CN1091649C - 制备羧酸盐和用于这种方法的催化剂的方法 - Google Patents

制备羧酸盐和用于这种方法的催化剂的方法 Download PDF

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Publication number
CN1091649C
CN1091649C CN95194794A CN95194794A CN1091649C CN 1091649 C CN1091649 C CN 1091649C CN 95194794 A CN95194794 A CN 95194794A CN 95194794 A CN95194794 A CN 95194794A CN 1091649 C CN1091649 C CN 1091649C
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CN
China
Prior art keywords
catalyst
copper
metal
hydroxide
monoethanolamine
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Expired - Fee Related
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CN95194794A
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English (en)
Chinese (zh)
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CN1156419A (zh
Inventor
J·R·艾伯纳
T·S·弗朗斯克
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Monsanto Technology LLC
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Monsanto Technology LLC
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Publication of CN1156419A publication Critical patent/CN1156419A/zh
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Publication of CN1091649C publication Critical patent/CN1091649C/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN95194794A 1994-07-01 1995-05-26 制备羧酸盐和用于这种方法的催化剂的方法 Expired - Fee Related CN1091649C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US26971894A 1994-07-01 1994-07-01
US08/269,718 1994-07-01
US08/407,723 1995-03-20
US08/407,723 US5689000A (en) 1994-07-01 1995-03-20 Process for preparing carboxylic acid salts and catalysts useful in such process

Publications (2)

Publication Number Publication Date
CN1156419A CN1156419A (zh) 1997-08-06
CN1091649C true CN1091649C (zh) 2002-10-02

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ID=26953850

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95194794A Expired - Fee Related CN1091649C (zh) 1994-07-01 1995-05-26 制备羧酸盐和用于这种方法的催化剂的方法

Country Status (23)

Country Link
US (2) US5689000A (https=)
EP (1) EP0768917B1 (https=)
JP (1) JPH10501728A (https=)
KR (1) KR970703816A (https=)
CN (1) CN1091649C (https=)
AT (1) ATE173956T1 (https=)
AU (1) AU711349B2 (https=)
BR (1) BR9508163A (https=)
CA (1) CA2193989C (https=)
DE (1) DE69506412T2 (https=)
DK (1) DK0768917T3 (https=)
ES (1) ES2126290T3 (https=)
GR (1) GR3029541T3 (https=)
HU (1) HUT76751A (https=)
IL (1) IL114412A (https=)
MX (1) MX206593B (https=)
MY (1) MY112727A (https=)
NZ (1) NZ288027A (https=)
PL (1) PL179923B1 (https=)
RU (1) RU2157727C2 (https=)
TW (1) TW449502B (https=)
UA (1) UA46736C2 (https=)
WO (1) WO1996001146A1 (https=)

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US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
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CN100393683C (zh) * 2000-08-18 2008-06-11 因维斯塔技术有限公司 选择性氧化用金催化剂
EP1401763B2 (en) * 2001-07-03 2010-02-10 Facultés Universitaires Notre-Dame de la Paix Catalyst supports and carbon nanotubes produced thereon
MX244781B (es) 2001-10-18 2007-04-03 Monsanto Technology Llc Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico.
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
DE10161674A1 (de) * 2001-12-14 2003-06-26 Basf Ag Katalysatoren zur Herstellung von Carbonsäuresalzen
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
MX261990B (es) * 2002-02-14 2008-11-07 Monsanto Technology Llc Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo.
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US7375053B2 (en) * 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
CN102276644B (zh) 2003-08-14 2014-09-03 孟山都技术公司 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途
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CN101529075B (zh) * 2006-06-13 2012-07-18 孟山都技术公司 重整醇动力系统
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CN111153788A (zh) * 2018-11-08 2020-05-15 中国科学院大连化学物理研究所 一种有机醇脱氢反应制备有机酸的方法、有机醇脱氢反应热力学可控调节的方法
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US5292936A (en) * 1993-04-12 1994-03-08 Monsanto Company Process to prepare amino carboxylic acid salts

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GB2148287A (en) * 1983-10-05 1985-05-30 Nippon Catalytic Chem Ind Preparation of aminocarboxylic acid salts from amino alcohols
WO1992009559A1 (fr) * 1990-11-27 1992-06-11 Nippon Shokubai Co., Ltd. Procede de production de sel d'acide carboxylique
US5292936A (en) * 1993-04-12 1994-03-08 Monsanto Company Process to prepare amino carboxylic acid salts

Also Published As

Publication number Publication date
JPH10501728A (ja) 1998-02-17
AU2692695A (en) 1996-01-25
ATE173956T1 (de) 1998-12-15
RU2157727C2 (ru) 2000-10-20
CA2193989C (en) 2006-11-14
DE69506412T2 (de) 1999-06-24
ES2126290T3 (es) 1999-03-16
EP0768917A1 (en) 1997-04-23
WO1996001146A1 (en) 1996-01-18
BR9508163A (pt) 1997-12-23
UA46736C2 (uk) 2002-06-17
PL317849A1 (en) 1997-04-28
HU9603630D0 (en) 1997-02-28
HUT76751A (en) 1997-11-28
AU711349B2 (en) 1999-10-14
NZ288027A (en) 1998-11-25
IL114412A (en) 1999-06-20
TW449502B (en) 2001-08-11
PL179923B1 (pl) 2000-11-30
DK0768917T3 (da) 1999-08-16
IL114412A0 (en) 1995-10-31
GR3029541T3 (en) 1999-06-30
CA2193989A1 (en) 1996-01-18
EP0768917B1 (en) 1998-12-02
MY112727A (en) 2001-08-30
KR970703816A (https=) 1997-08-09
MX9700060A (es) 1997-04-30
CN1156419A (zh) 1997-08-06
US5627125A (en) 1997-05-06
US5689000A (en) 1997-11-18
DE69506412D1 (de) 1999-01-14
MX206593B (es) 2002-02-08

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