CN204097344U - A kind of ceramic tile moulded pottery not yet put in a kiln to bake - Google Patents
A kind of ceramic tile moulded pottery not yet put in a kiln to bake Download PDFInfo
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- CN204097344U CN204097344U CN201420497003.6U CN201420497003U CN204097344U CN 204097344 U CN204097344 U CN 204097344U CN 201420497003 U CN201420497003 U CN 201420497003U CN 204097344 U CN204097344 U CN 204097344U
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- 239000000919 ceramic Substances 0.000 title claims abstract description 35
- 230000035515 penetration Effects 0.000 abstract description 50
- 239000000976 ink Substances 0.000 description 103
- 239000010410 layer Substances 0.000 description 41
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- 230000000694 effects Effects 0.000 description 28
- 238000007639 printing Methods 0.000 description 22
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- 238000001764 infiltration Methods 0.000 description 17
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- 238000000034 method Methods 0.000 description 15
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
- 239000011449 brick Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- 239000004744 fabric Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
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- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 239000012466 permeate Substances 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 6
- 229910001950 potassium oxide Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 229960001866 silicon dioxide Drugs 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 229910001948 sodium oxide Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- 230000004304 visual acuity Effects 0.000 description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 6
- 230000003204 osmotic effect Effects 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
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- 238000004140 cleaning Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
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- 239000011148 porous material Substances 0.000 description 2
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- 239000008107 starch Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
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- 239000002245 particle Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Abstract
The utility model provides a kind of ceramic tile moulded pottery not yet put in a kiln to bake, and it from bottom to top comprises, initial bed, short-tempered and the textured precoat of tool by rubbing down treat surface, transparent layer, pervious course, described permeation layer thickness is 1.0 ~ 2.5mm, and pervious course is completely through described transparent layer, and enters in precoat.Use the ceramic tile that it is prepared, the pervious course that penetration glaze ink is formed has certain thickness, and infiltrates in transparent, makes decorative pattern wear-resistant, solves in prior art and prints the problems such as the printed decor formed is not wear-resistant by typical inkjet.
Description
Technical field
The utility model relates to architectural pottery production technical field, particularly relates to a kind of ceramic tile moulded pottery not yet put in a kiln to bake.
Background technology
Ceramic ink jet printing technology is a kind of technology being widely used in ceramic tile production in recent years, ink printed is replaced the decorative means such as conventional screen stamp, roller printing on adobe surface by shower nozzle by it, because it is that a kind of noncontact prints, male and fomale(M&F) product " can be printed ", do not need plate-making in kind, turn version simply rapid, personalized production can be realized, produce reproducible, thus use range is more and more wider.But its shortcoming is just that the ornament layer printed is excessively shallow, and meanwhile, it is poor that rear wear resistance fired by ink; along with the prolongation of duration of service; decorative effect can be made to have a greatly reduced quality, thus have on the ornament layer after spray ink Printing and execute transparent or cloth clear frit, to protect the technique of ornament layer decorative pattern.No matter but be transparent or clear frit, in order to make ink-jet ornament layer present better decorative effect, just must enhance the transparency, but while transparency raising, wear resistance also can decline, and thus still fundamentally can not solve the problem keeping long-term decorative effect.And the percolating product that prior art is produced, due to limited penetration depth, infiltration plane is opaque, and it can only produce the pattern effect of plane infiltration, and does not have the pattern effect of three-dimensional infiltration.
Application number CN201210331440.6 discloses one and oozes colored porcelain brick and production method thereof, ooze colored ink and to be printed on by the mode of spray ink Printing by water miscible and to drench on the starch adhesive on adobe surface, although after infiltration, the decorative pattern of certain depth can be produced, but because the more high and thick degree of starch adhesive water ratio is larger, thus when firing due to inconsistent with end base shrinking percentage and then can distortion be produced, green strength reduces, and easily splits brick.
Application number CN201110187245.6 discloses and is a kind ofly applicable to the penetration glaze of spray ink Printing and the method for ceramic tile production thereof, be by spray ink Printing penetration glaze is directly printed on executed ground-coat enamel and cover-coat enamel adobe on, water spray helps and oozes again, the ceramic tile decorative effect that this method is produced is not three-dimensional, and uses water as penetration-assisting agent, limited penetration depth, if when adobe has a distortion, once polishing, the end base of distortion place will be exposed, affect decorative effect.
Summary of the invention
The purpose of this utility model is to propose a kind of ceramic tile moulded pottery not yet put in a kiln to bake and manufacture method thereof, prints the problems such as printed decor is not wear-resistant formed to solve in prior art by typical inkjet.
For reaching this object, the utility model by the following technical solutions: a kind of manufacture method of ceramic tile moulded pottery not yet put in a kiln to bake, it comprises the steps:
A, fabric and bed material carried out secondary material distributing by cloth system after compacting form adobe and dry; Rubbing down process is carried out to dried adobe surface, makes precoat surface short-tempered, and there is rubbing down lines; Then charity layer of transparent glaze;
B, spray ink Printing penetration glaze ink;
C, spray ink Printing penetration-assisting agent ink;
D, placement can obtain the ceramic tile moulded pottery not yet put in a kiln to bake with pervious course for more than 10 minutes.
Permeation layer thickness formed under normal circumstances is 1.0-2.5mm.Cross thin, easily wear and tear in later stage polished finish and use procedure, blocked up, need to use more penetration glaze ink and help and ooze glaze ink, easily cause blank strength to reduce, and then cause, the damaged or problem such as distortion when sintering during conveying.
This programme also provides a kind of method using above ceramic tile moulded pottery not yet put in a kiln to bake to manufacture ceramic tile, the ceramic tile moulded pottery not yet put in a kiln to bake obtained above is entered the ceramic tile that can obtain having pervious course after klining becomes.
This programme is by ink printed on transparent, and transparent contains certain moisture, can accelerate ink bleed, and shower nozzle ink-jet organic solvent type in wide aperture can be used to permeate ink, avoids ink to block and uneven problem, produces better osmotic effect; Solve that directly penetration glaze to be printed on the more high and thick degree of water ratio that water-based powder layer brings comparatively large, thus when firing due to inconsistent with end base shrinking percentage and then can distortion be produced, green strength reduces, and easily splits the problem of brick.
Further, in such scheme, the chemical composition of the described transparent in steps A comprises: aluminum oxide 18-21%, silicon-dioxide 65-72%, calcium oxide 0.5-1.5%, magnesium oxide 0.5-1.5%, potassium oxide 2-3.5%, sodium oxide 3-4.5%.The transparent of above component, the glaze paint fastness to rubbing formed after burning is high, and transparency is high, and the decorative pattern that penetration glaze ink is formed wherein enriches, and has solid layer feeling.
Further, in such scheme, the chemical composition of the described transparent in steps A also comprises: one or more combinations in 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate.Can color development be promoted by adding above component, reaching the object of saving ink.In addition, can obtain comprehensive color development and texture after high-temperature firing, level transition sense is strong and stereoscopic depth sense is strong, can produce abundanter color and darker osmotic effect, penetration glaze can be penetrated into and throw base flower-pattern layer; The tandem product of various luster degree also can be obtained after adopting the module polishing of different meshes and hardness.
Further, in such scheme, in described steps A, the glazing thickness of transparent is 0.2-0.5mm; The transparent of this thickness can allow penetration glaze ink fully permeate, and it is short-tempered and have the precoat of rubbing down lines to enter surface through it, allows decorative effect enrich more lastingly.
Further, in such scheme, the described penetration glaze ink in step B is organic solvent type.Organic solvent type has better osmotic effect, such as, glycol ether can be selected as the penetration glaze ink of solvent.
Described spray ink Printing penetration glaze ink in described step B is print polychrome penetration glaze ink by different spray nozzles successively; By the mixing of different colours ink, can obtain abundant decorative effect, such as conventional is blue, red, yellow, black 4 looks, certainly, in actual applications not by above restriction, can arrange in pairs or groups to ink color according to demand.
Described penetration-assisting agent ink in described step C is organic solvent type; What organic type helped that ink bleed water can be good permeate ink with organic type is combined, and has and promotes its effect of permeating in base substrate, better can control the consumption helping ink bleed water, and can control the thickness of pervious course by spray ink Printing mode.
The utility model also provides a kind of ceramic tile moulded pottery not yet put in a kiln to bake, it from bottom to top comprises, initial bed, short-tempered and the textured precoat of tool by rubbing down treat surface, transparent layer, pervious course, described permeation layer thickness is 1.0 ~ 2.5mm, and pervious course is completely through described transparent layer, and enter in precoat.
Further, in above-mentioned ceramic tile moulded pottery not yet put in a kiln to bake, transparent layer thickness is 0.2-0.5mm.
Further, in above-mentioned ceramic tile moulded pottery not yet put in a kiln to bake, depth of lines≤1.0mm that precoat rubbing down is formed.
Compared to the prior art, the scheme that the utility model provides solves in prior art, the problems such as the decorative pattern that spray ink Printing is formed is not wear-resistant, by the mode of infiltration, penetration glaze ink is infiltrated in the transparent in brick face, and through transparent, in the entering surface bed of material, the decorative pattern that penetration glaze ink is formed is wear-resisting especially, and penetration glaze ink can have certain diffusion after sintering in transparent, makes decorative effect more three-dimensional.
accompanying drawing explanation
Fig. 1 is that the utility model preferred embodiment prepares ceramic tile moulded pottery not yet put in a kiln to bake schematic flow sheet, shows with the cross section structure of moulded pottery not yet put in a kiln to bake;
Fig. 2 is the cross section structure schematic diagram of ceramic tile moulded pottery not yet put in a kiln to bake in the utility model preferred embodiment,
Wherein: initial bed 1, precoat 2, transparent layer 3, pervious course 4.
embodiment
The technical solution of the utility model is further illustrated by embodiment below in conjunction with accompanying drawing.
Shown in accompanying drawing 1 and Fig. 2, a kind of ceramic tile moulded pottery not yet put in a kiln to bake is provided in the present embodiment and uses its ceramic tile manufactured, above-mentioned moulded pottery not yet put in a kiln to bake from bottom to top comprises the initial bed 1 that thickness is 8 ~ 10mm, short-tempered and there is the precoat 2 that lines thickness is about 2mm by rubbing down treat surface, thickness is the transparent layer 3 of 0.2-0.5mm, the pervious course 4 on described transparent layer, and pervious course 4 thickness is 1.0-1.5mm, and pervious course is completely through described transparent layer 3, and have in the part entering surface bed of material.
The manufacturing process of above ceramic tile moulded pottery not yet put in a kiln to bake is as follows:
Adopt that known micro-powder brick is counter makes a call to twice Strand Feeding Technique, use known fabric and bed material, impact briquetting after cloth, form adobe; Carry out rubbing down by after brick bat drying to adobe surface, the rubbing down degree of depth is 0.5-0.6mm, forms the short-tempered and textured precoat 2 of tool; Then impose layer of transparent glaze on its surface, the chemical composition of transparent is: aluminum oxide 18%, silicon-dioxide 65%, calcium oxide 1%, magnesium oxide 0.5%, potassium oxide 3.5%, sodium oxide 4.5%.In order to obtain better glazing effect, usually before glazing, ash cleaning is blown to brick face, and water spray is wetting, to reduce the defects such as pinprick pore; And in above transparent, be also added with the assistant toners such as 2% titanium dioxide, 0.5% zinc oxide, 5% zirconium silicate, can promote that the coloring ion in penetration glaze ink forms the decorative effect of gradual change after sintering like this.
Then use the penetration glaze ink buied from metco company to carry out spray ink Printing and form decorative pattern, the resolving power of institute's use printer is 400dpi, aperture is 35PL, spray ink Printing is blue successively, red, yellow, black 4 look organic solvent type penetration glaze inks, here explanation is needed, in actual applications, the color of ink can have multiple choices, such as blue in the present embodiment, red, Huang can meet into multiple color color, and then obtain full-color effect, and black can the gray scale of adjustable colors, use the kind of ink and consumption can carry out selection collocation according to actual print pattern effect.In addition, the penetration glaze ink used in this enforcement is organic solvent type, and particularly, the organic solvent used is glycol ether, and certainly, this is also only exemplary, with reference to above principle, can arrange in pairs or groups by physical condition in actual use.
Containing corresponding inorganic colourant in penetration glaze ink, such as, containing dispersion cobalt ion in organic solvent in used in the present embodiment blue ink, it can infiltrate through certain depth in base substrate, can form certain thickness pervious course 4.Red, yellow, black ink is also corresponding to corresponding inorganic colourant.
Re-use and adopt resolving power is 400dpi, aperture is 85PL ink-jet printer at adobe surface spray ink Printing penetration-assisting agent ink, containing penetration-assisting agent in penetration-assisting agent ink, preferably, select the organic solvent type identical with penetration glaze ink in the present embodiment, like this, both have better mutual solubility, can promote that penetration glaze ink permeates in base substrate.Metco company also sells organic solvent type penetration-assisting agent ink.
In order to allow penetration glaze ink can infiltrate into desired depth in base substrate, the base substrate after by spray ink Printing penetration glaze ink and penetration-assisting agent ink is needed to place at least 10 minutes.
The ceramic tile moulded pottery not yet put in a kiln to bake above method obtained, enters klining, then after polishing chamfer machining, the ceramic tile with infiltration ornament layer can be obtained, the infiltration ornament layer of brick surface has certain thickness, and is embed adobe inside, has particularly preferred abrasion resistant effect.
In this enforcement, the kiln used is roller kiln, and the problem of burning till is 1210 ~ 1250 DEG C, and firing period is 90-120 minute.In actual applications, calcining system adjusts according to kiln conditions and body recipe system, and this belongs to art technology person and can obtain in limited number of time test, just no longer does additionally repeating.
In addition, under normal circumstances, the precoat thickness of adobe is generally about 3mm, and throw in order to avoid crossing in adobe rubbing down process, the rubbing down degree of depth is many more than 2mm, and can not consider the infiltration situation of penetration glaze ink, and the rubbing down degree of depth usually arranged is 0.6-1.0mm.And after adobe is burnt, likely need to carry out polished finish to it, scrap rate during polishing is generally 0.5-1.0mm, therefore for needing the product needed of carrying out polished finish to note matching with follow-up glossing, otherwise be difficult to throw and put down, and easily occurred the defects such as throwing.
Embodiment 2
In the present embodiment, in order to make penetration glaze ink bleed have gradation sense, striped or granular texture is embedded with at the precoat 2 of adobe.By above setting, permeation layer thickness can be made also to have corresponding difference (different material depth of penetration is different), in the present embodiment, permeation layer thickness is 1.0-1.5mm, the loss that so further minimizing causes because of polishing, meanwhile, also can enrich decorative effect.
Particularly, in a manufacturing process, in fabric, add known striped material or particulate material, and form the various textures such as wire, particulate state, cloud shape, wood grain, bag by magic distributing mode.
In the present embodiment, after cloth is shaping, moulded pottery not yet put in a kiln to bake is dry, then rubbing down process is carried out, the rubbing down degree of depth is about 0.5-0.6mm, the adobe of throwing after cutting is carried out executing transparent after surface cleaning, drifting dust, water spray, and the basic chemical composition of transparent is: aluminum oxide 21%, silicon-dioxide 68%, calcium oxide 0.5%, magnesium oxide 1.5%, potassium oxide 3.5%, sodium oxide 3%.In order to obtain better glazing effect, usually before glazing, ash cleaning is blown to brick face, and water spray is wetting, to reduce the defects such as pinprick pore; And be also added with 0.3% zinc oxide, 1.8% zirconium silicate in above transparent as assistant toner, the coloring ion color development in penetration glaze ink can be promoted like this, save ink consumption, and the decorative effect of gradual change can be formed after sintering.
Then use the penetration glaze ink buied from metco company to carry out spray ink Printing and form decorative pattern, the resolving power of institute's use printer is 400dpi, aperture is 50PL, spray ink Printing is blue successively, red, yellow, black 4 look organic solvent type penetration glaze inks, here explanation is needed, in actual applications, the color of ink can have multiple choices, such as blue in the present embodiment, red, Huang can meet into multiple color color, and then obtain full-color effect, and black can the gray scale of adjustable colors, use the kind of ink and consumption can carry out selection collocation according to actual print pattern effect.In addition, the penetration glaze ink used in this enforcement is organic solvent type, and particularly, the organic solvent used is glycol ether, and certainly, this is also only exemplary, with reference to above principle, can arrange in pairs or groups by physical condition in actual use.
Re-use and adopt resolving power is 400dpi, aperture is 85PL ink-jet printer at adobe surface spray ink Printing penetration-assisting agent ink, containing penetration-assisting agent in penetration-assisting agent ink, preferably, select the organic solvent type identical with penetration glaze ink in the present embodiment, like this, both have better mutual solubility, can promote that penetration glaze ink permeates in base substrate.Metco company also sells organic solvent type penetration-assisting agent ink.
In order to allow penetration glaze ink can infiltrate into desired depth in base substrate, the base substrate after by spray ink Printing penetration glaze ink and penetration-assisting agent ink is needed to place at least 10 minutes.In the present embodiment, the imitated time is about 30 minutes.
The present embodiment because of by ink printed on transparent, transparent contains certain moisture, can accelerate ink bleed, and shower nozzle ink-jet organic solvent type in wide aperture thus can be used to permeate ink, avoid ink to block and uneven problem, produce better osmotic effect.And because transparent layer moisture content is little, thickness is little, with an organic solvent type infiltration ink, avoid that penetration glaze to be printed on the more high and thick degree of water ratio that water-based powder layer brings larger, thus when firing due to inconsistent with end base shrinking percentage and then can distortion be produced, green strength reduces, and easily splits the problem of brick.
The ceramic tile moulded pottery not yet put in a kiln to bake above method obtained, enters klining, then after polishing chamfer machining, the ceramic tile with infiltration ornament layer can be obtained, the infiltration ornament layer of brick surface has certain thickness, and is embed adobe inside, has particularly preferred abrasion resistant effect.
In this enforcement, the kiln used is roller kiln, and the problem of burning till is 1210 ~ 1250 DEG C, and firing period is 90 minutes.In actual applications, calcining system adjusts according to kiln conditions and body recipe system, and this belongs to art technology person and can obtain in limited number of time test, just no longer does additionally repeating.
Embodiment 3
In the present embodiment, basic technology is as embodiment 2, institute's difference is, the pervious course that spray ink Printing penetration glaze ink is formed is part covering transparent layer, and be striated lines, such pervious course infiltrates in transparent layer, the diffuse texture of striated is formed in transparent surface layer, and it infiltrates in the precoat before transparent layer by part, can combine with the texture throwing base formation, obtain the effect embedding three-dimensional stripe in transparent layer, and can organically combine with the lines in base substrate in precoat.
In addition, the thickness of the transparent of institute's glazing is in the present embodiment 0.35mm, and the precoat rubbing down degree of depth is 0.8mm, and permeation layer thickness is 1.5-2.0mm.The chemical composition of transparent is the zirconium silicate of aluminum oxide 18%, silicon-dioxide 72%, calcium oxide 0.5%, magnesium oxide 0.5%, potassium oxide 2%, sodium oxide 3%, 4%.
Embodiment 4
In the present embodiment, basic technology is identical with embodiment 2, and institute's difference is, the precoat rubbing down degree of depth is 0.8mm, and the pervious course that spray ink Printing penetration glaze ink is formed is part covering transparent layer, and is mottled.Form permeation layer thickness and be about 2.0mm, the thickness of transparent layer is 0.4mm, and the chemical composition of transparent is: aluminum oxide 19%, silicon-dioxide 70%, calcium oxide 1%, magnesium oxide 1%, potassium oxide 3%, sodium oxide 3.5%, 1% titanium dioxide, 1.5% zirconium silicate.
Mottled pervious course after sintering, can form a lot of decoration particle embedded in transparent, and titanium dioxide in transparent and zirconium silicate can form fade effect with the coloring ion in penetration glaze ink, enrich decorative effect further.
The pervious course degree of depth determines with the penetration glaze ink consumption of institute's spray ink Printing substantially, but other factors, the such as consumption of penetration-assisting agent ink, the water ratio of base substrate, storage period all can impact it, in actual use, needs the pervious course that penetration glaze ink is formed, completely through transparent layer, and enter and be advisable in the precoat of rubbing down process.
Embodiment 5
The present embodiment provides a kind of specification to be the manufacture method of ceramic tile, and it comprises the steps:
Known forehand twice micro mist cloth mode is adopted to form initial bed 1 and precoat 2 pressing unfired brick, drying afterwards; Use rubbing down equipment facestock to carry out throwing base, throwing the base degree of depth is 0.8mm.
The adobe of throwing after cutting is carried out executing transparent after surface cleaning, drifting dust, water spray, glaze formula is: aluminum oxide 20%, silicon-dioxide 67.5%, calcium oxide 1.5%, magnesium oxide 1.5%, potassium oxide 3.2%, sodium oxide 4.5%, 1.5% titanium dioxide, 0.3% zinc oxide, the transparent layer of formation is 0.2mm.
Precoat 2 after after charity transparent adopts the ceramic digital ink-jet printer of resolving power 400dpi, aperture 35PL blue, red, yellow, the black 4 look organic solvent type penetration glaze inks of spray ink Printing successively, in this enforcement, because blue penetration glaze ink color development is darker, therefore the blue penetration glaze ink of first spray ink Printing, to ensure that the osmotic effect of itself and all the other inks matches.
Adopt in the adobe after the ceramic digital ink-jet printer of the nozzle of resolving power 400dpi, aperture 60PL and spray organic solvent type penetration-assisting agent ink.
Adobe after step D enters kiln and burns till at 1200 DEG C after stopping 60 minutes.
The depth of penetration of the pervious course of the ceramic tile of the present embodiment is 2.0-2.5mm, and the thickness throwing base ornament layer 22 is 0.8mm, and transparent layer thickness is 0.2mm.
The adobe of the present embodiment stops kiln-firing after 60 minutes, ensure that enough penetration time, thus depth of penetration can reach 2.0-2.5mm, infiltration ink can pass through the precoat that transparent layer enters into rubbing down process, and because containing 1.5% titanium dioxide, 0.3% zinc oxide assistant toner in transparent layer formula, pervious course is the infiltration of thick line shape; Wire infiltration is in conjunction with bringing like extending the effect being embedded in and throwing in base decorative pattern after transparent on sense organ; Color development ion in infiltration ink is combined can produces colour-change with titanium, zinc, thus the part infiltrating through transparent layer can produce gradient color, decorative effect is rich solid more, solve the defect that prior art can not produce longtitudinal dispersion, in addition, because blueness infiltration ink color development is comparatively dark, so the present embodiment first sprays blue ink spray other colors again, ensure that the effect of infiltration.
Below know-why of the present utility model is described in conjunction with specific embodiments.These describe just in order to explain principle of the present utility model, and can not be interpreted as the restriction to the utility model protection domain by any way.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present utility model, and these modes all will fall within protection domain of the present utility model.
Claims (3)
1. a ceramic tile moulded pottery not yet put in a kiln to bake, it from bottom to top comprises, initial bed, short-tempered and the textured precoat of tool by rubbing down treat surface, transparent layer, pervious course, described permeation layer thickness is 1.0 ~ 2.5mm, and pervious course is completely through described transparent layer, and enters in precoat.
2. ceramic tile moulded pottery not yet put in a kiln to bake as claimed in claim 1, it is characterized in that, described transparent layer thickness is 0.2-0.5mm.
3. ceramic tile moulded pottery not yet put in a kiln to bake as claimed in claim 1, is characterized in that, depth of lines≤1.0mm that described precoat rubbing down is formed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201420497003.6U CN204097344U (en) | 2014-08-29 | 2014-08-29 | A kind of ceramic tile moulded pottery not yet put in a kiln to bake |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420497003.6U CN204097344U (en) | 2014-08-29 | 2014-08-29 | A kind of ceramic tile moulded pottery not yet put in a kiln to bake |
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| CN204097344U true CN204097344U (en) | 2015-01-14 |
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| CN201420497003.6U Expired - Lifetime CN204097344U (en) | 2014-08-29 | 2014-08-29 | A kind of ceramic tile moulded pottery not yet put in a kiln to bake |
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| CN (1) | CN204097344U (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591786A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic sheet with infiltration layer |
| CN104591803A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic brick with good antifouling effects |
| CN104591805A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic sheet with good antifouling effects |
| CN104671833A (en) * | 2015-01-26 | 2015-06-03 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic brick with permeable layer |
| CN116283216A (en) * | 2023-03-30 | 2023-06-23 | 南安协进建材有限公司 | Old floor tile and production process thereof |
-
2014
- 2014-08-29 CN CN201420497003.6U patent/CN204097344U/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591786A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic sheet with infiltration layer |
| CN104591803A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic brick with good antifouling effects |
| CN104591805A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic sheet with good antifouling effects |
| CN104671833A (en) * | 2015-01-26 | 2015-06-03 | 佛山市东鹏陶瓷有限公司 | Manufacturing method of ceramic brick with permeable layer |
| CN116283216A (en) * | 2023-03-30 | 2023-06-23 | 南安协进建材有限公司 | Old floor tile and production process thereof |
| CN116283216B (en) * | 2023-03-30 | 2023-11-28 | 南安协进建材有限公司 | Old floor tile and production process thereof |
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Effective date of registration: 20170417 Address after: 528031 Chancheng, Foshan District, Jiangwan, No. three, No., layer 8, layer two Co-patentee after: GUANGDONG DONGPENG HOLDINGS Co.,Ltd. Patentee after: FOSHAN DONGPENG CERAMIC Co.,Ltd. Co-patentee after: QINGYUAN NAFUNA CERAMICS Co.,Ltd. Address before: Chancheng District of Jiangwan city of Foshan province Guangdong three road 528031 No. 8 two Foshan city Eastroc Ceramics Co. Ltd Co-patentee before: GUANGDONG DONGPENG HOLDINGS Co.,Ltd. Patentee before: FOSHAN DONGPENG CERAMIC Co.,Ltd. Co-patentee before: QINGYUAN NAFUNA CERAMICS Co.,Ltd. Co-patentee before: Guangdong Dongpeng Ceramic Co.,Ltd. |
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