CN108698965B - 制备萜烯醇混合物的方法 - Google Patents

制备萜烯醇混合物的方法 Download PDF

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Publication number
CN108698965B
CN108698965B CN201780012435.XA CN201780012435A CN108698965B CN 108698965 B CN108698965 B CN 108698965B CN 201780012435 A CN201780012435 A CN 201780012435A CN 108698965 B CN108698965 B CN 108698965B
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process according
formula
copper
carboxylic acid
terpinen
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Chinese (zh)
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CN108698965A (zh
Inventor
B·沃尔夫
M·雷克
S·班森
R·格策
H·克罗斯
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BASF Agro BV
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BASF Agro BV
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/56Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00Catalysts of the Raney type
    • B01J25/02Raney nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C07D303/06Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms in which the oxirane rings are condensed with a carbocyclic ring system having three or more relevant rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/67Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84Metals of the iron group
    • B01J2523/847Nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C07C35/18Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings with unsaturation at least in the ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201780012435.XA 2016-02-26 2017-02-16 制备萜烯醇混合物的方法 Active CN108698965B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16157543.6 2016-02-26
EP16157543 2016-02-26
PCT/EP2017/053468 WO2017144337A1 (en) 2016-02-26 2017-02-16 Process for preparing a mixture of terpene alcohols

Publications (2)

Publication Number Publication Date
CN108698965A CN108698965A (zh) 2018-10-23
CN108698965B true CN108698965B (zh) 2022-06-24

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Country Status (12)

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US (1) US10266468B2 (es)
EP (1) EP3419955B1 (es)
KR (1) KR20180117658A (es)
CN (1) CN108698965B (es)
AR (1) AR110461A1 (es)
AU (1) AU2017224166B2 (es)
BR (1) BR112018015531B1 (es)
DK (1) DK3419955T3 (es)
ES (1) ES2787895T3 (es)
IL (1) IL260737A (es)
MX (1) MX2018010304A (es)
WO (1) WO2017144337A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2856454T3 (es) 2015-05-08 2021-09-27 Basf Agro Bv Procedimiento para la preparación de epóxido de terpinoleno.
WO2017215929A1 (en) 2016-06-15 2017-12-21 BASF Agro B.V. Process for the epoxidation of a tetrasubstituted alkene
BR112018076043B1 (pt) 2016-06-15 2023-09-26 Basf Agro B.V Processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante
DK3515918T3 (da) 2016-09-19 2021-07-12 Basf Agro Bv Fremgangsmåde til fremstilling af 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptan
LT3535257T (lt) 2016-11-04 2021-02-25 Basf Se Pirazolpiridazinų gryninimo būdas
WO2018091338A1 (en) 2016-11-17 2018-05-24 Basf Se Process for the purification of 1-(4-chlorophenyl)pyrazol-3-ol
CN110337438B (zh) 2017-02-15 2024-03-26 巴斯夫农业公司 用于制备2-外-(2-甲基苄氧基)-1-甲基-4-异丙基-7-氧杂二环[2.2.1]庚烷的方法
WO2018172109A1 (en) 2017-03-20 2018-09-27 Basf Se Process for preparing bromotrichloromethane
EP3601295B1 (en) 2017-03-31 2021-05-12 BASF Agro B.V. Process for preparing 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane
US11358922B2 (en) 2017-11-02 2022-06-14 Basf Se Process for preparing 4-chlorobenzyl propargyl ether
IT201900015066A1 (it) 2019-08-27 2021-02-27 Versalis Spa Procedimento per il trattamento di idrocarburi polialchilaromatici.
CN111229233B (zh) * 2020-04-08 2022-07-08 福州大学 一种用于合成松油烯-4-醇的镍/氧化钛-氧化硅催化剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3609197A (en) * 1968-03-08 1971-09-28 Reynolds Tobacco Co R Preparation of a terpene alcohol
EP1412313A1 (de) * 2001-07-09 2004-04-28 Symrise GmbH & Co. KG ISO-$g(b)-BISABOLOL ALS DUFT-UND AROMASTOFF

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676504A (en) * 1970-09-10 1972-07-11 Reynolds Tobacco Co R Preparation of a terepene alcohol
FR2110781A5 (es) 1970-10-30 1972-06-02 Roure Bertrand Dupont Sa
US4670041A (en) 1981-12-16 1987-06-02 E. I. Du Pont De Nemours And Company Oxabicycloalkane herbicides
US4487945A (en) 1981-12-16 1984-12-11 Shell Oil Company Preparation of 2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes
US4542244A (en) 1982-09-13 1985-09-17 Shell Oil Company Oxabicycloalkane herbicides
JP2585737B2 (ja) 1988-08-10 1997-02-26 ヤスハラケミカル株式会社 テルペンアルコ―ルの製造方法
CN1202912C (zh) * 2003-06-02 2005-05-25 厦门中坤化学有限公司 一种改性氧化铜负载型催化剂的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3609197A (en) * 1968-03-08 1971-09-28 Reynolds Tobacco Co R Preparation of a terpene alcohol
EP1412313A1 (de) * 2001-07-09 2004-04-28 Symrise GmbH & Co. KG ISO-$g(b)-BISABOLOL ALS DUFT-UND AROMASTOFF

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Enantioselectivity in Odor Perception: Synthesis and Olfactory Properties of Iso-β-Bisabolol,a New Natural Product;Norbert A. Braun等;《helvetica chimica acta》;20031231;第2698-2708页 *

Also Published As

Publication number Publication date
KR20180117658A (ko) 2018-10-29
CN108698965A (zh) 2018-10-23
BR112018015531A2 (pt) 2018-12-26
DK3419955T3 (da) 2020-05-18
AU2017224166B2 (en) 2020-12-17
AR110461A1 (es) 2019-04-03
MX2018010304A (es) 2019-05-20
WO2017144337A1 (en) 2017-08-31
BR112018015531B1 (pt) 2022-04-12
AU2017224166A1 (en) 2018-09-06
US20190047928A1 (en) 2019-02-14
US10266468B2 (en) 2019-04-23
EP3419955A1 (en) 2019-01-02
IL260737A (en) 2018-10-31
EP3419955B1 (en) 2020-03-04
ES2787895T3 (es) 2020-10-19

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