CN108641054A - 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体 - Google Patents

经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体 Download PDF

Info

Publication number
CN108641054A
CN108641054A CN201810473937.9A CN201810473937A CN108641054A CN 108641054 A CN108641054 A CN 108641054A CN 201810473937 A CN201810473937 A CN 201810473937A CN 108641054 A CN108641054 A CN 108641054A
Authority
CN
China
Prior art keywords
monomer
oil
thermoplastic
triglyceride
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810473937.9A
Other languages
English (en)
Chinese (zh)
Inventor
E·W·寇趣闰
R·C·威廉姆斯
N·赫纳德兹
A·凯斯席恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Iowa State University Research Foundation Inc ISURF
Original Assignee
Iowa State University Research Foundation Inc ISURF
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Iowa State University Research Foundation Inc ISURF filed Critical Iowa State University Research Foundation Inc ISURF
Publication of CN108641054A publication Critical patent/CN108641054A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F122/10—Esters
    • C08F122/12—Esters of phenols or saturated alcohols
    • C08F122/20—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F242/00—Copolymers of drying oils with other monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J135/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C08L2555/82—Macromolecular constituents from natural renewable resources, e.g. starch, cellulose, saw dust, straw, hair or shells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
CN201810473937.9A 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体 Pending CN108641054A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361825241P 2013-05-20 2013-05-20
US61/825,241 2013-05-20
CN201480029039.4A CN105229045B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201480029039.4A Division CN105229045B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Publications (1)

Publication Number Publication Date
CN108641054A true CN108641054A (zh) 2018-10-12

Family

ID=50983166

Family Applications (3)

Application Number Title Priority Date Filing Date
CN201810473397.4A Active CN108641053B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN201480029039.4A Active CN105229045B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN201810473937.9A Pending CN108641054A (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Family Applications Before (2)

Application Number Title Priority Date Filing Date
CN201810473397.4A Active CN108641053B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN201480029039.4A Active CN105229045B (zh) 2013-05-20 2014-05-20 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Country Status (14)

Country Link
US (5) US9650463B2 (enExample)
EP (3) EP2999727B1 (enExample)
JP (1) JP2016528306A (enExample)
KR (1) KR20160009583A (enExample)
CN (3) CN108641053B (enExample)
AU (1) AU2014268692B2 (enExample)
BR (2) BR122017010545B1 (enExample)
CA (1) CA2910680A1 (enExample)
CL (1) CL2015003375A1 (enExample)
EA (1) EA201592176A1 (enExample)
HK (1) HK1220219A1 (enExample)
PH (1) PH12015502467A1 (enExample)
SG (3) SG11201509408UA (enExample)
WO (1) WO2014189939A2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641053A (zh) * 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN115738133A (zh) * 2022-11-10 2023-03-07 国网浙江省电力有限公司湖州供电公司 一种应用于电化学储能系统的自动灭火器材

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014017476B1 (pt) 2012-01-18 2021-03-30 Iowa State University Research Foundation, Inc Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico
US10253132B2 (en) * 2015-02-09 2019-04-09 Archer Daniels Midland Company Renewable source-derived polymer oil macroinitiators and thermoplastic block copolymers derived therefrom
EP3262082B1 (en) 2015-02-27 2020-10-21 Cargill, Incorporated Polymerized oils and methods of manufacturing the same
DE102015208810A1 (de) 2015-05-12 2016-11-17 Continental Reifen Deutschland Gmbh RAFT-Agens, Verfahren zur Polymerisation, Polymer und Kautschukmischung sowie deren Verwendung
HK1249897A1 (zh) * 2015-06-02 2018-11-16 内斯托尔株式会社 新型甘油三酯及其用途
US10323148B1 (en) 2016-05-26 2019-06-18 Marathon Petroleum Company Lp Method of making an asphalt composition containing ester bottoms
US10968173B2 (en) * 2016-07-07 2021-04-06 Iowa State University Research Foundation, Inc. Thiocarbonylthio compounds as chain transfer agents suitable for raft polymerization
WO2018009753A1 (en) * 2016-07-07 2018-01-11 Iowa State University Research Foundaton, Inc. Multiblock copolymer and method of making thereof
CN106433158B (zh) * 2016-07-07 2018-12-04 交通运输部科学研究院 改性生物沥青的制备方法和改性生物沥青及其用途
WO2018031373A1 (en) 2016-08-12 2018-02-15 Iowa State University Research Foundation, Inc. Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials
FR3058729A1 (fr) * 2016-11-17 2018-05-18 Compagnie Generale Des Etablissements Michelin Pneumatique comprenant une bande de roulement comprenant un elastomere thermoplastique et un systeme de reticulation a base de soufre
FR3060588A1 (fr) * 2016-12-20 2018-06-22 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant une poudrette de caoutchouc specifique
WO2018183261A1 (en) * 2017-03-27 2018-10-04 Iowa State University Research Foundation, Inc. Macro-raft chain transfer agents as anionic polymerization terminators
US10316192B2 (en) 2017-08-25 2019-06-11 Cargill, Incorporated Emulsions with polymerized oils and methods of manufacturing the same
CN108084071B (zh) * 2017-12-29 2019-11-22 云南铁峰矿业化工新技术有限公司 一种黄药真空制备装置
CN108503276A (zh) * 2018-04-20 2018-09-07 万玉梅 一种功能型路面养护材料及其制备方法
CN112384581A (zh) 2018-06-11 2021-02-19 宣伟投资管理有限公司 包含水分散性丙烯酸类嵌段共聚物的包装涂层
CA3103339A1 (en) 2018-06-18 2019-12-26 Cornell University Systems and methods for n-halamine-dopamine copolymers for high-performance, low-cost, and easy-to-apply antimicrobial coatings
CN109679001A (zh) * 2018-12-29 2019-04-26 锦州英诺威科技服务有限公司 一种用于聚丙烯生产的杀活剂
US11814506B2 (en) 2019-07-02 2023-11-14 Marathon Petroleum Company Lp Modified asphalts with enhanced rheological properties and associated methods
CA3088894C (en) 2020-05-21 2024-04-30 Marathon Petroleum Company Lp Systems and methods for venting asphalt transport tanks
CN112175555A (zh) * 2020-09-29 2021-01-05 杭州英创新材料有限公司 一种极性热熔胶及其制备方法
CA3214142A1 (en) * 2021-04-02 2022-10-06 Iowa State University Research Foundation, Inc. Thermoplastic graft elastomers via reactive compatibilization of polyacrylated epoxidized high oleic soybean oil and polydiene-containing copolymers
WO2022212880A1 (en) * 2021-04-02 2022-10-06 Iowa State University Research Foundation, Inc. Impact modification of polyesters via reactive extrusion with polyacrylated epoxidized high oleic soybean oil
CN113214575B (zh) * 2021-04-24 2022-03-25 温州市剑利鞋业有限公司 一种pvc鞋底及其制备工艺
CN114605653B (zh) * 2022-04-19 2023-07-04 东南大学 一种代替sbs的生物热塑性弹性体的制备方法及其应用
CN115160467B (zh) * 2022-06-22 2023-10-03 东南大学 一种新型生物基液体改性剂的制备方法及其应用
CN116144165B (zh) * 2022-12-27 2024-04-02 四川大学 可回收、可修复的热固性聚氨酯改性沥青材料及其制法
KR20250060701A (ko) * 2023-10-26 2025-05-07 롯데케미칼 주식회사 열가소성 수지 조성물 및 이로부터 제조된 성형품

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2190906A (en) * 1939-01-05 1940-02-20 Dow Chemical Co Styrene-tung oil copolymer
US3499857A (en) * 1967-04-17 1970-03-10 Cataphote Corp Thermoplastic resinous compositions,particularly using unsaturated triglycerides
CN101225141A (zh) * 2007-12-28 2008-07-23 沈阳工业大学 以大豆油为原料制备可降解聚合物
CN101230020A (zh) * 2008-02-26 2008-07-30 北京市丰信德科技发展有限公司 植物油合成聚合物多元醇用大分子单体的方法及其用途
CN108641053A (zh) * 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2192090A (en) 1934-06-14 1940-02-27 Nolde & Horst Co Knitted fabric
JPS6049668B2 (ja) * 1981-04-06 1985-11-02 大日本塗料株式会社 塗料組成物
JP2592622B2 (ja) * 1987-11-12 1997-03-19 伊藤製油株式会社 ポリウレタンの製造法
US6197905B1 (en) 1989-06-05 2001-03-06 Commonwealth Scientific & Industrial Resarch Organization Process for producing polymers or oligomers of controlled molecular weight and end group functionalities
US5932675A (en) 1989-06-05 1999-08-03 Commonwealth Scientific And Industrial Research Organisation Free-radical chain transfer polymerization process
FR2670497B1 (fr) 1990-12-18 1994-05-13 Elf France Composante bitume/polymere utilisable pour former des compositions bitume/polymere a tres faible susceptibilite thermique applicables a la realisation de revetements.
ATE166363T1 (de) 1991-02-06 1998-06-15 Commw Scient Ind Res Org Polymerisationsregelung
GB9306517D0 (en) 1993-03-29 1993-05-19 Polyphalt Inc Stabilized bitumen compositions
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
AUPN585595A0 (en) 1995-10-06 1995-11-02 Commonwealth Scientific And Industrial Research Organisation Control of molecular weight and end-group functionality in polymers
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
ES2108646B1 (es) 1995-11-30 1998-07-01 Telefonica Nacional Espana Co Estructura para un sistema de informacion electronica.
US6184289B1 (en) * 1996-03-26 2001-02-06 Daicel Chemical Industries, Ltd. Styrene resin composition and molding thereof
ATE210684T1 (de) 1996-07-10 2001-12-15 Du Pont POLYMERISATION MIT ßLIVINGß KENNZEICHEN
JP2001506423A (ja) 1997-07-11 2001-05-15 ベーセー コンポネンツ ホールディングス ベー ヴェー 高電圧抵抗及びこのような高電圧抵抗を有する高電圧電源
DE69840423D1 (de) 1997-07-21 2009-02-12 Commw Scient Ind Res Org Synthese von dithioester-kettentransferagentien
US6121398A (en) * 1997-10-27 2000-09-19 University Of Delaware High modulus polymers and composites from plant oils
BR9815179A (pt) 1997-12-18 2000-10-10 Du Pont Processo para produzir um polìmero, polìmero, composição de revestimento e agente de transferência de cadeia.
FR2785287B1 (fr) * 1998-10-30 2000-12-29 De Chily Pierre Charlier Procede de polymerisation par chauffage dielectrique d'acides gras insatures, d'esters d'acides gras insatures, d'hydrocarbures insatures, ou de derives insatures de ces produits
US20020095007A1 (en) 1998-11-12 2002-07-18 Larock Richard C. Lewis acid-catalyzed polymerization of biological oils and resulting polymeric materials
DE19930770A1 (de) * 1999-07-03 2001-01-04 Cognis Deutschland Gmbh Verfahren zur Herstellung von Faserverbundwerkstoffen
AU2001234890A1 (en) 2000-02-08 2001-08-20 Waste Technology Transfer, Inc. Petroleum asphalts modified by liquefied biomass additives
US6900261B2 (en) 2001-06-12 2005-05-31 The University Of Delaware Sheet molding compound resins from plant oils
JP2003012719A (ja) * 2001-06-27 2003-01-15 Kanegafuchi Chem Ind Co Ltd アルケニル基および硫黄原子含有ビニル系重合体
EP1384729A1 (en) 2002-07-25 2004-01-28 Dutch Polymer Institute Process for the radical coplymerisation of alpha-olefins with vinyl monomers
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
KR20060088478A (ko) 2003-06-26 2006-08-04 시믹스 테크놀러지스 인크. 리빙 자유 라디칼 방법에 의해 제조된 아크릴- 또는메타크릴-계 중합체 수지를 갖는 포토레지스트 중합체 및조성물
JP2007522262A (ja) 2003-06-26 2007-08-09 シミックス・テクノロジーズ・インコーポレイテッド フォトレジストポリマー
IL156870A0 (en) 2003-07-10 2004-02-08 Carmel Olefines Ltd Process for making thermoplastic vulcanizates
WO2005113612A1 (en) 2004-05-12 2005-12-01 E.I. Dupont De Nemours And Company Method for removing sulfur-containing end groups
US7553919B2 (en) 2005-05-06 2009-06-30 Board Of Trustees Of Michigan State University Starch-vegetable oil graft copolymers and their biofiber composites, and a process for their manufacture
WO2007007100A2 (en) 2005-07-12 2007-01-18 The Leeds Teaching Hospitals Nhs Trust Measurement of gastric acid secretion
EP1989237A1 (en) 2006-02-23 2008-11-12 Commonwealth Scientific and Industrial Research Organisation Process for synthesizing thiol terminated polymers
FI119431B (fi) 2006-03-06 2008-11-14 Upm Kymmene Oyj Luonnonrasvahappopohjainen akrylaattihybridipolymeeri ja menetelmä sen valmistamiseksi
ATE431368T1 (de) * 2006-08-17 2009-05-15 Rhodia Operations Blockcopolymere, verfahren zu deren herstellung und ihre verwendung in emulsionen
US20080153982A1 (en) * 2006-12-20 2008-06-26 John Ta-Yuan Lai Vinyl-Thiocarbonate and Polyol Containing Block Copolymers
US7501479B2 (en) 2007-05-07 2009-03-10 Pittsburg State University Cationic polymerization of biological oils with superacid catalysts
BRPI0908184B1 (pt) 2008-02-22 2020-02-18 Alm Holding Company Processo de pavimentação de misturas betuminosas em temperaturas reduzidas
US7994107B2 (en) 2008-05-06 2011-08-09 Archer-Daniels-Midland Company Lubricant additives
BRPI0913743A2 (pt) * 2008-10-30 2015-10-13 Du Pont "processo para preparar uma dispersão de copolímero aquosa de ligação transversal de um copolímero a diluível em água, dispersão de copolímero aquosa e uso da dispersão de copolímero aquosa"
KR101614978B1 (ko) * 2008-12-31 2016-04-22 가부시키가이샤 브리지스톤 코어-우선 나노입자 형성 방법, 나노입자 및 조성물
EP2430096B1 (en) 2009-05-07 2015-06-24 Shell Internationale Research Maatschappij B.V. Binder composition and asphalt mixture
US9382352B2 (en) * 2009-11-12 2016-07-05 Ndsu Research Foundation Polymers derived from plant oil
FR2961503B1 (fr) 2010-06-16 2012-07-27 Commissariat Energie Atomique Utilisation de nanoparticules pour le stockage "sec" longue duree de radicaux peroxydes.
CN102295718B (zh) 2011-05-26 2014-01-01 北京化工大学 一种生物基高度支化聚酯及其制备方法
AU2012278910A1 (en) * 2011-07-04 2014-01-16 Commonwealth Scientific And Industrial Research Organisation Nucleic acid complex
EP2604661B1 (en) 2011-12-12 2017-01-25 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Corrosion inhibiting pigments and methods for preparing the same
BR112014017476B1 (pt) 2012-01-18 2021-03-30 Iowa State University Research Foundation, Inc Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2190906A (en) * 1939-01-05 1940-02-20 Dow Chemical Co Styrene-tung oil copolymer
US3499857A (en) * 1967-04-17 1970-03-10 Cataphote Corp Thermoplastic resinous compositions,particularly using unsaturated triglycerides
CN101225141A (zh) * 2007-12-28 2008-07-23 沈阳工业大学 以大豆油为原料制备可降解聚合物
CN101230020A (zh) * 2008-02-26 2008-07-30 北京市丰信德科技发展有限公司 植物油合成聚合物多元醇用大分子单体的方法及其用途
CN108641053A (zh) * 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
MICAH BLACK，ET AL: "Chain Transfer of Vegetable Oil Macromonomers in Acrylic Solution Copolymerization", 《JOURNAL OF APPLIED POLYMER SCIENCE》 *
NESLIHAN ALEMDAR,ET AL: "Production of oil-based binder by RAFT polymerization technique", 《PROGRESS IN ORGANIC COATINGS》 *
NESLIHAN ALEMDAR，ET AL: "Styrenated Sunflower Oil Polymers from Raft Process for Coating Application", 《JOURNAL OF APPLIED POLYMER SCIENCE》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641053A (zh) * 2013-05-20 2018-10-12 爱荷华州立大学研究基金会有限公司 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN115738133A (zh) * 2022-11-10 2023-03-07 国网浙江省电力有限公司湖州供电公司 一种应用于电化学储能系统的自动灭火器材
CN115738133B (zh) * 2022-11-10 2023-09-29 国网浙江省电力有限公司湖州供电公司 一种应用于电化学储能系统的自动灭火器材

Also Published As

Publication number Publication date
US10730975B2 (en) 2020-08-04
US10752711B2 (en) 2020-08-25
CN108641053B (zh) 2021-04-23
WO2014189939A2 (en) 2014-11-27
PH12015502467A1 (en) 2016-02-22
US20140343192A1 (en) 2014-11-20
AU2014268692A1 (en) 2015-11-12
CL2015003375A1 (es) 2016-08-05
EP2999727B1 (en) 2019-07-10
EP3632942A1 (en) 2020-04-08
US20180171045A1 (en) 2018-06-21
BR112015028368B1 (pt) 2020-12-15
SG10201606742UA (en) 2016-10-28
US20190002608A1 (en) 2019-01-03
WO2014189939A3 (en) 2015-02-19
KR20160009583A (ko) 2016-01-26
AU2014268692B2 (en) 2018-02-01
US20180305478A1 (en) 2018-10-25
US10093758B2 (en) 2018-10-09
BR122017010545A2 (pt) 2019-09-03
BR122017010545B1 (pt) 2020-12-01
EP3327047A1 (en) 2018-05-30
BR112015028368A2 (pt) 2017-07-25
SG10201606740QA (en) 2016-10-28
CA2910680A1 (en) 2014-11-27
US20170218101A1 (en) 2017-08-03
JP2016528306A (ja) 2016-09-15
CN105229045B (zh) 2018-07-13
SG11201509408UA (en) 2015-12-30
CN105229045A (zh) 2016-01-06
CN108641053A (zh) 2018-10-12
EA201592176A1 (ru) 2016-04-29
HK1220219A1 (zh) 2017-04-28
EP2999727A2 (en) 2016-03-30
US9650463B2 (en) 2017-05-16
US9926392B2 (en) 2018-03-27

Similar Documents

Publication Publication Date Title
CN105229045B (zh) 经由甘油三酯的可逆加成-断裂链转移聚合的热塑性弹性体
CN108623762B (zh) 经由植物油的原子转移自由基聚合的热塑性弹性体
US10947340B2 (en) Poly(acrylated polyol) and method for making and using thereof as asphalt rubber modifiers, adhesives, fracking additives, or fracking fluids

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181012

WD01 Invention patent application deemed withdrawn after publication