CN1090197C - 缩聚反应的改进方法 - Google Patents

缩聚反应的改进方法 Download PDF

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Publication number
CN1090197C
CN1090197C CN97193459A CN97193459A CN1090197C CN 1090197 C CN1090197 C CN 1090197C CN 97193459 A CN97193459 A CN 97193459A CN 97193459 A CN97193459 A CN 97193459A CN 1090197 C CN1090197 C CN 1090197C
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China
Prior art keywords
reactor
melt
inert gas
agitator
polymerization
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Expired - Fee Related
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CN97193459A
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English (en)
Chinese (zh)
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CN1214707A (zh
Inventor
K·K·布哈蒂尔
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Invista Technologies Sarl
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EI Du Pont de Nemours and Co
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Filing date
Publication date
Priority claimed from US08/625,571 external-priority patent/US5677415A/en
Priority claimed from US08/771,494 external-priority patent/US5856423A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1214707A publication Critical patent/CN1214707A/zh
Application granted granted Critical
Publication of CN1090197C publication Critical patent/CN1090197C/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/785—Preparation processes characterised by the apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1887—Stationary reactors having moving elements inside forming a thin film
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2190/00—Compositions for sealing or packing joints

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
CN97193459A 1996-03-28 1997-03-24 缩聚反应的改进方法 Expired - Fee Related CN1090197C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/625,571 1996-03-28
US08/625,571 US5677415A (en) 1996-03-28 1996-03-28 Apparatus and process for a polycondensation reaction
US08/771,494 US5856423A (en) 1996-12-23 1996-12-23 Apparatus and process for a polycondensation reaction
US08/771,494 1996-12-23

Publications (2)

Publication Number Publication Date
CN1214707A CN1214707A (zh) 1999-04-21
CN1090197C true CN1090197C (zh) 2002-09-04

Family

ID=27089954

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97193459A Expired - Fee Related CN1090197C (zh) 1996-03-28 1997-03-24 缩聚反应的改进方法

Country Status (9)

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EP (1) EP0889922B1 (enExample)
JP (1) JP2000508009A (enExample)
CN (1) CN1090197C (enExample)
DE (1) DE69714231T2 (enExample)
ES (1) ES2178772T3 (enExample)
ID (1) ID16492A (enExample)
IN (1) IN191734B (enExample)
PT (1) PT889922E (enExample)
WO (1) WO1997035902A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103237598A (zh) * 2010-10-15 2013-08-07 罗地亚管理公司 反应物间平衡反应化学转化的方法和装置及这类化学转化的至少一参数的测定方法

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100373896B1 (ko) * 1998-06-16 2003-02-26 아사히 가세이 가부시키가이샤 중축합 중합체 제조용 시스템 및 방법
FR2789912B1 (fr) 1999-02-18 2002-12-20 Commissariat Energie Atomique Procede et dispositif de separation a membranes semi-permeables en polyimides sulfones
DE19907861B4 (de) * 1999-02-24 2006-04-13 Basf Coatings Ag Polyadditionsharze, herstellbar durch heterogene Katalyse, Verfahren und Verwendung
NL1017260C2 (nl) * 2001-02-01 2002-08-02 Dsm Nv Reactor en werkwijze voor het continu bereiden van een polyester.
US7135541B2 (en) * 2003-06-06 2006-11-14 Eastman Chemical Company Polyester process using a pipe reactor
DE102005034455B3 (de) * 2005-07-23 2006-11-02 Zimmer Ag Vorrichtung zur Schmelzepolykondensation mit einem Reaktorkäfig
DE102005034456B3 (de) * 2005-07-23 2006-11-02 Zimmer Ag Vorrichtung zur Schmelzepolykondensation mit doppeltem Rotor
DE102006025942B4 (de) * 2006-06-02 2011-07-07 Uhde Inventa-Fischer GmbH & Co. KG, 13509 Verfahren zur kontinuierlichen Herstellung von hochmolekularen Polyestern durch Veresterung von Dicarbonsäuren und/oder Umesterung von Dicarbonsäuren mit Diolen und/oder deren Mischungen sowie Vorrichtung hierzu
US7863407B2 (en) * 2007-08-10 2011-01-04 Eastman Chemical Company Integrated polyester production facility
US9957355B2 (en) * 2013-06-12 2018-05-01 Basf Se Device and method for synthesis of a polymer under separation of a gaseous substance
CN108970566B (zh) * 2018-08-17 2021-03-09 北京濮源新材料技术研究院(普通合伙) 用于生产聚碳酸酯的具有浸润性能的缩聚反应器
IT202000008935A1 (it) * 2020-04-24 2021-10-24 Garbo S R L Processo per depolimerizzare polietilene tereftalato (pet) tramite glicolisi, e relativo impianto per la sua realizzazione.
CN111804255A (zh) * 2020-05-19 2020-10-23 桐昆集团浙江恒通化纤有限公司 一种增强酯化反应釜搅拌效果的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686826A (en) * 1970-11-19 1972-08-29 Allied Chem Polymer finisher
GB1320678A (en) * 1970-07-25 1973-06-20 Kuraray Co Reactor
DE2309027A1 (de) * 1973-02-23 1974-08-29 Metallgesellschaft Ag Polykondensationsreaktor

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL125080C (enExample) * 1964-01-14

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1320678A (en) * 1970-07-25 1973-06-20 Kuraray Co Reactor
US3686826A (en) * 1970-11-19 1972-08-29 Allied Chem Polymer finisher
DE2309027A1 (de) * 1973-02-23 1974-08-29 Metallgesellschaft Ag Polykondensationsreaktor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103237598A (zh) * 2010-10-15 2013-08-07 罗地亚管理公司 反应物间平衡反应化学转化的方法和装置及这类化学转化的至少一参数的测定方法

Also Published As

Publication number Publication date
CN1214707A (zh) 1999-04-21
IN191734B (enExample) 2003-12-20
ID16492A (id) 1997-10-02
JP2000508009A (ja) 2000-06-27
ES2178772T3 (es) 2003-01-01
WO1997035902A1 (en) 1997-10-02
PT889922E (pt) 2002-10-31
EP0889922A1 (en) 1999-01-13
EP0889922B1 (en) 2002-07-24
DE69714231T2 (de) 2003-03-27
DE69714231D1 (de) 2002-08-29

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Owner name: INVISTA TECH SARL

Free format text: FORMER OWNER: E. I. DU PONT DE NEMOURS AND CO.

Effective date: 20060113

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TR01 Transfer of patent right

Effective date of registration: 20060113

Address after: Zurich Switzerland

Patentee after: INVISTA TECHNOLOGIES S.A.R.L.

Address before: Wilmington, Delaware, USA

Patentee before: E. I. du Pont de Nemours and Co.

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20020904

Termination date: 20130324