CN106083212B - A kind of infiltration ink marble ceramic and preparation method thereof - Google Patents

A kind of infiltration ink marble ceramic and preparation method thereof Download PDF

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Publication number
CN106083212B
CN106083212B CN201610393997.0A CN201610393997A CN106083212B CN 106083212 B CN106083212 B CN 106083212B CN 201610393997 A CN201610393997 A CN 201610393997A CN 106083212 B CN106083212 B CN 106083212B
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recess
irregular shape
marble ceramic
area
starch adhesive
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CN106083212A (en
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叶德林
叶永楷
简润桐
陈章武
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New Pearl Group Co.,Ltd.
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GUANGDONG GELAISI CERAMICS CO Ltd
Guangdong Xinmingzhu Ceramic Group Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint

Abstract

The present invention relates to a kind of infiltration ink marble ceramics and preparation method thereof, and wherein marble ceramic includes green body layer and surface layer, and surface layer is containing the starch adhesive layer for forming multicolour pattern by infiltration ink, it is characterised in that：The product surface has length, width, recessed linear slit not of uniform size and/or irregular shape depressed area, the lower recess seam of every square metre of area and/or the quantity of irregular shape depressed area are more than or equal to 10, lower recess is stitched and/or irregular shape recess section length is more than or equal to 10mm, and lower recess is stitched and/or the width of irregular shape depressed area is less than or equal to 1mm.It realizes on the surface of blank raw material, there is digital spray printing to copy the parian pattern texture ceramics tile product and production method of the natural pattern and several fine sink linear slit texture and/or irregular shape recess patterns areas of stone texture.

Description

A kind of infiltration ink marble ceramic and preparation method thereof
Technical field
The present invention relates to building ceramic tiles field, a kind of infiltration ink marble ceramic and its making side are particularly related to Method.
Background technology
In modern architecture finishing, the ornament materials of top fitting position is ranked, no more than high-grade lithotome, pattern shape Naturally, especially such as high-grade marble, texture is finely resistance to be seen state.But the attention with people to scarce resource, the attention to environmental protection, In construction and decoration, people, which are intended to select, to be had environmental protection "dead" and meets modern society's low-carbon green economic development tide Stream, and the durability ornament materials that can there is the decoration of fine household to enjoy, especially pass through Ceramic Tiles made of high-temperature firing Product.
As the current Ceramic Tiles in market copy the prevailing of Natural stone material product, the grade of consumer also increasingly improves, people It is not only required from the rich colors of vision more preferable, but also require it that there is the aesthetic effect of three-dimensional concave-convex level, The marbling effect of careful linear slit texture, or even have the effect requirements of sense of touch.
For this purpose, the developer in building ceramic tiles field, is doing to copy the marble ceramic of fine textures Effort.
The practice that existing Ceramic Tiles technique is passed through is to use male and female mold directly to green brick forming for concave-convex effect or green compact Scheduled concave-convex effect moulding is just produced when grinding and polishing, insider knows, the method being directly molded with a mold using press, by Need demoulding to enter subsequent processing after great tonnage press compacting, if the concaveconvex shape of mold it is narrow if, it is easy to it is viscous Mould, so it is hardly formed tiny linear slit and region, especially in the recess for being even less than 1mm or so width less than 2mm Linear slit area is even more difficult to realize.And the method for using green compact grinding and polishing, it is the mode of machinery, first, the linear slit that is formed and irregular The texture of shape is with regard to relatively simple, stiff, secondly mechanical system will cause green compact certain external force to damage, breakage rate will Very high, this is also unsuitable for industrialized production.So the prior art directly forms sagging linear slit and irregular in billet surface The effect in recess patterns area, all not fine enough, Shortcomings.
Other common methods for forming irregular shape depressed area and linear slit texture are to pass through lower collapsible ink or glaze The method of subregion superposition either spray printing glue, which burns the mode lost and volatilized, to carry out.Such as the middle promulgated by the State Council of Publication No. CN104309223 Described in a kind of bright patent application " Ceramic Tiles and its production method with braiding skin texture ", pass through the ink of high temperature low surface tension The compound of underwater gold category vanadium (or molybdenum or nickel or antimony) has the difference of suitable high temperature viscosity and interfacial tension with overglaze, from And the liquid phase that the ink for keeping high temperature viscosity low is formed is absorbed in the big overglaze of surface tension dissolving and spreading and be enclosed in around overglaze Form concave affect；And the Chinese invention patent application of publication number CN1587145 discloses a kind of Ceramics Ceramic glaze generation The method of granular relief, the method being superimposed using glaze subregion；Also one is in billet surface spray printing glue Texture is formed, the mode for forming sink linear slit and irregular shape pattern area after these glue burning mistake volatilization at high temperature carries out. The above method is all the product in conventional impermeable ink, and by conventional general marzacotto surface come real Existing.Insider all know that translucent and marzacotto surface is all not wear-resisting.So so that these products are answered Great limitation is also received in.
Invention content
In view of the above problem present in the prior art, the effect especially in the fine textures for making marble products It is difficult to realize, or the not wear-resisting limitation for waiting physicochemical properties of product surface that can be realized but be limited by frit material formation is asked Topic, the present invention provide a kind of infiltration ink marble ceramic and preparation method thereof, realize and match property with green body The surface layer starch adhesive floor that pattern is formed by infiltration ink generate finely sagging linear slit texture and/or irregular shape recess patterns area Artificial marble ceramic glazed tile product because the raw material of surface layer starch adhesive layer, which is the green body composition that is matched under it, forms high temperature sintering , surface is not conventional glaze layer, so, product of the present invention is with more high abrasion, high rigidity physicochemical property.
In order to solve the above technical problems, the present invention provides a kind of infiltration ink marble ceramics, it is characterised in that Marble ceramic includes green body layer and surface layer, and surface layer is containing the starch adhesive layer for forming multicolour pattern by infiltration ink, spy Sign is：The product surface has length, width, recessed linear slit not of uniform size and/or an irregular shape depressed area, every square The lower recess seam of rice and flour product and/or the quantity of irregular shape depressed area are more than or equal to 10, and lower recess is stitched and/or irregular shape Shape is recessed section length more than or equal to 10mm, and lower recess is stitched and/or the width of irregular shape depressed area is less than or equal to 1mm..
Preferably, above-mentioned marble ceramic, it is characterised in that green body layer is formed by different colour porcelain powders The green body layer of entire body pattern.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregular shape depressed area are recessed The state of falling into.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregular shape depressed area are portion Point or be all filled into one or more in glaze, clear frit, dry granular, the colored slurry prepared in advance.
Preferably, above-mentioned marble ceramic, it is characterised in that infiltration ink be by or iron ion or cobalt ions or The mixture for the acylate and ester that chromium ion or copper ion are formed.
Preferably, above-mentioned marble ceramic, it is characterised in that the thickness of starch adhesive layer is 0.1mm-1mm.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer raw material containing zinc oxide, titanium dioxide, At least one of zirconium silicate or nano silicon dioxide.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer containing white, red, black, yellow, Two or more in orange, blue or other color slurries.
The present invention also provides the production methods of above-mentioned marble ceramic, it is characterised in that this method includes following step Suddenly：
(1) press design and match slurry by mesh number prepare contain length, width, lower recess not of uniform size stitch And/or the enclosed area of irregular shape depressed area, other regions are the silk screen by area；
(2) routinely technique and raw material prepare green body and are dried；
(3) starch adhesive is prepared；
(4) use the silk screen of step (1) that the starch adhesive of step (3) is applied to the billet surface for the drying for being printed on step (2)；
(5) apply the adobe after starch adhesive and carry out second of drying；
(6) it presses layout spray printing and permeates ink；
(7) enter highest warm area up to firing in 1180 DEG C -1240 DEG C of kiln, obtain infiltration ink marmorean half at Product；
(8) soft throwing/or full polishing, edging are carried out to semi-finished product, obtains marble ceramic.
Preferably, further include by being no less than 10 minutes, not surpassing between step (6) and (7) in above-mentioned production method Cross the transmission time process on 2 hours pipelines；
Preferably, in above-mentioned production method, in the starch adhesive of step (3) also contain be suitable for silk-screen printing common stamp-pad ink, Print cream or glue.
Preferably, in above-mentioned production method, after step (4) silk-screen either before step (7) after step (6), To the lower recess seam of formation and/or irregular shape depressed area apply glaze, translucent dry granular or the frit of print different color Raw material forms filling.
Preferably, in above-mentioned production method, step (4) is by layout using digital spray printing, silk-screen printing or roller print Brush mode prints glue and forms several lower recess seam and/or irregular shape texture of protrusion, then drenches the starch adhesive for applying step (3).
Preferably, in above-mentioned production method, the silk-screen printing is changed to roller printing.
Beneficial effects of the present invention are as described below：
First, the present invention proposes a kind of infiltration ink marble ceramic and preparation method thereof pioneeringly, realizes On the surface of blank raw material, there is digital spray printing to copy the natural pattern of stone texture and several finely sagging linear slit textures And/or the parian pattern texture ceramics tile product and production method in irregular shape recess patterns area.
Second, the original prepared using the mud sand material for being matched with lower layer's porcelain body recipe due to surface layer starch adhesive of the present invention What material was manufactured, the unification being formulated up and down is provided with preferably sintering and vitreous characteristic, breaches existing Ceramic Tiles system Product all only copy the limitation of the technical method of natural marble using recess connection with production of structures is carried out on transparent glaze, also break through Not wear-resisting enough the limitation in the surface of traditional glaze process product.
Third, the bulk pattern that the present invention uses are that infiltration ink jet printing is formed, and ink is seeped under billet surface In green body, without applying the processing of glaze protection on surface；This with conventional ceramic ink can only spray printing needed in billet surface Apply glaze carry out protection be different.The present invention is the pattern formed in the billet surface of vitreous, and texture texture is more aobvious Naturally, being grown as interior.
4th, present invention employs entire body pattern feed dividing-distributing technologies so that product is more complete in the structure from face to green body There is to face the effect of imitated lithotome.
The present invention innovatively uses infiltration ink, spray printing/silk-screen/or roller print based on the slurry of body recipe The integration of technology realizes and generates such as the marmorean fine recess linear slit texture of glaze technique and do not advise on green body quality surface The then product and production method of the effect of shaped depressions pattern, this is that the prior art is not all disclosed and proposed, be it is non-aobvious and It is clear to, there is significant novelty and practicability and creativeness.
Hereinafter, by specific embodiment the present invention and its specific method is better described.
Embodiment 1
(1) the muds sand plain material such as kaolin, feldspar, quartz are selected, routinely ceramic process prepares green body porcelain powder, is formulated Weight percent group become silica 67%, aluminium oxide 21%, potassium oxide+sodium oxide molybdena 6%, calcium oxide+magnesia 1.5%, It is other be igloss and trace impurity, it is spare；
(2) by the recipe requirements for being matched with above-mentioned blank raw material, formulation weight percentage group becomes silica 70%, oxygen Change aluminium 20%, potassium oxide+sodium oxide molybdena 8%, calcium oxide+magnesia 0.5%, it is other be igloss and trace impurity, in this slurry In promote ink by least one of proper ratio addition zinc oxide, titanium dioxide, zirconium silicate or nano silicon dioxide again The requirement of water color development pressed 200 mesh screen residues within 0.5%, and proportion prepares starch adhesive in 1.80g/ ㎝ 3, what the present embodiment used It is the mode of silk-screen printing, so, it is furthermore preferred that being deployed into the common stamp-pad ink used as medium again in starch adhesive, it has been allowed to Certain viscosity, it is spare in favor of silk-screen printing or the control of roller printing；
(3) press design is enclosed area, Qi Tawei containing several length, width, irregular shape not of uniform size Mesh number is 100 purposes by area, and it is for use to prepare silk screen；
(4) ceramic tile blank of above-mentioned blank raw material is produced in conventional fashion and is dried, drying temperature is at 80 DEG C -250 DEG C, it is transmitted to subsequent processing after drying out；
(5) when the drying base that transmission comes cools to 50 DEG C -80 DEG C, the present embodiment is at 60 DEG C -70 DEG C, using step (3) silk screen, which applies the starch adhesive of step (2), to be printed on step (4) base temperature is on 60 DEG C -70 DEG C of dry base substrate surface afterwards, to be formed By the fine recess linear slit texture of design and irregular shape recess patterns area, starch adhesive weight about 1.3 on pulp surface floor ㎏/㎡；
(6) apply the adobe after starch adhesive to be input into second of drying；Here the temperature of redrying is carried out at 40 DEG C -180 DEG C, it is highly preferred that control is kept for about 35 minutes at 130 DEG C -160 DEG C, redrying is utilized using the waste heat of kiln, with more Save the consumption of the energy, if without the step for drying, can be easy to generate facial cleft, side in actual production and the matter such as split Amount problem；
(7) the adobe transmission of starch adhesive that is to be applied and foring fine recess texture reaches ink jet printer and base temperature is 40 Under conditions of DEG C -50 DEG C or so, ink and penetration-assisting agent are permeated by layout spray printing, and enter in the glaze line of a distance and reach To about 40 minutes time courses, so as to be seeped into base under infiltration ink；
(8) the pattern green body Jing Guo about 40 minutes times of penetration enters highest warm area up to 1180 DEG C -1240 DEG C of kiln Middle firing, obtain the infiltration ink marmorean half with fine recess linear slit and/or irregular shape pattern area texture at Product.
(9) soft throwing/is carried out to semi-finished product or full polishing, edging, the infiltration ink for obtaining the present invention is marmorean or soft The product of light or light.
Embodiment 2
(1) the muds sand plain material such as kaolin, feldspar, quartz are selected, routinely ceramic process prepares green body porcelain powder, is formulated Weight percent group become silica 67%, aluminium oxide 21%, potassium oxide+sodium oxide molybdena 6%, calcium oxide+magnesia 1.5%, It is other be igloss and trace impurity, it is spare；
(2) by the recipe requirements for being matched with above-mentioned blank raw material, formulation weight percentage group becomes silica 70%, oxygen Change aluminium 20%, potassium oxide+sodium oxide molybdena 8%, calcium oxide+magnesia 0.5%, it is other be igloss and trace impurity, in this slurry In promote ink by least one of proper ratio addition zinc oxide, titanium dioxide, zirconium silicate or nano silicon dioxide again The requirement of water color development pressed 200 mesh screen residues within 0.5%, and proportion prepares starch adhesive in 1.80g/ ㎝ 3；It gets ready simultaneously conventional The glue of mistake can be burnt for silk screen printing and in high temperature firing, it is spare as medium；
(3) be mesh number containing several length, width, linear slit not of uniform size by design it is 140 mesh by area, Its enclosed area, it is for use to prepare silk screen；
(4) ceramic tile blank of above-mentioned blank raw material is produced in conventional fashion and is dried, drying temperature is at 80 DEG C -250 DEG C, it is transmitted to subsequent processing after drying out；
(5) when the drying base that transmission comes cools to 50 DEG C -80 DEG C, the present embodiment is at 60 DEG C -70 DEG C, using step (3) silk screen, which applies the glue of step (2), to be printed on step (4) base temperature forms protrusion on 60 DEG C -70 DEG C of dry base substrate surface afterwards Texture, then advance to leaching sizing process, the starch adhesive of step (2) applied into leaching in the billet surface for having glue raised textural, from And the starch adhesive floor containing the fine linear slit texture and irregular shape pattern area formed by glue by design is formd, it applies The weight for drenching starch adhesive is about 1.3 ㎏/㎡；
(6) apply the adobe after starch adhesive to be input into second of drying；Here the temperature of redrying is carried out at 40 DEG C -180 DEG C, it is highly preferred that control is kept for about 35 minutes at 130 DEG C -160 DEG C, redrying is utilized using the waste heat of kiln, with more Save the consumption of the energy, if without the step for drying, can be easy to generate facial cleft, side in actual production and the matter such as split Amount problem；
(7) adobe that redrying comes out cools under conditions of 40 DEG C of -50 DEG C or so base temperature, is oozed by layout spray printing Strike through water and penetration-assisting agent, and enter and reach about 40 minutes time courses in the glaze line of a distance, so that under infiltration ink It is seeped into base；
(8) the pattern green body Jing Guo about 40 minutes times of penetration enters highest warm area up to 1180 DEG C -1240 DEG C of kiln Middle firing, during high-temperature firing, the glue of low temperature composition can burn mistake, recessed so as to form the position for being printed on glue in original It falls into, obtains the marmorean semi-finished product of infiltration ink with fine recess linear slit and/or irregular shape pattern area texture.
(9) soft throwing/is carried out to semi-finished product or full polishing, edging, the infiltration ink for obtaining the present invention is marmorean or soft The product of light or light.
It is furthermore preferred that in the present embodiment, the addition in glue can also be used to be deployed into dry granular, metal glaze, frit Expect composition, forms after the glue of low temperature composition burns mistake, the position that glue is printed in original is produced with dry granular, metal glaze The grain effect of material, frit material characteristic carries out soft throwing/or full polishing, edging to semi-finished product, obtains a kind of infiltration of the present invention Ink is marmorean or the product of sheen or light.
Embodiment 3
To embodiment 1 after step (5) silk-screen or before step (7) later the entrance kiln firing of step (8), Linear slit and/or irregular shape depressed area to several recess of formation carry out apply print different color or glaze or translucent Dry granular or frit raw material form filling, and can also be by the way of jump version commonly used in the trade, it will make recess texture shape Contain metal glaze effect, clear frit effect, transparent texture effect at more rich.
The marble ceramic that embodiment 1-3 is prepared by the starch adhesive layer for permeating ink because be provided with lower recess The marbling effect on ceramic surface is not only realized in seam or irregular shape depressed area, but also because using infiltration ink The visual effect for realizing lower recess seam or irregular shape depressed area is more preferably true to nature, the color coordination in gap and infiltration ink Aspect completely outstripped the effect of simple infiltration ink, enhance the three-dimensional sense of color, and also enhance gap or filling irrigating sealant The combination of the sense of reality of gap, two kinds of technologies makes marbling effect greatly improve.
The above, merely to illustrate the preferable preferred embodiment of the present invention, however it is to the present invention that it, which is not, Protection domain there are any restrictions, anyone familiar with this technology to be changed possibly also with the technology contents of the disclosure above Or it is modified to the equivalent embodiment of equivalent variations, a kind of infiltration ink Dali feldspar can be implemented by different requirements and performance Product and preparation method thereof.As it can be seen that every content without departing from technical solution of the present invention, the especially content of claim, according to According to the technical spirit of the present invention to any simple modification made by above example, equivalent variations and modification, still belong to the present invention In the range of technical solution.

Claims (12)

1. a kind of infiltration ink marble ceramic, it is characterised in that marble ceramic includes green body layer and surface layer, table Layer is containing the starch adhesive layer for forming multicolour pattern by infiltration ink, and the product surface has length, width, not of uniform size recessed Linear slit and/or irregular shape depressed area, the lower recess seam of every square metre of area and/or the quantity of irregular shape depressed area are big In equal to 10, lower recess seam and/or irregular shape recess section length are more than or equal to 10mm, lower recess seam and/or irregular The width in shaped depressions area is less than or equal to 1mm；
The production method of the marble ceramic includes the following steps：
(1) press design and match slurry by mesh number prepare containing length, width, lower recess not of uniform size seam and/ Or enclosed area, the other regions of irregular shape depressed area are the silk screen by area；
(2) routinely technique and raw material prepare green body and are dried；
(3) starch adhesive is prepared；
(4) use the silk screen of step (1) that the starch adhesive of step (3) is applied to the billet surface for the drying for being printed on step (2)；
(5) apply the adobe after starch adhesive and carry out second of drying；
(6) it presses layout spray printing and permeates ink；
(7) highest warm area is entered up to firing in 1180 DEG C -1240 DEG C of kiln, obtains the infiltration marmorean semi-finished product of ink；
(8) soft throwing is carried out to semi-finished product or full polishing, edging obtains marble ceramic.
2. marble ceramic according to claim 1, it is characterised in that green body layer is by different colour porcelain powders The green body layer of the entire body pattern of formation.
3. marble ceramic according to claim 1, it is characterised in that recessed linear slit and/or irregular shape recess Area is etat lacunaire.
4. marble ceramic according to claim 1, it is characterised in that recessed linear slit and/or irregular shape recess Area be partly or entirely be filled into it is one or more in glaze, clear frit, dry granular, the colored slurry prepared in advance.
5. marble ceramic according to claim 1, it is characterised in that infiltration ink be by iron ion, cobalt ions, The mixture for the acylate and ester that a kind of ion in chromium ion, copper ion is formed.
6. marble ceramic according to claim 1, it is characterised in that the thickness of starch adhesive layer is 0.1mm-1mm.
7. marble ceramic according to claim 1, it is characterised in that contain zinc oxide, dioxy in starch adhesive layer raw material Change at least one of titanium, zirconium silicate or nano silicon dioxide.
8. marble ceramic according to claim 1, it is characterised in that in starch adhesive layer containing white, red, black, Two or more in yellow, orange, blue or other color slurries.
9. marble ceramic according to claim 1, it is characterised in that：Between step (6) and (7), further include By being no less than 10 minutes, the transmission time process on pipeline no more than 2 hours.
10. marble ceramic according to claim 1, it is characterised in that：Also contain in the starch adhesive of step (3) and is suitble to In the common stamp-pad ink, print cream or glue of silk-screen printing.
11. marble ceramic according to claim 1, it is characterised in that：Either in step after step (4) silk-screen Suddenly after (6) before step (7), the lower recess seam of formation and/or irregular shape depressed area are carried out to apply print different color Glaze, translucent dry granular or frit raw material form filling.
12. marble ceramic according to claim 1, it is characterised in that：Step (4) is by layout using digital Spray printing, silk-screen printing or roller printing mode print several lower recess seam and/or irregular shape texture that glue forms protrusion, The starch adhesive for applying step (3) is drenched again.
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CN109382898A (en) * 2017-08-12 2019-02-26 主父春霖 A kind of production technology of spun gold marble tile product
CN107599138A (en) * 2017-10-12 2018-01-19 清远市简陶瓷有限公司 A kind of manufacture method of three-dimensional entire body texture ceramic tile
CN108394008A (en) * 2018-03-23 2018-08-14 广东萨米特陶瓷有限公司 Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof
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