CN108558446A - A kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect - Google Patents
A kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect Download PDFInfo
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- CN108558446A CN108558446A CN201810587557.8A CN201810587557A CN108558446A CN 108558446 A CN108558446 A CN 108558446A CN 201810587557 A CN201810587557 A CN 201810587557A CN 108558446 A CN108558446 A CN 108558446A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Abstract
A kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect comprising following steps：A, there is the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct to carry out first time firing at 600 1050 DEG C surface；B, the organic penetration glaze ink of charity and organic penetration-assisting agent ink on the green body after first time is burnt into；C, second is carried out at 1,150 1250 DEG C to be burnt into；D, it is polished, edging processing obtains ceramic brick product.The present invention is by using Ceramic Tiles made from the above method, the permeable formation that penetration glaze ink is formed has certain thickness, and it penetrates into precoat, so that decorative pattern is wear-resistant, solving the printed decor for printing to be formed by typical inkjet in the prior art does not have solid layer feeling and the problems such as intolerant to abrasion.
Description
Technical field
The present invention relates to architectural pottery technical field more particularly to a kind of manufactures of the Ceramic Tiles with three-dimensional decorative effect
Method.
Background technology
Ceramic ink jet printing technology is to be widely used in a kind of technology of ceramic tile production in recent years, will be black by nozzle
Water is printed upon the decorative means such as adobe face instead conventional screen stamp, roller printing, can since it is a kind of non-contact printing
" printing " male and fomale(M＆F) product, does not need plate-making in kind, turns version simply rapidly, it can be achieved that personalized produce, and production is reproducible, because
And use scope is more and more wider.But its disadvantage is that the decorative layer printed is excessively shallow, meanwhile, ink fire after wearability compared with
Difference can make decorative effect have a greatly reduced quality with the extension of usage time, thus have and applied in the decorative layer after inkjet printing
Bright glaze or cloth clear frit, to protect the technique of decorative layer decorative pattern.However, being clear frit or clear frit, in order to make ink-jet
Better decorative effect is presented in decorative layer, must just enhance the transparency, but while transparency raising, wearability can also decline
(contain the cosolvents such as lead and zinc in order to increase transparency, in glaze also makes glaze become more while increasing glaze transparency
It is soft, not wear-resisting), thus still cannot fundamentally solve the problems, such as to keep long-term decorative effect.
Application number CN201210331440.6 discloses one kind and oozing colored Imitation Rock Porcelain Tiles and its production method, is oozed water-soluble
Flower ink is printed upon leaching on the starch adhesive on adobe surface by way of inkjet printing, although after infiltration, can generate certain
The decorative pattern of depth, but because starch adhesive moisture content is higher, cause the infiltration difficulty of aqueous infiltration color glaze ink to increase, and due to brick
Base moisture evaporation also be easy to cause faulty nozzle to nozzle.In addition, being easily formed using the glaze slip that bell jar is drenched in adobe surface
The defect of edge protrusion, the color difference control being unfavorable for after polishing.In addition, worldwide aqueous infiltrating glaze ink is until current
Until and it is immature, be also applicable to far away on practical ink jet printer and produce.
Thus when firing due to inconsistent with bottom base shrinking percentage and then will produce deformation, raw green strength reduces, easy
Split brick.
Application number CN201110187245.6 discloses a kind of aqueous infiltrating glaze suitable for inkjet printing and its for making pottery
The method of ceramic tile production, is directly to be printed upon aqueous infiltrating glaze in adobe by inkjet printing, then spray water to help and ooze.But actually
Aqueous infiltrating glaze ink is up to the present and immature, is also applicable to far away on practical ink jet printer and produces.
Invention content
It is not wear-resisting it is an object of the invention to solve to print the printed decor to be formed by typical inkjet in the prior art
Damage, the problems such as three-dimensional sense is poor, propose a kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect.
For this purpose, the present invention uses following technical scheme：
1, a kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect comprising following steps：
A, there is the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct to carry out first time firing at 600-1050 DEG C surface；
B, the organic penetration glaze ink of charity and organic penetration-assisting agent ink on the green body after first time is burnt into；
C, second is carried out at 1150-1250 DEG C to be burnt into；
D, it is polished, edging processing obtains ceramic brick product.
Moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct is typically to carry out punch forming using the mold with Z-Correct bump mapping Z-correct and obtain.
Preferably, in the above-mentioned methods, between step B and step C further include the decoration of charity one protection in billet surface
The step of layer.Decoration protective layer is combined by any one or a few mode once and is formed, apply clear frit, the translucent dry granular of paving cloth or
Spread cloth clear frit.After secondary high-temperature firing, decoration protective layer can form the substance of one layer of glassy state, product can be made to have
There is better anti-pollution characteristic, while also assigning product more preferably decorative effect.
The first easy fired is carried out at 600-1050 DEG C, in order to the stomata in adobe be allowed fully to open (such as original
Organic matter in material) and permeated again after stomata opening, penetration glaze ink can ask diffusion admittance, diffusion with stomata
It can reinforce, reduce the dosage of organic inks, and diffusion can be made to be more uniformly distributed.
The purpose that second firing is carried out at 1150-1250 DEG C is the liquid generated in the process in order to allow blank sintering
The stomata for generating first time easy fired of meeting is closed, and keeps the anti-pollution characteristic of product more preferable.
Preferably, further include drying steps between step B and step C.
It is further preferred that the temperature of the drying is 50-200 DEG C, it is 10 minutes dry or more.
Preferably, described in stepb to permeate the mixture that color glaze ink is acylate and ester, wherein acylate is
At least one of carboxyl acid group, sulfonate radical, sulfinate, thionothiolic acid root with in the inorganic color development ion such as iron, cobalt, chromium, copper
At least one composition salt, the ester is long chain alkane, isooctyl acid methyl esters, at least one of pungent methyl caprate.It is above-mentioned
Esters have the effect of improving the viscosity performance of ink, promote ink bleed.
It is further preferred that the acylate be the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper in extremely
A kind of few salt of composition.
Preferably, organic penetration-assisting agent ink in stepb is the mixture of organic acid and ester, and the organic acid is
At least one of carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid, the ester are long chain alkane, isooctyl acid methyl esters, pungent methyl caprate
At least one of.The above raw material is organic liquid material.Using it is such help ink bleed water help ooze the time be 15-30 minutes.
Preferably, when organic penetration-assisting agent ink is in 30 ± 10 grams/m2, penetration depth is in 0.3-0.6mm；When penetration-assisting agent ink
For water in 50 ± 10 grams/m2, penetration depth is in 0.5-0.8mm；When penetration-assisting agent ink is in 80 ± 20 grams/m2, penetration depth exists
0.7-1.0mm。
Preferably, in step, the first time firing temperature is 850-1050 DEG C.
It is burnt into for the first time using through 850-1050 DEG C of low temperature, then the organic penetration glaze ink of charity and organic penetration-assisting agent ink
Mode, the stomata that the water of constitution and organic matter that can be allowed in green body are formed constitutes the infiltration lane of ink, can be less
Obtain that color development is good and deeper infiltration decorative layer under ink consumption, and in green body high-temperature sintering process, the liquid phase of generation can general
The stomata closing that first time easy fired generates, keeps the anti-pollution characteristic of product more preferable.And because first time low-temperature sintering allows base
Body has some strength, avoids larger to blank strength in organic penetration glaze ink and organic penetration-assisting agent ink consumption
It influences.
It is, of course, also possible to further include the steps that moulded pottery not yet put in a kiln to bake is dried between step A and step B, drying temperature is
150-350 DEG C, drying time >=10 minute.Setting can use lower temperature to carry out first time easy fired in this way, specifically,
It can achieve the effect that 850-1050 DEG C at 600-850 DEG C.Drying can utilize the waste heat of kiln, using pre-dry side
Case can reduce energy consumption.
Preferably, used moulded pottery not yet put in a kiln to bake has initial bed and precoat to constitute, and is just being beaten using well known or counter is beaten Strand Feeding Technique
It carries out cloth and cloth is preferably just beaten for such product.Moreover, in fabric, horn of plenty decorative effect, wherein can contain
Some striped material, these striped powders can be in fabrics by well known Strand Feeding Technique (such as using feeler, patterned roller etc.)
Texture is formed in layer, after male and female mold punch forming, Z-Correct bump mapping Z-correct can be formed on brick face, and be also embedded in precoat
Decorate texture.The grain effect of the product obtained after burning in this way is more three-dimensional, assigns product more rich expressive force.
By using Ceramic Tiles made from the above method, the permeable formation that penetration glaze ink is formed has certain thick the present invention
Degree, and penetrate into precoat so that decorative pattern is wear-resistant, solves in the prior art to print by typical inkjet to be formed
Printed decor do not have solid layer feeling and intolerant to abrasion the problems such as.
Specific implementation mode
The technical solution further illustrated the present invention below by specific implementation mode.
Embodiment 1
The present embodiment provides a kind of Ceramic Tiles and its manufacturing method with three-dimensional decorative effect,
The present invention provides a kind of Ceramic Tiles with three-dimensional decorative effect, includes from bottom to top:Initial bed has Z-Correct bump mapping Z-correct
Precoat and decoration protective layer.The precoat includes that thickness is the permeable formation that 0.3~0.6mm organic liquid materials are formed；
The decoration protective layer is translucent dry granular or the glass state material that frit granules are formed through high-temperature fusion postcooling.The above structure
Adobe, after sintering because permeable formation have certain thickness, add 0.2-0.5mm thickness translucent dry granular or frit
The glass state material that grain is formed through high-temperature fusion postcooling, can successfully carry out rubbing down processing, and permeable formation is formed by
Decorative pattern is also especially wear-resisting.
Certainly, for the entire body product regardless of initial bed and precoat can also scheme using the present invention, using bottom material
The mode that layer and precoat carry out double-layer cloth can obtain more abundant decorative effect.
In the above Ceramic Tiles, when containing striped material in fabric, after cloth punch forming, item can be embedded in precoat
Line or granular texture.The striated texture is to form (such as magic cloth) by Strand Feeding Technique well known to industry, can be with
It is the various textures such as threadiness, graininess, cloud shape, wood grain, stone pattern.Because remaining position with precoat for forming the above texture has
Different so that permeation layer thickness also has corresponding difference (different material penetration depth different), be further reduced because
Loss caused by polishing, meanwhile, it can also enrich decorative effect.
Specifically, it manufactures with the following method,
Strand Feeding Technique twice is just being beaten using well known, the use of add mass fraction on the basis of well known fabric is being 0.1-2% dioxies
Change titanium, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicates, 0.5-5% and help red dose, the mold with concave convex texture is used after cloth
Punch forming is formed in the adobe with Z-Correct bump mapping Z-correct on precoat.Certainly, it will be appreciated by those skilled in the art that above
Several auxiliary agents can only use it is one or more arrange in pairs or groups, in actual production, as needed formed decorative effect ink
Demand is handled into collocation.It is used to help red dose of main component for nano silicon dioxide, it can be public to color glaze feed additives
Department's purchase obtains, such as helps red dose to be purchased from Mei Gao companies used in the present invention.
After drying, adobe is sent into kiln and carries out first time easy fired, firing temperature is carried out according to body recipe component
Adjustment, in the present embodiment, selects 850-1050 degrees Celsius of progress first time easy fired by usually 600-1050 degrees Celsius.
After easy fired, the water of constitution in green body decomposes, and organic component burning can form some stomatas in adobe, these stomatas will
The channel subsequently permeated, by using treatment thereto mode, osmotic effect is more preferable, and green body through first time low temperature burn
After knot have some strength, can to avoid during follow-up ink bleed to the influence of blank strength.
It is that inkjet printing is blue, red, yellow, black successively by 200PL subsequently to use the resolution ratio 400dpi of printer, nozzle bore
4 colors or indigo plant, red, yellow, red 3 color (red ink-jet 2 times) organic solvent type penetration glaze ink.The ink ejection amount of mono ink is in 0-
50g/m2, to obtain the hair color effect of enough saturations.When inkjet printing, the temperature of green body is advisable between 45-55 degrees Celsius.
Organic penetration glaze ink is the mixture of acylate and ester, wherein the acylate is carboxyl acid group, sulfonic acid
What at least one of at least one of root, sulfinate, thionothiolic acid root and the inorganic color development ion such as iron, cobalt, chromium, copper were constituted
Salt；Ester is at least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.The color and coloring intensity of ink are by it
In the type of inorganic color development ion that contains it is related to dosage, can be allocated according to specific needs, it is organic in this embodiment
Hydrochlorate is carboxyl hydrochlorate, and ester is long chain alkane.
The color of ink can there are many selections, such as blue, red, yellow in the present embodiment can synthesize oozing for multiple color
Saturating color glaze ink, and then full-color effect is obtained, and black can adjust the gray scale of color, the type and dosage of used ink can
To carry out selection collocation according to practical print pattern effect.
Ink-jet printer is reused in adobe surface inkjet printing 1-3 all over penetration-assisting agent ink, the total ink ejection amount of penetration-assisting agent ink
In 30 ± 10 grams/m2, penetration depth meets the soft requirement for throwing technology controlling and process in 0.3-0.6mm.
By test, when penetration-assisting agent ink is in 30 ± 10 grams/m2, penetration depth is in 0.3-0.6mm；When penetration-assisting agent ink
In 50 ± 10 grams/m2, penetration depth is in 0.5-0.8mm；When penetration-assisting agent ink is in 80 ± 20 grams/m2, penetration depth exists
0.7-1.0mm.When in use, penetration depth that can be as needed carries out the dosage of setting penetration-assisting agent ink, such as can be with
Increase ink ejection amount or by the way of repeating inkjet printing.When penetration glaze ink and more penetration-assisting agent ink consumption, it can be formed
Deeper permeable formation can reduce the defect revealed the exact details caused by crossing throwing.
Contain penetration-assisting agent in penetration-assisting agent ink, it is preferable that selection in the present embodiment with permeate that color glaze ink is identical has
Solvent type can promote penetration glaze ink to be permeated into green body in this way, the two has better intersolubility.The present embodiment makes
Organic solvent type penetration-assisting agent ink, component is similar with organic penetration glaze ink, and the mixture all for machine acid and ester is organic
Acid is at least one of carboxylic acid, sulfonic acid, sulfinic acid, thionothiolic acid, and the fat is long chain alkane, isooctyl acid methyl esters, the pungent last of the ten Heavenly stems
At least one of sour methyl esters.Inorganic color development ion is not contained wherein, can be ensured that two kinds of inks have in this way and be dissolved each other well
Property, osmotic effect is good, and is not in because of colour cast or chromatic aberration defect caused by penetration depth is inconsistent.The penetration-assisting agent ink
Water can need repeatedly to realize by duplicate printing according to penetration depth.
In order to allow penetration glaze ink that can infiltrate into required depth in green body, need inkjet printing infiltration color glaze ink and
Green body after penetration-assisting agent ink is placed at least 10 minutes.Green body standing time is 15-30 minutes in the present embodiment, to be sent out
Color gradient is more stable, the greater concentration of adobe in color development region is preferably dried again after infiltration is completed in adobe, does
Dry temperature is 60-150 DEG C, and the time is 10-100 minutes.It needs exist for illustrating that the above placement and dry process are not the present invention
The indispensable step of scheme.The purpose placed and dried is to keep infiltration ink bleed effect more preferable, and placement makes infiltration more fill
Point, and dry the hole that ink can be promoted to be formed along first time low-temperature sintering in green body and be diffused, more preferably decorated
Effect, and the organic component in used organic type ink can also be made to volatilize in this way, it is reduced in firing to the shadow of green body
It rings.
By dry granular machine in adobe whole face one layer of translucent dry granular of uniform spreading, granularity is in 20-60 mesh ranges, to obtain thickness
Spend the having transparent decoration layer of 0.3mm or so.
The Ceramic Tiles moulded pottery not yet put in a kiln to bake that above method is obtained enters klining at then (the throwing amount of cutting is in 0.3- through high-strength flexible polishing
Within the scope of 0.5mm) and chamfer machining after, you can obtain have infiltration decorative layer Ceramic Tiles, the infiltration decorative layer on brick body surface
With certain thickness, and it is that there is particularly preferred abrasion resistant effect inside embedded adobe.
In this embodiment, used kiln is roller kilns, and firing temperature is 1150~1250 DEG C, firing period 50-
90 minutes.In practical applications, calcining system is adjusted according to kiln conditions and body recipe system, this belongs to this field
Technician can obtain in limited number of time experiment, just no longer do additionally repeating.The liquid phase that second of high temperature sintering generates can be by the
The Minute pores that low-temperature sintering generates are blocked, and product has better anti-fouling effect.
Comparative example 1
Without specified otherwise, the raw material type used in comparative example, technological parameter is same as Example 1.
A kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect comprising following steps：
A, the organic penetration glaze ink of charity and organic penetration-assisting agent ink on the moulded pottery not yet put in a kiln to bake with Z-Correct bump mapping Z-correct；
B, after step A, the decoration of charity one protective layer in billet surface；
C, it is burnt at 1150-1250 DEG C；
D, it is polished, edging processing obtains ceramic brick product.
The organic penetration glaze ink and organic penetration-assisting agent ink that the present embodiment uses are same as Example 1, and difference is
The present embodiment does not pass through first time easy fired, therefore since the diffusion of penetration glaze ink is not very strong, so increasing
The dosage of organic inks (in the case where obtaining identical coloring intensity and penetration depth, ink will increase the dosage of 20-30%), and
It does not spread uniformly, causes ceramic brick product obtained bad in the decorative effect of pattern, and wearability is not very good, figure
The solid layer feeling of case is nor apparent.In this comparative example, the breakage rate of adobe is also higher (compared with 1 high 5- of embodiment
7%), this is because process of osmosis is larger to the intensity effect of moulded pottery not yet put in a kiln to bake, when infiltration capacity is more, green body can soften and be easily deformed
It is broken.
Embodiment 2
The present embodiment is with 1 difference of embodiment：The inkjet printing mode of organic penetration glaze ink and organic penetration-assisting agent ink
Difference, and also dried after the organic penetration glaze ink of charity and organic penetration-assisting agent ink in the present embodiment.In this reality
It applies in example, organic penetration glaze ink is by the way of duplicate printing, and organic penetration-assisting agent ink is then substituted by the way of spraying
Inkjet printing.The more simple modes such as certain roll printing, silk-screen printing carry out penetration-assisting agent ink jet printing, above side
Formula can reach same effect.But from process control, especially for specific pattern is formed, inkjet printing is still first choice
Charity penetration glaze ink and penetration-assisting agent ink mode.
In the prior art, klining can be directly entered after ink-jet printed at this is to be directed to aqueous infiltrating agent.But it is used in this scheme
Be organic penetration glaze ink, if directly entering kiln high temperature firing, the organic component in ink can volatilize, and can influence color development in this way,
If organic component remain in it is more in green body, firing when be susceptible to stomata the defects of.In order to solve the above problem, at this
In scheme, increase the step of step drying, specifically, after by two kinds of inks of adobe inkjet printing, place 10 minutes or more, so
Feeding dry kiln is 15 minutes dry at one hundred and twenty degrees centigrade afterwards, it can make organic material slowly volatilize in this way, forms steady seepage
Gradient and contain the less precoat for thering is machine aided to ooze material.It is burnt into if being directly sent in kiln, the expansion of organic penetration glaze ink
It is poor to dissipate effect, and temperature drastically increases in firing, green body can also deformed caused by the volatilization discharge of black Organic substance in water.
Embodiment 3
In the present embodiment before twice firing, one layer of decoration protective layer is first formed on brick face, decoration protective layer passes through charity 30-
The translucent decoration dry granular of 60 purposes is constituted, and forms the substance of one layer of glassy state after burning on brick face, and the stomata that infiltration is generated seals
It is stifled, keep product antifouling property more preferable, while also more resistant.Certain this layer decoration protective layer can also be transparent by glazing or charity
The mode of frit obtains.
Embodiment 4
The present embodiment is first dried it, drying temperature 180 such as embodiment 1 the difference is that after moulded pottery not yet put in a kiln to bake molding substantially
DEG C, drying time is 30 minutes.After carrying out high temperature drying, first time firing can be carried out at a lower temperature.In this embodiment,
Firing temperature is 600-750 DEG C, because drying can be dried it using residual heat from kiln furnace, achievees the purpose that whole energy.
Dry temperature can be set as 150-350 DEG C in actual production, and drying time is not less than 10 minutes.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's
Principle, and it cannot be construed to limiting the scope of the invention in any way.Based on the explanation herein, the technology of this field
Personnel would not require any inventive effort the other specific implementation modes that can associate the present invention, these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. a kind of manufacturing method of the Ceramic Tiles with three-dimensional decorative effect, it is characterised in that：It includes the following steps：
A, there is the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct to carry out first time firing at 600-1050 DEG C surface；
B, the organic penetration glaze ink of charity and organic penetration-assisting agent ink on the green body after first time is burnt into；
C, second is carried out at 1150-1250 DEG C to be burnt into；
D, it is polished, edging processing obtains ceramic brick product.
2. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：Step B
Further include the steps that protective layer is decorated in charity one in billet surface between step C.
3. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：It is also wrapped
Include the drying steps between step B and step C.
4. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：In step
The mixture that color glaze ink is acylate and fat is permeated described in B, wherein acylate is carboxyl acid group, sulfonate radical, sub- sulphur
At least one of acid group, thionothiolic acid root and the salt constituted at least one of the inorganic color development ion such as iron, cobalt, chromium, copper,
The fat is at least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.
5. the manufacturing method of the Ceramic Tiles according to claim 4 with three-dimensional decorative effect, it is characterised in that：It is described to have
Machine hydrochlorate is the salt that at least one of inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is constituted.
6. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：In step
Organic penetration-assisting agent ink in B is the mixture of organic acid and ester, and the organic acid is carboxylic acid, sulfonic acid, sulfinic acid, sulphur
At least one of carboxylic acid, the fat are at least one of long chain alkane, isooctyl acid methyl esters, pungent methyl caprate.
7. the manufacturing method of the Ceramic Tiles according to claim 6 with three-dimensional decorative effect, it is characterised in that：When organic
The dosage of penetration-assisting agent ink is 20-100g/ ㎡.
8. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：In step
In A, the first time firing temperature is 850-1050 DEG C.
9. the manufacturing method of the Ceramic Tiles according to claim 1 with three-dimensional decorative effect, it is characterised in that：The step
Rapid further includes the steps that moulded pottery not yet put in a kiln to bake is dried between A and step B, and drying temperature is 150-350 DEG C, drying time >=10 point
Clock.
10. the manufacturing method of the Ceramic Tiles according to claim 2 with three-dimensional decorative effect, it is characterised in that：Using
As protective layer is decorated in the mode charity of one or more combinations under type：Apply clear frit, the translucent dry granular of paving cloth or paving cloth
Clear frit.
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| CN109626964A (en) * | 2019-02-25 | 2019-04-16 | 佛山石湾鹰牌陶瓷有限公司 | A kind of simulating ceramic tile and preparation method thereof |
| CN109678460A (en) * | 2019-02-26 | 2019-04-26 | 鹰牌陶瓷实业（河源）有限公司 | A kind of preparation method of high emulation ceramic tile blank |
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| CN109704814A (en) * | 2019-02-26 | 2019-05-03 | 河源市东源鹰牌陶瓷有限公司 | A kind of ink ejecting method of high Scagliola ceramic tile |
| CN116178055A (en) * | 2023-04-21 | 2023-05-30 | 佛山市东鹏陶瓷有限公司 | Twice-fired decorative porcelain matrix and preparation method thereof |
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| CN109626964A (en) * | 2019-02-25 | 2019-04-16 | 佛山石湾鹰牌陶瓷有限公司 | A kind of simulating ceramic tile and preparation method thereof |
| CN109704812A (en) * | 2019-02-25 | 2019-05-03 | 佛山石湾鹰牌陶瓷有限公司 | A kind of high emulation antibiotic ceramic tile and preparation method thereof |
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| CN109678460A (en) * | 2019-02-26 | 2019-04-26 | 鹰牌陶瓷实业（河源）有限公司 | A kind of preparation method of high emulation ceramic tile blank |
| CN109704814A (en) * | 2019-02-26 | 2019-05-03 | 河源市东源鹰牌陶瓷有限公司 | A kind of ink ejecting method of high Scagliola ceramic tile |
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| CN116178055A (en) * | 2023-04-21 | 2023-05-30 | 佛山市东鹏陶瓷有限公司 | Twice-fired decorative porcelain matrix and preparation method thereof |
| CN116178055B (en) * | 2023-04-21 | 2024-01-05 | 佛山市东鹏陶瓷有限公司 | Twice-fired decorative porcelain matrix and preparation method thereof |
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Application publication date: 20180921 |