CN109370785A - A kind of amino acid soap and preparation method thereof containing dried orange peel extracts - Google Patents
A kind of amino acid soap and preparation method thereof containing dried orange peel extracts Download PDFInfo
- Publication number
- CN109370785A CN109370785A CN201811158973.2A CN201811158973A CN109370785A CN 109370785 A CN109370785 A CN 109370785A CN 201811158973 A CN201811158973 A CN 201811158973A CN 109370785 A CN109370785 A CN 109370785A
- Authority
- CN
- China
- Prior art keywords
- orange peel
- dried orange
- peel extracts
- amino acid
- extracts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000284 extract Substances 0.000 title claims abstract description 120
- 239000000344 soap Substances 0.000 title claims abstract description 73
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 60
- 235000019441 ethanol Nutrition 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 31
- 229930003944 flavone Natural products 0.000 claims abstract description 23
- 235000011949 flavones Nutrition 0.000 claims abstract description 23
- 150000002213 flavones Chemical class 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 11
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- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005720 sucrose Substances 0.000 claims abstract description 10
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- 235000001014 amino acid Nutrition 0.000 claims description 41
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 238000000605 extraction Methods 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000000706 filtrate Substances 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 11
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- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 8
- 235000013922 glutamic acid Nutrition 0.000 claims description 8
- 239000004220 glutamic acid Substances 0.000 claims description 8
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- 238000002604 ultrasonography Methods 0.000 claims description 7
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- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims description 3
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- MTJZWYHTZFVEGI-INIZCTEOSA-N (2s)-2-(tetradecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O MTJZWYHTZFVEGI-INIZCTEOSA-N 0.000 claims description 3
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- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
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- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 4
- 229910021529 ammonia Inorganic materials 0.000 claims 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 claims 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Abstract
The invention belongs to facial soap technical fields, specifically disclose a kind of amino acid soap and preparation method thereof containing dried orange peel extracts, the amino acid soap containing dried orange peel extracts includes: N- acylamino acid: 30~40%；Triethanolamine: 18~25%；Ethyl alcohol: 6~12%；Polyalcohol: 5~10%；Sucrose: 1~2%；Dried orange peel extracts: 2~5%；Surplus is water；The weight percentage of flavones is 70~95% in the dried orange peel extracts.Present invention employs amino acid surfactants and dried orange peel extracts as main component, composition is simple, material is easy to get, not only property is mild for its obtained face cleaning product, there is the effect of anti-inflammatory significant antiallergic, moisturizing reparation, soothe the skin, it is particularly suitable for sensitivity skin, the impaired crowd of skin barrier also has certain repairing effect to the skin after solarization.
Description
Technical field
The invention belongs to facial soap technical field, it is related to a kind of amino acid cleansing soap, more particularly to a kind of containing dried orange peel extraction
Amino acid soap of object and preparation method thereof.
Background technique
Face cleaning product belongs to a big category in cosmetics, accounts for 20% or more of skin care item market.Face cleaning product originates from earliest
In soap, two class of soap base type and non-soap fundamental mode can be divided into.Soap base type contains fatty acid soaps ingredient, and foaming abundancy is easy to rinse, but
Product slightly stimulates, and degreasing power is strong, and washing rear skin has tight feeling.Non-soap basic product has soapy feeling after washing, because of the surface of compounding
Activating agent is different, and foaming power, cleaning strength and irritation are all different, if any non-soap basic product in order to improve foaming power, wash
Resulting net force and cost is reduced, the alkalinity such as lauryl sodium sulfate, Coconut Fatty Acid Monoethanolamide can be added compared with strong, the biggish table of irritation
Face activating agent, if this kind of product, which is used for a long time, can destroy sebum film, skin is highly susceptible to external injury, causes various
Skin problem.With the raising of customer demand, new surfactant is gradually found and applies, living with amino acid pattern surface
Property agent based on non-soap fundamental mode facial soap because its dirt-removing power is strong, foaming characteristic is good, flush performance is excellent, mild irritation is low, raw
Object degradability is good, to environmental and biological materials it is highly-safe the advantages that, favor by more and more consumers.But current city
The amino acid-based surfactant type face cleaning product formula in face is complicated, and technique is cumbersome, and some nourishing skin abilities are poor, quality ginseng
Difference is uneven.
Current social is in face of life and work pressure, environmental pollution, change heavy make-up, excessively cleaning exfoliating etc., the skin of people
Skin becomes more and more sensitive, and many application on human skin barriers are badly damaged, can be generated when using cleaning products shouting pain, it is tight,
Scorching hot, a large amount of skin problems such as itch, is rubescent.Therefore, the face cleaning product that a kind of antiallergic is anti-inflammatory, soothes the skin is developed to compel in eyebrow
Eyelash.
Summary of the invention
It is an object of the invention in view of the above problems, provide, a kind of antiallergic is anti-inflammatory, moisturizing reparation, soothes the skin
The amino acid soap containing dried orange peel extracts.
The purpose of the present invention is achieved through the following technical solutions: a kind of amino acid soap containing dried orange peel extracts, including as follows
The raw material of weight fraction:
N- acylamino acid: 30~40%；
Triethanolamine: 18~25%；
Ethyl alcohol: 6~12%；
Polyalcohol: 5~10%；
Sucrose: 1~2%；
Dried orange peel extracts: 2~5%；
Surplus is water；
The weight percentage of flavones is 70~95% in the dried orange peel extracts.
The preparations of the dried orange peel extracts the following steps are included:
(1) weigh and crush dried orange peel: claim dried orange peel is crushed, sieving；
(2) it extracts: smashed dried orange peel in step (1) being added in Extraction solvent and is impregnated, and dried orange peel and Extraction solvent is added
The citric acid of gross mass 0.1~0.5%, while being aided with ultrasound, and be heated to 50~60 DEG C and extract, extraction 2~3 times, every time
2~3h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 10%~20% when, obtain filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get dried orange peel extracts.
The Extraction solvent is that mass fraction is at least one of 30~50% ethyl alcohol, ethylene glycol, propylene glycol.
Dried orange peel is a kind of tradition of integration of drinking and medicinal herbs in China from rutaceae orange and its mature pericarp of variety
Chinese herbal medicine, bitter, pungent, warm-natured, return lung, the spleen channel have regulating qi-flowing for strengthening spleen, eliminating dampness and eliminating phlegm effect.Medicinal material be divided into " dried orange peel " and
" citrus chachiensis hortorum ", wherein with the quality of " citrus chachiensis hortorum " be it is excellent, in " citrus chachiensis hortorum " again using Xinhui tangerine peel as genunie medicinal materials.Dried orange peel is to pass through
Ripening fruits is won, strips pericarp, made of sun drying or low temperature drying, air-dry time is usually 1 year or more.Contain in dried orange peel
The chemical components such as flavone compound, alkaloid, volatile oil, polysaccharide and a variety of the essential trace elements of the human bodys, have it is anti-oxidant,
Anti-inflammatory, antiallergy and it is antitumor the effects of, pharmaceutically having been widely used and Utilization prospects.Dried orange peel is used as medicine or is used at present
It is more in food, but be seldom used in cosmetics.Multicomponent acts synergistically in dried orange peel extracts, can play enhancing function to skin
Effect.
The N- acylamino acid is lauroyl glutamate, cocoyl propyl glutamic acid, cocounut oil acyl glutamic acid, lauroyl day
At least one of aspartic acid, fatty acyl sarcosines, lauroyl lysine, myristoyl glutamic acid.
The amino acid soap containing dried orange peel extracts, further includes the plant extracts of 1~5 parts by weight.
The plant extracts is green-tea extract, camomile extract, Herba Saussureae Involueratae extract, aloe extract, dent
Amaranth extract, mulberry root bark extract, ginseng extract, Herba Lysimachiae foenumgraeci extract, gadol extract, Astragalus Root P.E, seaweed mention
Take at least one of object.
The dried orange peel extracts are Xinhui tangerine peel extract.
The amino acid soap containing dried orange peel extracts, further includes in the urea, trehalose, EDTA-2Na of 1~5 parts by weight
It is at least one.
The polyalcohol is ethylene glycol, propylene glycol, dipropylene glycol, butanediol, glycerine, pentaerythrite, xylitol, sorb
At least one of alcohol.
A kind of preparation method of amino acid soap containing dried orange peel extracts is claimed in the present invention simultaneously, comprising the following steps:
(1) materials such as N- acylamino acid, part ethyl alcohol, polyalcohol are mixed and is used as material, be stirred and heated to 70~80 DEG C, and
Constant temperature is kept, material is completely dissolved；
(2) triethanolamine, remaining second alcohol and water are mixed and is heated to 55~65 DEG C as second material, constant temperature, for use；
(3) second material is slowly added into material, is slowly stirred, 70~80 DEG C of constant temperature are saponified 5~20 minutes, obtain soap lye；
(4) dried orange peel extracts and sucrose are added in soap lye, are stirred evenly, 45~55 DEG C keep the temperature 10~15 minutes；
(5) soap lye for obtaining step (4) sprays a small amount of ethyl alcohol, is then injected into mold, and fast cooling is freezed to 30 DEG C, coagulates
Knot.
The present invention has the advantages that
1. present invention employs amino acid surfactants and dried orange peel extracts as constituent, relatively easy, material is formed
It is easy to obtain, not only property is mild for obtained face cleaning product, there is anti-inflammatory significant antiallergic, moisturizing reparation, the function soothed the skin
Effect is particularly suitable for sensitivity skin, the impaired crowd of skin barrier.Also there is certain repairing effect to the skin after solarization.
2. the amino acid soap dirt-removing power of the invention containing dried orange peel extracts is strong, without the stimulation such as preservative, essence, pigment
Property or cause hypersensitive raw material, very environmentally friendly, simple production process, be suitable for large-scale production, have a vast market foreground.
3. amino acid soap of the present invention containing dried orange peel extracts is using nearly dermatoid pH value prescription system, foam is fine and smooth, clearly
Skin tight feeling is not had after washing or false sliding sense, comfort level are high.
The invention will be further described by the following examples.
Specific embodiment
The technical solution used in the present invention is: a kind of amino acid soap containing dried orange peel extracts, by following weight fraction
Raw material composition:
N- acylamino acid: 30~40%；
Triethanolamine: 18~25%；
Ethyl alcohol: 6~12%；
Polyalcohol: 5~10%；
Sucrose: 1~2%；
Dried orange peel extracts: 2~5%；
Surplus is water；
The weight percentage of flavones is 70~95% in the dried orange peel extracts.
Flavones total amount is high in the content of dried orange peel extracts in the present invention, to the anti-inflammatory antiallergic of face cleaning, soothes the skin lifting
The effect wanted, and also contain a small amount of alkaloid, volatile oil, polysaccharide and microelement in dried orange peel extracts, these multicomponents association
Same-action can play synergistic effect to skin.
The measurement of flavones content is first to prepare flavones content-absorbance (A) by reference substance of rutin in dried orange peel extracts
Standard curve checks in corresponding flavones content by standard curve by the A value of measurement, and the specific test method is as follows:
(1) spectrophotometry of standard sample is established
0.0997g rutoside standard sample accurately is weighed in beaker, adds methanol to dissolve in 40 DEG C of water-bath low-grade fevers, after being cooled to room temperature
It is placed in 100ml volumetric flask, adds methanol to scale, shake up.Accurate measuring 10ml, which is placed in 100ml volumetric flask, is diluted with water to quarter
Degree, shakes up the standard solution to get 0.100mg/ml.
(2) foundation of standard curve
Accurate measuring standard solution 0ml, 0.5ml, 1.0ml, 2.0ml, 3.0ml, 4.0ml, 5.0ml adds in 10ml volumetric flask
Enter distilled water and be settled to 5ml, 5% sodium nitrite solution 0.3ml is added, shakes up, after placing 6~8 minutes, 10% nitric acid is added
0.3 ml of aluminum solutions, shakes up, and after placing 6~8 minutes, adds 1mol/L sodium hydroxide solution 4ml, distilled water is added to be diluted to quarter
Degree, shakes up, and places 20 minutes, its absorbance of survey, is averaged for parallel 3 times in 500nm at, makes standard curve.
(3) in dried orange peel extracts general flavone content measurement
Dried orange peel extracts 0.1g is weighed, with methanol constant volume into 100 ml volumetric flasks, takes 1.0 ml of sample liquid in 10ml volumetric flask
In, according to the method for step (2), its absorbance is surveyed everywhere in 500nm, is calculated according to the standard curve that step (2) obtains old
The content of flavones in bark extract.
The preparations of the dried orange peel extracts the following steps are included:
(1) weigh and crush dried orange peel: claim dried orange peel is crushed, sieving；
(2) it extracts: smashed dried orange peel in step (1) being added in Extraction solvent and is impregnated, and dried orange peel and Extraction solvent is added
The citric acid of gross mass 0.1~0.5%, while being aided with ultrasound, and be heated to 50~60 DEG C and extract, extraction 2~3 times, every time
2~3h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 10%~20% when, obtain filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get dried orange peel extracts.
The Extraction solvent is that mass fraction is at least one of 30~50% ethyl alcohol, ethylene glycol, propylene glycol.
Preferably, the Extraction solvent is the mixture of ethyl alcohol and ethylene glycol or ethyl alcohol and propylene glycol, ethyl alcohol and ethylene glycol
Or the mass ratio of ethyl alcohol and propylene glycol is 5:1~2:1.
Preferably, the dried orange peel extracts are Xinhui tangerine peel extract.
The storage time of the dried orange peel is 3~6 years.
The power of the ultrasound is 200~500W.
The solid-liquid ratio of the dried orange peel and the Extraction solvent are as follows: 1:10~1:50.
Preferably, the solid-liquid ratio of the dried orange peel and the Extraction solvent are as follows: 1:20~1:30.
The N- acylamino acid is lauroyl glutamate, cocoyl propyl glutamic acid, cocounut oil acyl glutamic acid, lauroyl day
At least one of aspartic acid, fatty acyl sarcosines, lauroyl lysine, myristoyl glutamic acid.
The amino acid soap containing dried orange peel extracts, further includes the plant extracts of 1~5 parts by weight.
The plant extracts is green-tea extract, camomile extract, Herba Saussureae Involueratae extract, aloe extract, dent
Amaranth extract, mulberry root bark extract, ginseng extract, Herba Lysimachiae foenumgraeci extract, gadol extract, Astragalus Root P.E, seaweed mention
Take at least one of object.
The amino acid soap containing dried orange peel extracts further includes in the urea, trehalose, EDTA- disodium of 1~5 parts by weight
At least one.
The polyalcohol is ethylene glycol, propylene glycol, dipropylene glycol, butanediol, glycerine, pentaerythrite, xylitol, sorb
At least one of alcohol.
Below with reference to embodiment, the invention will be further described.
Embodiment 1:
A kind of amino acid soap containing dried orange peel extracts, raw material composition such as the following table 1:
The raw material of amino acid soap of the table 1 containing dried orange peel extracts forms
The preparations of dried orange peel extracts of the invention the following steps are included:
(1) weigh and crush Xinhui tangerine peel: claim Xinhui tangerine peel 1g is crushed, sieving；
(2) extract: it is to impregnate in 50% Extraction solvent that smashed dried orange peel in step (1), which is added to 20ml mass fraction, is mentioned
Solvent is taken to be made of ethyl alcohol and ethylene glycol, mass ratio 3:1, and the citric acid of 0.1g is added, while being aided with ultrasound, and add
Heat is extracted to 55 DEG C, extract 3 times, each 2h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 10% when, obtain
Filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get flaxen dried orange peel extracts.
The measurement of flavones content is first to prepare flavones content-absorbance (A) by reference substance of rutin in dried orange peel extracts
Standard curve checks in corresponding flavones content by standard curve by the A value of measurement, in the dried orange peel extracts by above-mentioned preparation
The content of flavones is 83.2%.
A kind of amino acid soap containing dried orange peel extracts of the invention, preparation method are as follows:
(1) 32g cocounut oil acyl glutamic acid, 7g ethyl alcohol, 8g glycerine are mixed and is used as material, be stirred and heated to 70~80 DEG C, and protect
Constant temperature is held, material is completely dissolved；
(2) 22g triethanolamine, 3g ethyl alcohol and 20g water are mixed and is heated to 55~65 DEG C as second material, constant temperature, for use；
(3) second material is slowly added into material, is slowly stirred, 70~80 DEG C of constant temperature are saponified 15~20 minutes, obtain soap lye；
(4) 3g dried orange peel extracts and 1g sucrose are mixed in 4g water, is added in soap lye, stirs evenly, 45~55 DEG C of heat preservations
10~15 minutes；
(5) soap lye for obtaining step (4) sprays a small amount of ethyl alcohol, is then injected into mold, and fast cooling is freezed to 30 DEG C, coagulates
Knot.
Embodiment 2:
A kind of amino acid soap containing dried orange peel extracts, raw material composition such as the following table 2:
The raw material of amino acid soap of the table 2 containing dried orange peel extracts forms
The preparations of dried orange peel extracts of the invention the following steps are included:
(1) weigh and crush Xinhui tangerine peel: claim Xinhui tangerine peel 1g is crushed, sieving；
(2) extract: it is to impregnate in 50% Extraction solvent that smashed dried orange peel in step (1), which is added to 30ml mass fraction, is mentioned
Solvent is taken to be made of ethyl alcohol and propylene glycol, mass ratio 5:1, and the citric acid of 0.1g is added, while being aided with ultrasound, and add
Heat is extracted to 60 DEG C, extract 3 times, each 3h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 15% when, obtain
Filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get flaxen dried orange peel extracts.
The measurement of flavones content is first to prepare flavones content-absorbance (A) by reference substance of rutin in dried orange peel extracts
Standard curve checks in corresponding flavones content by standard curve by the A value of measurement, in the dried orange peel extracts by above-mentioned preparation
The content of flavones is 90.6%.
A kind of amino acid soap containing dried orange peel extracts of the invention, preparation method are as follows:
(1) 23g cocounut oil acyl glutamic acid, 12g fatty acyl sarcosines, 6g ethyl alcohol, 5g glycerine, 2g sorbierite are mixed and is used as first
Material, is stirred and heated to 70~80 DEG C, and keep constant temperature, is completely dissolved material, and the 0.2g EDTA- dissolved with a small amount of water is added
Disodium stirs evenly；
(2) 20g triethanolamine, 3g ethyl alcohol and 20g water are mixed and is heated to 55~65 DEG C as second material, constant temperature, for use；
(3) second material is slowly added into material, is slowly stirred, 70~80 DEG C of constant temperature are saponified 15~20 minutes, obtain soap lye；
(4) 2g dried orange peel extracts, 2g aloe extract and 1g sucrose are mixed in about 4g water, is added in soap lye, stirring is equal
Even, 45~55 DEG C keep the temperature 10~15 minutes；
(5) soap lye for obtaining step (4) sprays a small amount of ethyl alcohol, is then injected into mold, and fast cooling is freezed to 30 DEG C, coagulates
Knot.
Embodiment 3:
A kind of amino acid soap containing dried orange peel extracts, raw material composition such as the following table 3:
The raw material of amino acid soap of the table 3 containing dried orange peel extracts forms
| Raw material | Mass content |
| Cocounut oil acyl glutamic acid | 14 |
| Lauroyl glutamate | 20 |
| Triethanolamine | 18 |
| Glycerine | 10 |
| Ethyl alcohol | 10 |
| Dried orange peel extracts | 2 |
| Camomile extract | 1 |
| Marine algae extract | 1 |
| Sucrose | 1 |
| EDTA- disodium | 0.2 |
| Urea | 1 |
| Water | 21.8 |
The preparations of dried orange peel extracts of the invention the following steps are included:
(1) weigh and crush Xinhui tangerine peel: claim Xinhui tangerine peel 1g is crushed, sieving；
(2) extract: it is to impregnate in 40% Extraction solvent that smashed dried orange peel in step (1), which is added to 25ml mass fraction, is mentioned
Solvent is taken to be made of ethyl alcohol and propylene glycol, mass ratio 3:1, and the citric acid of 0.08g is added, while being aided with ultrasound, and
60 DEG C are heated to extract, extract 3 times, each 3h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 10% when,
Obtain filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get flaxen dried orange peel extracts.
The measurement of flavones content is first to prepare flavones content-absorbance (A) by reference substance of rutin in dried orange peel extracts
Standard curve checks in corresponding flavones content by standard curve by the A value of measurement, in the dried orange peel extracts by above-mentioned preparation
The content of flavones is 86.9%.
A kind of amino acid soap containing dried orange peel extracts of the invention, preparation method are as follows:
(1) 14g cocounut oil acyl glutamic acid, 20g lauroyl glutamate, 7g ethyl alcohol, 10g glycerine, 1g urea are mixed and are used as material,
70~80 DEG C are stirred and heated to, and keeps constant temperature, is completely dissolved material, the 0.2g EDTA- bis- dissolved with a small amount of water is added
Sodium stirs evenly；
(2) 18g triethanolamine, 3g ethyl alcohol and 18g water are mixed and is heated to 55~65 DEG C as second material, constant temperature, for use；
(3) second material is slowly added into material, is slowly stirred, 70~80 DEG C of constant temperature are saponified 15~20 minutes, obtain soap lye；
(4) 2g dried orange peel extracts, 1g camomile extract, 1g marine algae extract and 1g sucrose are mixed in about 4g water, is added
It into soap lye, stirs evenly, 45~55 DEG C keep the temperature 10~15 minutes；
(5) soap lye for obtaining step (4) sprays a small amount of ethyl alcohol, is then injected into mold, and fast cooling is freezed to 30 DEG C, coagulates
Knot.
Test case 1:
The amino acid soap containing dried orange peel extracts of embodiment 1-3 preparation is being tested for the property, obtained performance test data
It is as follows:
The performance test data of the amino acid soap containing dried orange peel extracts of 4 embodiment 1-3 of table
According to the physical and chemical index (QBT 2485-2008) of soap, as can be seen from Table 4, amino of the present invention containing dried orange peel extracts
Sour soap thoroughly is weakly acidic, and close to the normal ph of skin, and conventional toilet soaps are in alkalinity.Amino acid transparent soap foam of the invention is rich
Richness is free of alkaline matter, chlorine and phosphorus, and more mildly, environmental protection, decontamination while has both skin-care effect, be used for a long time it is highly-safe,
Skin effect is good.
Test case 2:
The effect of evaluating the soap of amino acid containing dried orange peel extracts of embodiment 1-3 using points-scoring system.Experimental subjects be 18 at the age
~40 years old 40 volunteers, every group of 10 people, male to female ratio 1:1 try out position face, are arbitrarily 3 groups of experimental groups and 1 group pair
According to group, washed one's face sooner or later using common facial soap daily within control group 30 days, containing for embodiment 1-3 is respectively adopted in experimental group sooner or later daily
Dried orange peel extracts amino acid is soaped face, uses 30 days altogether.Every using effect scoring total score is 5 points, and 5 points are best result, table
Show preferably, it is very satisfied；4 points are fine；3 points are that can receive；2 points to be bad, cannot receive；1 point to be very bad, completely not
It can endure.As a result it see the table below:
As can be seen from the above table, amino acid soap of the present invention containing dried orange peel extracts has excellent decontamination as common facial soap
Power, but amino acid milder of the present invention containing dried orange peel extracts, tight feeling and the satisfaction of stimulation degree are apparently higher than general after flushing
Logical facial soap, but also the ability with good moisture retention, alimentary, anti-inflammatory antiallergic and after-sun recovery.
Claims (9)
1. a kind of amino acid soap containing dried orange peel extracts, which is characterized in that the raw material including following weight fraction:
N- acylamino acid: 30~40%；
Triethanolamine: 18~25%；
Ethyl alcohol: 6~12%；
Polyalcohol: 5~10%；
Sucrose: 1~2%；
Dried orange peel extracts: 2~5%；
Surplus is water；
The weight percentage of flavones is 70~95% in the dried orange peel extracts.
2. the amino acid soap according to claim 1 containing dried orange peel extracts, it is characterized in that: the preparation of the dried orange peel extracts
The following steps are included:
(1) weigh and crush dried orange peel: claim dried orange peel is crushed, sieving；
(2) it extracts: smashed dried orange peel in step (1) being added in Extraction solvent and is impregnated, and dried orange peel and Extraction solvent is added
The citric acid of gross mass 0.1~0.5%, while being aided with ultrasound, and be heated to 50~60 DEG C and extract, extraction 2~3 times, every time
2~3h, filtering, filtrate merge, be concentrated under reduced pressure into Extraction solvent amount be 10%~20% when, obtain filtrate；
(3) dry: filtrate obtained in step (2) is freeze-dried to get dried orange peel extracts.
3. the amino acid soap according to claim 2 containing dried orange peel extracts, it is characterized in that: the Extraction solvent is quality point
Number combines for 30~50% one or both of ethyl alcohol, ethylene glycol, propylene glycol.
4. the amino acid soap according to claim 1 containing dried orange peel extracts, it is characterized in that: the N- acylamino acid is the moon
Osmanthus acyl glutamic acid, cocoyl propyl glutamic acid, cocounut oil acyl glutamic acid, lauroyl aspartic acid, fatty acyl sarcosines, lauroyl rely
At least one of propylhomoserin, myristoyl glutamic acid.
5. the amino acid soap according to claim 1 containing dried orange peel extracts, it is characterized in that: the ammonia containing dried orange peel extracts
Base acid soap further includes the plant extracts of 1~5 parts by weight.
6. the amino acid soap according to claim 5 containing dried orange peel extracts, it is characterized in that: the plant extracts is green tea
Extract, camomile extract, Herba Saussureae Involueratae extract, aloe extract, purslane extract, mulberry root bark extract, ginseng mention
Take at least one of object, Herba Lysimachiae foenumgraeci extract, gadol extract, Astragalus Root P.E, marine algae extract.
7. the amino acid soap according to claim 1 containing dried orange peel extracts, it is characterized in that: the polyalcohol be ethylene glycol,
At least one of propylene glycol, dipropylene glycol, butanediol, glycerine, pentaerythrite, xylitol, sorbierite.
8. the amino acid soap according to claim 1 containing dried orange peel extracts, it is characterized in that: the ammonia containing dried orange peel extracts
Base acid soap further includes at least one of urea, trehalose, EDTA-2Na of 1~5 parts by weight.
9. a kind of preparation method of the amino acid soap containing dried orange peel extracts according to claim 1, which is characterized in that including with
Lower step:
(1) materials such as N- acylamino acid, part ethyl alcohol, polyalcohol are mixed and is used as material, be stirred and heated to 70~80 DEG C, and
Constant temperature is kept, material is completely dissolved；
(2) triethanolamine, remaining second alcohol and water are mixed and is heated to 55~65 DEG C as second material, constant temperature, for use；
(3) second material is slowly added into material, is slowly stirred, 70~80 DEG C of constant temperature are saponified 5~20 minutes, obtain soap lye；
(4) dried orange peel extracts and sucrose are added in soap lye, are stirred evenly, 45~55 DEG C keep the temperature 10~15 minutes；
(5) soap lye for obtaining step (4) sprays a small amount of ethyl alcohol, is then injected into mold, and fast cooling is freezed to 30 DEG C, coagulates
Knot.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158973.2A CN109370785B (en) | 2018-09-30 | 2018-09-30 | Amino acid soap containing dried orange peel extract and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811158973.2A CN109370785B (en) | 2018-09-30 | 2018-09-30 | Amino acid soap containing dried orange peel extract and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109370785A true CN109370785A (en) | 2019-02-22 |
| CN109370785B CN109370785B (en) | 2021-02-05 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110251428A (en) * | 2019-06-10 | 2019-09-20 | 江门职业技术学院 | A kind of solid amino acid cleansing product and preparation method thereof |
| CN111234963A (en) * | 2020-03-12 | 2020-06-05 | 象鼻山香(杭州)生物科技有限公司 | Miao soap and its making method |
| CN112121731A (en) * | 2020-10-15 | 2020-12-25 | 崔万哲 | Washing article and preparation method thereof |
| CN115418283A (en) * | 2022-07-05 | 2022-12-02 | 济宁医学院 | Skin-care liquid soap and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062731A (en) * | 2015-08-20 | 2015-11-18 | 广州栋方生物科技股份有限公司 | Fermented-shea-butter amino acid transparent soap |
| CN105769730A (en) * | 2016-03-16 | 2016-07-20 | 广州市香事文化传播有限公司 | Agilawood pearl amino acid soap and preparation method thereof |
| CN106728213A (en) * | 2017-04-06 | 2017-05-31 | 广州市嘛咪食品有限公司 | A kind of dried orange peel extracts and its preparation method and application |
| CN107384597A (en) * | 2017-07-25 | 2017-11-24 | 北京斯利安药业有限公司 | A kind of amino acid soap and preparation method thereof |
| CN108125869A (en) * | 2018-02-01 | 2018-06-08 | 江门职业技术学院 | Dried orange peel general flavone and its application in cosmetics are extracted from dried orange peel using ultrasonic wave auxiliary law |
-
2018
- 2018-09-30 CN CN201811158973.2A patent/CN109370785B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062731A (en) * | 2015-08-20 | 2015-11-18 | 广州栋方生物科技股份有限公司 | Fermented-shea-butter amino acid transparent soap |
| CN105769730A (en) * | 2016-03-16 | 2016-07-20 | 广州市香事文化传播有限公司 | Agilawood pearl amino acid soap and preparation method thereof |
| CN106728213A (en) * | 2017-04-06 | 2017-05-31 | 广州市嘛咪食品有限公司 | A kind of dried orange peel extracts and its preparation method and application |
| CN107384597A (en) * | 2017-07-25 | 2017-11-24 | 北京斯利安药业有限公司 | A kind of amino acid soap and preparation method thereof |
| CN108125869A (en) * | 2018-02-01 | 2018-06-08 | 江门职业技术学院 | Dried orange peel general flavone and its application in cosmetics are extracted from dried orange peel using ultrasonic wave auxiliary law |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110251428A (en) * | 2019-06-10 | 2019-09-20 | 江门职业技术学院 | A kind of solid amino acid cleansing product and preparation method thereof |
| CN111234963A (en) * | 2020-03-12 | 2020-06-05 | 象鼻山香(杭州)生物科技有限公司 | Miao soap and its making method |
| CN112121731A (en) * | 2020-10-15 | 2020-12-25 | 崔万哲 | Washing article and preparation method thereof |
| CN115418283A (en) * | 2022-07-05 | 2022-12-02 | 济宁医学院 | Skin-care liquid soap and preparation method thereof |
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| CN109370785B (en) | 2021-02-05 |
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Denomination of invention: An amino acid soap containing Chenpi extract and its preparation method Granted publication date: 20210205 Pledgee: Industrial and Commercial Bank of China Limited Jiangmen Xinhui sub branch Pledgor: Guangdong Lingnan Health Ecological Technology Group Co.,Ltd. Registration number: Y2024980002459 |
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