CN104671833A - Manufacturing method of ceramic brick with permeable layer - Google Patents
Manufacturing method of ceramic brick with permeable layer Download PDFInfo
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- CN104671833A CN104671833A CN201510038698.0A CN201510038698A CN104671833A CN 104671833 A CN104671833 A CN 104671833A CN 201510038698 A CN201510038698 A CN 201510038698A CN 104671833 A CN104671833 A CN 104671833A
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Abstract
The invention discloses a manufacturing method of a ceramic brick with a permeable layer. The method comprises the following steps: A, feeding dried mud blanks into a kiln and carrying out primary sintering at the temperature of 600-1,050 DEG C; B, applying organic permeating glaze ink and organic permeation-promoter ink on the blank body subjected to primary sintering; C, carrying out secondary sintering at the temperature of 1,150-1,250 DEG C; D, and polishing and edging to obtain a ceramic brick product. By using the ceramic brick manufactured by using the method, a permeation layer formed by the permeating glaze ink has a certain thickness, and the permeating glaze ink is permeated into a fabric layer, so that decorative patterns are abrasion-resistant, and the problems that a printing decoration layer formed by using conventional ink spraying printing has no sense of three-dimensional layering and is easy to abrade are solved.
Description
Technical field
The present invention relates to architectural pottery technical field, particularly relate to a kind of manufacture method with the ceramic tile of pervious course.
Background technology
Ceramic ink jet printing technology is a kind of technology being widely used in ceramic tile production in recent years, ink printed is replaced the decorative means such as conventional screen stamp, roller printing on adobe surface by shower nozzle by it, because it is that a kind of noncontact prints, male and fomale(M&F) product " can be printed ", do not need plate-making in kind, turn version simply rapid, personalized production can be realized, produce reproducible, thus use range is more and more wider.But its shortcoming is just that the ornament layer printed is excessively shallow, and meanwhile, it is poor that rear wear resistance fired by ink; along with the prolongation of duration of service; decorative effect can be made to have a greatly reduced quality, thus have on the ornament layer after spray ink Printing and execute transparent or cloth clear frit, to protect the technique of ornament layer decorative pattern.No matter but be transparent or clear frit, better decorative effect is presented in order to make ink-jet ornament layer, just must enhance the transparency, but it is (in order to increase transparency, many containing solubility promoters such as plumbous and zinc in glaze that while transparency improves, wear resistance also can decline, it is while increase glaze paint transparency, also glaze paint deliquescing is made, not wear-resisting), thus still fundamentally can not solve the problem keeping long-term decorative effect.
Application number CN201210331440.6 discloses one and oozes colored porcelain brick and production method thereof, ooze colored ink and to be printed on by the mode of spray ink Printing by water miscible and to drench on the starch adhesive on adobe surface, although after infiltration, the decorative pattern of certain depth can be produced, but because starch adhesive water ratio is higher, cause the infiltration difficulty of the infiltration color glaze ink of water-based to increase, and also easily cause faulty nozzle because raw brick moisture content evaporate into shower nozzle.In addition, adopt the bell jar glaze slip drenched in adobe surface also easily to form the defect of edge projection, be unfavorable for the Difference Control after polishing.In addition, worldwide aqueous infiltrating glaze ink up to this point and immature, also can be applied to far away on actual ink jet unit and produce.
Thus when firing due to inconsistent with end base shrinking percentage and then can distortion be produced, raw green strength reduces, and easily splits brick.
Application number CN201110187245.6 discloses and is a kind ofly applicable to the aqueous infiltrating glaze of spray ink Printing and the method for ceramic tile production thereof, is directly be printed in adobe by aqueous infiltrating glaze by spray ink Printing, then water spray helps and oozes.Up to the present and immature but in fact aqueous infiltrating glaze ink, also can be applied to far away on actual ink jet unit and produce.
Summary of the invention
The object of the invention is to solve in prior art and print a kind of manufacture method with the ceramic tile of pervious course of the problems such as the printed decor formed is not wear-resistant, stereoscopic sensation is poor proposition by typical inkjet.
For reaching this object, the present invention by the following technical solutions:
Have a manufacture method for the ceramic tile of pervious course, it comprises the steps:
A, moulded pottery not yet put in a kiln to bake is sent in kiln, at 600-1050 DEG C, carry out first time burn till;
B, first time burn till after base substrate on charity organic penetration glaze ink and organic penetration-assisting agent ink;
C, at 1150-1250 DEG C, carry out second time burn till;
D, carry out polishing, edging processing obtains ceramic tile product.
The first easy fired is carried out at 600-1050 DEG C, object is to allow the pore in adobe fully open (organism in such as raw material) and to permeate after pore is opened again, pore can as diffusion admittance, the diffusion of penetration glaze ink can be strengthened, reduce the consumption of organic inks, and diffusion can be made more even.
Carrying out the second time object of burning till at 1150-1250 DEG C is to allow blank sintering, and the pore that first time easy fired produces can be closed by the liquid phase produced in the process, makes the anti-pollution characteristic of product better.
Preferably, it is also included in the drying step between step B and step C.
Preferred further, the temperature of described drying is 50-200 DEG C, and time of drying is more than 10 minutes.The object of carrying out redrying is to allow organic penetration glaze ink evaporate under relative speed stably with the organic constituent in organic penetration-assisting agent ink, also make the inorganic color development ion diffuse in organic penetration glaze fully spread, save ink simultaneously.If directly enter klining, steep temperature rise in kiln, the organism in ink volatilizees rapidly, may cause the defects such as blank deformation.
Preferably, described infiltration color glaze ink is the mixture of organic acid salt and ester in stepb, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper, ester is long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.Above-mentioned ester has the viscosity performance improving ink, the effect promoting ink bleed.
Preferred further, described organic acid salt is the salt that at least one in the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is formed.
Preferably, described organic penetration-assisting agent ink is in stepb the mixture of organic acid and ester deter-mation, described organic acid is at least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid, described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate, and above organic acid and ester deter-mation is organic liquid material; The time of oozing preferably is helped to be 15-30 minute.Organic penetration-assisting agent ink and organic penetration glaze ink are same system, make both have good mutual solubility.Can promote that it permeates.
By measuring and calculating, when organic penetration-assisting agent ink is at 30 ± 10 Ke/㎡, depth of penetration is at 0.3-0.6mm; When penetration-assisting agent ink is at 50 ± 10 Ke/㎡, depth of penetration is at 0.5-0.8mm; When penetration-assisting agent ink is at 80 ± 20 Ke/㎡, depth of penetration is at 0.7-1.0mm.
Preferably, the moulded pottery not yet put in a kiln to bake used is made up of initial bed and precoat, adopts known forehand or instead beat Strand Feeding Technique to carry out cloth, for this series products, and preferably forehand cloth.Instead break cloth if adopted, biscuiting again after base first thrown by preferred dry base, ink-jet are permeated.Because, in fabric, horn of plenty decorative effect, wherein some striped material can be contained, these striped powders can form texture by known Strand Feeding Technique (such as using feeler, patterned roller etc.) in precoat, but these textures are unintelligible in the performance at adobe most surface place after impact briquetting, after throw base process, can allow the showing of above clean mark, enrich decorative effect.The grain decorating effect that the product infiltration decorative effect obtained after such burning and cloth are formed merges mutually, gives the expressive force that product is abundanter.
The ceramic tile of the present invention by adopting aforesaid method obtained, the pervious course that penetration glaze ink is formed has certain thickness, and in infiltration precoat, make decorative pattern wear-resistant, solve and print by typical inkjet the printed decor formed in prior art and there is no solid layer feeling and the problem such as not wear-resistant.
In addition, preferably, in the method, moulded pottery not yet put in a kiln to bake described in steps A carries out first time again and burns till after needing first to carry out drying, drying temperature is 150-350 DEG C, time of drying >=10 minutes.Arrange like this and lesser temps can be used to carry out first time easy fired, particularly, the effect of 850-1050 DEG C can be reached at 600-850 DEG C.The dry waste heat that can utilize kiln, adopts pre-dry scheme, can reduce production energy consumption.
Adopt after low temperature first time biscuiting, the mode of charity organic penetration glaze ink and organic penetration-assisting agent ink again, the pore that the constitution water in base substrate and organism can be allowed to be formed forms the infiltration lane of ink, good and the darker infiltration ornament layer of color development can be obtained under less ink consumption, and at base substrate high-temperature sintering process, the pore that first time easy fired produces can be closed by the liquid phase produced, and makes the anti-pollution characteristic of product better.And because low-temperature sintering allows base substrate have some strength for the first time, avoid the impact on blank strength under organic penetration glaze ink and the larger situation of organic penetration-assisting agent ink consumption.
Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
Embodiment 1
The present embodiment provides a kind of ceramic tile and the manufacture method thereof with pervious course,
The invention provides a kind of ceramic tile with pervious course, it from bottom to top comprises: initial bed and precoat.It is the pervious course that 0.3 ~ 0.6mm organic liquid material is formed that described precoat comprises thickness.The adobe of above structure, after sintering because pervious course has certain thickness, successfully can carry out rubbing down process, and the decorative pattern that pervious course is formed is also wear-resisting especially.
Certainly, also can adopt the solution of the present invention for the entire body product regardless of initial bed and precoat, the mode adopting initial bed and precoat to carry out double-layer cloth can obtain the decorative effect of more horn of plenty.
In the present embodiment, in above ceramic tile, described precoat surface has texture.Described texture forms (such as magic cloth) by the known Strand Feeding Technique of industry, can be the various textures such as wire, particulate state, cloud shape, wood grain, bag.Because what form above texture has different with all the other positions of green body layer, make permeation layer thickness also have corresponding difference (different material depth of penetration is different), reduce the loss caused because of polishing further, meanwhile, also can enrich decorative effect.
Particularly, it adopts the ceramic tile manufacturing with the following method and have pervious course,
Adopt known forehand twice Strand Feeding Technique, use and known fabric basis adds mass fraction is 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate, 0.5-5% help red dose, impact briquetting after cloth, form adobe.Certainly, it will be appreciated by those skilled in the art that and can only use one or more to arrange in pairs or groups in above several assistant toner, in actual production, the ink demand forming decorative effect as required enters collocation process.Here need to illustrate, help the main component of red dose to be nano silicon, it is the same with other several component, all has and promotes the effect of ink color development, help the nano silicon in red dose can promote look red colour system color development in ink.Used in embodiments of the present invention help red dose all purchased from Mei Gao company.
After drying, adobe sent in kiln and carry out first time easy fired, firing temperature adjusts according to body recipe component, be generally 600-1050 degree Celsius, in the present embodiment, select 850-1050 degree Celsius and carry out first time easy fired, firing time is 40-90 minute.After easy fired, constitution water in base substrate decomposes, organic constituent burning can form some pores in adobe, the passage that these pores will be follow-up infiltration, by adopting processing mode as above, osmotic effect is better, and base substrate has some strength after first time low-temperature sintering, can avoid the impact on blank strength in follow-up ink bleed process.
Subsequently use the resolving power 400dpi of printer, nozzle bore for blue, red, yellow, black 4 looks of 200PL successively spray ink Printing or indigo plant, red, yellow, red 3 looks (red ink-jet 2 times) organic solvent type penetration glaze ink.The ink ejection amount of mono ink at 0-50g/ ㎡, to obtain enough saturated hair color effect.During spray ink Printing, the temperature of base substrate is advisable between 45-55 degree Celsius.
The mixture that the organic penetration glaze ink used is organic acid salt and ester, the salt that wherein said organic acid salt is carboxyl acid group, at least one in the inorganic color development ion such as at least one and iron, cobalt, chromium, copper in sulfonate radical, sulfinate, thionothiolic acid root is formed, ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.The color of ink is relevant with consumption by the kind of the inorganic color development ion wherein contained with coloring intensity, can allocate according to specific needs, in this enforcement, organic acid salt is carboxyl hydrochlorate, and ester is long chain alkane and pungent methyl caprate is the mixture of 1:2 by volume.
The color of ink can have multiple choices, such as blue, red, Huang can combinationally use and can obtain abundant decorative effect in the present embodiment, and then obtain full-color effect, black can the gray scale of adjustable colors, use the kind of ink and consumption can carry out selection collocation according to actual print pattern effect.
Re-use ink-jet printer at adobe surface spray ink Printing 1-3 all over penetration-assisting agent ink, the total ink ejection amount of penetration-assisting agent ink is when 30 ± 10 Ke/㎡, and depth of penetration, at 0.3-0.6mm, meets the requirement of soft throwing technology controlling and process.
By test, when penetration-assisting agent ink is at 30 ± 10 Ke/㎡, depth of penetration is at 0.3-0.6mm; When penetration-assisting agent ink is at 50 ± 10 Ke/㎡, depth of penetration is at 0.5-0.8mm; When penetration-assisting agent ink is at 80 ± 20 Ke/㎡, depth of penetration is at 0.7-1.0mm.In use, depth of penetration as required can carry out the consumption setting penetration-assisting agent ink, such as, can increase ink ejection amount or adopt the mode repeating spray ink Printing.Penetration glaze ink and penetration-assisting agent ink consumption more time, darker pervious course can be formed, can reduce because of cross throw cause the defect of revealing the exact details.
Containing penetration-assisting agent in penetration-assisting agent ink, preferably, select the organic solvent type identical with infiltration color glaze ink in the present embodiment, like this, both have better mutual solubility, can promote that penetration glaze ink permeates in base substrate, component and organic penetration glaze ink of organic penetration-assisting agent ink are similar, it is all the mixture of machine acid and ester, organic acid is carboxylic acid, sulfonic acid,-sulfinic acid, at least one in thionothiolic acid, described ester is long chain alkane, isocaprylic acid methyl esters, at least one in pungent methyl caprate, not containing inorganic color development ion in penetration-assisting agent ink, can ensure that two kinds of inks have good mutual solubility like this, osmotic effect is good, and there will not be because the inconsistent colour cast that causes of depth of penetration or chromatic aberration defect.Penetration-assisting agent ink can according to depth of penetration need repeatedly realized by duplicate printing.
In order to allow penetration glaze ink can infiltrate into desired depth in base substrate, the base substrate after spray ink Printing being permeated color glaze ink and penetration-assisting agent ink is needed to place at least 10 minutes.Base substrate storage period is 15-30 minute in the present embodiment, the adobe that color development gradient is more stable to obtain, color development region is more concentrated, and after adobe completes infiltration, preferably carry out again dry, drying temperature is 60-150 DEG C, and the time is 10-100 minute.Here need to illustrate that above placement and dry process are not the indispensable steps of the present invention program.Carrying out the object of placing with dry is make infiltration ink bleed better effects if, placement makes infiltration more abundant, and drying can promote that the hole that ink is formed along first time low-temperature sintering in base substrate spreads, obtain better decorative effect, and the organic constituent in used organic type ink can also be made like this to volatilize, reduce its impact on base substrate when burning till.
The ceramic tile moulded pottery not yet put in a kiln to bake that above method is obtained, enter klining, then after high-strength flexible polishing (the throwing amount of cutting is within the scope of 0.3-0.5mm) and chamfer machining, the ceramic tile with infiltration ornament layer can be obtained, the infiltration ornament layer of brick surface has certain thickness, and be embed adobe inside, there is particularly preferred abrasion resistant effect.
In this enforcement, the kiln used is roller kiln, and the problem of burning till is 1150 ~ 1250 DEG C, and firing period is 50-90 minute.In actual applications, calcining system adjusts according to kiln conditions and body recipe system, and this belongs to art technology person and can obtain in limited number of time test, just no longer does additionally repeating.The Minute pores that first time low-temperature sintering produces can be carried out shutoff by the liquid phase that second time high temperature sintering produces, and product has better anti-fouling effect.
Comparative example 1
Without specified otherwise, the raw material type used in comparative example, processing parameter is identical with embodiment 1.
Have a manufacture method for the ceramic tile of pervious course, it comprises the steps:
Charity organic penetration glaze ink and organic penetration-assisting agent ink on A, moulded pottery not yet put in a kiln to bake base substrate after the drying;
B, to burn till at 1150-1250 DEG C;
C, carry out polishing, edging processing obtains ceramic tile product.
Organic penetration glaze ink that the present embodiment uses is identical with embodiment 1 with organic penetration-assisting agent ink, difference is that the present embodiment does not pass through first time easy fired, therefore because the diffusion of penetration glaze ink is not very strong, so the consumption adding organic inks (is obtaining under identical coloring intensity and depth of penetration, ink will increase the consumption of 20-30%), and diffusion is not evenly, cause the ceramic tile product that obtains not good at the decorative effect of pattern, and wear resistance neither be fine, the solid layer feeling of pattern neither be clearly.In this comparative example, the breakage rate of adobe also higher (comparatively the high 5-7% of embodiment 1), this is because process of osmosis is comparatively large to the intensity effect of moulded pottery not yet put in a kiln to bake, when infiltration capacity is more, understand deliquescing and be easily out of shape fragmentation by base substrate.
Embodiment 2
The present embodiment is from embodiment 1 difference: the spray ink Printing mode of organic penetration glaze ink and organic penetration-assisting agent ink is different, after ink-jet, also carry out drying.Namely the base substrate after spray ink Printing is being placed after more than 10 minutes, dry 10-120 minute under 50-200 degree Celsius, be chosen as 80 degrees Celsius of dryings 30 minutes in the present embodiment.In the prior art, usually base substrate is directly entered klining, this is the permeate agent for water-based, then should not adopt with upper type for organic permeate agent.Because in kiln sintering process, temperature sharply raises, the process of this steep temperature rise, makes the organic constituent penetrated in base substrate gasify rapidly volatilization, may cause blank deformation.Increase drying step, can discharge fast by the organic constituent in base substrate under relatively mild condition, and in the process, the coloring ion in ink also fully can spread along with in base substrate.
In addition, in the present embodiment, organic penetration glaze ink adopts the mode of duplicate printing, and organic penetration-assisting agent ink then adopts the mode of spraying to substitute spray ink Printing.The more simple modes such as certain roll printing, silk screen printing carry out the printing of penetration-assisting agent ink jet, and above mode all can reach same effect.But from process control, particularly in order to form specific pattern, spray ink Printing is still first-selected charity penetration glaze ink and the mode of penetration-assisting agent ink.
Embodiment 3
By the agency of in summary of the invention, in order to obtain the infiltration ink-jet products of surperficial matt effect, basic as embodiment 1, institute's difference is, at embodiment 1 work in-process after firing, change the fast order array of soft rubbing down by known technology to close, reach the sub-light product of glossiness within the scope of 5-30 degree.Sub-light product has more high-grade decorative effect, can give product better added value.And the product of matt effect, because its polishing tolerance is less, the phenomenon of revealing the exact details occurred because crossing throwing can be avoided.
Embodiment 4
In the present embodiment; in order to make shaping ceramic tile, there is super flat effect; in the present embodiment; press upper mold core adopts minute surface punching block or super flat ebonite film; lower mold core adopts isostatic pressed fish line or reticulate pattern mould; obtain adobe surfacing, interior solid degree is even, thus effectively reduce the production difficulty of flexible polishing.Powder is divided into bed material and fabric, and fabric is made up of plurality of raw materials, wherein have formed decoration texture lines material.The finished product wave transformation after complete soft throwing is less, substantially reaches the polishing effect of " pure flat ".All the other techniques and embodiment are substantially identical, in addition, also being added with in fabric that mass percent is 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate, 0.5-5% help the auxiliary component of red dose, by the use of above component, the chromophoe constituent in ink is made to have better hair color effect.
Embodiment 5
Substantially the same manner as Example 2, institute's difference is in the present embodiment, on moulded pottery not yet put in a kiln to bake surface, there is Z-Correct bump mapping Z-correct, this Z-Correct bump mapping Z-correct be adopt have Z-Correct bump mapping Z-correct die stamping shaping time formed, product final so also have for Z-Correct bump mapping Z-correct, make product have more three-dimensional decorative effect.
Embodiment 6
The present embodiment is substantially the same manner as Example 5; institute's difference is; before twice firing; on brick face, first form one deck decoration protective layer; decoration protective layer is consisted of the translucent decoration dry granular of charity 30-60 object, forms the material of one deck vitreous state after burning on brick face, by the pore shutoff that infiltration produces; make product antifouling property better, simultaneously also more wear-resisting.Certainly this layer of decoration protective layer can also be obtained by the mode of glazing or charity clear frit.
Embodiment 7
Basic as embodiment 1, institute's difference is, first drying 15 minutes at 300 DEG C after the first step green brick forming; And then carry out first time and burn till.In this enforcement, firing temperature is 600-750 DEG C, because drying can utilize using residual heat from kiln furnace to carry out drying to it, reaches the object of whole energy.Temperature dry in actual production can be set as 150-350 DEG C, is not less than 10 minutes time of drying.
Below know-why of the present invention is described in conjunction with specific embodiments.These describe just in order to explain principle of the present invention, and can not be interpreted as limiting the scope of the invention by any way.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present invention, and these modes all will fall within protection scope of the present invention.
Claims (10)
1. there is a manufacture method for the ceramic tile of pervious course, it is characterized in that: it comprises the steps:
A, moulded pottery not yet put in a kiln to bake is sent in kiln, at 600-1050 DEG C, carry out first time burn till;
B, first time burn till after base substrate on charity organic penetration glaze ink and organic penetration-assisting agent ink;
C, at 1150-1250 DEG C, carry out second time burn till;
D, carry out polishing, edging processing obtains ceramic tile product.
2. the manufacture method with the ceramic tile of pervious course according to claim 1, is characterized in that: it is also included in the drying step between step B and step C.
3. the manufacture method with the ceramic tile of pervious course according to claim 2, is characterized in that: the temperature of described drying is 50-200 DEG C, and time of drying is more than 10 minutes.
4. the manufacture method with the ceramic tile of pervious course according to claim 1, it is characterized in that: described infiltration color glaze ink is the mixture of organic acid salt and ester in stepb, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper, described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.
5. the manufacture method with the ceramic tile of pervious course according to claim 4, is characterized in that: described organic acid salt is the salt that at least one in the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is formed.
6. the manufacture method with the ceramic tile of pervious course according to claim 1, it is characterized in that: described organic penetration-assisting agent ink is in stepb the mixture of organic acid and ester deter-mation, described organic acid is at least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid, and described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.
7. the manufacture method with the ceramic tile of pervious course according to claim 6, is characterized in that: when the consumption of organic penetration-assisting agent ink is 20-100g/ ㎡.
8. the manufacture method with the ceramic tile of pervious course according to claim 1, is characterized in that: described first time firing temperature be 850-1050 DEG C.
9. the manufacture method with the ceramic tile of pervious course according to claim 1, is characterized in that: in described steps A, moulded pottery not yet put in a kiln to bake adopts fabric impact briquetting after upper forehand cloth by bed material and fabric, and the precoat thickness of formation is 0.5-2mm.
10. the manufacture method with the ceramic tile of pervious course according to claim 1, is characterized in that: moulded pottery not yet put in a kiln to bake described in steps A carries out first time again and burns till after needing first to carry out drying, drying temperature is 150-350 DEG C, time of drying >=10 minutes.
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| CN201510038698.0A CN104671833A (en) | 2015-01-26 | 2015-01-26 | Manufacturing method of ceramic brick with permeable layer |
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| CN201510038698.0A CN104671833A (en) | 2015-01-26 | 2015-01-26 | Manufacturing method of ceramic brick with permeable layer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106083006A (en) * | 2016-06-06 | 2016-11-09 | 广东格莱斯陶瓷有限公司 | A kind of secondary drenches slurry Imitation Rock Porcelain Tiles combining infiltration ink and preparation method thereof |
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| CN204097344U (en) * | 2014-08-29 | 2015-01-14 | 佛山市东鹏陶瓷有限公司 | A kind of ceramic tile moulded pottery not yet put in a kiln to bake |
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| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN104230382A (en) * | 2014-08-29 | 2014-12-24 | 佛山市东鹏陶瓷有限公司 | Method for manufacturing ceramic tile mortar blank |
| CN204097344U (en) * | 2014-08-29 | 2015-01-14 | 佛山市东鹏陶瓷有限公司 | A kind of ceramic tile moulded pottery not yet put in a kiln to bake |
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| Publication number | Priority date | Publication date | Assignee | Title |
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