CN109019685A - 一种合成CuBi2O4基胶体材料的方法 - Google Patents
一种合成CuBi2O4基胶体材料的方法 Download PDFInfo
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- CN109019685A CN109019685A CN201811060139.XA CN201811060139A CN109019685A CN 109019685 A CN109019685 A CN 109019685A CN 201811060139 A CN201811060139 A CN 201811060139A CN 109019685 A CN109019685 A CN 109019685A
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- Prior art keywords
- cubi
- solution
- distilled water
- reaction
- synthesis
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- 239000000463 material Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 22
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 16
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000012153 distilled water Substances 0.000 claims abstract description 41
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 239000000084 colloidal system Substances 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000002243 precursor Substances 0.000 claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 239000002585 base Substances 0.000 claims description 20
- 239000011259 mixed solution Substances 0.000 claims description 20
- 150000001621 bismuth Chemical class 0.000 claims description 11
- 239000012266 salt solution Substances 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 9
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims description 7
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 150000001879 copper Chemical class 0.000 claims description 6
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000012805 post-processing Methods 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 description 8
- 238000006555 catalytic reaction Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- 229910052927 chalcanthite Inorganic materials 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G29/00—Compounds of bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Colloid Chemistry (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201811060139.XA CN109019685B (zh) | 2018-09-12 | 2018-09-12 | 一种合成CuBi2O4基胶体材料的方法 |
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CN201811060139.XA CN109019685B (zh) | 2018-09-12 | 2018-09-12 | 一种合成CuBi2O4基胶体材料的方法 |
Publications (2)
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CN109019685A true CN109019685A (zh) | 2018-12-18 |
CN109019685B CN109019685B (zh) | 2021-01-01 |
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CN201811060139.XA Expired - Fee Related CN109019685B (zh) | 2018-09-12 | 2018-09-12 | 一种合成CuBi2O4基胶体材料的方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110479295A (zh) * | 2019-07-18 | 2019-11-22 | 广东省测试分析研究所(中国广州分析测试中心) | 一种四方晶型铋酸铜光催化剂的快速水热制备方法及其在降解亚甲基蓝中的应用 |
CN113731430A (zh) * | 2021-09-26 | 2021-12-03 | 辽宁大学 | 双Z型CuO/CuBi2O4/Bi2O3复合光催化剂及其制备方法和应用 |
CN113957394A (zh) * | 2021-09-27 | 2022-01-21 | 山东省科学院能源研究所 | 一种p型半导体薄膜氧化铋铜及其制备方法与应用 |
CN115141070A (zh) * | 2022-07-07 | 2022-10-04 | 西南科技大学 | 一种纳米铝热剂及其纳米铝热剂微自毁芯片的制备方法 |
Citations (6)
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JP2007273463A (ja) * | 2006-03-10 | 2007-10-18 | National Institute Of Advanced Industrial & Technology | 可視光応答性の半導体素子および光電極、並びにそれを用いた光エネルギー変換システム |
CN102030374A (zh) * | 2010-12-31 | 2011-04-27 | 陕西科技大学 | 一种微波水热法制备铁酸铋粉体的方法 |
CN102826608A (zh) * | 2012-08-24 | 2012-12-19 | 华南理工大学 | 一种溶剂热法制备铁酸铋粉体的方法 |
CN103112900A (zh) * | 2013-03-06 | 2013-05-22 | 广西大学 | 纳米复合氧化物La1-xBixCuyMn1-yO3及其制备方法和应用 |
US20170183787A1 (en) * | 2014-09-12 | 2017-06-29 | Fujifilm Corporation | Photocatalyst electrode for water decomposition |
CN106944043A (zh) * | 2017-03-17 | 2017-07-14 | 佛山科学技术学院 | 一种微纳异质结可见光复合光催化剂及其制备方法和应用 |
-
2018
- 2018-09-12 CN CN201811060139.XA patent/CN109019685B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007273463A (ja) * | 2006-03-10 | 2007-10-18 | National Institute Of Advanced Industrial & Technology | 可視光応答性の半導体素子および光電極、並びにそれを用いた光エネルギー変換システム |
CN102030374A (zh) * | 2010-12-31 | 2011-04-27 | 陕西科技大学 | 一种微波水热法制备铁酸铋粉体的方法 |
CN102826608A (zh) * | 2012-08-24 | 2012-12-19 | 华南理工大学 | 一种溶剂热法制备铁酸铋粉体的方法 |
CN103112900A (zh) * | 2013-03-06 | 2013-05-22 | 广西大学 | 纳米复合氧化物La1-xBixCuyMn1-yO3及其制备方法和应用 |
US20170183787A1 (en) * | 2014-09-12 | 2017-06-29 | Fujifilm Corporation | Photocatalyst electrode for water decomposition |
CN106944043A (zh) * | 2017-03-17 | 2017-07-14 | 佛山科学技术学院 | 一种微纳异质结可见光复合光催化剂及其制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
A.M. ABDULKAREM ET AL.: ""CuBi2O4 single crystal nanorods prepared by hydrothermal method:Growth mechanism and optical properties"", 《MATERIALS RESEARCH BULLETIN》 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110479295A (zh) * | 2019-07-18 | 2019-11-22 | 广东省测试分析研究所(中国广州分析测试中心) | 一种四方晶型铋酸铜光催化剂的快速水热制备方法及其在降解亚甲基蓝中的应用 |
CN110479295B (zh) * | 2019-07-18 | 2022-07-08 | 广东省测试分析研究所(中国广州分析测试中心) | 一种四方晶型铋酸铜光催化剂的快速水热制备方法及其在降解亚甲基蓝中的应用 |
CN113731430A (zh) * | 2021-09-26 | 2021-12-03 | 辽宁大学 | 双Z型CuO/CuBi2O4/Bi2O3复合光催化剂及其制备方法和应用 |
CN113731430B (zh) * | 2021-09-26 | 2023-11-10 | 辽宁大学 | 双Z型CuO/CuBi2O4/Bi2O3复合光催化剂及其制备方法和应用 |
CN113957394A (zh) * | 2021-09-27 | 2022-01-21 | 山东省科学院能源研究所 | 一种p型半导体薄膜氧化铋铜及其制备方法与应用 |
CN113957394B (zh) * | 2021-09-27 | 2023-09-26 | 山东省科学院能源研究所 | 一种p型半导体薄膜氧化铋铜及其制备方法与应用 |
CN115141070A (zh) * | 2022-07-07 | 2022-10-04 | 西南科技大学 | 一种纳米铝热剂及其纳米铝热剂微自毁芯片的制备方法 |
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