CN109641201A - 成型凝胶制品和由其制备的烧结制品 - Google Patents

成型凝胶制品和由其制备的烧结制品 Download PDF

Info

Publication number
CN109641201A
CN109641201A CN201780052254.XA CN201780052254A CN109641201A CN 109641201 A CN109641201 A CN 109641201A CN 201780052254 A CN201780052254 A CN 201780052254A CN 109641201 A CN109641201 A CN 109641201A
Authority
CN
China
Prior art keywords
weight
colloidal sol
casting
group
formed gel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780052254.XA
Other languages
English (en)
Chinese (zh)
Inventor
K·M·汗帕尔
M·A·拉基
B·U·科尔布
P·D·彭宁顿
M·J·亨德里克森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN109641201A publication Critical patent/CN109641201A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157—After-treatment of gels
    • C01B33/158—Purification; Drying; Dehydrating
    • C01B33/1585—Dehydration into aerogels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/003—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
    • B29C39/006—Monomers or prepolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157—After-treatment of gels
    • C01B33/158—Purification; Drying; Dehydrating
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/624—Sol-gel processing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62625—Wet mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62625—Wet mixtures
    • C04B35/6264—Mixing media, e.g. organic solvents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/6265—Thermal treatment of powders or mixtures thereof other than sintering involving reduction or oxidation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62655—Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0045—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by a process involving the formation of a sol or a gel, e.g. sol-gel or precipitation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B29K2033/08—Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0058—Liquid or visquous
    • B29K2105/0061—Gel or sol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0026—Transparent
    • B29K2995/0027—Transparent for light outside the visible spectrum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2028/00—Nets or the like
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5454—Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6023—Gel casting
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/77—Density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646—Optical properties
    • C04B2235/9653—Translucent or transparent ceramics other than alumina
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/042—Elimination of an organic solid phase
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/02—Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
    • C08J2205/026—Aerogel, i.e. a supercritically dried gel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Materials For Medical Uses (AREA)
  • Nanotechnology (AREA)
CN201780052254.XA 2016-09-02 2017-08-16 成型凝胶制品和由其制备的烧结制品 Pending CN109641201A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662382944P 2016-09-02 2016-09-02
US62/382,944 2016-09-02
PCT/US2017/047064 WO2018044565A1 (en) 2016-09-02 2017-08-16 Shaped gel articles and sintered articles prepared therefrom

Publications (1)

Publication Number Publication Date
CN109641201A true CN109641201A (zh) 2019-04-16

Family

ID=59791131

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780052254.XA Pending CN109641201A (zh) 2016-09-02 2017-08-16 成型凝胶制品和由其制备的烧结制品

Country Status (6)

Country Link
US (1) US11884550B2 (enExample)
EP (1) EP3507011B1 (enExample)
JP (1) JP7055970B2 (enExample)
KR (1) KR102446800B1 (enExample)
CN (1) CN109641201A (enExample)
WO (1) WO2018044565A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114276132A (zh) * 2022-01-07 2022-04-05 超瓷材料技术(深圳)有限公司 一种高固相含量微波介质陶瓷注射成型喂料及其制备方法和应用

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018158528A (ja) * 2017-03-23 2018-10-11 国立大学法人横浜国立大学 セラミックス成形体の製造方法
WO2019030635A1 (en) 2017-08-11 2019-02-14 3M Innovative Properties Company MULTIFIBRE OPTICAL SPLICE ELEMENT AND CASSETTE
US11448832B2 (en) 2017-10-18 2022-09-20 3M Innovative Properties Company Optical fiber connection system
US11194100B2 (en) 2017-10-18 2021-12-07 3M Innovative Properties Company Optical fiber connection system
JP7774383B2 (ja) 2018-06-29 2025-11-21 スリーエム イノベイティブ プロパティズ カンパニー 熱膨張又は収縮中に光フェルールの位置合わせを維持するための装置及び方法
US20200317870A1 (en) * 2019-04-04 2020-10-08 Lawrence Livermore National Security, Llc Curable polymer resins for 3d-printable hierarchical nanoporous foams and aerogels
KR102684623B1 (ko) * 2019-08-09 2024-07-15 주식회사 엘지화학 습윤겔 블랭킷의 건조방법 및 이를 이용한 에어로겔 블랭킷의 제조방법
CN114391188A (zh) 2019-09-18 2022-04-22 3M创新有限公司 包括纳米结构化表面和封闭空隙的制品及其制备方法
CN111559746B (zh) * 2020-05-25 2021-12-14 航天特种材料及工艺技术研究所 一种柔性超低密度气凝胶复合材料加工方法
US20240043340A1 (en) * 2020-08-27 2024-02-08 3M Innovative Properties Company Haptic articles and applications using sintered articles prepared from molded gel compositions
WO2022234360A1 (en) 2021-05-06 2022-11-10 3M Innovative Properties Company Angular physical vapor deposition for coating substrates
EP4392488B1 (en) * 2021-08-27 2025-07-30 Nissan Chemical America Corporation Functionalized silica nanoparticles for use in thiolene cure 3d printing
WO2023042016A1 (en) 2021-09-15 2023-03-23 3M Innovative Properties Company Acoustic articles and methods of making the same
CN119462093B (zh) * 2024-11-25 2025-09-16 浙江大学 一种彩色隔热气凝胶及其制备方法和应用

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298252A (ja) * 1997-04-23 1998-11-10 Mitsubishi Rayon Co Ltd 硬化性組成物およびその製造方法
JP2005162781A (ja) * 2003-11-28 2005-06-23 Mitsubishi Rayon Co Ltd 硬化性組成物、および物品
WO2009152229A1 (en) * 2008-06-10 2009-12-17 Nanotune Technologies Corp. Nanoporous materials and related methods
JP2012211231A (ja) * 2011-03-31 2012-11-01 Sumitomo Bakelite Co Ltd シリコーンゴム系硬化性組成物、シリカフィラーの表面処理方法、成形体、及び医療用チューブ
WO2013009984A2 (en) * 2011-07-12 2013-01-17 Board Of Trustees Of Michigan State University Porous sol gels and methods and structures related thereto
CN103857625A (zh) * 2011-10-10 2014-06-11 3M创新有限公司 气凝胶、煅烧和结晶制品以及制备它们的方法
CN104080815A (zh) * 2012-02-10 2014-10-01 昭和电工株式会社 固化性组合物和其用途
CN104321376A (zh) * 2012-05-21 2015-01-28 昭和电工株式会社 可固化组合物及其固化材料
JP2015108068A (ja) * 2013-12-04 2015-06-11 昭和電工株式会社 半導体ナノ粒子含有硬化性組成物、硬化物、光学材料および電子材料
CN105899623A (zh) * 2014-01-15 2016-08-24 3M创新有限公司 包含烷氧基化的多(甲基)丙烯酸酯单体和经表面处理的纳米粒子的硬质涂膜

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5125917A (en) 1991-01-04 1992-06-30 William Whealin Ostomy appliances
US5240488A (en) 1992-08-14 1993-08-31 At&T Bell Laboratories Manufacture of vitreous silica product via a sol-gel process using a polymer additive
US5435816A (en) 1993-01-14 1995-07-25 Minnesota Mining And Manufacturing Company Method of making an abrasive article
BR9407536A (pt) 1993-09-13 1997-08-26 Minnesota Mining & Mfg Artigo abrasivo processos de fabricação e de refino de peça em trabalho corn o mesmo ferramenta de produção para fabricação do mesmo e processo de produção de matriz mestra para formação da mesma
US5975987A (en) 1995-10-05 1999-11-02 3M Innovative Properties Company Method and apparatus for knurling a workpiece, method of molding an article with such workpiece, and such molded article
US5912433A (en) 1997-01-17 1999-06-15 Minnesota Mining And Manufacturing Company Cable closure injection sealed with low surface energy adhesive
US5946991A (en) 1997-09-03 1999-09-07 3M Innovative Properties Company Method for knurling a workpiece
DE60042038D1 (de) * 1999-10-28 2009-05-28 3M Innovative Properties Co Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers
US6730282B2 (en) * 2001-11-05 2004-05-04 N Vara Technology S.R.L. Sol-gel process for the manufacture of nanocomposite photoluminescent materials
EP1700830A1 (en) 2005-03-09 2006-09-13 Novara Technology S.R.L. Process for the production of monoliths by means of the invert sol-gel process
US7264410B1 (en) 2006-03-16 2007-09-04 Corning Cable Systems Llc Dual function splice component for mechanical splice connector
WO2008145182A1 (en) 2007-05-30 2008-12-04 Degussa Novara Technology S.P.A. Method to produce precision structured preforms of glass
US7802927B2 (en) 2008-05-30 2010-09-28 Corning Cable Systems Llc Bent optical fiber couplers and opto-electrical assemblies formed therefrom
WO2010003455A1 (en) 2008-07-09 2010-01-14 Degussa Novara Technology S.P.A. Silicon-based green bodies
CN111718259A (zh) 2013-03-15 2020-09-29 3M创新有限公司 用于制备生物基醇的(甲基)丙烯酸酯及其聚合物的方法
US20180044245A1 (en) 2015-03-03 2018-02-15 3M Innovative Properties Company Gel compositions, shaped gel articles and a method of making a sintered article

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298252A (ja) * 1997-04-23 1998-11-10 Mitsubishi Rayon Co Ltd 硬化性組成物およびその製造方法
JP2005162781A (ja) * 2003-11-28 2005-06-23 Mitsubishi Rayon Co Ltd 硬化性組成物、および物品
WO2009152229A1 (en) * 2008-06-10 2009-12-17 Nanotune Technologies Corp. Nanoporous materials and related methods
JP2012211231A (ja) * 2011-03-31 2012-11-01 Sumitomo Bakelite Co Ltd シリコーンゴム系硬化性組成物、シリカフィラーの表面処理方法、成形体、及び医療用チューブ
WO2013009984A2 (en) * 2011-07-12 2013-01-17 Board Of Trustees Of Michigan State University Porous sol gels and methods and structures related thereto
CN103857625A (zh) * 2011-10-10 2014-06-11 3M创新有限公司 气凝胶、煅烧和结晶制品以及制备它们的方法
CN104080815A (zh) * 2012-02-10 2014-10-01 昭和电工株式会社 固化性组合物和其用途
CN104321376A (zh) * 2012-05-21 2015-01-28 昭和电工株式会社 可固化组合物及其固化材料
JP2015108068A (ja) * 2013-12-04 2015-06-11 昭和電工株式会社 半導体ナノ粒子含有硬化性組成物、硬化物、光学材料および電子材料
CN105899623A (zh) * 2014-01-15 2016-08-24 3M创新有限公司 包含烷氧基化的多(甲基)丙烯酸酯单体和经表面处理的纳米粒子的硬质涂膜

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114276132A (zh) * 2022-01-07 2022-04-05 超瓷材料技术(深圳)有限公司 一种高固相含量微波介质陶瓷注射成型喂料及其制备方法和应用

Also Published As

Publication number Publication date
EP3507011B1 (en) 2024-06-26
JP7055970B2 (ja) 2022-04-19
WO2018044565A1 (en) 2018-03-08
KR102446800B1 (ko) 2022-09-23
US20190185328A1 (en) 2019-06-20
KR20190042658A (ko) 2019-04-24
US11884550B2 (en) 2024-01-30
EP3507011A1 (en) 2019-07-10
JP2019534228A (ja) 2019-11-28

Similar Documents

Publication Publication Date Title
CN109641201A (zh) 成型凝胶制品和由其制备的烧结制品
JP6093744B2 (ja) 有機無機複合体及びその製造方法、有機無機複合膜及びその製造方法、フォトニック結晶、コーティング材、熱可塑性組成物、微細構造体、光学材料、反射防止部材、並びに、光学レンズ
CN103314063B (zh) 含有有机无机复合物的涂布材料、有机无机复合膜和防反射部件
JP6948946B2 (ja) ゲル組成物、形状化ゲル物品及び焼結物品の製造方法
JP5167582B2 (ja) ジルコニア透明分散液及び透明複合体並びに透明複合体の製造方法
JP5348400B2 (ja) シリカ粒子分散液およびその製造方法
CN107635531A (zh) 包含纳米氧化锆颗粒的溶胶在用于制备三维制品的增材制造方法中的用途
JP2005146042A (ja) 有機無機複合材料及びその製造方法並びに光学素子
AU2020286969B2 (en) Production of glass bodies from polymerisable solutions
JP2005003772A (ja) 光学材料用組成物および光学素子
JP2011162765A (ja) 有機・無機複合材料及びその製造方法、並びに光学部材
JP5682824B2 (ja) ポリマーで固定化されたコロイド結晶の製造方法、及び、ポリマーで固定化されたコロイド結晶
JP2012214311A (ja) 二酸化チタン分散液、二酸化チタン分散液の製造方法、および有機光学素子
JP2007171555A (ja) ハードコート膜と光学機能膜及び光学レンズ並びに光学部品
Yun et al. Silica/Ultraviolet-Cured Resin Nanocomposites for Replica Molds in Ultraviolet Nanoimprinting
TWI464198B (zh) 綠色環保奈米高分子複合基材配方及其製法
JP2005131917A (ja) 複合型光学素子の製造方法及び複合型光学素子
KR20070030777A (ko) 표면-변형 입자를 함유하는 경화형 조성물

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination