AU711349B2 - Process for preparing carboxylic acid salts and catalysts useful in such process - Google Patents

Process for preparing carboxylic acid salts and catalysts useful in such process Download PDF

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Publication number
AU711349B2
AU711349B2 AU26926/95A AU2692695A AU711349B2 AU 711349 B2 AU711349 B2 AU 711349B2 AU 26926/95 A AU26926/95 A AU 26926/95A AU 2692695 A AU2692695 A AU 2692695A AU 711349 B2 AU711349 B2 AU 711349B2
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AU
Australia
Prior art keywords
catalyst
metal
catalytically active
anchor metal
anchor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU26926/95A
Other languages
English (en)
Other versions
AU2692695A (en
Inventor
Jerry Rudolph Ebner
Thaddeus Stephan Franczyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of AU2692695A publication Critical patent/AU2692695A/en
Application granted granted Critical
Publication of AU711349B2 publication Critical patent/AU711349B2/en
Assigned to MONSANTO TECHNOLOGY LLC reassignment MONSANTO TECHNOLOGY LLC Alteration of Name(s) in Register under S187 Assignors: MONSANTO COMPANY
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU26926/95A 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process Ceased AU711349B2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US26971894A 1994-07-01 1994-07-01
US08/269718 1994-07-01
US08/407,723 US5689000A (en) 1994-07-01 1995-03-20 Process for preparing carboxylic acid salts and catalysts useful in such process
US08/407723 1995-03-20
PCT/US1995/006754 WO1996001146A1 (en) 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process

Publications (2)

Publication Number Publication Date
AU2692695A AU2692695A (en) 1996-01-25
AU711349B2 true AU711349B2 (en) 1999-10-14

Family

ID=26953850

Family Applications (1)

Application Number Title Priority Date Filing Date
AU26926/95A Ceased AU711349B2 (en) 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process

Country Status (23)

Country Link
US (2) US5689000A (https=)
EP (1) EP0768917B1 (https=)
JP (1) JPH10501728A (https=)
KR (1) KR970703816A (https=)
CN (1) CN1091649C (https=)
AT (1) ATE173956T1 (https=)
AU (1) AU711349B2 (https=)
BR (1) BR9508163A (https=)
CA (1) CA2193989C (https=)
DE (1) DE69506412T2 (https=)
DK (1) DK0768917T3 (https=)
ES (1) ES2126290T3 (https=)
GR (1) GR3029541T3 (https=)
HU (1) HUT76751A (https=)
IL (1) IL114412A (https=)
MX (1) MX206593B (https=)
MY (1) MY112727A (https=)
NZ (1) NZ288027A (https=)
PL (1) PL179923B1 (https=)
RU (1) RU2157727C2 (https=)
TW (1) TW449502B (https=)
UA (1) UA46736C2 (https=)
WO (1) WO1996001146A1 (https=)

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WO1994024091A1 (en) * 1993-04-12 1994-10-27 Monsanto Company Process to prepare amino carboxylic acid salts
US5916840A (en) * 1994-07-01 1999-06-29 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
JP2001501130A (ja) * 1996-09-26 2001-01-30 アクゾ ノーベル ナムローゼ フェンノートシャップ アミノアルコールをアミノカルボン酸へと脱水素するかまたはエチレングリコール（誘導体）をオキシカルボン酸へと脱水素するための触媒、その製造法および該触媒の使用
DE19644107A1 (de) * 1996-10-31 1998-05-07 Basf Ag Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
CN1210283C (zh) * 1998-02-12 2005-07-13 孟山都技术有限责任公司 通过氧化n－取代的草甘膦制备草甘膦的方法
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
ITTO980249A1 (it) * 1998-03-23 1999-09-23 Finchimica Srl Procedimento per la preparazione di sali di acidi carbossilici
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
AR043078A1 (es) 1998-09-14 2005-07-20 Dow Agrosciences Llc Procesos para preparar acidos carboxilicos
DK1173406T3 (da) 1999-05-03 2007-01-08 Monsanto Technology Llc Fremgangsmåde til fremstilling af carboxylsyresalte ud fra primære alkoholer
US6414188B1 (en) * 1999-07-05 2002-07-02 Atanor S.A. Method of preparing amino-, imino-, and nitrilocarboxylic acids and silver-promoted copper catalyst for use in said method
EP1505071B1 (en) 1999-12-21 2008-02-13 Monsanto Technology LLC Use of a supplemental promoter in conjunction with a carbon-supported, noble metal containing catalyst in liquid phase oxidation reactions
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EP1125634B1 (de) 2000-02-18 2010-12-08 Evonik Degussa GmbH Geformter Festbettraney-Kupferkatalysator
US20020038051A1 (en) * 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
AU2001264605C1 (en) 2000-05-15 2005-10-06 Monsanto Technology Llc Preparation of iminodiacetic acid compounds from monoethanolamine substrates
DE60115019T2 (de) 2000-05-22 2006-08-03 Monsanto Technology Llc. Reaktionssysteme zur herstellung von n-(phosphonomethyl)glyzin verbindungen
MY122994A (en) 2000-07-03 2006-05-31 Shell Int Research Catalyst and process fo rthe preparation of hydrocarbons
AU2000267914A1 (en) * 2000-08-18 2002-03-04 E.I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
JP4068056B2 (ja) * 2001-07-03 2008-03-26 ファキュルテ ユニヴェルシテール ノートル−ダム ド ラ ペ 触媒担体およびその上で生成されたカーボンナノチューブ
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DE10161674A1 (de) * 2001-12-14 2003-06-26 Basf Ag Katalysatoren zur Herstellung von Carbonsäuresalzen
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
BRPI0307672B1 (pt) * 2002-02-14 2015-12-22 Monsanto Technology Llc processo para a oxidação de aminas terciárias
EP1551755A1 (en) * 2002-10-18 2005-07-13 Monsanto Technology LLC Use of metal supported copper catalysts for reforming alcohols
US6992039B2 (en) * 2003-03-13 2006-01-31 General Motors Corporation Method for making monodispersed noble metal nanoparticles supported on oxide substrates
US7375053B2 (en) * 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
AU2004264436B2 (en) * 2003-08-14 2010-11-25 Monsanto Technology Llc Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts
MXPA06002111A (es) * 2003-08-22 2006-05-31 Monsanto Technology Llc Procedimiento para preparar n-fosfonometilglicina y sus derivados.
DE10349095A1 (de) 2003-10-17 2005-05-19 Basf Ag Verfahren zur Herstellung von Aminen
US20050100494A1 (en) 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US7304011B2 (en) * 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
AR051926A1 (es) * 2004-09-15 2007-02-21 Monsanto Technology Llc Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma
JP2006142137A (ja) * 2004-11-16 2006-06-08 Nissan Motor Co Ltd 排ガス浄化用触媒及びその製造方法
AU2006214086B2 (en) * 2005-02-17 2012-01-19 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
JP5383184B2 (ja) 2005-04-27 2014-01-08 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 流動接触分解時にＮＯｘ排出物を低減する組成物および方法
DE102005041532A1 (de) 2005-08-31 2007-03-01 Basf Ag Verfahren zur Herstellung von Aminen
WO2007098432A2 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts
RU2451800C2 (ru) * 2006-06-13 2012-05-27 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ получения механической или электрической энергии из топлива, содержащего спирт
CN101802263A (zh) 2007-09-13 2010-08-11 维罗西股份有限公司 多孔化学镀沉积涂层
US20090264283A1 (en) * 2008-04-16 2009-10-22 Basf Catalysts Llc Stabilized Iridium and Ruthenium Catalysts
US20090263300A1 (en) * 2008-04-16 2009-10-22 Yang Xiaolin D Stabilized Iridium and Ruthenium Catalysts
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
US20110011772A1 (en) * 2009-07-15 2011-01-20 Stephen Raymond Schmidt Nickel and Cobalt Plated Sponge Catalysts
US8309759B2 (en) 2010-02-19 2012-11-13 Basf Se Preparing ether carboxylates
KR101802915B1 (ko) 2010-02-19 2017-11-30 바스프 에스이 에테르 카르복실레이트의 제조 방법
US9062278B2 (en) 2010-02-19 2015-06-23 Basf Se Preparing ether carboxylates
CN102762529B (zh) 2010-02-19 2016-12-21 巴斯夫欧洲公司 制备醚羧酸盐的方法
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US10450193B2 (en) 2012-03-30 2019-10-22 Monsanto Technology Llc Alcohol reformer for reforming alcohol to mixture of gas including hydrogen
CN111153788A (zh) * 2018-11-08 2020-05-15 中国科学院大连化学物理研究所 一种有机醇脱氢反应制备有机酸的方法、有机醇脱氢反应热力学可控调节的方法
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CN116419915A (zh) * 2021-01-15 2023-07-11 巴斯夫欧洲公司 制备羧酸的方法
CN116144009B (zh) * 2022-12-22 2025-02-11 上海发凯化工有限公司 一种聚乙二醇二羧酸的制备方法

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US4782183A (en) * 1983-10-05 1988-11-01 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for manufacture of amino-carboxylic acid salts
US4810426A (en) * 1986-01-28 1989-03-07 Monsanto Company Process for making glyphosate from n-phosphonomethyl-2-oxazolidone
EP0513396A1 (en) * 1990-11-27 1992-11-19 Nippon Shokubai Co., Ltd. Process for producing amino carboxylic acid salt

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US4782183A (en) * 1983-10-05 1988-11-01 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for manufacture of amino-carboxylic acid salts
US4810426A (en) * 1986-01-28 1989-03-07 Monsanto Company Process for making glyphosate from n-phosphonomethyl-2-oxazolidone
EP0513396A1 (en) * 1990-11-27 1992-11-19 Nippon Shokubai Co., Ltd. Process for producing amino carboxylic acid salt

Also Published As

Publication number Publication date
PL179923B1 (pl) 2000-11-30
HU9603630D0 (en) 1997-02-28
DE69506412T2 (de) 1999-06-24
IL114412A0 (en) 1995-10-31
MX206593B (es) 2002-02-08
AU2692695A (en) 1996-01-25
WO1996001146A1 (en) 1996-01-18
JPH10501728A (ja) 1998-02-17
ES2126290T3 (es) 1999-03-16
PL317849A1 (en) 1997-04-28
GR3029541T3 (en) 1999-06-30
KR970703816A (https=) 1997-08-09
MX9700060A (es) 1997-04-30
ATE173956T1 (de) 1998-12-15
UA46736C2 (uk) 2002-06-17
HUT76751A (en) 1997-11-28
IL114412A (en) 1999-06-20
EP0768917B1 (en) 1998-12-02
DE69506412D1 (de) 1999-01-14
RU2157727C2 (ru) 2000-10-20
CN1156419A (zh) 1997-08-06
MY112727A (en) 2001-08-30
EP0768917A1 (en) 1997-04-23
US5689000A (en) 1997-11-18
BR9508163A (pt) 1997-12-23
CN1091649C (zh) 2002-10-02
CA2193989A1 (en) 1996-01-18
DK0768917T3 (da) 1999-08-16
CA2193989C (en) 2006-11-14
US5627125A (en) 1997-05-06
TW449502B (en) 2001-08-11
NZ288027A (en) 1998-11-25

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