CN108707161A - 一种三氟化硼单乙胺络合物的制备方法 - Google Patents
一种三氟化硼单乙胺络合物的制备方法 Download PDFInfo
- Publication number
- CN108707161A CN108707161A CN201810453654.8A CN201810453654A CN108707161A CN 108707161 A CN108707161 A CN 108707161A CN 201810453654 A CN201810453654 A CN 201810453654A CN 108707161 A CN108707161 A CN 108707161A
- Authority
- CN
- China
- Prior art keywords
- boron trifluoride
- preparation
- mono aminoethane
- complex compound
- filled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 49
- JDVIRCVIXCMTPU-UHFFFAOYSA-N ethanamine;trifluoroborane Chemical compound CCN.FB(F)F JDVIRCVIXCMTPU-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims abstract description 67
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims abstract description 61
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000006243 chemical reaction Methods 0.000 claims abstract description 47
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 36
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910015900 BF3 Inorganic materials 0.000 claims abstract description 28
- 239000000047 product Substances 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 15
- 238000000926 separation method Methods 0.000 claims description 14
- 239000003599 detergent Substances 0.000 claims description 13
- 239000012265 solid product Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 abstract description 11
- 239000012535 impurity Substances 0.000 abstract description 6
- 150000001412 amines Chemical class 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 27
- 238000003756 stirring Methods 0.000 description 26
- 239000000843 powder Substances 0.000 description 17
- 239000002002 slurry Substances 0.000 description 10
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000012046 mixed solvent Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- HVABKWYVQHSGHW-UHFFFAOYSA-N boron;ethanamine Chemical compound [B].CCN HVABKWYVQHSGHW-UHFFFAOYSA-N 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- JFNWATIZEGZGSY-UHFFFAOYSA-N n,n-diethylethanamine;trifluoroborane Chemical compound FB(F)F.CCN(CC)CC JFNWATIZEGZGSY-UHFFFAOYSA-N 0.000 description 2
- STQYDSASXIHUJU-UHFFFAOYSA-N n-ethylethanamine;trifluoroborane Chemical compound FB(F)F.CCNCC STQYDSASXIHUJU-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- HCQJIRFMDPGREW-UHFFFAOYSA-N propan-2-one;trifluoroborane Chemical compound CC(C)=O.FB(F)F HCQJIRFMDPGREW-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
项目 | 外观 | 水分(%) | 洗涤后纯度(%) | 熔点(℃) | 收率(%) |
实施例1 | 白色 | 1.05 | 99.60 | 95-115 | 82.8 |
实施例2 | 白色 | 0.9 | 99.5 | 95-115 | 90.45 |
实施例3 | 白色 | 1.02 | 99.72 | 95-115 | 90.92 |
实施例4 | 白色 | 1.52 | 99.65 | 95-115 | 91.4 |
实施例5 | 淡黄 | 0.85 | 99.56 | 95-115 | 83.28 |
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810453654.8A CN108707161B (zh) | 2018-05-14 | 2018-05-14 | 一种三氟化硼单乙胺络合物的制备方法 |
DE102018133528.8A DE102018133528B4 (de) | 2018-05-14 | 2018-12-21 | Verfahren zum Herstellen von Bortrifluoridmonoethylamin-Komplex |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810453654.8A CN108707161B (zh) | 2018-05-14 | 2018-05-14 | 一种三氟化硼单乙胺络合物的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108707161A true CN108707161A (zh) | 2018-10-26 |
CN108707161B CN108707161B (zh) | 2019-11-26 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201810453654.8A Active CN108707161B (zh) | 2018-05-14 | 2018-05-14 | 一种三氟化硼单乙胺络合物的制备方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN108707161B (zh) |
DE (1) | DE102018133528B4 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115043861A (zh) * | 2022-06-06 | 2022-09-13 | 山东合益气体股份有限公司 | 一种固体三氟化硼苯胺络合物的制备方法 |
CN116162104A (zh) * | 2023-02-23 | 2023-05-26 | 山东合益气体股份有限公司 | 一种三氟化硼异丙胺络合物的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276638A (zh) * | 2011-06-09 | 2011-12-14 | 格兰特医药科技(南通)有限公司 | 三氟化硼络合物的生产工艺 |
CN104628755A (zh) * | 2015-02-05 | 2015-05-20 | 复旦大学 | 胺硼烷络合物的生产方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102532179A (zh) | 2011-12-26 | 2012-07-04 | 杜云花 | 三氟化硼络合物生产方法 |
-
2018
- 2018-05-14 CN CN201810453654.8A patent/CN108707161B/zh active Active
- 2018-12-21 DE DE102018133528.8A patent/DE102018133528B4/de active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276638A (zh) * | 2011-06-09 | 2011-12-14 | 格兰特医药科技(南通)有限公司 | 三氟化硼络合物的生产工艺 |
CN104628755A (zh) * | 2015-02-05 | 2015-05-20 | 复旦大学 | 胺硼烷络合物的生产方法 |
Non-Patent Citations (1)
Title |
---|
JOSE-LUIS M. ABBOUD,ET AL.: "Dihydrogen Generation from Amine/Boranes: Synthesis, FT-ICR, and Computational Studies", 《CHEM. EUR. J.》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115043861A (zh) * | 2022-06-06 | 2022-09-13 | 山东合益气体股份有限公司 | 一种固体三氟化硼苯胺络合物的制备方法 |
CN115043861B (zh) * | 2022-06-06 | 2023-02-03 | 山东合益气体股份有限公司 | 一种固体三氟化硼苯胺络合物的制备方法 |
CN116162104A (zh) * | 2023-02-23 | 2023-05-26 | 山东合益气体股份有限公司 | 一种三氟化硼异丙胺络合物的制备方法 |
CN116162104B (zh) * | 2023-02-23 | 2024-03-15 | 山东合益气体股份有限公司 | 一种三氟化硼异丙胺络合物的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE102018133528B4 (de) | 2023-02-16 |
DE102018133528A1 (de) | 2019-11-14 |
CN108707161B (zh) | 2019-11-26 |
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Effective date of registration: 20190723 Address after: 257500 Shengtuo Fine Chemical Park, Kenli County, Dongying City, Shandong Province (east of Heyi Road, north of Shengtuo Industrial Park) Applicant after: DONGYING HEYI CHEMICAL CO., LTD. Applicant after: Wang Zhiqiang Address before: 257500 Shengtuo Fine Chemical Park, Kenli County, Dongying City, Shandong Province (east of Heyi Road, north of Shengtuo Industrial Park) Applicant before: DONGYING HEYI CHEMICAL CO., LTD. |
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TA01 | Transfer of patent application right |
Effective date of registration: 20190906 Address after: 257 000 Shengtuo Town Fine Chemical Park, Kenli District, Dongying City, Shandong Province (east of Heyi Road, north of Shengtuo Industrial Park) Applicant after: DONGYING HEYI CHEMICAL CO., LTD. Address before: 257500 Shengtuo Fine Chemical Park, Kenli County, Dongying City, Shandong Province (east of Heyi Road, north of Shengtuo Industrial Park) Applicant before: DONGYING HEYI CHEMICAL CO., LTD. Applicant before: Wang Zhi Qiang |
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GR01 | Patent grant | ||
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CP03 | Change of name, title or address |
Address after: 257500 Shengtuo fine chemical park, Kenli District, Dongying City, Shandong Province (east of Heyi road and north of Shengjing Road, Shengtuo Industrial Park) Patentee after: Shandong Heyi Gas Co., Ltd Address before: 257 000 Shengtuo Town Fine Chemical Park, Kenli District, Dongying City, Shandong Province (east of Heyi Road, north of Shengtuo Industrial Park) Patentee before: Dongying Heyi Chemical Co.,Ltd. |
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CP03 | Change of name, title or address |