CN109651617A - 一种聚醚改性有机硅、消泡剂组合物及其应用 - Google Patents
一种聚醚改性有机硅、消泡剂组合物及其应用 Download PDFInfo
- Publication number
- CN109651617A CN109651617A CN201811509888.6A CN201811509888A CN109651617A CN 109651617 A CN109651617 A CN 109651617A CN 201811509888 A CN201811509888 A CN 201811509888A CN 109651617 A CN109651617 A CN 109651617A
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- Prior art keywords
- polyether
- organic silicon
- modified
- integer
- silicon modified
- Prior art date
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- 150000003233 pyrroles Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyethers (AREA)
- Paints Or Removers (AREA)
- Silicon Polymers (AREA)
Abstract
Description
使用的有机硅产物 | 使用的表面活性剂 | |
实施例1 | A | 二乙二醇单油酸酯 |
实施例2 | B | 失水山梨醇月桂酸酯 |
实施例3 | C | 失水山梨醇月桂酸酯 |
实施例4 | D | 二乙二醇单油酸酯 |
实施例5 | E | 聚氧乙烯单硬脂酸酯 |
实施例6 | F | 聚氧乙烯单硬脂酸酯 |
对比例1 | G | 聚氧乙烯单硬脂酸酯 |
对比例2 | PDMS(100cst) | 聚氧乙烯单硬脂酸酯 |
XP2651体系 | 抑泡 | 消泡 | 流平 | 缩孔 |
实施例1 | 2 | 2 | 1 | 无 |
实施例2 | 2 | 3 | 1- | 无 |
实施例3 | 3 | 3 | 1- | 无 |
实施例4 | 2 | 1 | 1 | 无 |
实施例5 | 2 | 3 | 1 | 无 |
实施例6 | 3 | 2 | 1 | 无 |
对比例1 | 4 | 4 | 1- | 无 |
对比例2 | 5 | 4 | 2 | 有 |
XK-12体系 | 抑泡 | 消泡 | 流平 | 缩孔 |
实施例1 | 3- | 3 | 1 | 无 |
实施例2 | 2 | 3- | 1- | 无 |
实施例3 | 3 | 2- | 1 | 无 |
实施例4 | 2- | 2 | 1- | 无 |
实施例5 | 3- | 2 | 1- | 无 |
实施例6 | 2- | 3 | 1 | 无 |
对比例1 | 5 | 4 | 1- | 无 |
对比例2 | 4 | 4 | 2 | 有 |
Claims (11)
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110776641A (zh) * | 2019-12-13 | 2020-02-11 | 江西省科学院能源研究所 | 氨基聚醚改性聚硅氧烷的制备方法 |
CN114599742A (zh) * | 2019-10-29 | 2022-06-07 | 信越化学工业株式会社 | 涂料添加剂、涂料组合物及涂层 |
CN114728215A (zh) * | 2019-11-06 | 2022-07-08 | 陶氏东丽株式会社 | 水溶性有机硅消泡剂组合物及含有其的水性涂料 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07316284A (ja) * | 1994-05-30 | 1995-12-05 | Sanyo Chem Ind Ltd | ポリエーテルの製造方法およびポリエーテル組成物 |
US6531223B1 (en) * | 1998-03-11 | 2003-03-11 | The Sherwin-Williams Company | Primerless latex paint with tannin blocking |
EP2138526A1 (de) * | 2008-06-27 | 2009-12-30 | Evonik Goldschmidt GmbH | Neue Polyethersiloxane enthaltende Alkoxylierungsprodukte durch direkte Alkoxylierung organomodifizierter alpha, omega-Dihydroxysiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
CN103214895A (zh) * | 2013-04-26 | 2013-07-24 | 广东省石油化工研究院 | 有机硅涂料流平剂及其制备方法 |
CN103877753A (zh) * | 2012-12-21 | 2014-06-25 | 南京四新科技应用研究所有限公司 | 一种有机硅乳液消泡剂及其制备方法 |
CN104069656A (zh) * | 2014-07-09 | 2014-10-01 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
CN104784980A (zh) * | 2015-04-02 | 2015-07-22 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
CN107551610A (zh) * | 2017-09-30 | 2018-01-09 | 徐州中泰能源科技有限公司 | 一种复合有机硅液体消泡剂 |
CN107722171A (zh) * | 2017-10-18 | 2018-02-23 | 海门埃夫科纳化学有限公司 | 一种磷酸酯分散剂及其制备方法和应用 |
CN108864430A (zh) * | 2018-08-09 | 2018-11-23 | 成都东恒新材料科技有限公司 | 一种封端聚醚和环氧共改性硅油及其制备方法 |
-
2018
- 2018-12-11 CN CN201811509888.6A patent/CN109651617B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07316284A (ja) * | 1994-05-30 | 1995-12-05 | Sanyo Chem Ind Ltd | ポリエーテルの製造方法およびポリエーテル組成物 |
US6531223B1 (en) * | 1998-03-11 | 2003-03-11 | The Sherwin-Williams Company | Primerless latex paint with tannin blocking |
EP2138526A1 (de) * | 2008-06-27 | 2009-12-30 | Evonik Goldschmidt GmbH | Neue Polyethersiloxane enthaltende Alkoxylierungsprodukte durch direkte Alkoxylierung organomodifizierter alpha, omega-Dihydroxysiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
CN103877753A (zh) * | 2012-12-21 | 2014-06-25 | 南京四新科技应用研究所有限公司 | 一种有机硅乳液消泡剂及其制备方法 |
CN103214895A (zh) * | 2013-04-26 | 2013-07-24 | 广东省石油化工研究院 | 有机硅涂料流平剂及其制备方法 |
CN104069656A (zh) * | 2014-07-09 | 2014-10-01 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
CN104784980A (zh) * | 2015-04-02 | 2015-07-22 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
CN107551610A (zh) * | 2017-09-30 | 2018-01-09 | 徐州中泰能源科技有限公司 | 一种复合有机硅液体消泡剂 |
CN107722171A (zh) * | 2017-10-18 | 2018-02-23 | 海门埃夫科纳化学有限公司 | 一种磷酸酯分散剂及其制备方法和应用 |
CN108864430A (zh) * | 2018-08-09 | 2018-11-23 | 成都东恒新材料科技有限公司 | 一种封端聚醚和环氧共改性硅油及其制备方法 |
Non-Patent Citations (3)
Title |
---|
刘武辉,编著: "《现代印刷材料》", 30 September 2007, 印刷工业出版社 * |
室井宗一,著,吴国和等,译,: "《高分子乳液在建筑涂料中的应用》", 31 July 1988, 化学工业出版社 * |
张东辉等: "氨基聚醚改性有机硅的合成与消泡性能研究", 《化学工程与技术》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114599742A (zh) * | 2019-10-29 | 2022-06-07 | 信越化学工业株式会社 | 涂料添加剂、涂料组合物及涂层 |
CN114599742B (zh) * | 2019-10-29 | 2023-06-06 | 信越化学工业株式会社 | 涂料添加剂、涂料组合物及涂层 |
CN114728215A (zh) * | 2019-11-06 | 2022-07-08 | 陶氏东丽株式会社 | 水溶性有机硅消泡剂组合物及含有其的水性涂料 |
CN114728215B (zh) * | 2019-11-06 | 2023-09-22 | 陶氏东丽株式会社 | 水溶性有机硅消泡剂组合物及含有其的水性涂料 |
EP4056248A4 (en) * | 2019-11-06 | 2024-01-24 | Dow Toray Co Ltd | WATER-SOLUBLE SILICONE ANTI-FOAM AGENT COMPOSITION AND AQUEOUS COATING MATERIAL CONTAINING SAME |
CN110776641A (zh) * | 2019-12-13 | 2020-02-11 | 江西省科学院能源研究所 | 氨基聚醚改性聚硅氧烷的制备方法 |
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