CN1088047C - 作为混凝土添加剂的非离子、水分散的聚异氰酸酯 - Google Patents
作为混凝土添加剂的非离子、水分散的聚异氰酸酯 Download PDFInfo
- Publication number
- CN1088047C CN1088047C CN97126255A CN97126255A CN1088047C CN 1088047 C CN1088047 C CN 1088047C CN 97126255 A CN97126255 A CN 97126255A CN 97126255 A CN97126255 A CN 97126255A CN 1088047 C CN1088047 C CN 1088047C
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- China
- Prior art keywords
- weight
- water
- content
- polymeric polyisocyanate
- dispersion
- Prior art date
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- Expired - Fee Related
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- 239000005056 polyisocyanate Substances 0.000 title claims abstract description 89
- 229920001228 polyisocyanate Polymers 0.000 title claims abstract description 89
- 239000004567 concrete Substances 0.000 title claims abstract description 60
- 239000000654 additive Substances 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 44
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920000570 polyether Polymers 0.000 claims abstract description 28
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- 239000000463 material Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 22
- 238000002360 preparation method Methods 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 17
- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 10
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 claims description 10
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 7
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- ANJPRQPHZGHVQB-UHFFFAOYSA-N hexyl isocyanate Chemical class CCCCCCN=C=O ANJPRQPHZGHVQB-UHFFFAOYSA-N 0.000 claims description 5
- DOFHXXBIPRPYSZ-UHFFFAOYSA-N [cyclohexyl(isocyanato)methyl]cyclohexane Chemical class C1CCCCC1C(N=C=O)C1CCCCC1 DOFHXXBIPRPYSZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000151 polyglycol Polymers 0.000 claims description 4
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- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 29
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 239000004568 cement Substances 0.000 description 15
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 14
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 13
- 239000004575 stone Substances 0.000 description 11
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- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
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- 125000005442 diisocyanate group Chemical group 0.000 description 5
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- -1 isocyanuric acid ester Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
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- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
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- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
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- 235000011089 carbon dioxide Nutrition 0.000 description 2
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- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
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- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- 230000006872 improvement Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- YDNLNVZZTACNJX-UHFFFAOYSA-N isocyanatomethylbenzene Chemical compound O=C=NCC1=CC=CC=C1 YDNLNVZZTACNJX-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000005837 radical ions Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- 239000007762 w/o emulsion Substances 0.000 description 2
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
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- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
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- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- QMEQBOSUJUOXMX-UHFFFAOYSA-N 2h-oxadiazine Chemical compound N1OC=CC=N1 QMEQBOSUJUOXMX-UHFFFAOYSA-N 0.000 description 1
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- PIWKPBJCKXDKJR-UHFFFAOYSA-N Isoflurane Chemical compound FC(F)OC(Cl)C(F)(F)F PIWKPBJCKXDKJR-UHFFFAOYSA-N 0.000 description 1
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- 235000019738 Limestone Nutrition 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
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- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
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- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
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- 150000002513 isocyanates Chemical class 0.000 description 1
- DUDXQIXWPJMPRQ-UHFFFAOYSA-N isocyanatomethylcyclohexane Chemical class O=C=NCC1CCCCC1 DUDXQIXWPJMPRQ-UHFFFAOYSA-N 0.000 description 1
- 229960002725 isoflurane Drugs 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical class COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
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- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DQFBYFPFKXHELB-VAWYXSNFSA-N trans-chalcone Chemical compound C=1C=CC=CC=1C(=O)\C=C\C1=CC=CC=C1 DQFBYFPFKXHELB-VAWYXSNFSA-N 0.000 description 1
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- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/282—Polyurethanes; Polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Glass Compositions (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
- Paints Or Removers (AREA)
- Silicon Compounds (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19654429A DE19654429A1 (de) | 1996-12-24 | 1996-12-24 | Wasserdispergierbare Polyisocyanatgemische als Additive für Beton |
| DE19654429.7 | 1996-12-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1189471A CN1189471A (zh) | 1998-08-05 |
| CN1088047C true CN1088047C (zh) | 2002-07-24 |
Family
ID=7816261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97126255A Expired - Fee Related CN1088047C (zh) | 1996-12-24 | 1997-12-24 | 作为混凝土添加剂的非离子、水分散的聚异氰酸酯 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6007619A (enExample) |
| EP (1) | EP0850896B9 (enExample) |
| JP (1) | JP3946332B2 (enExample) |
| KR (1) | KR100531705B1 (enExample) |
| CN (1) | CN1088047C (enExample) |
| AT (1) | ATE236104T1 (enExample) |
| CA (1) | CA2224956C (enExample) |
| DE (2) | DE19654429A1 (enExample) |
| DK (1) | DK0850896T3 (enExample) |
| ES (1) | ES2195074T3 (enExample) |
| MX (1) | MX201523B (enExample) |
| TW (1) | TW422867B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101793076A (zh) * | 2010-02-26 | 2010-08-04 | 哈尔滨工业大学深圳研究生院 | 外加剂的混凝土构件及制备方法 |
| WO2013007004A1 (zh) | 2011-07-08 | 2013-01-17 | 江苏博特新材料有限公司 | 水分散两性聚氨酯、制备方法及其在混凝土增韧中的应用 |
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|---|---|---|---|---|
| DE19740454A1 (de) * | 1997-09-15 | 1999-03-18 | Bayer Ag | Wasserdispergierbare bzw. wasserlösliche Polyurethane als Additive für Beton |
| DE19805022A1 (de) * | 1998-02-09 | 1999-08-12 | Koester Bauchemie Gmbh | Abdichtungssystem |
| DE19822890A1 (de) * | 1998-05-22 | 1999-11-25 | Bayer Ag | Neue wäßrige 2 K-PUR-Beschichtungssysteme |
| ES2209274T3 (es) * | 1998-05-22 | 2004-06-16 | Bayer Aktiengesellschaft | Mezclas de poliisocianatos modificadas mediante polieteres dispersables. |
| FR2780396B1 (fr) * | 1998-06-30 | 2000-08-04 | Coatex Sa | Nouveaux agents de type polycondensat pour ameliorer la maniabilite des liants hydrauliques, leur procede de preparation, les liants les contenant et leurs applications |
| DE19958170A1 (de) * | 1999-12-02 | 2001-06-07 | Bayer Ag | Hochfunktionelle wasserdispergierbare Polyisocyanatgemische |
| MXPA02008041A (es) * | 2000-02-18 | 2004-09-06 | Stroup Willie W | Mezcla de cemento de escoria de cubilote y metodos para elaborar y usar la misma. |
| KR20010007776A (ko) * | 2000-09-06 | 2001-02-05 | 김형봉 | 시멘트 도로 및 구체의 균열 파손을 빠르게 성형 복구하는초속 성형 복구재의 제조방법과 이를 이용한 시공공법 |
| US6709758B2 (en) * | 2001-11-09 | 2004-03-23 | Lord Corporation | Room temperature curable X-HNBR coating |
| KR20030052218A (ko) * | 2001-12-20 | 2003-06-26 | 한일종합실란트 주식회사 | 콘크리트 도로 및 공항 상부 단면 파손 복구재 콘크리트급조 성형재 제조기술 |
| US6777026B2 (en) * | 2002-10-07 | 2004-08-17 | Lord Corporation | Flexible emissive coatings for elastomer substrates |
| US6838516B2 (en) | 2002-07-26 | 2005-01-04 | Great Eastern Resins Industrial Co., Ltd. | Water dispersible polyisocyanate composition and its uses |
| CA2627509C (en) | 2005-11-15 | 2013-10-22 | Valspar Sourcing, Inc. | Crush resistant latex topcoat composition for fiber cement substrates |
| US9783622B2 (en) | 2006-01-31 | 2017-10-10 | Axalta Coating Systems Ip Co., Llc | Coating system for cement composite articles |
| US8293361B2 (en) | 2006-01-31 | 2012-10-23 | Valspar Sourcing, Inc. | Coating system for cement composite articles |
| DE102006011153A1 (de) * | 2006-03-10 | 2007-09-13 | Construction Research & Technology Gmbh | Fluormodifiziertes Zusatzmittel für zementäre Produkte, Verfahren zu seiner Herstellung und dessen Verwendung |
| MX2008014749A (es) | 2006-05-19 | 2009-02-04 | Valspar Sourcing Inc | Sistema de recubrimiento para articulos compuestos de cemento. |
| EP2035516B2 (en) * | 2006-06-02 | 2017-01-04 | Valspar Sourcing, Inc. | High performance aqueous coating compositions |
| EP2043967B1 (en) | 2006-07-07 | 2018-07-04 | Valspar Sourcing, Inc. | Coating systems for cement composite articles |
| US8415009B2 (en) * | 2006-12-13 | 2013-04-09 | James Hardie Technology Limited | Engineered composite building materials and methods of making same |
| JP5130723B2 (ja) * | 2007-01-22 | 2013-01-30 | Dic株式会社 | ウレタンセメント系組成物、床材及びその施工方法 |
| US8202581B2 (en) | 2007-02-16 | 2012-06-19 | Valspar Sourcing, Inc. | Treatment for cement composite articles |
| US8490916B2 (en) | 2007-10-19 | 2013-07-23 | Lord Corporation | Suspension system for aircraft auxiliary power unit with elastomeric member |
| BRPI0917455B1 (pt) | 2008-08-15 | 2018-11-21 | Valspar Sourcing Inc | composição de revestimento, método para preparar um artigo revestido, e, artigo revestido |
| AU2009316285A1 (en) | 2008-11-24 | 2010-05-27 | Valspar Sourcing, Inc. | Coating system for cement composite articles |
| CN101787771B (zh) * | 2010-02-26 | 2012-01-11 | 哈尔滨工业大学深圳研究生院 | 用外加剂产生二氧化碳制备的再生混凝土构件及制备方法 |
| EP2365013A1 (de) * | 2010-03-12 | 2011-09-14 | Rhein Chemie Rheinau GmbH | Neue witterungsbeständige Polyurethangiessmassen, ein Verfahren zu deren Herstellung und deren Verwendung |
| CN102786272B (zh) * | 2012-05-04 | 2014-10-01 | 武汉理工大学 | 一种高延展性致密匀质c60海洋混凝土及其制备方法 |
| EP2849941A1 (en) | 2012-05-14 | 2015-03-25 | Basf Se | Moisture-resistant gypsum boards and slurries for making same |
| PL2990398T3 (pl) | 2014-08-29 | 2019-06-28 | Covestro Deutschland Ag | Hydrofilne estry kwasu poliasparginowego |
| CN104529219B (zh) * | 2014-12-04 | 2017-01-11 | 江苏科技大学 | 一种水泥稳泡剂及其水泥组合物及应用方法 |
| CN104945634A (zh) * | 2015-06-02 | 2015-09-30 | 江苏奥莱特新材料有限公司 | 一种氨酯型缓凝聚羧酸系减水剂的制备方法 |
| JP6995475B2 (ja) * | 2016-12-27 | 2022-02-04 | コベストロ、ドイチュラント、アクチエンゲゼルシャフト | 無黄変セメント系ポリウレタン発泡複合体及びその製造方法 |
| EP4015546A1 (de) | 2020-12-15 | 2022-06-22 | Covestro Deutschland AG | Nichtionisch hydrophilierte polyisocyanate mit sehr niedrigem monomergehalt |
| CN120693357A (zh) | 2023-06-01 | 2025-09-23 | 洛德公司 | 储存稳定的导热反应性复合物和方法 |
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| JPH08183646A (ja) * | 1994-12-28 | 1996-07-16 | Aron Kasei Co Ltd | 改良された熱可塑性セメント組成物及びその製造方法 |
| JPH08217516A (ja) * | 1995-02-10 | 1996-08-27 | Toubu Kagaku Kk | 改良された熱可塑性セメントの製造方法 |
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| US4211680A (en) * | 1968-05-13 | 1980-07-08 | Imperial Chemical Industries Limited | Quick-set compositions of hydraulic cement, silica, water, polyisocyanate and polyol |
| BE793375A (fr) * | 1972-01-03 | 1973-06-27 | Ici Ltd | Nouvelles compositions cimentaires |
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| DE2359611C3 (de) * | 1973-11-30 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von durch Harze auf Isocyanatbasis gebundenen Füllstoffen |
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| US5725654A (en) * | 1997-06-06 | 1998-03-10 | Arco Chemical Technology, L.P. | Cement composition |
-
1996
- 1996-12-24 DE DE19654429A patent/DE19654429A1/de not_active Withdrawn
-
1997
- 1997-12-11 US US08/988,575 patent/US6007619A/en not_active Expired - Fee Related
- 1997-12-12 AT AT97121921T patent/ATE236104T1/de active
- 1997-12-12 DE DE59709688T patent/DE59709688D1/de not_active Expired - Lifetime
- 1997-12-12 ES ES97121921T patent/ES2195074T3/es not_active Expired - Lifetime
- 1997-12-12 DK DK97121921T patent/DK0850896T3/da active
- 1997-12-12 EP EP97121921A patent/EP0850896B9/de not_active Expired - Lifetime
- 1997-12-16 CA CA002224956A patent/CA2224956C/en not_active Expired - Fee Related
- 1997-12-17 TW TW086119024A patent/TW422867B/zh not_active IP Right Cessation
- 1997-12-18 MX MX9710337A patent/MX201523B/es not_active IP Right Cessation
- 1997-12-22 JP JP36481697A patent/JP3946332B2/ja not_active Expired - Fee Related
- 1997-12-23 KR KR1019970072503A patent/KR100531705B1/ko not_active Expired - Fee Related
- 1997-12-24 CN CN97126255A patent/CN1088047C/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08183646A (ja) * | 1994-12-28 | 1996-07-16 | Aron Kasei Co Ltd | 改良された熱可塑性セメント組成物及びその製造方法 |
| JPH08217516A (ja) * | 1995-02-10 | 1996-08-27 | Toubu Kagaku Kk | 改良された熱可塑性セメントの製造方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101793076A (zh) * | 2010-02-26 | 2010-08-04 | 哈尔滨工业大学深圳研究生院 | 外加剂的混凝土构件及制备方法 |
| WO2013007004A1 (zh) | 2011-07-08 | 2013-01-17 | 江苏博特新材料有限公司 | 水分散两性聚氨酯、制备方法及其在混凝土增韧中的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1189471A (zh) | 1998-08-05 |
| ES2195074T3 (es) | 2003-12-01 |
| JP3946332B2 (ja) | 2007-07-18 |
| DE59709688D1 (de) | 2003-05-08 |
| ATE236104T1 (de) | 2003-04-15 |
| JPH10203855A (ja) | 1998-08-04 |
| KR100531705B1 (ko) | 2006-01-27 |
| EP0850896A1 (de) | 1998-07-01 |
| CA2224956A1 (en) | 1998-06-24 |
| TW422867B (en) | 2001-02-21 |
| CA2224956C (en) | 2007-07-31 |
| DK0850896T3 (da) | 2003-07-07 |
| EP0850896B1 (en) | 2003-04-02 |
| US6007619A (en) | 1999-12-28 |
| EP0850896B9 (de) | 2003-10-22 |
| MX9710337A (es) | 1998-08-30 |
| KR19980064514A (ko) | 1998-10-07 |
| DE19654429A1 (de) | 1998-06-25 |
| MX201523B (es) | 2001-04-24 |
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Granted publication date: 20020724 Termination date: 20131224 |