 |
CN110066505B true CN110066505B (zh) | 2021-07-02 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110980631B (zh) * | 2019-12-13 | 2023-06-06 | 深圳先进技术研究院 | 一种柔性电极及其制备方法 |
CN111410836B (zh) * | 2020-05-26 | 2022-01-28 | 西南科技大学 | 一种用于光学薄膜的pc/pmma复合材料的制备方法 |
CN114075380A (zh) * | 2020-08-18 | 2022-02-22 | 中石化南京化工研究院有限公司 | 一种高强高抗冲pc/abs合金材料及其制备方法 |
CN112795161B (zh) * | 2020-12-30 | 2022-06-21 | 广州辰东新材料有限公司 | 一种用于改善数码产品壳体熔接痕的pc/abs聚合物合金及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044874A (zh) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | 低光泽度聚碳酸酯/苯乙烯基树脂组合物及其制备方法 |
CN106751658A (zh) * | 2016-12-09 | 2017-05-31 | 上海中镭新材料科技有限公司 | 一种pc/abs合金材料、其制备方法及用途 |
CN108660742A (zh) * | 2018-05-21 | 2018-10-16 | 北京化工大学常州先进材料研究院 | 一种聚酰亚胺纤维表面化学修饰碳纳米管的制备方法 |
Family Cites Families (1)
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JP2005068349A (ja) * | 2003-08-27 | 2005-03-17 | Toray Ind Inc | 熱可塑性樹脂組成物およびそれからなる成形品 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044874A (zh) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | 低光泽度聚碳酸酯/苯乙烯基树脂组合物及其制备方法 |
CN106751658A (zh) * | 2016-12-09 | 2017-05-31 | 上海中镭新材料科技有限公司 | 一种pc/abs合金材料、其制备方法及用途 |
CN108660742A (zh) * | 2018-05-21 | 2018-10-16 | 北京化工大学常州先进材料研究院 | 一种聚酰亚胺纤维表面化学修饰碳纳米管的制备方法 |
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Inventor after: Chen Weicheng Inventor after: Wang Fei Inventor before: Wang Fei |
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Effective date of registration: 20210611 Address after: 313000 No.166, Chenda village, Xichuan village, Meishan Town, Changxing County, Huzhou City, Zhejiang Province Applicant after: Chen Weicheng Address before: No 11 Group 18 zhekeng village Huanggang Town Xiushui County Jiujiang City Jiangxi Province Applicant before: Wang Fei |
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Effective date of registration: 20210908 Address after: 313100 No. 50, Daxiang Road, Meishan Town Industrial Park, Changxing County, Huzhou City, Zhejiang Province Patentee after: Huzhou Weiyue polymer material Co.,Ltd. Address before: 313000 No.166, Chenda village, Xichuan village, Meishan Town, Changxing County, Huzhou City, Zhejiang Province Patentee before: Chen Weicheng |