CN104609903A - Manufacturing method of ceramic tiles - Google Patents
Manufacturing method of ceramic tiles Download PDFInfo
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- CN104609903A CN104609903A CN201510038961.6A CN201510038961A CN104609903A CN 104609903 A CN104609903 A CN 104609903A CN 201510038961 A CN201510038961 A CN 201510038961A CN 104609903 A CN104609903 A CN 104609903A
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Abstract
The invention discloses a manufacturing method of ceramic tiles. The manufacturing method comprises the following steps: A. selecting common raw materials for preparing the ceramic tiles, and using the raw materials to prepare briquettes; B. spraying organic colored glaze-permeating ink; C. spraying organic permeation promoting ink; D. drying the briquettes at the temperature of 50-200 DEG C for 10-60 minutes to obtain ceramic tile blanks; E. putting the blanks into a kiln, and firing the blanks at 1150-1250 DEG C; F. polishing and edging to obtain the ceramic tiles. According to the ceramic tiles, the glaze-permeating ink forms the permeable layer with a certain thickness and permeates into the precoat to enable the decorative patterns to be abrasion-resistant, so that the problems that in the prior art the printed decorative layer formed by normal ink jet printing is free of stereoscopic layering feeling and fails to resist abrasion are solved.
Description
Technical field
The present invention relates to architectural pottery product manufacturing technical field, particularly relate to a kind of manufacture method of ceramic tile.
Background technology
Ceramic ink jet printing technology is a kind of technology being widely used in ceramic tile production in recent years, ink printed is replaced the decorative means such as conventional screen stamp, roller printing on adobe surface by shower nozzle by it, because it is that a kind of noncontact prints, male and fomale(M&F) product " can be printed ", do not need plate-making in kind, turn version simply rapid, personalized production can be realized, produce reproducible, thus use range is more and more wider.But its shortcoming is just that the ornament layer printed is excessively shallow, and meanwhile, it is poor that rear wear resistance fired by ink; along with the prolongation of duration of service; decorative effect can be made to have a greatly reduced quality, thus have on the ornament layer after spray ink Printing and execute transparent or cloth clear frit, to protect the technique of ornament layer decorative pattern.No matter but be transparent or clear frit, better decorative effect is presented in order to make ink-jet ornament layer, just must enhance the transparency, but it is (in order to increase transparency, many containing solubility promoters such as plumbous and zinc in glaze that while transparency improves, wear resistance also can decline, it is while increase glaze paint transparency, also glaze paint deliquescing is made, not wear-resisting), thus still fundamentally can not solve the problem keeping long-term decorative effect.
Application number CN 201210331440.6 discloses one and oozes colored porcelain brick and production method thereof, ooze colored ink and to be printed on by the mode of spray ink Printing by water miscible and to drench on the starch adhesive on adobe surface, although after infiltration, the decorative pattern of certain depth can be produced, but because starch adhesive water ratio is higher, cause the infiltration difficulty of the infiltration color glaze ink of water-based to increase, and also easily cause faulty nozzle because raw brick moisture content evaporate into shower nozzle.In addition, adopt the bell jar glaze slip drenched in adobe surface also easily to form the defect of edge projection, be unfavorable for the Difference Control after polishing.In addition, worldwide aqueous infiltrating glaze ink up to this point and immature, also can be applied to far away on actual ink jet unit and produce.
Thus when firing due to inconsistent with end base shrinking percentage and then can distortion be produced, raw green strength reduces, and easily splits brick.
Application number CN 201110187245.6 discloses and is a kind ofly applicable to the aqueous infiltrating glaze of spray ink Printing and the method for ceramic tile production thereof, is directly be printed in adobe by aqueous infiltrating glaze by spray ink Printing, then water spray helps and oozes.Up to the present and immature but in fact aqueous infiltrating glaze ink, also can be applied to far away on actual ink jet unit and produce.
In prior art, directly can enter klining after ink-jet printed, this is for aqueous infiltrating agent.But what adopt in this scheme is organic penetration glaze ink, and burn till if directly enter kiln high temperature, the organic constituent in ink can volatilize, and can affect color development like this, and if organic constituent remain in base substrate more, easily there is the defects such as pore when burning till.For overcoming the above problems, with in this programme, after charity organic infiltration color glaze ink and organic penetration-assisting agent ink, carry out drying, it can make organic materials slowly volatilize, and forms steady seepage gradient and contains the less precoat having machine aided to ooze material.So process can also save ink consumption simultaneously.
Preferably, in the above-mentioned methods, between step C and step D, also wrap a placement moulded pottery not yet put in a kiln to bake help the step of oozing and forming pervious course, help the time of oozing to be no less than 10 minutes.Ink carries out subsequent drying step as well after needing to form certain depth of penetration in base substrate again, because the organic constituent in drying process ink inside can volatilize, this can promote that the chromophoe constituent in ink spreads, if but the pervious course not forming certain depth just carries out drying, be easy to occur because of the too fast problem causing depth of penetration more shallow of volatilizing.For this reason, preferably before carrying out drying, first place to help for more than 10 minutes to base substrate and ooze, after forming the pervious course of certain depth, carry out drying again.
Preferably, described adobe is in step that after fabric and bed material adopt forehand secondary material distributing, compacting forms adobe and drying, and precoat thickness is 0.5-2.0mm.
The mode using bed material and fabric to carry out cloth has forehand cloth and instead breaks cloth two kinds, the mode of both differentiations is that precoat is in top or bottom, anti-beat cloth can better in the holding surface bed of material because of the texture of distributing technique formation, forehand cloth then easily control adobe thickness and planeness.For this, the moulded pottery not yet put in a kiln to bake provided in the present invention also tool uses penetration glaze ink to decorate, darker infiltration ornament layer is formed together with penetration-assisting agent ink, to this, the mode of preferred employing forehand cloth, because it can control thickness and its planeness of precoat in adobe preferably, and, precoat upper, in follow-up process of osmosis without the need to base substrate is overturn.
Preferred further, the thickness of described precoat is 0.8-1.2mm.
Preferably, described organic infiltration color glaze ink is the mixture of organic acid salt and ester in stepb, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper; Described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.The color development of organic infiltration color glaze ink mainly relies on inorganic color development ion wherein, different ions and different kinds of ions various combination can produce different colours, such as independent cobalt can produce bright-coloured blueness, the combination of iron, cobalt and chromium can produce black, can form abundant full-color effect by combining above.
Preferred further, described organic acid salt is the salt that at least one in the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is formed.Carboxylic acid, compared to other organic acid, have better osmotic effect, and it easily volatilizees in base substrate, residual few in base substrate, avoids the increased number of stomata produced in follow-up burning till because its volatilization produces, improves product quality.
Preferably, described spray ink Printing penetration glaze ink is print polychrome penetration glaze ink by different spray nozzles successively in stepb; By the mixing of different colours ink, can obtain abundant decorative effect, such as conventional is blue, red, yellow, black 4 looks, certainly, in actual applications not by above restriction, can arrange in pairs or groups to ink color according to demand.Also certain infiltration color glaze can repeatedly be printed repeatedly, to obtain saturated form and aspect.
Certainly, the spray ink Printing in step B can also use the mode of screen printing or rotary printing to substitute, but as ink, the mode charity of its more suitable use spray ink Printing, and ink-jet has better control to charity amount.
Preferably, the described penetration-assisting agent ink in step C is the mixture of organic acid and ester deter-mation, and organic acid is at least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid; Ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate, is organic liquid material.Organic type penetration-assisting agent ink can be good permeate color glaze ink with organic type and be combined, have and promote its effect of permeating in base substrate, better can be saved the consumption of penetration-assisting agent ink by spray ink Printing mode, and the thickness of pervious course can be controlled.And according to the needs of depth of penetration, different depths infiltration (depth of penetration is adjustable within the scope of 0.2-1.5mm) can be realized by changing penetration-assisting agent ink printed number of times, the more simple methods such as spraying, roll printing, silk screen printing can certainly be increased below to reach same effect.Preferably adopt repeatedly inkjet printing methods.
Preferably, in this programme, the time of oozing is helped to be advisable for 15-30 minute, the depth of penetration that too short very difficult formation is enough, long, then can affect production efficiency.
Preferably, when the raw material that steps A uses is divided into fabric and bed material, in fabric containing mass percent be 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate or 0.5-5% help at least one in red dose.Can color development be promoted by adding above component, reaching the object of saving ink.Help red dose for a kind of assistant toner, its main component is nano silicon, and can obtain by buying, such as Mei Gao company has related products to sell.
When adopting bed material and fabric to carry out cloth, adobe its from bottom to top comprise: initial bed, precoat, it is the pervious course that 0.3 ~ 1.5mm organic liquid material is formed that described precoat comprises thickness.By the adobe of above structure, because pervious course has certain thickness after sintering, rubbing down process can be carried out, and the decorative pattern that pervious course is formed is also wear-resisting especially.
Further, in above ceramic tile moulded pottery not yet put in a kiln to bake, described precoat is embedded with striped or granular texture.Described striated texture forms (such as magic cloth) by the known Strand Feeding Technique of industry, can be the various textures such as wire, particulate state, cloud shape, wood grain, bag.Because what form above texture has different with all the other positions of precoat, make permeation layer thickness also have corresponding difference (different material depth of penetration is different), reduce the loss caused because of polishing further, meanwhile, also can enrich decorative effect.
Further, the thickness >=permeation layer thickness of described striped or granular texture.Even if like this because pervious course is crossed throwing in rubbing down process, be also unlikely to the Integral decoration effect affecting brick.
Compared with prior art, the present invention is by the fabric of penetration glaze ink charity after secondary material distributing, and use organic penetration-assisting agent of identical type, because both character are identical, use-pattern is identical, thus can ensure better depth of penetration, make the Wear Resistance after firing good, decorative pattern keeps lasting, and has certain thickness due to ornament layer, can carry out the processing such as chamfering.
Simultaneously, due to can the change of cloth system and the design of spray ink Printing pattern be passed through, the grain effect of precoat is combined with the decorative effect of penetration glaze, thus on starch adhesive, prints penetration glaze than prior art CN 201210331440.6 and there is easier operation and effectively solve the defects such as the infiltration of starch adhesive moisture disaster and edge projection; Owing to adding titanium dioxide, zinc oxide in fabric, help red dose, the assistant toner such as zirconium silicate, can obtain comprehensive color development and texture after high-temperature firing, the strong and stereoscopic depth sense of level transition sense by force, can produce abundanter color and darker osmotic effect; The tandem product of various luster degree also can be obtained after adopting the module polishing of known different meshes and hardness; Adopt the mould pressing unfired brick of different surfaces Z-Correct bump mapping Z-correct to obtain and there is the tandem product that stereoscopic sensation is stronger, texture is finer and smoother.
The ceramic tile that the present invention is prepared by adopting above-mentioned ceramic tile moulded pottery not yet put in a kiln to bake, the pervious course that penetration glaze ink is formed has certain thickness, and in infiltration precoat, make decorative pattern wear-resistant, solve and print by typical inkjet the printed decor formed in prior art and there is no solid layer feeling and the problem such as not wear-resistant.
Summary of the invention
The object of the invention is to print the problems such as the printed decor formed is not wear-resistant, stereoscopic sensation is poor by typical inkjet in solution prior art and propose a kind of ceramic tile and manufacture method thereof.
For reaching this object, the present invention by the following technical solutions:
A manufacture method for ceramic tile, it comprises the steps:
A, Ceramics brick are commonly used raw material and are made adobe;
B, charity organic infiltration color glaze ink;
C, the organic penetration-assisting agent ink of charity;
D, at 50-200 DEG C of temperature, dry 10-60 minute obtains ceramic tile moulded pottery not yet put in a kiln to bake;
E, enter kiln and burn till at 1150-1250 DEG C;
Ceramic tile is obtained after F, polishing, edging.
Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
Embodiment 1
The ceramic tile that the present embodiment provides a kind of manufacture method of ceramic tile moulded pottery not yet put in a kiln to bake to use it to manufacture.
A manufacture method for ceramic tile, it comprises the steps:
A, select known ceramic adobe bed material and fabric, form adobe through forehand cloth, in base substrate, precoat thickness is 1.2mm, carries out drying to adobe;
B, by dried adobe spray ink Printing organic infiltration color glaze ink; During spray ink Printing, adobe temperature is 45-55 DEG C;
The organic penetration-assisting agent ink of C, spray ink Printing;
D, adobe is placed more than 10 minutes, organic penetration-assisting agent ink is played one's part to the full, what form certain depth helps infiltration layer (being generally more than 0.3mm);
E, at 50 DEG C of temperature, redrying obtains ceramic tile moulded pottery not yet put in a kiln to bake in 60 minutes;
F, enter kiln and burn till 50-90 minute at 1210-1250 DEG C;
G, to after burning goods carry out polishing, edging obtains ceramic tile product.
Here be described above technique, the storage period of adobe in step D can regulate according to need of production, but lower than 10 minutes, otherwise should not be difficult to the effect ensureing infiltration; Carrying out redrying in step e is have larger difference part with prior art, in prior art, adobe just can enter klining after carrying out oozing flower decoration at once, but this mode is based upon on the basis of aqueous infiltrating agent, for organic infiltration ink, adopt redrying that organic constituent wherein can be made to volatilize, except can allow osmotic effect more fully except, organic constituent can also be reduced remain, avoid acutely volatilizing in the rapid heating condition burnt till at kiln, form increased number of stomata, the decorative effect in brick face and antifouling property are impacted.Therefore, its drying temperature is generally no more than 200 DEG C, and the too low drying efficiency that affects of temperature, therefore, setting drying temperature is 50-200 DEG C usually, and time of drying is 10-60 minute.Consider from drying effect and efficiency balance, be preferably set as that drying temperature is 70-120 DEG C, time of drying is 15-30 minute.
The ink used in step B and step C is organic inks, there is similar component, the mixture that organic infiltration color glaze ink that wherein step B uses is organic acid salt and ester, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper; Ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.And the mixture that the organic penetration-assisting agent ink used in step C is organic acid and fat, organic acid is at least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid, and ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.Both have similar component, time used in combination, also can have similar effect.The organic acid selected in the present embodiment is carboxylic acid, and ester is pungent methyl caprate.
Particularly, the organic infiltration chromatic ink used in step B is divided into indigo plant, red, yellow black four looks according to its hair color effect, then uses the resolving power 400dpi of printer, nozzle bore for blue, red, yellow, the black 4 look organic solvent type infiltration color glaze inks of 200PL successively spray ink Printing.The ink ejection amount of mono ink is at 0-50g/m
2, to obtain enough saturated hair color effect.Here explanation is needed, in actual applications, the color of ink can have multiple choices, such as blue, red, Huang can synthesize the infiltration color glaze ink of multiple color in the present embodiment, and then obtain full-color effect, and black can the gray scale of adjustable colors, concrete institute uses the kind of ink and consumption can carry out selection according to actual print pattern effect and arranges in pairs or groups.
Step C is for re-using ink-jet printer at adobe surface spray ink Printing 1-3 all over penetration-assisting agent ink, and the total ink ejection amount of penetration-assisting agent ink is at 30 ± 10 grams/m
2time, depth of penetration, at 0.3-0.6mm, meets the requirement of soft throwing technology controlling and process.
The ceramic tile moulded pottery not yet put in a kiln to bake that above method is obtained, enter klining, then after high-strength flexible polishing (the throwing amount of cutting is within the scope of 0.3-0.5mm) and chamfer machining, the ceramic tile with infiltration ornament layer can be obtained, the infiltration ornament layer of brick surface has certain thickness, and be embed adobe inside, there is particularly preferred abrasion resistant effect.
In this enforcement, the kiln used is roller kiln, and the problem of burning till is 1210 ~ 1250 DEG C, and firing period is 50-90 minute.In actual applications, calcining system adjusts according to kiln conditions and body recipe system, and this belongs to art technology person and can carry out judging or obtaining through limited number of time experiment according to knowhow, just no longer does additionally repeating.
In addition, by test, when penetration-assisting agent ink is at 30 ± 10 grams/m
2time, depth of penetration is at 0.3-0.6mm; When penetration-assisting agent ink is at 50 ± 10 grams/m
2time, depth of penetration is at 0.5-0.8mm; When penetration-assisting agent ink is at 80 ± 20 grams/m
2time, depth of penetration is at 0.7-1.0mm.In use, depth of penetration as required can carry out the consumption setting penetration-assisting agent ink, such as, can increase ink ejection amount or adopt the mode repeating spray ink Printing.Penetration glaze ink and penetration-assisting agent ink consumption more time, darker pervious course can be formed, can reduce because of cross throw cause the defect of revealing the exact details.
Embodiment 2
A manufacture method for ceramic tile, it comprises the steps:
A, select known ceramic adobe bed material and fabric, form adobe through forehand cloth, in base substrate, precoat thickness is 2mm, carries out drying to adobe;
B, by dried adobe spray ink Printing organic infiltration color glaze ink; During spray ink Printing, adobe temperature is 45-55 DEG C;
C, silk screen and cylinder combine the organic penetration-assisting agent ink of printing charity; The consumption of organic penetration-assisting agent ink is 80 ± 20 grams/m
2;
D, adobe is placed 30 minutes, organic penetration-assisting agent ink is played one's part to the full, what form certain depth helps infiltration layer;
E, at 120 DEG C of temperature, redrying obtains having the ceramic tile moulded pottery not yet put in a kiln to bake that the pervious course degree of depth is about 0.9mm for 20 minutes;
F, enter kiln and burn till 80-90 minute at 1150-1230 DEG C;
G, to after burning goods carry out polishing, edging obtains ceramic tile product.
The ink used is identical with embodiment 1 system.
In step, containing assistant toner in the fabric used, it is titanium dioxide, zinc oxide, help red dose, at least one in zirconium silicate.Addition is the 0.1-2% titanium dioxide of fabric quality percentage ratio, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate or 0.5-5% help red dose.Here used help red dose for known a kind of additive promoting red component colour developing in ink in the industry, just there is related products technique in such as U.S. high company, and that mentions in embodiment in the present invention helps red dose, all purchased from Mei Gao company.
Specifically, what use in this enforcement is the titanium dioxide of 1% and the zirconium silicate of 3%.
By using above assistant toner, organic penetration glaze ink color development can be made more abundant, while saving valuable raw material, also can obtain better decorative effect.
Embodiment 3
A manufacture method for ceramic tile, it comprises the steps:
A, select known ceramic adobe bed material and fabric, form adobe through forehand cloth, in base substrate, precoat thickness is 0.8mm, carries out drying to adobe;
B, by dried adobe spray ink Printing organic infiltration color glaze ink; During spray ink Printing, adobe temperature is 45-55 DEG C;
C, silk screen and cylinder combine the organic penetration-assisting agent ink of printing charity; The consumption of organic penetration-assisting agent ink is 50 ± 10 grams/m
2;
D, adobe is placed 15 minutes, organic penetration-assisting agent ink is played one's part to the full, what form certain depth helps infiltration layer;
E, at 80 DEG C of temperature, redrying obtains having the ceramic tile moulded pottery not yet put in a kiln to bake that the pervious course degree of depth is about 0.8mm for 35 minutes.Permeation layer thickness is substantially identical with precoat thickness;
F, enter kiln and burn till 70-80 minute at 1200-1250 DEG C;
G, to after burning goods carry out polishing, edging obtains ceramic tile product.
The ink used is identical with embodiment 1 system.
In step, containing assistant toner in the fabric used, it is titanium dioxide, zinc oxide, help red dose, at least one in zirconium silicate.Addition is the 0.1-2% titanium dioxide of fabric quality percentage ratio, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate or 0.5-5% help red dose.In this enforcement use be 1% titanium dioxide, 0.3% zinc oxide, 2% zirconium silicate and 3% help red dose.
By using above assistant toner, organic penetration glaze ink color development can be made more abundant, while saving valuable raw material, also can obtain better decorative effect.
In the present embodiment, after burning, polishing adopts known block combiner, obtains the matt effect that glossiness is 5-30 °.
Embodiment 4
A manufacture method for ceramic tile, it comprises the steps:
A, select known ceramic adobe bed material and fabric, form adobe through forehand cloth, in base substrate, precoat thickness is 1.6mm, carries out drying to adobe; Fabric has plurality of raw materials to form in the present embodiment, adopt known magic distributing mode in precoat, form many decoration textures when cloth, after drying, rubbing down is carried out to adobe, throw blank process and adopt 150 order abrasive disk 6-10 groups and wool felt mill 3-6 group, rubbing down cutting output is at 0.3-1.2mm, this technique corresponding, rubbing down cutting output is 0.6-0.8mm.Certainly also can be dry again after rubbing down, the texture in precoat can be allowed to display by rubbing down process, meanwhile, through rubbing down process, also make the pore of billet surface open, be more conducive to follow-up infiltration.
B, by organic for adobe spray ink Printing infiltration color glaze ink; During spray ink Printing, adobe temperature is 45-55 DEG C; The mixture that the ink used is organic acid salt and ester, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper; Ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.Ink is four colour system inks, is specially indigo plant, Huang, red, black, uses ink-jet printer to carry out ink-jet printed, form decorative pattern.
The organic penetration-assisting agent ink of C, spray ink Printing; The consumption of organic penetration-assisting agent ink is 100 ± 10 grams/m
2; Machine aided ink bleed water is had to be the mixture of organic acid and fat.
D, adobe is placed 20 minutes, organic penetration-assisting agent ink is played one's part to the full, what form certain depth helps infiltration layer;
E, at 150 DEG C of temperature, redrying obtains having the ceramic tile moulded pottery not yet put in a kiln to bake that the pervious course degree of depth is about 0.6mm for 15 minutes;
F, above-mentioned moulded pottery not yet put in a kiln to bake to be sent in kiln and burn till, firing temperature is 1200-1250 degree Celsius;
G, carry out polishing, edging process, the ceramic tile product that there is texture He ooze colored ornament layer can be obtained.
Embodiment 5
Embodiment 5 is substantially the same manner as Example 4, and difference is carrying out burning till step after on adobe surface, also charity has layer of transparent or translucent ornamental dry granular, and the particle diameter of ornamental dry granular is about 30 orders.Like this after subsequent high temperature sintering, the vitreous decoration protective layer of one deck can be formed on surface.The thickness of ornamental dry granular is 0.3-1mm, and the thickness of the glassiness decoration protective layer formed is 0.2-0.8mm.
By arranging above decoration protective layer, further protection can be done to pervious course, and there is three-dimensional decorative effect.
Certainly, except using ornamental dry granular, frit or glaze also can play similar effect, and those skilled in the art can carry out collocation according to demand and select with actual environment.
Embodiment 6
Different from above several embodiment, in the present embodiment, the upper surface of the punch-forming mold used has the adobe that concave convex texture is stamped to form, and adobe surface has Z-Correct bump mapping Z-correct.Product surface prepared like this has Z-Correct bump mapping Z-correct, and this also makes the decorative effect of brick more three-dimensional.
In addition, above several mode can also be combined, such as, burn till again after the adobe surface charity frit of preparation in enforcement 6.Use super flat-die tool, such as press upper mold core adopts minute surface punching block or super flat ebonite film, and lower mold core adopts isostatic pressed fish line or reticulate pattern mould, obtains adobe surfacing, interior solid degree is even, thus effectively reduces the production difficulty of flexible polishing.The finished product wave transformation after complete soft throwing is less, substantially reaches the polishing effect of " pure flat ".
Below know-why of the present invention is described in conjunction with specific embodiments.These describe just in order to explain principle of the present invention, and can not be interpreted as limiting the scope of the invention by any way.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present invention, and these modes all will fall within protection scope of the present invention.
Claims (10)
1. a manufacture method for ceramic tile, is characterized in that: it comprises the steps:
A, Ceramics brick are commonly used raw material and are made moulded pottery not yet put in a kiln to bake;
B, charity organic infiltration color glaze ink;
C, the organic penetration-assisting agent ink of charity;
D, at 50-200 DEG C of temperature, dry 10-60 minute obtains ceramic tile moulded pottery not yet put in a kiln to bake;
E, enter kiln and burn till at 1150-1250 DEG C;
Ceramic tile is obtained after F, polishing, edging.
2. the manufacture method of ceramic tile according to claim 1, is characterized in that, also comprises a placement moulded pottery not yet put in a kiln to bake and helps the step of oozing and forming pervious course, help the time of oozing to be no less than 10 minutes between step C and step D.
3. the manufacture method of ceramic tile according to claim 1, is characterized in that: moulded pottery not yet put in a kiln to bake described in steps A adopts fabric impact briquetting after upper forehand cloth by bed material and fabric, and the precoat thickness of formation is 0.5-2mm.
4. the manufacture method of ceramic tile according to claim 3, is characterized in that: the thickness of described precoat is 0.8-1.2mm.
5. the manufacture method of ceramic tile according to claim 1, it is characterized in that: described infiltration color glaze ink is the mixture of organic acid salt and ester in stepb, wherein organic acid salt be carboxyl acid group, at least one in sulfonate radical, sulfinate, thionothiolic acid root and the salt formed with at least one in the inorganic color development ion such as iron, cobalt, chromium, copper, described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.
6. the manufacture method of ceramic tile according to claim 5, is characterized in that: described organic acid salt is the salt that at least one in the inorganic color development ion such as carboxyl acid group and iron, cobalt, chromium, copper is formed.
7. the manufacture method of ceramic tile according to claim 1, is characterized in that: the described penetration-assisting agent ink in step C is the mixture of organic acid and ester deter-mation, and described organic acid is at least one in carboxylic acid, sulfonic acid,-sulfinic acid, thionothiolic acid; Described ester is at least one in long chain alkane, isocaprylic acid methyl esters, pungent methyl caprate.
8. the manufacture method of ceramic tile according to claim 2, is characterized in that: described in help the time of oozing to be 15-30 minute.
9. the manufacture method of ceramic tile according to claim 3, is characterized in that, in described fabric containing mass percent be 0.1-2% titanium dioxide, 0.1-0.5% zinc oxide, 0.1-5% zirconium silicate or 0.5-5% help at least one in red dose.
10. the manufacture method of ceramic tile according to claim 1; it is characterized in that; also be included in the step of adobe surface charity protective layer between described step D and step e, described protective layer is made up of at least one in glaze, clear frit particle or translucent decoration dry granular.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105175026A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Inkjet infiltrating glazed porcelain tile and preparation method thereof |
| CN105175027A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Ceramic with three-dimensional decoration effect and preparation method thereof |
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Cited By (7)
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|---|---|---|---|---|
| CN105175026A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Inkjet infiltrating glazed porcelain tile and preparation method thereof |
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| CN106800423A (en) * | 2015-11-26 | 2017-06-06 | 佛山市东鹏陶瓷有限公司 | A kind of preparation method for oozing colored ceramic tile |
| CN106800422A (en) * | 2015-11-26 | 2017-06-06 | 佛山市东鹏陶瓷有限公司 | A kind of manufacture method of Ceramic Tiles |
| CN106800423B (en) * | 2015-11-26 | 2019-07-16 | 佛山市东鹏陶瓷有限公司 | A kind of preparation method for seeping flower ceramic tile |
| CN106003374A (en) * | 2016-07-19 | 2016-10-12 | 东莞市唯美陶瓷工业园有限公司 | Ultrathin-fabric and whole-porcelain-body tile production process and device |
| CN108238819A (en) * | 2017-03-11 | 2018-07-03 | 肇庆乐华陶瓷洁具有限公司 | A kind of high texture Antique Imitation Tiles with fluorescence and preparation method thereof |
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