CN109890861B - 热固性组合物以及由其形成三维物体 - Google Patents

热固性组合物以及由其形成三维物体 Download PDF

Info

Publication number
CN109890861B
CN109890861B CN201780066567.0A CN201780066567A CN109890861B CN 109890861 B CN109890861 B CN 109890861B CN 201780066567 A CN201780066567 A CN 201780066567A CN 109890861 B CN109890861 B CN 109890861B
Authority
CN
China
Prior art keywords
composition
network
tpa
acrylate
based polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780066567.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN109890861A (zh
Inventor
保卢斯·安东尼厄斯·玛丽亚·斯蒂曼
马尔科·马库斯·马特乌斯·德里森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stratasys Inc
Original Assignee
Covestro Netherlands BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP16196338.4A external-priority patent/EP3315292A1/en
Priority claimed from EP16196334.3A external-priority patent/EP3315522A1/en
Application filed by Covestro Netherlands BV filed Critical Covestro Netherlands BV
Publication of CN109890861A publication Critical patent/CN109890861A/zh
Application granted granted Critical
Publication of CN109890861B publication Critical patent/CN109890861B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/064—Polymers containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/061—Polyesters; Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
    • G03F7/0388—Macromolecular compounds which are rendered insoluble or differentially wettable with ethylenic or acetylenic bands in the side chains of the photopolymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/141—Processes of additive manufacturing using only solid materials
    • B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Polymerisation Methods In General (AREA)
CN201780066567.0A 2016-10-28 2017-10-30 热固性组合物以及由其形成三维物体 Active CN109890861B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP16196338.4A EP3315292A1 (en) 2016-10-28 2016-10-28 Thermosetting compositions and forming three-dimensional objects therefrom
EP16196334.3 2016-10-28
EP16196338.4 2016-10-28
EP16196334.3A EP3315522A1 (en) 2016-10-28 2016-10-28 Thermosetting compositions and forming three-dimensional objects therefrom
PCT/EP2017/077782 WO2018078160A1 (en) 2016-10-28 2017-10-30 Thermosetting compositions and forming three-dimensional objects therefrom

Publications (2)

Publication Number Publication Date
CN109890861A CN109890861A (zh) 2019-06-14
CN109890861B true CN109890861B (zh) 2022-04-05

Family

ID=60302093

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201780066646.1A Active CN109982829B (zh) 2016-10-28 2017-10-30 热固性组合物以及由其形成三维物体
CN201780066567.0A Active CN109890861B (zh) 2016-10-28 2017-10-30 热固性组合物以及由其形成三维物体

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201780066646.1A Active CN109982829B (zh) 2016-10-28 2017-10-30 热固性组合物以及由其形成三维物体

Country Status (8)

Country Link
US (5) US11492505B2 (enExample)
EP (2) EP3532518B1 (enExample)
JP (2) JP7701780B2 (enExample)
KR (1) KR102424313B1 (enExample)
CN (2) CN109982829B (enExample)
AU (1) AU2017351802B2 (enExample)
CA (1) CA3041660A1 (enExample)
WO (2) WO2018078160A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7701780B2 (ja) 2016-10-28 2025-07-02 ストラタシス，インコーポレイテッド 熱硬化性組成物及びそれからの三次元物体の形成
CN111836723B (zh) * 2017-12-31 2023-05-23 斯特拉塔西斯公司 可用于在低温下三维物体的增材制造的模型材料制剂
WO2020095846A1 (ja) * 2018-11-07 2020-05-14 ナガセケムテックス株式会社 光硬化性樹脂組成物および樹脂硬化物
CN113423788B (zh) * 2018-12-27 2024-01-12 斯特拉塔西斯公司 使用经加强材料的积层制造
EP3909747A1 (en) * 2020-05-12 2021-11-17 TIGER Coatings GmbH & Co. KG Thermosetting material for use in a 3d printing process
CN111978479B (zh) * 2020-08-11 2021-11-12 珠海赛纳三维科技有限公司 三维成型用材料、三维物体及其切片层
WO2022150458A1 (en) * 2021-01-08 2022-07-14 Opt Industries, Inc. Multi-cure polymer systems for additive manufacturing
EP4049841A1 (en) 2021-02-26 2022-08-31 Cubicure GmbH Hybrid resin composition
JP2022135224A (ja) * 2021-03-05 2022-09-15 株式会社リコー 立体造形物の製造方法および立体造形用キット
JPWO2024010080A1 (enExample) * 2022-07-08 2024-01-11

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877118A (zh) * 2015-06-18 2015-09-02 上海天洋热熔粘接材料股份有限公司 一种适于作为3d打印材料的共聚酯及其制备方法
CN105601794A (zh) * 2015-11-16 2016-05-25 复旦大学 一种海泡石与丙烯酸酯复合的光固化材料及其制备方法
CN105801819A (zh) * 2016-06-01 2016-07-27 昆山天洋热熔胶有限公司 一种适于作为3d打印材料的共聚酯及其制备方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2931608B2 (ja) * 1988-03-02 1999-08-09 ディーエスエム ナムローゼ フェンノートシャップ 変形を軽減させうる組成物を用いる立体造形法
US4942001A (en) * 1988-03-02 1990-07-17 Inc. DeSoto Method of forming a three-dimensional object by stereolithography and composition therefore
JPH0586149A (ja) 1991-09-30 1993-04-06 I C I Japan Kk 光立体成形用樹脂組成物並びに立体成形体の形成方法
US5566027A (en) * 1993-01-18 1996-10-15 Canon Kabushiki Kaisha Photocurable resin composition and optical lens produced therefrom
JP3115792B2 (ja) * 1995-05-15 2000-12-11 早川ゴム株式会社 活性エネルギー線硬化型樹脂組成物、その製造方法、活性エネルギー線硬化型樹脂の成形硬化品
US8481241B2 (en) * 2000-03-13 2013-07-09 Stratasys Ltd. Compositions and methods for use in three dimensional model printing
JP2003226724A (ja) * 2002-02-04 2003-08-12 Mitsubishi Rayon Co Ltd 造形用ラジカル重合性樹脂組成物、及び立体造形物
US7495034B2 (en) 2002-02-22 2009-02-24 Henkel Corporation Deformable soft molding compositions
KR20050007372A (ko) 2002-05-03 2005-01-17 디에스엠 아이피 어셋츠 비.브이. 방사선 경화성 수지 조성물 및 이를 이용한 쾌속 성형법
EP1645583A1 (en) 2004-10-06 2006-04-12 Cytec Surface Specialties, S.A. Radiation curable powder coating compositions
KR20070067217A (ko) 2004-10-15 2007-06-27 디에스엠 아이피 어셋츠 비.브이. 방사선 경화성 코팅 조성물
WO2007046741A1 (en) * 2005-10-18 2007-04-26 Perstorp Specialty Chemicals Ab Dual cure composition
EP1845143A1 (en) * 2006-04-14 2007-10-17 Cytec Surface Specialties, S.A. Aqueous radiation curable polyurethane compositions
US9676899B2 (en) 2006-05-01 2017-06-13 Dsm Ip Assets B.V. Radiation curable resin composition and rapid three dimensional imaging process using the same
US20080103226A1 (en) 2006-10-31 2008-05-01 Dsm Ip Assets B.V. Photo-curable resin composition
EP2118169B2 (en) * 2007-03-14 2021-03-17 3D Systems, Inc. Curable composition
EP1985674A1 (en) * 2007-04-27 2008-10-29 Cytec Surface Specialties, S.A. Polymer Compositions
KR101326497B1 (ko) 2008-12-01 2013-11-08 에이제이아이 가부시끼가이샤 조형 방법
US20100190881A1 (en) 2009-01-28 2010-07-29 3D Systems, Incorporated Radiation Curable Compositions Useful in Solid Freeform Fabrication Systems
WO2010104603A2 (en) 2009-03-13 2010-09-16 Dsm Ip Assets B.V Radiation curable resin composition and rapid three-dimensional imaging process using the same
KR101833078B1 (ko) * 2009-12-17 2018-02-27 디에스엠 아이피 어셋츠 비.브이. 적층식 제작을 위한 발광 다이오드 경화성 액체 수지 조성물
CN102844352A (zh) 2010-04-15 2012-12-26 太阳控股株式会社 聚酯及其改性物的制造方法
JP5890990B2 (ja) 2010-11-01 2016-03-22 株式会社キーエンス インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法
CN104487221B (zh) * 2012-03-01 2017-09-26 纳斯达克有限公司 阳离子可聚合组合物及其使用方法
EP2847288B1 (en) * 2012-05-09 2018-05-23 Dow Global Technologies LLC A polyester composition and method of producing the same
JP2015010169A (ja) 2013-06-28 2015-01-19 東洋インキＳｃホールディングス株式会社 光学的立体造形用樹脂組成物、及び立体造形物
JP6275413B2 (ja) * 2013-08-19 2018-02-07 デンカ株式会社 光造形用（メタ）アクリル系樹脂組成物及び支持体の製造方法
WO2015037574A1 (ja) 2013-09-11 2015-03-19 東レ株式会社 熱融解積層方式三次元造形用素材および熱融解積層方式３ｄプリント機器用フィラメント
JP6406003B2 (ja) 2014-12-26 2018-10-17 東洋インキＳｃホールディングス株式会社 光学的立体造形活性エネルギー線重合性樹脂組成物、及び立体造形物
KR102422383B1 (ko) * 2016-07-22 2022-07-21 코베스트로 (네덜란드) 비.브이. 적층식 제조에 의해 3차원 물체를 형성하기 위한 방법 및 조성물
JP7701780B2 (ja) * 2016-10-28 2025-07-02 ストラタシス，インコーポレイテッド 熱硬化性組成物及びそれからの三次元物体の形成

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877118A (zh) * 2015-06-18 2015-09-02 上海天洋热熔粘接材料股份有限公司 一种适于作为3d打印材料的共聚酯及其制备方法
CN105601794A (zh) * 2015-11-16 2016-05-25 复旦大学 一种海泡石与丙烯酸酯复合的光固化材料及其制备方法
CN105801819A (zh) * 2016-06-01 2016-07-27 昆山天洋热熔胶有限公司 一种适于作为3d打印材料的共聚酯及其制备方法

Also Published As

Publication number Publication date
US11492505B2 (en) 2022-11-08
CN109890861A (zh) 2019-06-14
WO2018078159A1 (en) 2018-05-03
US20190249018A1 (en) 2019-08-15
CN109982829B (zh) 2021-09-28
EP3532518A1 (en) 2019-09-04
WO2018078160A1 (en) 2018-05-03
US20230106589A1 (en) 2023-04-06
EP3532273A1 (en) 2019-09-04
US20230056681A1 (en) 2023-02-23
EP3532518B1 (en) 2022-08-10
KR20190078598A (ko) 2019-07-04
JP7081871B2 (ja) 2022-06-07
US11999861B2 (en) 2024-06-04
CA3041660A1 (en) 2018-05-03
US11485865B2 (en) 2022-11-01
US11926748B2 (en) 2024-03-12
CN109982829A (zh) 2019-07-05
US20190284405A1 (en) 2019-09-19
AU2017351802B2 (en) 2023-06-29
JP7701780B2 (ja) 2025-07-02
JP2019535845A (ja) 2019-12-12
AU2017351802A1 (en) 2019-05-02
US20250002735A1 (en) 2025-01-02
EP3532273B1 (en) 2022-08-03
KR102424313B1 (ko) 2022-07-26
JP2020504029A (ja) 2020-02-06
US12378425B2 (en) 2025-08-05

Similar Documents

Publication Publication Date Title
CN109890861B (zh) 热固性组合物以及由其形成三维物体
KR101714798B1 (ko) 방사선-경화성 수지 조성물 및 이를 이용한 쾌속 3차원 이미지화 방법
CN111491776A (zh) 用于增材制造的杂合光聚合物组合物
CN108778688B (zh) 具有改善韧性耐高温性的加成法制造用可辐射固化组合物
EP3814392A1 (en) Curable compositions based on multistage polymers
CN111788269B (zh) 用于高温喷射粘性热固性材料以经由增材制造创建固体制品的组合物和方法
EP3315522A1 (en) Thermosetting compositions and forming three-dimensional objects therefrom
EP3315292A1 (en) Thermosetting compositions and forming three-dimensional objects therefrom
WO2024141342A1 (en) Methods for preparing multistage polymer particle compositions and curable formulations for three-dimensional printing processes
WO2024141344A1 (en) Multistage polymer compositions and coatings comprising cured multistage polymer compositions

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: Newhagen, the Netherlands

Applicant after: Kostron (Netherlands) Co.,Ltd.

Address before: Newhagen, the Netherlands

Applicant before: MS Holdings Ltd.

CB02 Change of applicant information
TA01 Transfer of patent application right

Effective date of registration: 20211208

Address after: Newhagen, the Netherlands

Applicant after: MS Holdings Ltd.

Address before: Holland Heerlen

Applicant before: DSM IP ASSETS B.V.

TA01 Transfer of patent application right
CB02 Change of applicant information
CB02 Change of applicant information

Address after: Geleen

Applicant after: Kostron (Netherlands) Co.,Ltd.

Address before: Newhagen, the Netherlands

Applicant before: Kostron (Netherlands) Co.,Ltd.

GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20240401

Address after: American Minnesota

Patentee after: STRATASYS, Inc.

Country or region after: U.S.A.

Address before: Geleen

Patentee before: Kostron (Netherlands) Co.,Ltd.

Country or region before: Netherlands

TR01 Transfer of patent right