CN1090607C - 炔属不饱和化合物羰基化的方法 - Google Patents
炔属不饱和化合物羰基化的方法 Download PDFInfo
- Publication number
- CN1090607C CN1090607C CN97193382A CN97193382A CN1090607C CN 1090607 C CN1090607 C CN 1090607C CN 97193382 A CN97193382 A CN 97193382A CN 97193382 A CN97193382 A CN 97193382A CN 1090607 C CN1090607 C CN 1090607C
- Authority
- CN
- China
- Prior art keywords
- catalyst system
- phosphine
- acetylenically unsaturated
- carbonylation
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
实施例 | b)@(mmole) | d)#(mmole) | c)(mmole) | 丙二烯(%) | T(℃) | 操作时间(hr) | 反应速率(mol/mol.小时) | MMA选择性(%) |
A(对比)B(对比)C(对比)D(对比)E(对比)F(对比)12345678 | -PN(1)6-Cl-PN(1)6-Cl-PN(1)PN(1)6-Me-PN(1)PN(1)PN(0.5)PN(0.25)PN(1)PN(1)6-Cl-PN(1)6-Bu-PN(1)2,6-DPPN(0.25) | PPh3(4)----二甲基-对甲苯胺(10)PPh3(2)PPh3(3.5)PPh3(3.75)P(m-ClPh)3(3)P(p-MeOPh)3(3)PPh3(3)PPh3(3)PPh3(3.75) | MSA(4)MSA(2)TMSA(2)TMSA(2)TMSA(2)MSA(2)MSA(2)MSA(4)MSA(4)MSA(4)MSA(4)MSA(4)MSA(4)MSA(4) | 3.03.52.22.22.32.03.12.02.85.08.2*3.71.31.3 | 6070457050607060607080806060 | 5.05.00.51.55.05.00.50.51.00.250.250.51.00.5 | <101.00024.0004.0006257.00030.00025.0007.00042.00040.00028.00018.00020.000 | 89.099.299.699.499.099.999.098.899.298.698.999.499.899.8 |
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96200823.1 | 1996-03-26 | ||
EP96200823 | 1996-03-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1214671A CN1214671A (zh) | 1999-04-21 |
CN1090607C true CN1090607C (zh) | 2002-09-11 |
Family
ID=8223816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97193382A Expired - Lifetime CN1090607C (zh) | 1996-03-26 | 1997-03-25 | 炔属不饱和化合物羰基化的方法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5908958A (zh) |
EP (1) | EP0891321B1 (zh) |
JP (1) | JP4087448B2 (zh) |
CN (1) | CN1090607C (zh) |
AT (1) | ATE204253T1 (zh) |
AU (1) | AU717171B2 (zh) |
BR (1) | BR9708579A (zh) |
CA (1) | CA2249992C (zh) |
DE (1) | DE69706156T2 (zh) |
MY (1) | MY116872A (zh) |
TW (1) | TW414789B (zh) |
WO (1) | WO1997035832A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160039308A (ko) * | 2008-03-25 | 2016-04-08 | 수미토모 케미칼 컴퍼니 리미티드 | 알콕시카보닐 화합물의 제조 방법 |
CN102190583A (zh) * | 2010-03-08 | 2011-09-21 | 中国科学院成都有机化学有限公司 | 一种钯膦络合物催化乙炔羰基合成丙烯酸低碳醇酯的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0386833A1 (en) * | 1989-03-03 | 1990-09-12 | Shell Internationale Researchmaatschappij B.V. | Carbonylation catalyst system |
EP0565199A2 (en) * | 1992-04-08 | 1993-10-13 | Shell Internationale Researchmaatschappij B.V. | Carbonylation process using palladium phosphine catalyst |
WO1995005357A1 (en) * | 1993-08-19 | 1995-02-23 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of acetylenically unsaturated compounds |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8432376D0 (en) * | 1984-12-21 | 1985-02-06 | Shell Int Research | Carbonylation of acetylenically unsaturated compounds |
CA1331173C (en) * | 1986-12-05 | 1994-08-02 | Eit Drent | Process for the carbonylation of acetylenically unsaturated compounds |
KR0148012B1 (ko) * | 1989-03-03 | 1998-08-17 | 오노 알버어스 | 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법 |
CA2034971A1 (en) * | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
GB9002521D0 (en) * | 1990-02-05 | 1990-04-04 | Shell Int Research | Carbonylation catalyst system |
-
1997
- 1997-03-13 TW TW086103110A patent/TW414789B/zh not_active IP Right Cessation
- 1997-03-24 MY MYPI97001244A patent/MY116872A/en unknown
- 1997-03-25 DE DE69706156T patent/DE69706156T2/de not_active Expired - Lifetime
- 1997-03-25 CN CN97193382A patent/CN1090607C/zh not_active Expired - Lifetime
- 1997-03-25 BR BR9708579A patent/BR9708579A/pt not_active IP Right Cessation
- 1997-03-25 AT AT97914316T patent/ATE204253T1/de not_active IP Right Cessation
- 1997-03-25 AU AU21605/97A patent/AU717171B2/en not_active Expired
- 1997-03-25 JP JP53404597A patent/JP4087448B2/ja not_active Expired - Lifetime
- 1997-03-25 WO PCT/EP1997/001555 patent/WO1997035832A1/en active IP Right Grant
- 1997-03-25 CA CA002249992A patent/CA2249992C/en not_active Expired - Lifetime
- 1997-03-25 EP EP97914316A patent/EP0891321B1/en not_active Expired - Lifetime
- 1997-03-26 US US08/824,858 patent/US5908958A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0386833A1 (en) * | 1989-03-03 | 1990-09-12 | Shell Internationale Researchmaatschappij B.V. | Carbonylation catalyst system |
EP0565199A2 (en) * | 1992-04-08 | 1993-10-13 | Shell Internationale Researchmaatschappij B.V. | Carbonylation process using palladium phosphine catalyst |
WO1995005357A1 (en) * | 1993-08-19 | 1995-02-23 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of acetylenically unsaturated compounds |
Also Published As
Publication number | Publication date |
---|---|
CA2249992C (en) | 2006-08-01 |
US5908958A (en) | 1999-06-01 |
JP4087448B2 (ja) | 2008-05-21 |
CA2249992A1 (en) | 1997-10-02 |
JP2000507257A (ja) | 2000-06-13 |
ATE204253T1 (de) | 2001-09-15 |
TW414789B (en) | 2000-12-11 |
WO1997035832A1 (en) | 1997-10-02 |
AU717171B2 (en) | 2000-03-16 |
CN1214671A (zh) | 1999-04-21 |
MY116872A (en) | 2004-04-30 |
DE69706156T2 (de) | 2002-04-11 |
AU2160597A (en) | 1997-10-17 |
DE69706156D1 (de) | 2001-09-20 |
BR9708579A (pt) | 1999-08-03 |
EP0891321B1 (en) | 2001-08-16 |
EP0891321A1 (en) | 1999-01-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: INEOS ACRYLICS UK LTD. Free format text: FORMER OWNER: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. Effective date: 20011024 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20011024 Address after: England Hampshire Applicant after: Inois Acrylic Acid British PLC Address before: Holland Hague Applicant before: Shell Internationale Research Maatschappij B. V. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: LUSEAT INTERNATIONAL BRITISH CO., LTD. Free format text: FORMER NAME OR ADDRESS: INEOS ACRYLICS UK LTD. |
|
CP01 | Change in the name or title of a patent holder |
Patentee after: Luxit International Uk Ltd Patentee before: Inois Acrylic Acid British PLC |
|
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20020911 |