CN108623297A - 一种加快发酵过程的陶瓷及其制备方法 - Google Patents

一种加快发酵过程的陶瓷及其制备方法 Download PDF

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CN108623297A
CN108623297A CN201810434016.1A CN201810434016A CN108623297A CN 108623297 A CN108623297 A CN 108623297A CN 201810434016 A CN201810434016 A CN 201810434016A CN 108623297 A CN108623297 A CN 108623297A
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高忠青
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Geng Chenyang
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Zibo Famous Education And Technology Co Ltd
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Abstract

本发明公开了一种加快发酵过程的陶瓷及其制备方法,包括以下重量份的原料:尖晶石8‑13份、稀土化合物1.6‑3份、聚四氟乙烯微粉5‑8份、金刚石微粉3‑6份、纳米氧化锌1.5‑2.4份、磁波石4‑8份、明胶4‑5份、橄榄石6‑10份、紫砂0.8‑1.5份、云母4‑6份和玉米5‑10份。本发明原料来源广泛,降低了生产成本,通过将不同的原料采用不同的制备工艺并且将各种原料进行二次烧结,制备的成品可以加快酒分子的布朗运动,缩短酒的酿造周期,提高了酿酒者的经济效益,使用效果好;本产品还可以适用于其他发酵领域,使用范围广。

Description

一种加快发酵过程的陶瓷及其制备方法
技术领域
本发明涉及特种陶瓷,具体是一种加快发酵过程的陶瓷。
背景技术
陶瓷在中国有悠久的历史,如今已在全世界范围内广泛使用,陶瓷是用陶土和瓷土这两种不同性质的粘土为原料,经过配料、成型、干燥、焙烧等工艺流程制成的器物,陶瓷的发展史是中华文明史的一个重要的组成部分,中国作为四大文明古国之一,为人类社会的进步和发展做出了卓越的贡献,其中陶瓷的发明和发展更具有独特的意义,中国历史上各朝各代有着不同艺术风格和不同技术特点。
发酵指人们借助微生物在有氧或无氧条件下的生命活动来制备微生物菌体本身、或者直接代谢产物或次级代谢产物的过程,是人类较早接触的一种生物化学反应,如今在食品工业、生物和化学工业中均有广泛应用,其也是生物工程的基本过程,即发酵工程。发酵在人们的生活和生产中也有许多应用,酿酒就是其中一种,众所周知,酿酒的周期长,导致回报周期长,人们目前也采用微波、电磁能的方法加快发酵过程从而缩短发酵时间,但是这些技术的设备成本高,需要场地大,这就为其应用带来了限制。
发明内容
本发明的目的在于提供一种加快发酵过程的陶瓷,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种加快发酵过程的陶瓷,包括以下重量份的原料:尖晶石8-13份、稀土化合物1.6-3份、聚四氟乙烯微粉5-8份、金刚石微粉3-6份、纳米氧化锌1.5-2.4份、磁波石4-8份、明胶4-5份、橄榄石6-10份、紫砂0.8-1.5份、云母4-6份和玉米5-10份。
作为本发明进一步的方案:稀土化合物包括稀土硝酸盐、稀土碳酸盐、稀土硫酸盐以及稀土磷酸盐中的至少一种。
作为本发明进一步的方案:聚四氟乙烯微粉的粒径为30-65um,金刚石微粉的粒径为12-25um,纳米氧化锌的粒径为45-80nm。
所述加快发酵过程的陶瓷的制备方法,具体步骤如下:
步骤一,将玉米榨成汁并且在30-45摄氏度以及PH值为4.5-6的环境下酶解5-8小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至100-150目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在50-60摄氏度下的球磨机中球磨均匀,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在520-580摄氏度下煅烧90-135分钟,自然冷却至40-55摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为2-4分钟,完全加入玉米发酵液后继续研磨60-80分钟,得到第二混合物;
步骤五,将明胶溶于其重量2-3倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为3600-4500rpm的球磨机中球磨50-75分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在850-920摄氏度的烧结炉中保持2-4小时,然后以15-20摄氏度/分钟的速度升温至1350-1560摄氏度并且保持7-10小时,自然冷却即得到成品。
作为本发明进一步的方案:步骤三球磨机的球料比为45-60:1,球磨速度为90-150rpm。
与现有技术相比,本发明的有益效果是:本发明原料来源广泛,降低了生产成本,通过将不同的原料采用不同的制备工艺并且将各种原料进行二次烧结,制备的成品可以加快酒分子的布朗运动,缩短酒的酿造周期,提高了酿酒者的经济效益,使用效果好;本产品还可以适用于其他发酵领域,使用范围广。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
一种加快发酵过程的陶瓷,包括以下重量份的原料:尖晶石8份、稀土化合物1.6份、聚四氟乙烯微粉5份、金刚石微粉3份、纳米氧化锌1.5份、磁波石4份、明胶4份、橄榄石6份、紫砂0.8份、云母4份和玉米5份。稀土化合物包括稀土硝酸盐以及稀土磷酸盐的混合物。
所述加快发酵过程的陶瓷的制备方法,具体步骤如下:
步骤一,将玉米榨成汁并且在38摄氏度以及PH值为4.7的环境下酶解6小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至120目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在54摄氏度下的球磨机中球磨均匀,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在560摄氏度下煅烧125分钟,自然冷却至48摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为3分钟,完全加入玉米发酵液后继续研磨66分钟,得到第二混合物;
步骤五,将明胶溶于其重量2倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为3900rpm的球磨机中球磨65分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在870摄氏度的烧结炉中保持3小时,然后以18摄氏度/分钟的速度升温至1480摄氏度并且保持8小时,自然冷却即得到成品。
将实施例1的产品作为容器,将酒厂刚蒸馏出来的原浆白酒进行密封,同时将同样的白酒装入普通瓷瓶密封作为对比;密封30天之后开启密封,实施例1的酒绵柔醇和、香味浓郁,后味长,相当于窖藏 1 年的效果;而对比样新酒气味浓,燥辣、后味短,酒的品质没有发生改变,再次密封并继续保存50天,再次开启密封,实施例1的酒相当于窖藏3年的效果,对比例酒的品质没有太大改变。
实施例2
一种加快发酵过程的陶瓷,包括以下重量份的原料:尖晶石10份、稀土化合物2.2份、聚四氟乙烯微粉6.4份、金刚石微粉3.8份、纳米氧化锌1.9份、磁波石5.5份、明胶4.3份、橄榄石7.2份、紫砂1.1份、云母4.8份和玉米7份。聚四氟乙烯微粉的粒径为48um,金刚石微粉的粒径为16um,纳米氧化锌的粒径为70nm。
所述加快发酵过程的陶瓷的制备方法,具体步骤如下:
步骤一,将玉米榨成汁并且在38摄氏度以及PH值为5.2的环境下酶解7小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至140目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在56摄氏度下的球磨机中球磨均匀,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在540摄氏度下煅烧115分钟,自然冷却至44摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为3分钟,完全加入玉米发酵液后继续研磨75分钟,得到第二混合物;
步骤五,将明胶溶于其重量3倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为3900rpm的球磨机中球磨68分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在900摄氏度的烧结炉中保持3.5小时,然后以19摄氏度/分钟的速度升温至1530摄氏度并且保持8小时,自然冷却即得到成品。
将实施例2的产品作为容器,将酒厂刚蒸馏出来的原浆白酒进行密封,同时将同样的白酒装入普通瓷瓶密封作为对比;密封34天之后开启密封,实施例2的酒绵柔醇和、香味浓郁,后味长,相当于窖藏 1 年的效果;而对比样新酒气味浓,燥辣、后味短,酒的品质没有发生改变,再次密封并继续保存60天,再次开启密封,实施例2的酒相当于窖藏3年的效果,对比例酒的品质没有太大改变
实施例3
一种加快发酵过程的陶瓷,包括以下重量份的原料:尖晶石12份、稀土化合物2.6份、聚四氟乙烯微粉7.2份、金刚石微粉5.5份、纳米氧化锌2.2份、磁波石7份、明胶4.7份、橄榄石9.5份、紫砂1.4份、云母5.6份和玉米9份。稀土化合物包括稀土硝酸盐、稀土硫酸盐以及稀土磷酸盐的混合物。
所述加快发酵过程的陶瓷的制备方法,具体步骤如下:
步骤一,将玉米榨成汁并且在42摄氏度以及PH值为5.5的环境下酶解7小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至120目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在58摄氏度下和球料比为50:1的球磨机中球磨均匀,球磨速度为120rpm,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在555摄氏度下煅烧130分钟,自然冷却至48摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为3分钟,完全加入玉米发酵液后继续研磨70分钟,得到第二混合物;
步骤五,将明胶溶于其重量3倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为4200rpm的球磨机中球磨60分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在910摄氏度的烧结炉中保持3小时,然后以18摄氏度/分钟的速度升温至1390摄氏度并且保持10小时,自然冷却即得到成品。
将实施例3的产品作为容器,将酒厂刚蒸馏出来的原浆白酒进行密封,同时将同样的白酒装入普通瓷瓶密封作为对比;密封25天之后开启密封,实施例3的酒绵柔醇和、香味浓郁,后味长,相当于窖藏 1 年的效果;而对比样新酒气味浓,燥辣、后味短,酒的品质没有发生改变,再次密封并继续保存45天,再次开启密封,实施例3的酒相当于窖藏3年的效果,对比例酒的品质没有太大改变
实施例4
一种加快发酵过程的陶瓷,包括以下重量份的原料:尖晶石13份、稀土化合物3份、聚四氟乙烯微粉8份、金刚石微粉6份、纳米氧化锌2.4份、磁波石8份、明胶5份、橄榄石10份、紫砂1.5份、云母6份和玉米10份。稀土化合物包括稀土硝酸盐、稀土碳酸盐、稀土硫酸盐以及稀土磷酸盐的混合物。聚四氟乙烯微粉的粒径为55um,金刚石微粉的粒径为20um,纳米氧化锌的粒径为70nm。
所述加快发酵过程的陶瓷的制备方法,具体步骤如下:
步骤一,将玉米榨成汁并且在40摄氏度以及PH值为5.2的环境下酶解6小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至120目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在55摄氏度下和球料比为60:1的球磨机中球磨均匀,球磨速度为135rpm,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在550摄氏度下煅烧120分钟,自然冷却至48摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为4分钟,完全加入玉米发酵液后继续研磨75分钟,得到第二混合物;
步骤五,将明胶溶于其重量3倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为3600rpm的球磨机中球磨68分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在860摄氏度的烧结炉中保持3小时,然后以15摄氏度/分钟的速度升温至1450摄氏度并且保持8小时,自然冷却即得到成品。
将实施例4的产品作为容器,将酒厂刚蒸馏出来的原浆白酒进行密封,同时将同样的白酒装入普通瓷瓶密封作为对比;密封40天之后开启密封,实施例4的酒绵柔醇和、香味浓郁,后味长,相当于窖藏 1 年的效果;而对比样新酒气味浓,燥辣、后味短,酒的品质没有发生改变,再次密封并继续保存70天,再次开启密封,实施例4的酒相当于窖藏3年的效果,对比例酒的品质没有太大改变。
本发明的产品中将玉米进行发酵,将橄榄石、尖晶石等采用玉米发酵液进行改性,提高官能团的活性,同时将稀土化合物等先煅烧再采用玉米发酵液研磨均匀,再将各种原料采用二次烧结制备成品,利用稀土元素、磁波石等可以释放红外线并且形成磁场,加快酒分子的布朗运动,促进发酵过程,缩短发酵时间,从而大大缩短了酒的酿造周期。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。

Claims (5)

1.一种加快发酵过程的陶瓷,其特征在于,包括以下重量份的原料:尖晶石8-13份、稀土化合物1.6-3份、聚四氟乙烯微粉5-8份、金刚石微粉3-6份、纳米氧化锌1.5-2.4份、磁波石4-8份、明胶4-5份、橄榄石6-10份、紫砂0.8-1.5份、云母4-6份和玉米5-10份。
2.根据权利要求1所述的加快发酵过程的陶瓷,其特征在于,所述稀土化合物包括稀土硝酸盐、稀土碳酸盐、稀土硫酸盐以及稀土磷酸盐中的至少一种。
3.根据权利要求1所述的加快发酵过程的陶瓷,其特征在于,所述聚四氟乙烯微粉的粒径为30-65um,金刚石微粉的粒径为12-25um,纳米氧化锌的粒径为45-80nm。
4.一种如权利要求1-3任一所述的加快发酵过程的陶瓷的制备方法,其特征在于,具体步骤如下:
步骤一,将玉米榨成汁并且在30-45摄氏度以及PH值为4.5-6的环境下酶解5-8小时,酶解结束后灭酶,得到玉米发酵液,将玉米发酵液平均分成两份;
步骤二,将尖晶石、稀土化合物、磁波石、橄榄石、紫砂和云母分别粉碎至100-150目,备用;
步骤三,将尖晶石粉末、聚四氟乙烯微粉、橄榄石粉末、紫砂粉末以及一份玉米发酵液在50-60摄氏度下的球磨机中球磨均匀,得到第一混合物;
步骤四,将磁波石粉末、金刚石微粉、纳米氧化锌、云母粉末以及稀土化合物在高混机中搅拌均匀,然后在520-580摄氏度下煅烧90-135分钟,自然冷却至40-55摄氏度,研磨并且边研磨边匀速加入另一份玉米发酵液,玉米发酵液加入的时间为2-4分钟,完全加入玉米发酵液后继续研磨60-80分钟,得到第二混合物;
步骤五,将明胶溶于其重量2-3倍的热水中,得到明胶溶液,将第一混合物、第二混合物以及明胶溶液在转速为3600-4500rpm的球磨机中球磨50-75分钟,得到第三混合物;
步骤六,将第三混合物加入挤压机中,挤压得到半成品,再将半成品在850-920摄氏度的烧结炉中保持2-4小时,然后以15-20摄氏度/分钟的速度升温至1350-1560摄氏度并且保持7-10小时,自然冷却即得到成品。
5.根据权利要求4所述的加快发酵过程的陶瓷的制备方法,其特征在于,所述步骤三球磨机的球料比为45-60:1,球磨速度为90-150rpm。
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101913798A (zh) * 2010-08-18 2010-12-15 郴州功田电子陶瓷技术有限公司 环保型微波介质陶瓷基板
US20140187732A1 (en) * 2013-01-02 2014-07-03 PosiBond LLC Grout and mortar compositions
CN104876538A (zh) * 2015-04-27 2015-09-02 苏州统明机械有限公司 一种具有稀土元素的陶瓷及其制备方法
CN105164323A (zh) * 2013-03-15 2015-12-16 克洛佩塑料产品公司 提供改进的红外发射率的聚合材料
CN105368648A (zh) * 2015-12-25 2016-03-02 湖南毕胜酒业有限公司 一种酱香型白酒酿造方法及其装置
CN106497310A (zh) * 2016-10-07 2017-03-15 常州创索新材料科技有限公司 一种高散热性机械涂层的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104987052A (zh) * 2015-06-02 2015-10-21 安徽省含山瓷业股份有限公司 一种纳米金刚石增强的陶瓷碗及其制备方法
CN107602109B (zh) * 2017-05-04 2021-01-26 武汉理工大学 一种Cr3+掺杂富铝镁铝尖晶石荧光透明陶瓷及其制备方法
CN107540341B (zh) * 2017-08-28 2020-09-22 福建省德化县盛艺窑瓷业有限公司 一种耐磨的特种陶瓷及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101913798A (zh) * 2010-08-18 2010-12-15 郴州功田电子陶瓷技术有限公司 环保型微波介质陶瓷基板
US20140187732A1 (en) * 2013-01-02 2014-07-03 PosiBond LLC Grout and mortar compositions
CN105164323A (zh) * 2013-03-15 2015-12-16 克洛佩塑料产品公司 提供改进的红外发射率的聚合材料
CN104876538A (zh) * 2015-04-27 2015-09-02 苏州统明机械有限公司 一种具有稀土元素的陶瓷及其制备方法
CN105368648A (zh) * 2015-12-25 2016-03-02 湖南毕胜酒业有限公司 一种酱香型白酒酿造方法及其装置
CN106497310A (zh) * 2016-10-07 2017-03-15 常州创索新材料科技有限公司 一种高散热性机械涂层的制备方法

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