CN109790489A - 低pH衣物洗涤剂组合物 - Google Patents
低pH衣物洗涤剂组合物 Download PDFInfo
- Publication number
- CN109790489A CN109790489A CN201780060995.2A CN201780060995A CN109790489A CN 109790489 A CN109790489 A CN 109790489A CN 201780060995 A CN201780060995 A CN 201780060995A CN 109790489 A CN109790489 A CN 109790489A
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- weight
- particle
- aqueous mixture
- acid
- zeolite
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- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 235000014393 valine Nutrition 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
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- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- C11D1/66—Non-ionic compounds
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- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
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- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
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- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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Abstract
本发明涉及一种用于制备喷雾干燥的衣物洗涤剂颗粒的方法，其中该方法包括使沸石与含水混合物中的单体有机羧酸接触的步骤，其中含水混合物具有4.2或更低的pH，其中含水混合物包含去污表面活性剂，其中含水混合物基本上不含硅酸盐，并且其中含水混合物基本上不含碳酸盐，其中沸石与单体有机羧酸反应以形成二氧化硅，其中含水混合物被喷雾干燥以形成喷雾干燥的衣物洗涤剂颗粒，其中颗粒包含：去污表面活性剂；单体有机羧酸；和二氧化硅，其中颗粒基本上不含硅酸盐，并且其中颗粒基本上不含碳酸盐。
Description
技术领域
本发明涉及用于制备喷雾干燥的衣物洗涤剂颗粒的方法。该颗粒基本上不含硅酸盐和碳酸盐，并且具有良好的颗粒特征，诸如良好的物理特性、饼强度、流动性以及良好的分配、溶解和织物残留性能(即在洗涤过程之后的经洗涤的织物上留下低水平的残留物)。
背景技术
在衣物洗涤剂制造工业中最近的趋势是提供衣物洗涤剂粉末，该衣物洗涤剂粉末在用水溶解时产生通常具有在7.0至9.0范围内的pH的洗涤液体。如今，常规衣物洗涤剂粉末在用水溶解时提供pH在10.5至11.0范围内，并且有时更高的洗涤液体。虽然在这些典型范围内的高洗涤pH提供了良好的清洁性能，但难以提供织物护理有益效果。在寻求改善衣物洗涤剂粉末的织物护理性能时，洗涤剂配方设计师正在开发提供低pH洗涤液体的衣物洗涤粉末。通常，这需要从粉末中去除向洗涤液体提供碱度的本体成分。此类成分通常是碳酸盐诸如碳酸钠和硅酸盐诸如硅酸钠。这些成分通常被配制成衣物洗涤粉末，不仅提供pH为约10.5的洗涤液体，而且还为衣物洗涤粉末提供良好的物理特性。
衣物洗涤剂粉末的基础颗粒通常通过喷雾干燥方法制备。在此方法期间，洗涤剂成分诸如洗涤表面活性剂、聚合物、填料盐(如果使用的话)形成为含水混合物，通常被称为搅和机混合物，并且然后喷雾干燥以形成喷雾干燥的衣物洗涤剂颗粒。这种喷雾干燥的颗粒可用作衣物洗涤剂粉末产品，或者(并且更常见地)喷雾干燥的颗粒与其它成分诸如漂白剂颗粒、酶颗粒、香料和有时还有附加的表面活性剂颗粒和其它干燥加入的颗粒如填料颗粒诸如硫酸钠颗粒混合以形成全配方衣物洗涤剂粉末。
喷雾干燥的基础颗粒中存在碳酸盐和硅酸盐不仅提供洗涤剂配方设计师通常用于提供良好清洁的碱度(约10.5)，而且还为喷雾干燥的基础洗涤剂颗粒提供良好的物理特征。此类物理特征包括良好的饼强度和良好的流动性。
然而，最近向在较低pH下配制衣物洗涤剂粉末以及因此喷雾干燥的基础洗涤剂粉末的行动导致需要从喷雾干燥的基础粉末中去除诸如碳酸盐和硅酸盐的成分。这继而导致喷雾干燥的颗粒中物理特性差的问题，该喷雾干燥的颗粒正在被开发用于这些低pH衣物洗涤粉末产品。
诸如二氧化硅的成分被认为是喷雾干燥的颗粒中碳酸盐和硅酸盐的替代物。然而，在制造过程期间难以处理二氧化硅。二氧化硅的密度非常低且粒径小意味着需要复杂和精细的加工设备和控制，以便在喷雾干燥混合物之前在搅和机混合物中加入二氧化硅以形成喷雾干燥的基础颗粒。二氧化硅在引入搅和机混合物中期间的行为通常被描述为气态，或类似烟雾，并产生许多问题，诸如粉尘和精确的剂量。
本发明人已经发现，不是将二氧化硅作为起始材料引入并试图将其加入到搅和机混合物中，而是可通过沸石的反应在搅和机混合物中原位形成二氧化硅，该沸石在低pH的条件下在含水环境中形成二氧化硅。为此，必须小心控制搅和机混合物的pH，以便发生这种反应。
沸石用作常规洗涤剂成分，其常用于衣物洗涤剂粉末中。将沸石掺入搅和机混合物中的制造方法和方式是很好理解的。几十年前，沸石作为在转移到不存在磷酸盐衣物洗涤剂粉末期间的衣物洗涤剂粉末化学品获得了普及。此时，沸石被用作磷酸盐助洗剂诸如三聚磷酸钠(STPP)的良好替代品，并且沸石在衣物洗涤粉末中的使用增加。沸石被认为是一种良好的洗涤剂助洗剂。然而，在过去十年中，衣物洗涤粉末制造商已经转向低成本衣物洗涤剂粉末，并且沸石在衣物洗涤粉末中的使用已显著降低。
代替将沸石重新引入喷雾干燥的粉末中，本发明人发现沸石可用作基质以在喷雾干燥过程期间原位形成二氧化硅。沸石转化为二氧化硅，并且所得喷雾干燥的衣物洗涤颗粒不仅适用于低pH衣物洗涤粉末，也适用于低成本衣物洗涤粉末。由于沸石在制造过程期间转化为二氧化硅，因此所得颗粒还具有低成本衣物洗涤剂粉末的分配、溶解和良好的织物残留性能特征。
该方法提供了一种生产喷雾干燥的颗粒的方法，该颗粒可用于配制低pH衣物洗涤粉末，其受益于二氧化硅的存在，诸如良好的物理特征，但没有与尝试按剂量的二氧化硅作为起始成分直接进入搅和机混合物中相关联的所有问题。此外，通过该方法生产的颗粒还具有良好的分配、溶解和良好的织物残留性能特征。
发明内容
本发明涉及一种用于制备喷雾干燥的衣物洗涤剂颗粒的方法，其中该方法包括使沸石与含水混合物中的单体有机羧酸接触的步骤，其中含水混合物具有4.2或更低的pH，其中含水混合物包含去污表面活性剂，其中含水混合物基本上不含硅酸盐，并且其中含水混合物基本上不含碳酸盐，其中沸石与单体有机羧酸反应以形成二氧化硅，其中含水混合物被喷雾干燥以形成喷雾干燥的衣物洗涤剂颗粒，其中颗粒包含：去污表面活性剂；单体有机羧酸；和二氧化硅，其中颗粒基本上不含硅酸盐，并且其中颗粒基本上不含碳酸盐。
具体实施方式
用于制备喷雾干燥的衣物洗涤剂颗粒的方法：用于制备喷雾干燥的衣物洗涤剂颗粒的方法包括使沸石与含水混合物中的单体有机羧酸接触的步骤，其中含水混合物具有4.2或更低的pH，其中含水混合物包含去污表面活性剂，其中含水混合物基本上不含硅酸盐，并且其中含水混合物基本上不含碳酸盐，其中沸石与单体有机羧酸反应以形成二氧化硅，其中含水混合物被喷雾干燥以形成喷雾干燥的衣物洗涤剂颗粒，其中颗粒包含：去污表面活性剂；单体有机羧酸；和二氧化硅，其中颗粒基本上不含硅酸盐，并且其中颗粒基本上不含碳酸盐。
下面更详细地描述形成含水混合物和喷雾干燥含水混合物的步骤。喷雾干燥过程可使用任何典型的喷雾干燥设备进行。通常，该设备包括混合器，通常被称为搅和机混合物。在第一混合器之后使用第二混合器或容器并不少见，其常见的示例是滴罐。通常，使用管道，通常与一个或多个泵组合以将含水混合物从混合器转移到喷嘴，其中随后将含水混合物通过喷嘴转移到喷雾干燥塔中。通常，使用第一低压泵，然后使用第二高压泵将含水混合物通过管道转移。
形成含水混合物：含水混合物通常通过接触去污表面活性剂、单体有机羧酸、沸石和水形成，当沸石与单体有机羧酸接触时，高度优选的是，存在去污表面活性剂。优选的加入顺序是使去污表面活性剂与水接触，然后接触单体羧酸，并且然后最终接触沸石。重要的是含水混合物的pH为4.2或更低，以便发生由沸石形成二氧化硅。由沸石形成二氧化硅是pH依赖性反应。对于沸石溶解并形成二氧化硅需要4.2或更低的pH。优选地，含水混合物的pH为3.5或更低。沸石与单体有机羧酸反应以形成二氧化硅。控制单体有机羧酸与沸石的重量比也是本发明的优选特征。
含水混合物基本上不含硅酸盐。含水混合物也基本上不含碳酸盐。所谓的基本上不含通常意味着没有有意加入的。在通过控制含水混合物的pH形成二氧化硅之后，根据洗涤剂配方设计师所需的洗涤液体的所需pH，将一些碱度引回入含水混合物中可能是有用的。然而，不使用本体碱性化学品，诸如碳酸盐和/或硅酸盐。在这方面，碱性试剂诸如NaOH特别有用。通常，可包含喷雾干燥的颗粒的全配方衣物洗涤剂粉末应当在20℃和在去离子水中以1g/L的浓度溶解时，具有在7.0至9.0，优选地7.5至9.0，或7.5至8.5范围内的pH。这被认为是低pH衣物洗涤剂粉末提供良好的织物护理有益效果，同时还提供良好的织物清洁性能的最佳pH。本发明的方法允许形成具有通常比最终洗涤液体的最佳pH低得多的低pH特征的喷雾干燥的颗粒。
通常，喷雾干燥的颗粒当在去离子水中以1g/L的浓度并且在20℃的温度下溶解时具有6.0或更低、或者甚至5.0或更低、或者4.2或更低、或者甚至3.5或更低的pH。当配制衣物洗涤剂粉末时仍然可使用该pH特征，因为喷雾干燥的颗粒可与其它成分组合以将洗涤液体的pH升高回到上述理想的pH范围(例如7.0至9.5)。例如，将过碳酸钠漂白剂作为干燥加入剂引入衣物洗涤粉末中以与喷雾干燥的基础颗粒组合使用是一种此类碱度来源。洗涤剂配方设计师在配制其所需的衣物洗涤剂粉末时可考虑所有这些pH效应。
喷雾干燥含水混合物：通常，含水混合物的喷雾干燥包括将含水混合物通过管道引入第一泵并且然后引入第二泵转移到多个喷嘴的步骤。第一泵通常是低压泵，诸如能够产生3×105Pa至1×106Pa的压力的泵。通常，第二泵是高压泵，诸如能够产生2×106Pa至1×107Pa的压力的泵。第一泵出口处的管道中的压力可小于1×106Pa。任选地，使含水洗涤剂浆液转移通过粉碎机，诸如由Hosakawa Micron供应的粉碎机。通常，粉碎机定位在泵之间。含水洗涤剂浆液沿管道的流量通常在800kg/小时至2,000kg/小时的范围内。
合适的喷嘴是喷雾系统T4C8喷嘴。优选地，含水洗涤剂浆液处于60℃至130℃的温度下。合适的喷雾干燥塔是顺流喷雾干燥塔或逆流喷雾干燥塔。优选地，喷雾干燥塔的入口空气温度在220℃至350℃的范围内。优选地，喷雾干燥塔的排气温度在60℃至100℃的范围内。喷雾干燥的粉末可进行冷却，例如空气提升。通常，对喷雾干燥的粉末进行粒度分级以去除过大的材料(>1.8mm)，以形成自由流动的喷雾干燥的粉末。细小的材料(<0.15mm)用喷雾干燥塔中的废气淘洗，然后收集在塔后的粉尘密封系统中。
含水混合物：含水混合物具有4.2或更低，优选地3.5或更低的pH。优选地，含水混合物中存在的单体有机羧酸与沸石的重量比为至少1.0，优选地至少1.2，或甚至至少1.2，并且最优选地至少1.6。具有过量的单体有机羧酸与沸石确保了二氧化硅形成的良好反应动力学并且还保持并使得能够对含水混合物进行良好的pH控制。
含水混合物，也可被称为搅和机混合物，也可含有适用于包含在喷雾干燥的衣物洗涤剂颗粒中的其它洗涤剂成分。合适的成分在下面更详细地描述，但包括聚合物、螯合剂、调色染料、增白剂、colouant和颜料。优选地，含水混合物包含羧酸盐聚合物。
在沸石与单体有机羧酸反应之后，含水混合物的优选的化学组成使得含水混合物包含：(a)20重量％至40重量％的水；(b)7.2重量％至24重量％的去污表面活性剂；(c)2.4重量％至8重量％的单体有机羧酸；(d)0.3重量％至2.4重量％的二氧化硅；(e)任选地，1.2重量％至8重量％的硫酸镁；(f)任选地，0.3重量％至4重量％的聚合物；以及(g)任选地，21重量％至64重量％的硫酸钠。
喷雾干燥的衣物洗涤剂颗粒：颗粒包含：去污表面活性剂；单体有机羧酸；和二氧化硅。颗粒基本上不含硅酸盐，并且颗粒基本上不含碳酸盐。在颗粒中可包含其它成分，这些成分在下面更详细地描述。优选地，颗粒包含：(a)12重量％至30重量％的去污表面活性剂；(b)4重量％至10重量％的单体有机羧酸；(c)0.5重量％至3重量％的二氧化硅；(d)任选地，2重量％至10重量％的硫酸镁；(e)任选地，0.5重量％至5重量％的聚合物；(f)任选地，35重量％至80重量％的硫酸钠；以及(g)任选地，0重量％至6重量％的水。
如上所述，颗粒当在去离子水中以10重量％的浓度并且在25℃的温度下溶解时可具有6.0或更低、或者5.0或更低、或者4.2或更低、或者3.5或更低的pH。颗粒可包含碱性试剂，优选的碱性试剂是NaOH。
颗粒可包含硫酸镁，优选地颗粒包含无定形形式的硫酸镁。
单体有机羧酸：单体有机羧酸优选地为单体有机多元羧酸，最优选地柠檬酸。其它合适的酸包括：
甲酸、乙酸、丙酸、丁酸、辛酸和月桂酸、硬脂酸、亚油酸和丙烯酸、甲基丙烯酸、氯乙酸和柠檬酸、乳酸、乙醛酸、乙酰乙酸、草酸、丙二酸、己二酸和苯乙酸、苯甲酸、水杨酸、甘氨酸和丙氨酸、缬氨酸、天冬氨酸、谷氨酸、赖氨酸和苯丙氨酸、烟酸、吡啶甲酸、富马酸、乳酸、苯甲酸、谷氨酸；琥珀酸、乙醇酸。优选地，有机酸选自柠檬酸、苹果酸、琥珀酸、乳酸、乙醇酸、富马酸、酒石酸和甲酸、以及它们的混合物。更优选地，酸为柠檬酸、乳酸和酒石酸。
沸石：合适的沸石包括4A型沸石，其通常具有1.0的硅与铝的比率。不受理论的束缚，本发明人认为该特定比率及其所得结构允许酸进入在一定pH下完全去离子化的铝分子。鉴于铝在硅分子之间分布良好，铝分子的完全去离子需要硅分子的分解，稍后形成为单硅酸，最终作为聚合二氧化硅沉淀。经历铝离子溶解的其它类型的沸石也是合适的，然而，硅分子可能仅经历部分溶解。铝离子的分解允许硅离子最终溶解。因此，铝与硅分子的相对位置可能是重要的，并且这由其比率决定。具有1.0至小于3.0、和1.0至1.6、或1.0至1.2的硅与铝的比率的沸石也是合适的。
去污表面活性剂：优选的去污表面活性剂为烷基苯磺酸盐。合适的去污表面活性剂包括阴离子去污表面活性剂、非离子去污表面活性剂、阳离子去污表面活性剂、两性离子去污表面活性剂和两性去污表面活性剂。合适的去污表面活性剂可为直链或支链、取代或未取代的，并且可衍生自石化材料或生物材料。
阴离子去污表面活性剂：合适的阴离子去污表面活性剂包括磺酸盐去污表面活性剂和硫酸盐去污表面活性剂。
合适的磺酸盐去污表面活性剂包括磺酸甲酯、α烯烃磺酸盐、烷基苯磺酸盐，尤其是烷基苯磺酸盐，优选地C10-13烷基苯磺酸盐。合适的烷基苯磺酸盐(LAS)是可获得的，优选地通过使可商购获得的直链烷基苯(LAB)磺化获得；合适的LAB包括低级2-苯基LAB，其它合适的LAB包括高级2-苯基LAB，诸如以商品名由Sasol供应的那些。
合适的硫酸盐去污表面活性剂包括烷基硫酸盐，优选地为C8-18烷基硫酸盐，或主要为C12烷基硫酸盐。
优选的硫酸盐去污表面活性剂为烷基烷氧基化硫酸盐，优选地烷基乙氧基化硫酸盐，优选地C8-18烷基烷氧基化硫酸盐，优选地C8-18烷基乙氧基化硫酸盐，优选地烷基烷氧基化硫酸盐具有0.5至20，优选地0.5至10的平均烷氧基化度，优选地烷基烷氧基化硫酸盐为C8-18烷基乙氧基化硫酸盐，其具有0.5至10，优选地0.5至5，更优选地0.5至3，并且最优选地0.5至1.5的平均乙氧基化度。
烷基硫酸盐、烷基烷氧基化硫酸盐和烷基苯磺酸盐可为直链或支链、取代或未取代的，并且可衍生自石化材料或生物材料。
其它合适的阴离子去污表面活性剂包括烷基醚羧酸盐。
合适的阴离子去污表面活性剂可为盐的形式，合适的抗衡离子包括钠、钙、镁、氨基醇、以及它们的任何组合。优选的抗衡离子为钠。
非离子去污表面活性剂：合适的非离子去污表面活性剂选自：C8-C18烷基乙氧基化物，诸如来自Shell的非离子表面活性剂；C6-C12烷基酚烷氧基化物，其中优选地烷氧基化物单元为乙烯氧基单元、丙烯氧基单元、或它们的混合物；C12-C18醇和C6-C12烷基酚与环氧乙烷/环氧丙烷嵌段聚合物的缩合物，诸如购自BASF的烷基多糖，优选地烷基多苷；甲酯乙氧基化物；多羟基脂肪酸酰胺；醚封端的聚(烷氧基化)醇表面活性剂；以及它们的混合物。
合适的非离子去污表面活性剂为烷基多葡萄糖苷和/或烷基烷氧基化醇。
合适的非离子去污表面活性剂包括烷基烷氧基化醇，优选地C8-18烷基烷氧基化醇，优选地C8-18烷基乙氧基化醇，优选地烷基烷氧基化醇具有1至50，优选地1至30，或1至20，或1至10的平均烷氧基化度，优选地烷基烷氧基化醇为C8-18烷基乙氧基化醇，其具有1至10，优选地1至7，更优选地1至5，并且最优选地3至7的平均乙氧基化度。烷基烷氧基化醇可为直链或支链、以及取代或未取代的。
合适的非离子去污表面活性剂包括基于仲醇的去污表面活性剂。
阳离子去污表面活性剂：合适的阳离子去污表面活性剂包括烷基吡啶鎓化合物、烷基季铵化合物、烷基季鏻化合物、烷基三元锍化合物、以及它们的混合物。
优选的阳离子去污表面活性剂为具有以下通式的季铵化合物：
(R)(R1)(R2)(R3)N+X-
其中，R为直链或支链、取代或未取代的C6-18烷基或烯基部分，R1和R2独立地选自甲基或乙基部分，R3为羟基、羟甲基或羟乙基部分，X为提供电中性的阴离子，优选的阴离子包括：卤离子，优选地氯离子；硫酸根；和磺酸根。
两性离子去污表面活性剂：合适的两性离子去污表面活性剂包括氧化胺和/或甜菜碱。
羧酸盐聚合物：合适的羧酸盐聚合物包括聚合物诸如马来酸酯/丙烯酸酯无规共聚物或聚丙烯酸酯均聚物。合适的羧酸盐聚合物包括：具有4,000Da至9,000Da的分子量的聚丙烯酸酯均聚物；具有30,000Da至100,000Da、或50,000Da至100,000Da、或60,000Da至80,000Da的分子量的马来酸酯/丙烯酸酯无规共聚物。
另一种合适的羧酸盐聚合物是共聚物，其包含：(i)50重量％至小于98重量％的衍生自一种或多种包含羧基基团的单体的结构单元；(ii)1重量％至小于49重量％的衍生自一种或多种包含磺酸根部分的单体的结构单元；以及(iii)1重量％至49重量％的衍生自一类或多类单体的结构单元，该单体选自由式(I)和(II)表示的含醚键的单体：
式(I)：
其中在式(I)中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0至5，前提条件是当R为单键时X表示数字1至5，并且R1为氢原子或C1至C20有机基团；
式(II)
其中在式(II)中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0至5，并且R1为氢原子或C1至C20有机基团。
可优选的是，聚合物具有至少30kDa、或至少50kDa、或甚至至少70kDa的重均分子量。
可通过本发明的方法获得的产品：可通过根据本发明的方法获得的产品由于其制造方法而具有不同的产品特征。产品具有良好的物理特性，诸如良好的饼强度和良好的流动性。产品还具有织物残留性能的良好的分配、溶解。这是由于与二氧化硅作为起始材料加入到搅和机混合物中相比，而原位形成二氧化硅。
自由流动的固体颗粒状衣物洗涤剂组合物：通常，通过本发明的方法制备的喷雾干燥的颗粒可与其它颗粒组合以形成自由流动的固体颗粒状衣物洗涤剂组合物，该自由流动的固体颗粒状衣物洗涤剂组合物是全配方衣物洗涤剂粉末组合物。通常，固体组合物包含多个化学上不同的颗粒，诸如喷雾干燥的基础洗涤剂颗粒与一个或多个附聚的洗涤剂颗粒和/或挤出的洗涤剂颗粒的组合。喷雾干燥的颗粒可与一个或多个、通常两个或更多个、或者五个或更多个、或者甚至十个或更多个颗粒组合使用，该颗粒选自：表面活性剂颗粒，包括表面活性剂附聚物、表面活性剂挤出物、表面活性剂针状物、表面活性剂面状物、表面活性剂片状物；磷酸盐颗粒；沸石颗粒；聚合物颗粒，诸如羧酸盐聚合物颗粒、纤维素聚合物颗粒、淀粉颗粒、聚酯颗粒、聚胺颗粒、对苯二甲酸聚合物颗粒、聚乙二醇颗粒；美观颗粒，诸如有色条粒、针状物、层状颗粒和环颗粒；酶颗粒，诸如蛋白酶颗粒、淀粉酶颗粒、脂肪酶颗粒、纤维素酶颗粒、甘露聚糖酶颗粒、果胶酸裂解酶颗粒、木葡聚糖酶颗粒、漂白酶颗粒和这些酶中的任一种的共颗粒，优选地这些酶颗粒包含硫酸钠；漂白剂颗粒，诸如过碳酸盐颗粒，尤其是涂覆的过碳酸盐颗粒，诸如涂覆有碳酸盐、硫酸盐、硅酸盐、硼硅酸盐、或它们的任何组合的过碳酸盐，过硼酸盐颗粒，漂白活化剂颗粒诸如四乙酰基乙二胺颗粒和/或烷基氧基苯磺酸盐颗粒，漂白催化剂颗粒诸如过渡金属催化剂颗粒，和/或异喹啉鎓漂白催化剂颗粒，预成形过酸颗粒，尤其是涂覆的预成形过酸颗粒；填料颗粒，诸如硫酸盐颗粒和氯化物颗粒；粘土颗粒，诸如蒙脱石颗粒和粘土与硅氧烷颗粒；絮凝剂颗粒，诸如聚环氧乙烷颗粒；蜡颗粒，诸如蜡质附聚物；硅氧烷颗粒，增白剂颗粒；染料转移抑制剂颗粒；染料固定剂颗粒；香料颗粒，诸如香料微胶囊和淀粉包封的香料谐香剂颗粒，以及前香料颗粒，诸如席夫碱反应产物颗粒；调色染料颗粒；螯合剂颗粒，诸如螯合剂附聚物；以及它们的任何组合。
组合物可包含：硅酸盐颗粒，尤其是硅酸钠颗粒；和/或碳酸盐颗粒，尤其是碳酸氢钠颗粒。然而，可优选的是，组合物不含硅酸盐颗粒，尤其是不含硅酸钠颗粒。也可优选的是，组合物不含碳酸盐颗粒，尤其是不含碳酸钠颗粒。
优选地，组合物包含1重量％至10重量％的干燥加入的酸性颗粒，优选地2重量％至8重量％的干燥加入的酸性颗粒。合适的干燥加入的酸是有机酸，优选地羧酸，优选地cirtric酸。
洗涤剂成分：合适的衣物洗涤剂组合物包含选自以下的洗涤剂成分：去污表面活性剂，诸如阴离子去污表面活性剂、非离子去污表面活性剂、阳离子去污表面活性剂、两性离子去污表面活性剂和两性去污表面活性剂；聚合物，诸如羧酸盐聚合物、去垢性聚合物、抗再沉积聚合物、纤维素聚合物和护理聚合物；漂白剂，诸如过氧化氢源、漂白活化剂、漂白催化剂和预形成的过酸；光漂白剂，诸如诸如磺化酞菁锌和/或磺化酞菁铝；酶，诸如蛋白酶、淀粉酶、纤维素酶、脂肪酶；沸石助洗剂；磷酸盐助洗剂；辅助助洗剂，诸如柠檬酸和柠檬酸盐；硫酸盐，诸如硫酸钠；氯化物盐，诸如氯化钠；增白剂；螯合剂；调色剂；染料转移抑制剂；染料固定剂；香料；硅氧烷；织物柔软剂，诸如粘土；絮凝剂，诸如聚环氧乙烷；抑泡剂；以及它们的任何组合。
组合物可包含：硅酸盐，尤其是硅酸钠；和/或碳酸盐，尤其是碳酸氢钠和/或碳酸钠。然而，可优选的是，组合物不含硅酸盐，尤其是不含硅酸钠。也可优选的是，组合物不含碳酸盐，尤其是不含碳酸钠和/或碳酸氢钠。
组合物可具有pH特征，使得在20℃的温度下在去离子水中以1g/L的浓度稀释时，组合物具有在7.0至9.0，优选地7.0至8.5，或甚至7.5至8.5范围内的pH。
合适的衣物洗涤剂组合物可具有低缓冲能力。此类衣物洗涤剂组合物通常具有小于5.0gNaOH/100g，优选地小于3.0gNaOH/100g的至pH 7.5的储备碱度。
组合物优选地基本上不含预形成的过酸。组合物优选地基本上不含邻苯二甲酰亚氨基-过氧己酸。基本上不含是指没有有意加入的。
去污表面活性剂：合适的去污表面活性剂如上所述。
聚合物：合适的聚合物包括羧酸盐聚合物、去垢性聚合物、抗再沉积聚合物、纤维素聚合物、护理聚合物、以及它们的任何组合。
羧酸盐聚合物：合适的羧酸盐聚合物如上所述。
去垢性聚合物：组合物可包含去垢性聚合物。合适的去垢性聚合物具有如由以下结构(I)、(II)或(III)中的一种定义的结构：
(I)-[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(II)-[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(III)-[(OCHR5-CHR6)c-OR7]f
其中：
a、b和c为1至200；
d、e和f为1至50；
Ar为1,4-取代的亚苯基；
sAr为在5位被SO3Me取代的1,3-取代的亚苯基；
Me为Li、K、Mg/2、Ca/2、Al/3、铵、单烷基铵、二烷基铵、三烷基铵或四烷基铵，其中烷基基团为C1-C18烷基或C2-C10羟烷基、或它们的混合物；
R1、R2、R3、R4、R5和R6独立地选自H或C1-C18正烷基或C1-C18异烷基；并且
R7为直链或支链的C1-C18烷基，或者直链或支链的C2-C30烯基，或者具有5至9个碳原子的环烷基基团，或者C8-C30芳基基团，或者C6-C30芳烷基基团。
合适的去垢性聚合物由Clariant以系列聚合物出售，例如SRN240和SRA300。其它合适的去垢性聚合物由Solvay以系列聚合物出售，例如SF2和Crystal。
抗再沉积聚合物：合适的抗再沉积聚合物包括聚乙二醇聚合物和/或聚乙烯亚胺聚合物。
合适的聚乙二醇聚合物包括无规接枝共聚物，该无规接枝共聚物包含：(i)包含聚乙二醇的亲水性主链；以及(ii)一条或多条疏水性侧链，该一条或多条疏水性侧链选自：C4-C25烷基基团、聚亚丙基、聚亚丁基、饱和C1-C6一元羧酸的乙烯基酯、丙烯酸或甲基丙烯酸的C1-C6烷基酯、以及它们的混合物。合适的聚乙二醇聚合物具有聚乙二醇主链，该聚乙二醇主链具有无规接枝的聚乙酸乙烯酯侧链。聚乙二醇主链的平均分子量可在2,000Da至20,000Da、或4,000Da至8,000Da的范围内。聚乙二醇主链与聚乙酸乙烯酯侧链的分子量比率可在1:1至1:5、或1:1.2至1:2的范围内。每个亚乙基氧单元的平均接枝位点数可小于1、或小于0.8，每个亚乙基氧单元的平均接枝位点数可在0.5至0.9的范围内，或者每个亚乙基氧单元的平均接枝位点数可在0.1至0.5、或0.2至0.4的范围内。合适的聚乙二醇聚合物为Sokalan HP22。合适的聚乙二醇聚合物描述于WO08/007320中。
纤维素聚合物：合适的纤维素聚合物选自烷基纤维素、烷基烷氧基烷基纤维素、羧基烷基纤维素、烷基羧基烷基纤维素、磺酸基烷基纤维素，更优选地选自羧甲基纤维素、甲基纤维素、甲基羟乙基纤维素、甲基羧甲基纤维素、以及它们的混合物。
合适的羧甲基纤维素具有0.5至0.9的羧甲基取代度和100,000Da至300,000Da的分子量。
合适的羧甲基纤维素具有大于0.65的取代度和大于0.45的嵌段度，例如，如描述于WO09/154933中的。
护理聚合物：合适的护理聚合物包括阳离子改性或疏水改性的纤维素聚合物。此类改性的纤维素聚合物在洗涤循环期间可向织物提供抗磨蚀有益效果和染料锁定有益效果。合适的纤维素聚合物包括阳离子改性的羟乙基纤维素。
其它合适的护理聚合物包括染料锁定聚合物，例如通过咪唑和表氯醇，优选地以1:4:1比率缩合产生的缩合低聚物。合适的可商购获得的染料锁定聚合物为FDI(Cognis)。
其它合适的护理聚合物包括氨基-硅氧烷，其可提供织物触感有益效果和织物成形保持有益效果。
漂白剂：合适的漂白剂包括过氧化氢源、漂白活化剂、漂白催化剂、预形成的过酸、以及它们的任何组合。尤其合适的漂白剂包括过氧化氢源与漂白活化剂和/或漂白催化剂的组合。
过氧化氢源：合适的过氧化氢源包括过硼酸钠和/或过碳酸钠。
漂白活化剂：合适的漂白活化剂包括四乙酰基乙二胺和/或烷基苯酚磺酸盐。
漂白催化剂：组合物可包含漂白催化剂。合适的漂白催化剂包括过氧亚胺正离子的漂白催化剂、过渡金属漂白催化剂，尤其是锰和铁漂白催化剂。合适的漂白催化剂具有符合以下通式的结构：
其中R13选自2-乙基己基、2-丙基庚基、2-丁基辛基、2-戊基壬基、2-己基癸基、正十二烷基、正十四烷基、正十六烷基、正十八烷基、异壬基、异癸基、异十三烷基和异十五烷基。
预形成的过酸：合适的预形成的过酸包括邻苯二甲酰亚氨基-过氧己酸。
酶：合适的酶包括脂肪酶、蛋白酶、纤维素酶、淀粉酶、以及它们的任何组合。
蛋白酶：合适的蛋白酶包括金属蛋白酶和丝氨酸蛋白酶。合适的中性或碱性蛋白酶的示例包括：枯草杆菌蛋白酶(EC 3.4.21.62)；胰蛋白酶型或胰凝乳蛋白酶型蛋白酶；和金属蛋白酶。合适的蛋白酶包括前述合适蛋白酶的经化学修饰或基因修饰的突变体。
合适的可商购获得的蛋白酶包括以商品名 LiquanaseSavinase 和由Novozymes A/S(Denmark)出售的那些；以商品名 Preferenz系列蛋白酶，包括P280、P281、P2018-C、P2081-WE、P2082-EE和P2083-A/J、PurafectPurafect和Purafect由DuPont出售的那些；以商品名和由SolvayEnzymes出售的那些；购自Henkel/Kemira的那些，即BLAP(序列示于US 5,352,604的图29中，具有以下突变：S99D+S101R+S103A+V104I+G159S，下文称为BLAP)；均来自Henkel/Kemira的BLAP R(具有S3T+V4I+V199M+V205I+L217D的BLAP)、BLAP X(具有S3T+V4I+V205I的BLAP)和BLAP F49(具有S3T+V4I+A194P+V199M+V205I+L217D的BLAP)；以及来自Kao的KAP(具有突变A230V+S256G+S259N的嗜碱芽孢杆菌枯草杆菌蛋白酶)。
合适的蛋白酶描述于WO11/140316和WO11/072117中。
淀粉酶：合适的淀粉酶衍生自内源于芽孢杆菌属(Bacillus sp.)DSM12649的AA560α淀粉酶，优选地具有以下突变：R118K、D183*、G184*、N195F、R320K和/或R458K。合适的可商购获得的淀粉酶包括 Plus、Natalase、Ultra、SZ、(均得自Novozymes)和AA、Preferenz系列淀粉酶、和Ox Am、HT Plus(均得自Du Pont)。
合适的淀粉酶描述于WO06/002643中。
纤维素酶：合适的纤维素酶包括细菌或真菌来源的那些。化学改性的或蛋白质工程化的突变型也是合适的。合适的纤维素酶包括来自芽孢杆菌属、假单胞菌属(Pseudomonas)、腐质霉属(Humicola)、镰孢属(Fusarium)、草根霉属(Thielavia)、枝顶孢霉属(Acremonium)的纤维素酶，例如由特异腐质霉(Humicola insolens)、嗜热毁丝菌(Myceliophthora thermophila)和尖孢镰孢菌(Fusarium oxysporum)产生的真菌纤维素酶。
可商购获得的纤维素酶包括和Premium、和(Novozymes A/S)、系列酶(DuPont)、以及系列酶(AB Enzymes)。合适的可商购获得的纤维素酶包括Premium、Classic。合适的蛋白酶描述于WO07/144857和WO10/056652中。
脂肪酶：合适的脂肪酶包括细菌、真菌或合成来源、以及它们的变体的那些。化学改性的或蛋白质工程化的突变型也是合适的。合适的脂肪酶的示例包括来自腐质霉属(同义词嗜热霉属(Thermomyces))，例如来自柔毛腐质霉(H.lanuginosa)(疏棉状嗜热丝孢菌(T.lanuginosus))的脂肪酶。
脂肪酶可为“第一循环脂肪酶”，例如，诸如描述于WO06/090335和WO13/116261中的那些。在一个方面，脂肪酶为第一洗涤脂肪酶，优选地为来自包含T231R和/或N233R突变的疏棉状嗜热丝孢菌的野生型脂肪酶的变体。优选的脂肪酶包括以商品名和由Novozymes(Bagsvaerd，Denmark)出售的那些。
其它合适的脂肪酶包括：Lipr1 139，例如如描述于WO2013/171241中的；和TfuLip2，例如如描述于WO2011/084412和WO2013/033318中的。
其它酶：其它合适的酶是漂白酶，诸如过氧化物酶/氧化酶，其包括植物、细菌或真菌来源、以及它们的变体的那些。可商购获得的过氧化物酶包括(NovozymesA/S)。其它合适的酶包括胆碱氧化酶和过水解酶，诸如，用于Gentle Power BleachTM中的那些。
其它合适的酶包括以商品名(来自Novozymes A/S，Bagsvaerd，Denmark)和(DuPont)出售的果胶酸裂解酶和以商品名(Novozymes A/S，Bagsvaerd，Denmark)和(Du Pont)出售的甘露聚糖酶。
沸石助洗剂：组合物可包含沸石助洗剂。组合物可包含0重量％至5重量％的沸石助洗剂，或3重量％的沸石助洗剂。组合物可甚至基本上不含沸石助洗剂；基本上不含是指“没有有意加入的”。典型的沸石助洗剂包括沸石A、沸石P和沸石MAP。
磷酸盐助洗剂：组合物可包含磷酸盐助洗剂。组合物可包含0重量％至5重量％的磷酸盐助洗剂，或至3重量％的磷酸盐助洗剂。组合物可甚至基本上不含磷酸盐助洗剂；基本上不含是指“没有有意加入的”。典型的磷酸盐助洗剂为三聚磷酸钠。
碳酸盐：组合物可包含碳酸盐。组合物可包含0重量％至5重量％的碳酸盐。组合物可甚至基本上不含碳酸盐；基本上不含是指“没有有意加入的”。合适的碳酸盐包括碳酸钠和碳酸氢钠。
硅酸盐：组合物可包含硅酸盐。组合物可包含0重量％至5重量％的硅酸盐。组合物可甚至基本上不含硅酸盐；基本上不含是指“没有有意加入的”。优选的硅酸盐为硅酸钠，尤其优选的是具有1.0至2.8，优选地1.6至2.0的Na2O:SiO2比率的硅酸钠。
硫酸盐：合适的硫酸盐为硫酸钠。
增白剂：合适的荧光增白剂包括：二苯乙烯基联苯化合物，例如CBS-X，二氨基二苯乙烯二磺酸化合物，例如DMS pure Xtra和HRH，以及吡唑啉化合物，例如SN和香豆素化合物，例如SWN。
优选的增白剂为：2(4-苯乙烯基-3-磺苯基)-2H-萘酚[1,2-d]三唑钠、4,4'-双{[(4-苯胺基-6-(N甲基-N-2-羟乙基)氨基1,3,5-三嗪-2-基)]氨基}二苯乙烯-2-2'二磺酸二钠、4,4'-双{[(4-苯胺基-6-吗啉代-1,3,5-三嗪-2-基)]氨基}二苯乙烯-2-2'二磺酸二钠、和4,4'-双(2-磺基苯乙烯基)联苯二钠。合适的荧光增白剂为C.I.荧光增白剂260，该增白剂可以其β或α晶形或这些晶形的混合物形式使用。
螯合剂：组合物还可包含螯合剂，该螯合剂选自：二亚乙基三胺五乙酸盐、二亚乙基三胺五(甲基膦酸)、乙二胺-N’N’-二琥珀酸、乙二胺四乙酸盐、乙二胺四(亚甲基膦酸)、和羟乙烷二(亚甲基膦酸)。优选的螯合剂是乙二胺-N’N’-二琥珀酸(EDDS)和/或羟基乙烷二膦酸(HEDP)。组合物优选地包含乙二胺-N’N’-二琥珀酸或其盐。优选地乙二胺-N’N’-二琥珀酸为S,S对映体形式。优选地，组合物包含4,5-二羟基-间苯二磺酸二钠盐。优选的螯合剂也可充当碳酸钙晶体生长抑制剂，诸如：1-羟基乙烷二磷酸(HEDP)及其盐；N,N-二羧甲基-2-氨基戊烷-1,5-二酸及其盐；2-膦酰基丁烷-1,2,4-三羧酸及其盐；以及它们的组合。
调色剂：合适的调色剂包括小分子染料，通常属于酸性、直接、碱性、活性(包括它们水解的形式)或溶剂或分散染料的颜色索引(C.I.)分类，例如被分类为蓝、紫、红、绿或黑的染料，并且单独地或组合地提供期望色调。优选的此类调色剂包括酸性紫50，直接紫9、66和99，溶剂紫13，以及它们的任何组合。
可适用于本发明的许多调色剂是已知的并且描述于本领域中，诸如描述于WO2014/089386中的调色剂。
合适的调色剂包括酞菁和偶氮染料缀合物，诸如描述于WO2009/069077中的。
合适的调色剂可为烷氧基化的。此类烷氧基化化合物可通过有机合成制备，这可产生具有不同烷氧基化度的分子的混合物。此类混合物可直接用于提供调色剂，或可经历纯化步骤，以增加目标分子的比例。合适的调色剂包括烷氧基化的双偶氮染料，诸如描述于WO2012/054835中的，和/或烷氧基化的噻吩偶氮染料，诸如描述于WO2008/087497和WO2012/166768中的。
调色剂可作为反应混合物的一部分被掺入洗涤剂组合物中，该反应混合物是通过一个或多个任选纯化步骤有机合成染料分子的结果。此类反应混合物一般包含染料分子自身，并且此外还可包含未反应的起始材料和/或有机合成途径的副产物。合适的调色剂可被掺入调色染料颗粒中，诸如描述于WO 2009/069077中的。
染料转移抑制剂：合适的染料转移抑制剂包括聚胺N-氧化物聚合物、N-乙烯基吡咯烷酮和N-乙烯基咪唑的共聚物、聚乙烯基吡咯烷酮、聚乙烯基噁唑烷酮、聚乙烯基咪唑、以及它们的混合物。优选的是聚(乙烯基吡咯烷酮)、聚(乙烯基吡啶甜菜碱)、聚(乙烯基吡啶N-氧化物)、聚(乙烯基吡咯烷酮-乙烯基咪唑)、以及它们的混合物。合适的可商购获得的染料转移抑制剂包括PVP-K15和K30(Ashland)，HP165、HP50、HP53、HP59、HP56K、HP56、HP66(BASF)，S-400、S403E和S-100(Ashland)。
香料：合适的香料包括选自以下的香料材料：(a)具有小于3.0的ClogP和小于250℃沸点的香料材料(第1象限香料材料)；(b)具有小于3.0的ClogP和250℃或更大沸点的香料材料(第2象限香料材料)；(c)具有3.0或更大的ClogP和小于250℃沸点的香料材料(第3象限香料材料)；和(d)具有3.0或更大的ClogP和250℃或更大沸点的香料材料(第4象限香料材料)；以及(e)它们的混合物。
对于香料可优选的是为香料递送技术的形式。此类递送技术还稳定并且增强沉积和香料材料从洗涤过的织物上的释放。此类香料递送技术也可用于进一步增加从洗涤过的织物上释放香料的持久性。合适的香料递送技术包括：香料微胶囊、前香料、聚合物辅助递送、分子辅助递送、纤维辅助递送、胺辅助递送、环糊精、淀粉包封的谐香剂、沸石和其它无机载体、以及它们的任何混合物。合适的香料微胶囊描述于WO2009/101593中。
硅氧烷：合适的硅氧烷包括聚二甲基硅氧烷和氨基-硅氧烷。合适的硅氧烷描述于WO05075616中。
实施例
制备喷雾干燥的颗粒组合物的方法-浆液pH对加工和粉末质量的影响：
通过首先将水加入到浆液制造容器(搅和机)中来制备含水洗涤剂浆液A。然后将搅和机设定成充分搅拌，同时使用以下加入顺序依次加入其余成分：
1.LAS糊状物
2.柠檬酸
3.丙烯酸-马来酸聚合物盐
4. 4A型铝硅酸盐助洗剂
5.硫酸镁
6.硫酸钠
将具有9至11.5的pH的LAS糊状物加入到在搅和机中充分搅拌的水中。接着加入柠檬酸，然后加入聚合物，然后加入沸石。将沸石加入到酸性混合物中，确保其适当分散以使其能够溶解。此时所得混合物必须具有小于4.2的pH。在这种酸性环境中，将沸石脱铝，然后硅分解，随后最终沉淀为无定形二氧化硅。将浆液混合直至实现所有成分的充分分散，其中最终pH为3.5，在25C下使用去离子水以10％溶液测量。通过使用直接蒸汽注入(压力为6.0x105Pa的饱和蒸汽)至搅和机，实现最终85℃的批料浆液温度。在将浆液混合物泵送并雾化至喷雾干燥塔之前，将浆液混合物转移至较大的混合容器中。
通过首先在充分搅拌的搅和机中将苛性碱溶液加入到水中来制备含水洗涤剂浆液B。按照制备含水洗涤剂浆液A中使用的相同加入顺序加入其余材料。在该混合物中，浆液pH在整个混合过程中显著高于浆液A，以确保沸石保持其结晶形式。
将雾化的浆液干燥，冷却并过筛以去除过大的材料(>1.8mm)以形成喷雾干燥的粉末。细小的材料(<0.15mm)用喷雾干燥塔中的废的废气淘析，然后收集在塔后的密封系统中。将喷雾干燥的粉末干燥至含水量为2重量％。
喷雾干燥的粉末：
然后根据下述方法测量喷雾干燥的粉末的pH和饼强度。比较例B中的饼强度具有不可接受的高饼强度。代表本发明的一种实例A具有可接受的低饼强度。
用于测量饼强度的方法：
将内径6.35cm且长15.9cm的光滑塑性圆筒承载在合适的基板上。在圆筒上钻通0.65cm的孔，孔中央距基板相对端9.2cm。
将金属芯棒穿过所述孔，并将内径6.35cm且长15.25cm的光滑塑性套筒围绕内圆筒定位，使得套筒可自由上下移动圆筒并且支撑在金属芯棒上。接着向套筒的内部空间填充(不轻拍或过度振动)喷雾干燥的粉末，使得喷雾干燥的粉末与套筒顶部齐平。将封盖定位在套筒顶部上并且在封盖上定位5kg砝码。接着抽出芯棒，并且允许喷雾干燥的粉末压实2分钟。2分钟之后移除砝码，将套筒降低以露出粉饼，封盖保留在粉末顶部。
然后以54cm/min的速率降下金属探针，使得它接触封盖中央并且使饼破碎。记录破碎饼所需的最大力，并且它是测试结果。0N的饼强度表示无饼形成。
本文所公开的量纲和值不应理解为严格限于所引用的精确数值。相反，除非另外指明，否则每个此类量纲旨在表示所述值以及围绕该值功能上等同的范围。例如，公开为“40mm”的量纲旨在表示“约40mm”。
Claims (14)
1.一种用于制备喷雾干燥的衣物洗涤剂颗粒的方法，
其中所述方法包括在含水混合物中使沸石与单体有机羧酸接触的步骤，
其中所述含水混合物具有4.2或更低的pH，
其中所述含水混合物包含去污表面活性剂，其中所述含水混合物基本上不含硅酸盐，并且其中所述含水混合物基本上不含碳酸盐，
其中所述沸石与所述单体有机羧酸反应以形成二氧化硅，
其中所述含水混合物被喷雾干燥以形成喷雾干燥的衣物洗涤剂颗粒，
其中所述颗粒包含：去污表面活性剂；单体有机羧酸；和二氧化硅，
其中所述颗粒基本上不含硅酸盐，并且其中所述颗粒基本上不含碳酸盐。
2.根据权利要求1所述的方法，其中所述含水混合物具有3.5或更低的pH。
3.根据前述权利要求中任一项所述的方法，其中所述颗粒当在去离子水中以10重量％的浓度并且在25℃的温度下溶解时具有6.0或更低的pH。
4.根据前述权利要求中任一项所述的方法，其中所述颗粒当在去离子水中以10重量％的浓度并且在25℃的温度下溶解时具有4.2或更低的pH。
5.根据前述权利要求中任一项所述的方法，其中所述颗粒当在去离子水中以10重量％的浓度并且在20℃的温度下溶解时具有3.5或更低的pH。
6.根据前述权利要求中任一项所述的方法，其中所述单体有机羧酸为单体有机多元羧酸。
7.根据权利要求6所述的方法，其中所述单体有机多元羧酸为柠檬酸。
8.根据前述权利要求中任一项所述的方法，其中所述去污表面活性剂为烷基苯磺酸盐。
9.根据前述权利要求中任一项所述的方法，其中所述含水混合物中存在的单体有机羧酸与沸石的重量比为至少1.6。
10.根据前述权利要求中任一项所述的方法，其中所述含水混合物包含硫酸镁，并且其中所述颗粒包含无定形形式的硫酸镁。
11.根据前述权利要求中任一项所述的方法，其中所述含水混合物包含羧酸盐聚合物，并且其中所述颗粒包含羧酸盐聚合物。
12.根据前述权利要求中任一项所述的方法，其中所述颗粒包含：
(a)12重量％至30重量％的去污表面活性剂；
(b)4重量％至10重量％的单体有机羧酸；
(c)0.5重量％至3重量％的二氧化硅；
(d)任选地，2重量％至10重量％的硫酸镁；
(e)任选地，0.5重量％至5重量％的聚合物；
(f)任选地，35重量％至80重量％的硫酸钠；以及
(g)任选地，0重量％至6重量％的水。
13.根据前述权利要求中任一项所述的方法，其中在所述沸石与所述单体有机羧酸反应之后，所述含水混合物包含：
(a)20重量％至40重量％的水；
(b)7.2重量％至24重量％的去污表面活性剂；
(c)2.4重量％至8重量％的单体有机羧酸；
(d)0.3重量％至2.4重量％的二氧化硅；
(e)任选地，1.2重量％至8重量％的硫酸镁；
(f)任选地，0.3重量％至4重量％的聚合物；以及
(g)任选地，21重量％至64重量％的硫酸钠。
14.一种产品，所述产品能够通过根据前述权利要求中任一项所述的方法获得。
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| EP17177087.8A EP3301153B1 (en) | 2016-10-03 | 2017-06-21 | Process for preparing a spray-dried laundry detergent particle |
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| CN201780058644.8A Pending CN109790488A (zh) | 2016-10-03 | 2017-10-03 | 低ph衣物洗涤剂组合物 |
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| Country | Link |
|---|---|
| US (3) | US10676703B2 (zh) |
| EP (3) | EP3301152B1 (zh) |
| CN (3) | CN109790489B (zh) |
| ES (2) | ES2758226T3 (zh) |
| HU (1) | HUE046263T2 (zh) |
| MX (3) | MX2019003842A (zh) |
| PL (2) | PL3301153T3 (zh) |
| RU (1) | RU2716255C1 (zh) |
| WO (3) | WO2018067493A1 (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3344741B1 (en) * | 2015-08-31 | 2019-10-30 | Diversey, Inc. | Method and composition for stable liquid tetraacetylethylenediamine composition |
| EP3415601A1 (en) | 2017-06-15 | 2018-12-19 | The Procter & Gamble Company | Water-soluble unit dose article comprising a solid laundry detergent composition |
| EP3415606A1 (en) | 2017-06-15 | 2018-12-19 | The Procter & Gamble Company | Water-soluble unit dose article comprising a solid laundry detergent composition |
| US10550357B2 (en) | 2017-06-15 | 2020-02-04 | The Procter & Gamble Company | Water-soluble unit dose article comprising a solid laundry detergent composition |
| US11214761B2 (en) * | 2019-12-31 | 2022-01-04 | Henkel IP & Holding GmbH | Solid perfume composition delivering fabric care |
| WO2022243283A1 (en) | 2021-05-19 | 2022-11-24 | Unilever Ip Holdings B.V. | Process for preparing a spray dried detergent particle |
| CN117242164A (zh) | 2021-05-19 | 2023-12-15 | 联合利华知识产权控股有限公司 | 制备喷雾干燥的洗涤剂颗粒的方法 |
| CN117940542A (zh) | 2021-09-15 | 2024-04-26 | 联合利华知识产权控股有限公司 | 制备喷雾干燥的洗涤剂颗粒的方法 |
| WO2024022962A1 (en) * | 2022-07-29 | 2024-02-01 | Unilever Ip Holdings B.V. | Laundry detergent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2106482A (en) * | 1981-09-28 | 1983-04-13 | Colgate Palmolive Co | Method for retarding gelation of bicarbonate-carbonate-zeolite- silicate crutcher slurries |
| EP0520582A1 (en) * | 1991-06-28 | 1992-12-30 | Colgate-Palmolive Company | Zeolite based spray-dried detergent compositions and process for preparing same |
| CN102858933A (zh) * | 2010-04-19 | 2013-01-02 | 宝洁公司 | 洗涤剂组合物 |
Family Cites Families (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4405483A (en) * | 1982-04-27 | 1983-09-20 | The Procter & Gamble Company | Stable liquid detergents containing aluminosilicate ion exchange material |
| EP0137669B1 (en) * | 1983-08-27 | 1988-07-06 | The Procter & Gamble Company | Detergent compositions |
| DE3444960A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Koerniges adsorptionsmittel |
| CA1286563C (en) * | 1986-04-04 | 1991-07-23 | Jan Hendrik Eertink | Detergent powders and processes for preparing them |
| ATE187490T1 (de) | 1989-08-25 | 1999-12-15 | Henkel Research Corp | Alkalisches proteolytisches enzym und verfahren zur herstellung |
| EP0456315B1 (en) * | 1990-05-08 | 1996-08-21 | The Procter & Gamble Company | Low pH granular laundry detergent compositions containing aluminosilicate citric acid and carbonate builders |
| US5268283A (en) * | 1990-10-05 | 1993-12-07 | Miles Inc. | Method for the production of detergent builder formulations utilizing spray granulated citric acid and salts thereof |
| EP0651053A1 (en) * | 1993-11-03 | 1995-05-03 | The Procter & Gamble Company | Laundry detergent compositions |
| EP0781836A1 (en) | 1995-12-29 | 1997-07-02 | Colgate-Palmolive Company | Detergent composition having improved cleaning power in neutral or acidic medium |
| US5972869A (en) | 1996-12-17 | 1999-10-26 | Colgate-Palmolive Co | Mildly acidic laundry detergent composition providing improved protection of fine fabrics during washing and enhanced rinsing in hand wash |
| US6162259A (en) | 1997-03-25 | 2000-12-19 | The Procter & Gamble Company | Machine dishwashing and laundry compositions |
| CA2344997C (en) | 1998-09-25 | 2003-11-11 | The Procter & Gamble Company | Detergent granules |
| MXPA03002120A (es) | 2000-09-11 | 2003-06-19 | Procter & Gamble | Articulos de lavanderia y metodos para la combinacion de limpieza y cuidado de telas. |
| DE10153551A1 (de) * | 2001-10-30 | 2003-05-22 | Henkel Kgaa | Im wesentlichen sedimentfrei dispergierbares Wasch- oder Reinigungsmittel |
| EP2022841B1 (en) | 2004-02-03 | 2013-04-03 | The Procter and Gamble Company | A composition for use in the laundering or treatment of fabrics |
| EP1566432A1 (en) * | 2004-02-23 | 2005-08-24 | The Procter & Gamble Company | Laundry detergent composition comprising an anionic detersive surfactant sulphamic acid and/or water soluble salts thereof |
| US20050197275A1 (en) | 2004-03-03 | 2005-09-08 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Solid laundry detergents with polyanionic ammonium surfactant |
| WO2006002643A2 (en) | 2004-07-05 | 2006-01-12 | Novozymes A/S | Alpha-amylase variants with altered properties |
| US7720943B2 (en) * | 2004-07-26 | 2010-05-18 | Centillium Communications, Inc. | Communication device for obtaining an application image or configuration from a service provider |
| JP4932713B2 (ja) * | 2004-08-11 | 2012-05-16 | ザ プロクター アンド ギャンブル カンパニー | 水に溶解すると透明な洗浄溶液を形成する、非常に水溶性の固体洗濯洗剤組成物 |
| EP1693440A1 (en) | 2005-02-22 | 2006-08-23 | The Procter & Gamble Company | Detergent compositions |
| WO2007057859A2 (en) | 2005-11-18 | 2007-05-24 | The Procter & Gamble Company | Fabric care article |
| EP1867707B1 (en) | 2006-06-16 | 2011-09-07 | The Procter & Gamble Company | Detergent compositions |
| ATE502998T1 (de) | 2006-07-07 | 2011-04-15 | Procter & Gamble | Waschmittelzusammensetzungen |
| ES2314833T3 (es) * | 2006-07-27 | 2009-03-16 | Evonik Degussa Gmbh | Particulas envueltas de percarbonato de sodio. |
| EP2104729B1 (en) | 2007-01-19 | 2010-11-03 | The Procter & Gamble Company | Laundry care composition comprising a whitening agent for cellulosic substrates |
| WO2009069077A2 (en) | 2007-11-26 | 2009-06-04 | The Procter & Gamble Company | Detergent compositions |
| CN101910393A (zh) * | 2008-01-04 | 2010-12-08 | 宝洁公司 | 包含糖基水解酶的衣物洗涤剂组合物 |
| PL2247275T3 (pl) | 2008-02-15 | 2018-05-30 | The Procter And Gamble Company | Cząstka przenosząca |
| GB0805908D0 (en) * | 2008-04-01 | 2008-05-07 | Reckitt Benckiser Inc | Laundry treatment compositions |
| ATE550415T1 (de) | 2008-06-20 | 2012-04-15 | Procter & Gamble | Waschzusammensetzung |
| EP2138565A1 (en) | 2008-06-25 | 2009-12-30 | The Procter and Gamble Company | A spray-drying process |
| EP2138567A1 (en) | 2008-06-25 | 2009-12-30 | The Procter & Gamble Company | Spray-drying process |
| ES2398026T3 (es) | 2008-07-03 | 2013-03-13 | Henkel Ag & Co. Kgaa | Composición sólida conteniendo un polisacárido, para el cuidado de textiles |
| EP2166077A1 (en) | 2008-09-12 | 2010-03-24 | The Procter and Gamble Company | Particles comprising a hueing dye |
| CN102216439A (zh) | 2008-11-14 | 2011-10-12 | 宝洁公司 | 包含聚合物和酶的组合物 |
| EP2510092A1 (en) | 2009-12-09 | 2012-10-17 | The Procter & Gamble Company | Fabric and home care products |
| JP2013515139A (ja) | 2009-12-21 | 2013-05-02 | ダニスコ・ユーエス・インク | サーモビフィダ・フスカのリパーゼを含む洗剤組成物、及びその使用方法 |
| EP2357220A1 (en) | 2010-02-10 | 2011-08-17 | The Procter & Gamble Company | Cleaning composition comprising amylase variants with high stability in the presence of a chelating agent |
| EP2363455A1 (en) | 2010-03-01 | 2011-09-07 | The Procter & Gamble Company | Composition comprising co-bleach particle and amylase |
| EP2380957A1 (en) | 2010-04-19 | 2011-10-26 | The Procter & Gamble Company | Solid laundry detergent composition having a dynamic in-wash ph profile |
| EP2377914B1 (en) | 2010-04-19 | 2016-11-09 | The Procter & Gamble Company | Mildly alkaline, low-built, solid fabric treatment detergent composition comprising perhydrolase |
| EP3279319B1 (en) * | 2010-04-26 | 2020-06-10 | Novozymes A/S | Enzyme granules |
| CA2798451C (en) | 2010-05-06 | 2020-10-06 | Danisco Us Inc. | Compositions and methods comprising subtilisin variants with t022a-e271f substitutions |
| US20120101018A1 (en) | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
| CA2817718C (en) | 2010-11-12 | 2016-02-09 | The Procter & Gamble Company | Laundry care compositions comprising charged thiophene azo dyes |
| EP2502980A1 (en) | 2011-03-25 | 2012-09-26 | The Procter & Gamble Company | Spray-dried laundry detergent particles |
| MX2013014021A (es) | 2011-06-03 | 2014-01-23 | Procter & Gamble | Composiciones que comtienen colorantes par el cuidado en el lavado de ropa. |
| AR087745A1 (es) | 2011-08-31 | 2014-04-16 | Danisco Us Inc | Composiciones y metodos que comprenden una variante de enzima lipolitica |
| CN103946360A (zh) * | 2011-09-06 | 2014-07-23 | 太阳产品公司 | 固体和液体纺织品处理组合物 |
| US20130072416A1 (en) | 2011-09-20 | 2013-03-21 | The Procter & Gamble Company | High suds detergent compositions comprising isoprenoid-based surfactants |
| CN104080902B (zh) | 2012-02-03 | 2018-08-03 | 宝洁公司 | 具有脂肪酶的用于表面处理的组合物和方法 |
| MX2014013727A (es) | 2012-05-16 | 2015-02-10 | Novozymes As | Composiciones que comprenden lipasa y metodos de utilizacion de estas. |
| PL2669001T3 (pl) | 2012-06-01 | 2015-06-30 | Procter & Gamble | Proces suszenia rozpyłowego |
| CN104769094B (zh) * | 2012-06-08 | 2018-03-09 | 宝洁公司 | 尤其可与粉末或颗粒组合物组合使用的具有提高的水溶解度的视觉反差美观颗粒 |
| MX2015006935A (es) | 2012-12-06 | 2015-09-21 | Procter & Gamble | Bolsa soluble que comprende un tinte tonalizador. |
| EP2801606A1 (en) * | 2013-05-07 | 2014-11-12 | The Procter and Gamble Company | Spray-dried particle comprising sulphate |
| EP3004307A1 (en) * | 2013-05-24 | 2016-04-13 | The Procter & Gamble Company | Low ph detergent composition comprising nonionic surfactants |
| CN105745316B (zh) * | 2013-12-27 | 2018-09-11 | 花王株式会社 | 粉末清洁剂组合物 |
| KR20170003922A (ko) * | 2014-05-09 | 2017-01-10 | 바스프 에스이 | 세탁용 세제에서 사용하기 위한 2-층 코팅을 갖는 아실히드라존 과립물 |
| US20160168780A1 (en) | 2014-12-16 | 2016-06-16 | Washing Systems, Llc | Process to produce hygienically clean textile |
| ES2661440T5 (es) | 2015-02-05 | 2021-09-23 | Dalli Werke Gmbh & Co Kg | Composición de limpieza que comprende un catalizador de blanqueo y carboximetilcelulosa |
-
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- 2017-06-21 EP EP17177087.8A patent/EP3301153B1/en active Active
- 2017-06-21 ES ES17177079T patent/ES2915331T3/es active Active
- 2017-06-21 EP EP17177076.1A patent/EP3301151A1/en active Pending
- 2017-10-03 RU RU2019107496A patent/RU2716255C1/ru active
- 2017-10-03 CN CN201780060995.2A patent/CN109790489B/zh active Active
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- 2017-10-03 MX MX2019003846A patent/MX2019003846A/es unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2106482A (en) * | 1981-09-28 | 1983-04-13 | Colgate Palmolive Co | Method for retarding gelation of bicarbonate-carbonate-zeolite- silicate crutcher slurries |
| EP0520582A1 (en) * | 1991-06-28 | 1992-12-30 | Colgate-Palmolive Company | Zeolite based spray-dried detergent compositions and process for preparing same |
| CN102858933A (zh) * | 2010-04-19 | 2013-01-02 | 宝洁公司 | 洗涤剂组合物 |
Also Published As
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| EP3301152B1 (en) | 2022-05-04 |
| WO2018067494A1 (en) | 2018-04-12 |
| US20180094227A1 (en) | 2018-04-05 |
| EP3301153A1 (en) | 2018-04-04 |
| WO2018067493A1 (en) | 2018-04-12 |
| PL3301152T3 (pl) | 2022-06-13 |
| US10676703B2 (en) | 2020-06-09 |
| CN109790488A (zh) | 2019-05-21 |
| EP3301152A1 (en) | 2018-04-04 |
| ES2915331T3 (es) | 2022-06-21 |
| MX2019003842A (es) | 2019-06-24 |
| MX2019003847A (es) | 2019-06-24 |
| US20180094225A1 (en) | 2018-04-05 |
| US20180094210A1 (en) | 2018-04-05 |
| MX2019003846A (es) | 2019-06-24 |
| CN109715773A (zh) | 2019-05-03 |
| CN109715773B (zh) | 2021-12-24 |
| RU2716255C1 (ru) | 2020-03-11 |
| EP3301153B1 (en) | 2019-09-11 |
| ES2758226T3 (es) | 2020-05-04 |
| WO2018067489A1 (en) | 2018-04-12 |
| EP3301151A1 (en) | 2018-04-04 |
| CN109790489B (zh) | 2021-06-01 |
| PL3301153T3 (pl) | 2020-03-31 |
| HUE046263T2 (hu) | 2020-02-28 |
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