CN109281171A - 一种防断丝织带涂料的制备方法 - Google Patents

一种防断丝织带涂料的制备方法 Download PDF

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CN109281171A
CN109281171A CN201811134848.8A CN201811134848A CN109281171A CN 109281171 A CN109281171 A CN 109281171A CN 201811134848 A CN201811134848 A CN 201811134848A CN 109281171 A CN109281171 A CN 109281171A
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穆得宣
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Anhui Yongxin Ribbon Co Ltd
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

本发明公开一种防断丝织带涂料的制备方法，包括以下操作步骤：（1）将聚合型乳化剂、碳酸氢钠、消泡剂、引发剂加入至去离子水中，混合搅拌均匀后，然后缓慢的向其中加入聚合单体，在氮气保护下，聚合反应后，制得种子乳液；（2）将种子乳液、4,6‑二氯烟酸乙酯、氯甲酸二甘醇酯、异丙醇频哪醇硼酸酯、纳米ATO、去离子水混合搅拌均匀，陈化处理后，制得防断丝织带涂料。本发明制得的织带涂料，能有效的提升织带表面的耐磨、耐氧化性能，同时还能提升织带的手感，提升其表面的细腻度，尤其是本发明制得的织带涂料，能有效的防止织带出现断丝的情况，极大地提升了织带的品质。

Description

一种防断丝织带涂料的制备方法
技术领域
本发明属于织带编织技术领域，具体涉及一种防断丝织带涂料的制备方法。
背景技术
织带是以各种纱线为原料制成狭幅状织物或管状织物，带织物品种繁多，广泛用于服饰、鞋材、箱包、工业、农业、军需、交通运输等各产业部门。但是现有技术中制得的织带，在使用时，存在着容易断丝的技术缺陷，进而严重影响了织带的使用寿命。
发明内容
为了解决上述技术问题，本发明提供一种防断丝织带涂料的制备方法。
本发明是通过以下技术方案实现的。
一种防断丝织带涂料的制备方法，包括以下操作步骤：
（1）按重量份计，将2-5份聚合型乳化剂、0.6-0.8份碳酸氢钠、0.1-0.3份消泡剂、1-4份引发剂加入至90-100份去离子水中，混合搅拌均匀后，然后缓慢的向其中加入55-60份聚合单体，在氮气保护下，将混合物水浴加热至70-75℃后，聚合反应30-40min后，制得种子乳液，其中聚合单体由以下重量份的组分制成：甲基丙烯酸环氧丙酯13-20份、甲基丙烯酸甲酯10-15份、γ-（甲基丙烯酰氧基）丙基三甲氧基硅烷2-7份；
（2）按重量份计，将44-50份种子乳液、1-2份4,6-二氯烟酸乙酯、1-3份氯甲酸二甘醇酯、0.6-0.8份异丙醇频哪醇硼酸酯、0.4-0.7份纳米ATO、9-13份去离子水混合搅拌均匀，陈化处理5-7小时后，制得防断丝织带涂料。
具体地，上述步骤（1）中，消泡剂为乳化硅油，引发剂为过氧化苯甲酸叔丁酯、过氧化叔戊酸叔丁基酯中的任意一种。
具体地，上述步骤（2）中，陈化处理前将混合物水浴加热至40-45℃，陈化过程中维持上述温度。
具体地，上述步骤（2）中，纳米ATO由氧化锡和氧化锑按照质量比为9:1的比例组成。
由以上的技术方案可知，本发明的有益效果是：
本发明制得的织带涂料，能有效的提升织带表面的耐磨、耐氧化性能，同时还能提升织带的手感，提升其表面的细腻度，尤其是本发明制得的织带涂料，能有效的防止织带出现断丝的情况，极大地提升了织带的品质。本发明制得的种子乳液，在织带表面的附着力高，成膜后，能赋予织带表面细腻的手感，同时能在织带表面形成一层较薄的、力学性能优异的膜层，进而有效的防止了织带出现断丝的情况。
具体实施方式
下面通过具体的实施例对本发明进行详细说明，但这些举例性实施方式的用途和目的仅用来例举本发明，并非对本发明的实际保护范围构成任何形式的任何限定，更非将本发明的保护范围局限于此。
实施例1
一种防断丝织带涂料的制备方法，包括以下操作步骤：
（1）按重量份计，将2份聚合型乳化剂、0.6份碳酸氢钠、0.1份消泡剂、1份引发剂加入至90份去离子水中，混合搅拌均匀后，然后缓慢的向其中加入55份聚合单体，在氮气保护下，将混合物水浴加热至70℃后，聚合反应30min后，制得种子乳液，其中聚合单体由以下重量份的组分制成：甲基丙烯酸环氧丙酯13份、甲基丙烯酸甲酯10份、γ-（甲基丙烯酰氧基）丙基三甲氧基硅烷2份；
（2）按重量份计，将44份种子乳液、1份4,6-二氯烟酸乙酯、1份氯甲酸二甘醇酯、0.6-0.8份异丙醇频哪醇硼酸酯、0.4-0.7份纳米ATO、9-13份去离子水混合搅拌均匀，陈化处理5-7小时后，制得防断丝织带涂料。
具体地，上述步骤（1）中，消泡剂为乳化硅油，引发剂为过氧化苯甲酸叔丁酯。
具体地，上述步骤（2）中，陈化处理前将混合物水浴加热至40℃，陈化过程中维持上述温度。
具体地，上述步骤（2）中，纳米ATO由氧化锡和氧化锑按照质量比为9:1的比例组成。
实施例2
一种防断丝织带涂料的制备方法，包括以下操作步骤：
（1）按重量份计，将3份聚合型乳化剂、0.7份碳酸氢钠、0.2份消泡剂、3份引发剂加入至95份去离子水中，混合搅拌均匀后，然后缓慢的向其中加入58份聚合单体，在氮气保护下，将混合物水浴加热至73℃后，聚合反应35min后，制得种子乳液，其中聚合单体由以下重量份的组分制成：甲基丙烯酸环氧丙酯16份、甲基丙烯酸甲酯13份、γ-（甲基丙烯酰氧基）丙基三甲氧基硅烷5份；
（2）按重量份计，将48份种子乳液、1份4,6-二氯烟酸乙酯、2份氯甲酸二甘醇酯、0.7份异丙醇频哪醇硼酸酯、0.6份纳米ATO、11份去离子水混合搅拌均匀，陈化处理6小时后，制得防断丝织带涂料。
具体地，上述步骤（1）中，消泡剂为乳化硅油，引发剂为过氧化苯甲酸叔丁酯。
具体地，上述步骤（2）中，陈化处理前将混合物水浴加热至43℃，陈化过程中维持上述温度。
具体地，上述步骤（2）中，纳米ATO由氧化锡和氧化锑按照质量比为9:1的比例组成。
实施例3
一种防断丝织带涂料的制备方法，包括以下操作步骤：
（1）按重量份计，将5份聚合型乳化剂、0.8份碳酸氢钠、0.3份消泡剂、4份引发剂加入至100份去离子水中，混合搅拌均匀后，然后缓慢的向其中加入60份聚合单体，在氮气保护下，将混合物水浴加热至75℃后，聚合反应40min后，制得种子乳液，其中聚合单体由以下重量份的组分制成：甲基丙烯酸环氧丙酯20份、甲基丙烯酸甲酯15份、γ-（甲基丙烯酰氧基）丙基三甲氧基硅烷7份；
（2）按重量份计，将50份种子乳液、2份4,6-二氯烟酸乙酯、3份氯甲酸二甘醇酯、0.8份异丙醇频哪醇硼酸酯、0.7份纳米ATO、13份去离子水混合搅拌均匀，陈化处理7小时后，制得防断丝织带涂料。
具体地，上述步骤（1）中，消泡剂为乳化硅油，引发剂为过氧化叔戊酸叔丁基酯。
具体地，上述步骤（2）中，陈化处理前将混合物水浴加热至45℃，陈化过程中维持上述温度。
具体地，上述步骤（2）中，纳米ATO由氧化锡和氧化锑按照质量比为9:1的比例组成。
分别用各实施例和对比例的方法制得防断丝织带涂料，然后将其涂刷在腰带用织带表面，查看腰带用织带在使用过程中是否发生断丝的现象，试验结果如表1所示：
表1腰带用织带是否发生断丝现象
由表1可知，本实施例提供的一种防断丝织带涂料的制备方法，能有效的防止织带在使用的过程中出现断丝的现象。
最后说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的宗旨和范围，其均应涵盖在本发明的权利要求范围当中。

Claims (4)

1.一种防断丝织带涂料的制备方法，其特征在于，包括以下操作步骤：
（1）按重量份计，将2-5份聚合型乳化剂、0.6-0.8份碳酸氢钠、0.1-0.3份消泡剂、1-4份引发剂加入至90-100份去离子水中，混合搅拌均匀后，然后缓慢的向其中加入55-60份聚合单体，在氮气保护下，将混合物水浴加热至70-75℃后，聚合反应30-40min后，制得种子乳液，其中聚合单体由以下重量份的组分制成：甲基丙烯酸环氧丙酯13-20份、甲基丙烯酸甲酯10-15份、γ-（甲基丙烯酰氧基）丙基三甲氧基硅烷2-7份；
（2）按重量份计，将44-50份种子乳液、1-2份4,6-二氯烟酸乙酯、1-3份氯甲酸二甘醇酯、0.6-0.8份异丙醇频哪醇硼酸酯、0.4-0.7份纳米ATO、9-13份去离子水混合搅拌均匀，陈化处理5-7小时后，制得防断丝织带涂料。
2.根据权利要求1所述的一种防断丝织带涂料的制备方法，其特征在于，上述步骤（1）中，消泡剂为乳化硅油，引发剂为过氧化苯甲酸叔丁酯、过氧化叔戊酸叔丁基酯中的任意一种。
3.根据权利要求1所述的一种防断丝织带涂料的制备方法，其特征在于，上述步骤（2）中，陈化处理前将混合物水浴加热至40-45℃，陈化过程中维持上述温度。
4.根据权利要求1所述的一种防断丝织带涂料的制备方法，其特征在于，上述步骤（2）中，纳米ATO由氧化锡和氧化锑按照质量比为9:1的比例组成。
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