CN109244588A - 一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 - Google Patents
一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 Download PDFInfo
- Publication number
- CN109244588A CN109244588A CN201811396756.7A CN201811396756A CN109244588A CN 109244588 A CN109244588 A CN 109244588A CN 201811396756 A CN201811396756 A CN 201811396756A CN 109244588 A CN109244588 A CN 109244588A
- Authority
- CN
- China
- Prior art keywords
- lithium
- ternary
- nickel
- cobalt
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 84
- 238000000034 method Methods 0.000 title claims abstract description 57
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 title claims abstract description 29
- 229910052808 lithium carbonate Inorganic materials 0.000 title claims abstract description 29
- 239000002243 precursor Substances 0.000 title claims abstract description 23
- 238000005406 washing Methods 0.000 claims abstract description 21
- 238000001914 filtration Methods 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 61
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 59
- 239000000843 powder Substances 0.000 claims description 43
- 239000000126 substance Substances 0.000 claims description 39
- 239000000047 product Substances 0.000 claims description 31
- 229910017052 cobalt Inorganic materials 0.000 claims description 30
- 239000010941 cobalt Substances 0.000 claims description 30
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 30
- 229910052759 nickel Inorganic materials 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 28
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 28
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 27
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 claims description 25
- 239000004411 aluminium Substances 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 25
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000011575 calcium Substances 0.000 claims description 24
- 229910052791 calcium Inorganic materials 0.000 claims description 22
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 20
- 238000005984 hydrogenation reaction Methods 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 18
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- 239000011777 magnesium Substances 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002893 slag Substances 0.000 claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 13
- 238000000197 pyrolysis Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000011572 manganese Substances 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 10
- 238000001514 detection method Methods 0.000 claims description 10
- 238000005485 electric heating Methods 0.000 claims description 10
- 229910052748 manganese Inorganic materials 0.000 claims description 10
- 230000001376 precipitating effect Effects 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 238000002386 leaching Methods 0.000 claims description 8
- 238000012797 qualification Methods 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 8
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- DDXROPFGVVLFNZ-UHFFFAOYSA-H cobalt(2+) manganese(2+) nickel(2+) tricarbonate Chemical compound [Mn+2].[Co+2].C([O-])([O-])=O.[Ni+2].C([O-])([O-])=O.C([O-])([O-])=O DDXROPFGVVLFNZ-UHFFFAOYSA-H 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000009434 installation Methods 0.000 claims description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000006228 supernatant Substances 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 5
- 150000004985 diamines Chemical class 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 claims description 5
- 229910012375 magnesium hydride Inorganic materials 0.000 claims description 5
- 239000006148 magnetic separator Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910001431 copper ion Inorganic materials 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 4
- -1 iron ion Chemical class 0.000 claims description 4
- 239000012266 salt solution Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
- 239000006230 acetylene black Substances 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 150000004678 hydrides Chemical class 0.000 claims description 3
- 229940099596 manganese sulfate Drugs 0.000 claims description 3
- 235000007079 manganese sulphate Nutrition 0.000 claims description 3
- 239000011702 manganese sulphate Substances 0.000 claims description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 3
- 239000005416 organic matter Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000011775 sodium fluoride Substances 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001424 calcium ion Inorganic materials 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000009938 salting Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 2
- HVTHJRMZXBWFNE-UHFFFAOYSA-J sodium zincate Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Zn+2] HVTHJRMZXBWFNE-UHFFFAOYSA-J 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000005496 tempering Methods 0.000 claims description 2
- 238000012360 testing method Methods 0.000 claims description 2
- 238000004065 wastewater treatment Methods 0.000 claims description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- SOXUFMZTHZXOGC-UHFFFAOYSA-N [Li].[Mn].[Co].[Ni] Chemical compound [Li].[Mn].[Co].[Ni] SOXUFMZTHZXOGC-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000003660 carbonate based solvent Substances 0.000 description 3
- 229920001429 chelating resin Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000013024 sodium fluoride Nutrition 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FSRBKVBHPUPTSP-UHFFFAOYSA-L C([O-])([O-])=O.[Li+].[Mn+2].[Co+2].[Ni+2] Chemical compound C([O-])([O-])=O.[Li+].[Mn+2].[Co+2].[Ni+2] FSRBKVBHPUPTSP-UHFFFAOYSA-L 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- PNEFIWYZWIQKEK-UHFFFAOYSA-N carbonic acid;lithium Chemical compound [Li].OC(O)=O PNEFIWYZWIQKEK-UHFFFAOYSA-N 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000010926 waste battery Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Li | Al | PVDF | 乙炔黑 | 碳酸酯类溶剂 | Ni | Co | Mn | 氧原子 | 其他 |
6.63 | 2.75 | 1.95 | 1.45 | 0.34 | 28.04 | 11.27 | 15.75 | 30.59 | 1.23 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811396756.7A CN109244588B (zh) | 2018-11-22 | 2018-11-22 | 一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811396756.7A CN109244588B (zh) | 2018-11-22 | 2018-11-22 | 一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109244588A true CN109244588A (zh) | 2019-01-18 |
CN109244588B CN109244588B (zh) | 2022-08-23 |
Family
ID=65075707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811396756.7A Active CN109244588B (zh) | 2018-11-22 | 2018-11-22 | 一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109244588B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111129486A (zh) * | 2019-12-27 | 2020-05-08 | 中天新兴材料有限公司 | 锂电池三元正极材料配料方法 |
CN111924897A (zh) * | 2020-08-07 | 2020-11-13 | 厦门厦钨新能源材料股份有限公司 | 锂离子电池材料前驱体及其制备方法 |
CN114950005A (zh) * | 2022-06-29 | 2022-08-30 | 格林爱科(荆门)新能源材料有限公司 | 三元正极前驱体生产再生废液回收系统及回收方法 |
CN115959719A (zh) * | 2023-02-01 | 2023-04-14 | 合肥国轩高科动力能源有限公司 | 正极材料前驱体浆料处理方法及其制备的正极材料 |
WO2024055071A1 (en) * | 2022-09-14 | 2024-03-21 | Gelion Technologies Pty Ltd | A recycling method for recovery of valuable metal elements from waste battery materials |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005026089A (ja) * | 2003-07-02 | 2005-01-27 | Toyota Motor Corp | リチウム電池、その製造方法ならびに処理方法 |
US20110002825A1 (en) * | 2009-07-06 | 2011-01-06 | Nippon Mining & Metals Co., Ltd. | Preparation method of lithium carbonate from lithium-ion secondary battery recovered material |
CN102101701A (zh) * | 2010-12-31 | 2011-06-22 | 湖南邦普循环科技有限公司 | 一种从废钴酸锂中回收钴锂并制备钴酸锂的方法 |
JP2012229481A (ja) * | 2011-04-27 | 2012-11-22 | Japan Metals & Chem Co Ltd | 使用済みリチウムイオン電池類の有価物の分別回収方法 |
CN103958412A (zh) * | 2011-09-15 | 2014-07-30 | 奥若可博有限公司 | 用于从浓锂卤水制备碳酸锂的方法 |
CN104868190A (zh) * | 2015-05-13 | 2015-08-26 | 中国科学院过程工程研究所 | 一种锂离子电池正极废料中金属的浸出及回收方法 |
KR101823952B1 (ko) * | 2016-10-28 | 2018-01-31 | 타운마이닝리소스주식회사 | 리튬이온 2차전지의 폐 양극재로부터 리튬을 회수하여 탄산리튬을 제조하는 방법 |
CN107768764A (zh) * | 2017-10-19 | 2018-03-06 | 湖北碧拓新材料科技有限公司 | 一种废旧锂离子电池回收制作三元前驱体工艺 |
CN108002408A (zh) * | 2016-10-31 | 2018-05-08 | 湖南金源新材料股份有限公司 | 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法 |
WO2018181816A1 (ja) * | 2017-03-31 | 2018-10-04 | Jx金属株式会社 | リチウムイオン電池スクラップの処理方法 |
-
2018
- 2018-11-22 CN CN201811396756.7A patent/CN109244588B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005026089A (ja) * | 2003-07-02 | 2005-01-27 | Toyota Motor Corp | リチウム電池、その製造方法ならびに処理方法 |
US20110002825A1 (en) * | 2009-07-06 | 2011-01-06 | Nippon Mining & Metals Co., Ltd. | Preparation method of lithium carbonate from lithium-ion secondary battery recovered material |
CN102101701A (zh) * | 2010-12-31 | 2011-06-22 | 湖南邦普循环科技有限公司 | 一种从废钴酸锂中回收钴锂并制备钴酸锂的方法 |
JP2012229481A (ja) * | 2011-04-27 | 2012-11-22 | Japan Metals & Chem Co Ltd | 使用済みリチウムイオン電池類の有価物の分別回収方法 |
CN103958412A (zh) * | 2011-09-15 | 2014-07-30 | 奥若可博有限公司 | 用于从浓锂卤水制备碳酸锂的方法 |
CN104868190A (zh) * | 2015-05-13 | 2015-08-26 | 中国科学院过程工程研究所 | 一种锂离子电池正极废料中金属的浸出及回收方法 |
KR101823952B1 (ko) * | 2016-10-28 | 2018-01-31 | 타운마이닝리소스주식회사 | 리튬이온 2차전지의 폐 양극재로부터 리튬을 회수하여 탄산리튬을 제조하는 방법 |
CN108002408A (zh) * | 2016-10-31 | 2018-05-08 | 湖南金源新材料股份有限公司 | 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法 |
WO2018181816A1 (ja) * | 2017-03-31 | 2018-10-04 | Jx金属株式会社 | リチウムイオン電池スクラップの処理方法 |
CN107768764A (zh) * | 2017-10-19 | 2018-03-06 | 湖北碧拓新材料科技有限公司 | 一种废旧锂离子电池回收制作三元前驱体工艺 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111129486A (zh) * | 2019-12-27 | 2020-05-08 | 中天新兴材料有限公司 | 锂电池三元正极材料配料方法 |
CN111129486B (zh) * | 2019-12-27 | 2021-05-14 | 中天新兴材料有限公司 | 锂电池三元正极材料配料方法 |
CN111924897A (zh) * | 2020-08-07 | 2020-11-13 | 厦门厦钨新能源材料股份有限公司 | 锂离子电池材料前驱体及其制备方法 |
CN114950005A (zh) * | 2022-06-29 | 2022-08-30 | 格林爱科(荆门)新能源材料有限公司 | 三元正极前驱体生产再生废液回收系统及回收方法 |
WO2024055071A1 (en) * | 2022-09-14 | 2024-03-21 | Gelion Technologies Pty Ltd | A recycling method for recovery of valuable metal elements from waste battery materials |
CN115959719A (zh) * | 2023-02-01 | 2023-04-14 | 合肥国轩高科动力能源有限公司 | 正极材料前驱体浆料处理方法及其制备的正极材料 |
CN115959719B (zh) * | 2023-02-01 | 2024-04-09 | 合肥国轩高科动力能源有限公司 | 正极材料前驱体浆料处理方法及其制备的正极材料 |
Also Published As
Publication number | Publication date |
---|---|
CN109244588B (zh) | 2022-08-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109244588A (zh) | 一种废三元锂电池生产三元前驱体和高纯碳酸锂的方法 | |
CN109088115B (zh) | 废旧锂离子电池正极材料循环利用制备三元正极材料方法 | |
CN107994288B (zh) | 废旧镍钴锰酸锂三元电池正极材料中有价金属回收方法 | |
CN110783658B (zh) | 一种退役动力三元锂电池回收示范工艺方法 | |
CN107653378A (zh) | 一种废旧镍钴锰锂离子电池中有价金属的回收方法 | |
CN101831548B (zh) | 一种自废旧锰酸锂电池中回收有价金属的方法 | |
CN108878866A (zh) | 利用废旧锂离子电池三元正极材料制备三元材料前驱体及回收锂的方法 | |
CN109650415B (zh) | 一种从报废的磷酸铁锂电池正极粉中提取碳酸锂的方法 | |
CN107419096B (zh) | 一种废旧锂电池回收再生三元正极材料的制备方法 | |
KR20210031459A (ko) | 폐 리튬 이온 전지의 재활용 방법 | |
CN106129511A (zh) | 一种从废旧锂离子电池材料中综合回收有价金属的方法 | |
CN104538696A (zh) | 从镍钴锰酸锂正极材料的废锂离子电池中回收金属的方法 | |
CN108011150A (zh) | 一种从废旧三元锂离子电池电极粉料中制取碳酸锂的方法 | |
CN109439907A (zh) | 一种从回收废锂离子电池过程中的酸浸液中除铁铝的方法 | |
WO2015195454A1 (en) | Systems and methods for the hydrometallurgical recovery of lead from spent lead-acid batteries and the preparation of lead oxide for use in new lead-acid batteries | |
CN106186445A (zh) | 一种钢丝绳酸洗废酸和含高锌、铅污泥共处置系统及工艺 | |
CN104466294A (zh) | 从镍钴锰酸锂废电池中回收金属的方法 | |
CN107046154B (zh) | 一种废三元锂电池强化还原浸出的方法 | |
CN114031099B (zh) | 一种高效处理铝电解固体废弃物的酸化焙烧方法 | |
CN104485493A (zh) | 废锂离子电池中钴酸锂正极活性材料的修复再生方法 | |
CN110092398A (zh) | 一种废旧锂离子电池焙烧尾气资源化利用的方法 | |
JP6648674B2 (ja) | 金属マンガンの製造方法 | |
CN109609761A (zh) | 一种废旧锂离子电池的回收方法 | |
CN114317977B (zh) | 从废旧钴酸锂电池中回收金属的方法 | |
CN104466293A (zh) | 锂离子电池正极材料钴酸锂废料的再生方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20201012 Address after: 415400 Hunan city of Changde Province Jin City Industrial Zone tuanhu Lake Avenue Applicant after: HUNAN TIANTAI TIANRUN NEW ENERGY TECHNOLOGY Co.,Ltd. Address before: 419400 Copper Mine Dormitory in Mayang Miao Autonomous County, Huaihua City, Hunan Province Applicant before: Tan Chunbo |
|
TA01 | Transfer of patent application right | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Method for Producing Ternary Precursors and High Purity Lithium Carbonate from Waste Ternary Lithium Batteries Effective date of registration: 20231027 Granted publication date: 20220823 Pledgee: Hunan Jinshi Rural Commercial Bank Co.,Ltd. Yaopodu Sub branch Pledgor: HUNAN TIANTAI TIANRUN NEW ENERGY TECHNOLOGY CO.,LTD. Registration number: Y2023980062988 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |