CN109704814A - A kind of ink ejecting method of high Scagliola ceramic tile - Google Patents
A kind of ink ejecting method of high Scagliola ceramic tile Download PDFInfo
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- CN109704814A CN109704814A CN201910142811.8A CN201910142811A CN109704814A CN 109704814 A CN109704814 A CN 109704814A CN 201910142811 A CN201910142811 A CN 201910142811A CN 109704814 A CN109704814 A CN 109704814A
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Abstract
The present invention relates to a kind of ink ejecting methods of high Scagliola ceramic tile, and described method includes following steps: 1) ceramic tile blank being carried out first sintering at 850-1000 DEG C；2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes the organic adhesive of 8-14%；3) second is carried out within the scope of Tf+150 DEG C to T1-50 DEG C to the green body after charity ground coat enamel to be sintered, wherein the Tf is the decomposition temperature of the organic binder, the T1 is first sintering temperature；4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments is being corresponded to away from green body in Texture Boundaries at 150-200 micron, and ink ejection amount 50-80g/m2mm, the m2 are billet surface area, and the mm is ground coat enamel thickness；5) green body completed to ink-jet carries out that infiltration is helped to handle.Technical solution, which carries out ink-jet, according to the present invention can efficiently control the degree of ink pigments infiltration, and the texture goodness of fit is high on green body and ground coat enamel longitudinal profile, greatly improves the three-dimensional sense and fidelity of ceramic tile.
Description
Technical field
The present invention relates to a kind of ink ejecting methods of ceramic tile, and in particular to a kind of ink ejecting method of high Scagliola ceramic tile.
Background technique
Natural marble is because of the stone decoration material that the appearance of its elegant is always that people pursue, however natural marble
Masonry is a kind of non-renewable resources, and exploitation and cost of manufacture are higher and higher, and in order to meet, people are growing to obtain natural marble
Stone demand rationally controls cost of manufacture simultaneously, occurs more and more artificial marbles on the market at present.However due to technology
Not good enough, the artificial marble fidelity and three-dimensional sense being prepared are undesirable, greatly affected marmorean fidelity.
Application No. is CN201110187245.6 Chinese patents to obtain the ceramic percolation suitable for inkjet printing by research and development
Glaze, specifically, change technical solution be by it is one or more of can the soluble metallic salt of color development to be dissolved in deionized water be main
In the prepared solution of glycerine organic solvent in certain ratio, after being completely dissolved, surface-active is added in solvent, ethylene glycol
Colorant and preservative can be also added to improve performance in agent, viscosity modifier, bleeding agent, pH value adjustment agent, reconcile and be for viscosity
1-10mpas, conductivity are greater than the aqueous glaze that 100ms/m, pH value 7-8.5 have penetration property, which can make pottery
It uses on porcelain ink jet printing device, is burnt by the ceramic tile after inkjet printing layout through 1080 DEG C~1200 DEG C high temperature of roller kilns
After system, different texture and color decorative effect are showed.However, due to lacking specific control technique, the above method is obtained
Penetration glaze still have the problems such as osmotic effect is undesirable, and texture is unintelligible, seriously affected the three-dimensional sense of ceramic tile and true to nature
Degree.
Application No. is the Chinese invention patents of CN201210331440.6 to disclose a kind of preparation method for seeping flower Imitation Rock Porcelain Tiles,
This method includes the water-soluble metal salt containing Fe, the water-soluble metal salt containing Au, the water solubility gold containing Cr by selecting
Belong to the ink of one or more of salt, water-soluble metal salt containing Co and select and contains SiO2:60%~70%, Al2O3:
15%~25%, MgO+CaO:0~3%, K2O+Na2O:3.5%~8%, ZnO:0.2%~5%, TiO2:0.2%~5%,
Surplus is impurity, and the fineness of starch adhesive is 325 mesh sieve margins within 0.5%, and specific gravity is the starch adhesive of 1.60~1.90g/cm3, is adopted
With the mode of ink jet printing by emitting ink on green compact.Since this method is only optimized the composition of ink and ground coat enamel,
It is not directed to the technologic matching of control, therefore still can have that ink penetration is uncontrollable, the inadequate problem of fidelity.
Number of patent application is a kind of ceramics with three-dimensional decorative effect of Chinese invention patent of CN201810587557.8
The manufacturing method of brick comprising following steps: A, there is the moulded pottery not yet put in a kiln to bake of Z-Correct bump mapping Z-correct to carry out first at 600-1050 DEG C surface
Secondary firing；B, the organic penetration glaze ink of charity and organic penetration-assisting agent ink on the green body after first time is burnt into；C, in 1150-
It carries out being burnt into for second at 1250 DEG C；D, it is polished, edging processing obtains ceramic brick product.Although being carried out at 600-1050 DEG C
First easy fired can allow the stomata in adobe sufficiently to open and permeated again after stomata opening, penetration glaze ink meeting
Diffusion admittance is asked with stomata, and diffusion can be reinforced, and reduce the dosage of organic inks, and diffusion can be made more uniform.But
This method is the influence after capable of considering charity ground coat enamel to ink bleed, it is clear that the Dali stone ceramic tile fidelity of above method preparation
It is not ideal enough.
Above content is only used to facilitate the understanding of the technical scheme, and is not represented and is recognized that above content is existing skill
Art.
Summary of the invention
For presently, there are ink bleed is uncontrollable, technical problem that the inadequate three-dimensional sense of ceramic tile fidelity is not strong, this
Invention provides a kind of preparation method with three-dimensional sense simulating ceramic tile, it is intended to solve the above problems, improve the fidelity of ceramic tile
And three-dimensional sense.
Technical solution provided by the invention is as follows:
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 850-1000 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes the organic adhesive of 8-14%；
3) second is carried out within the scope of Tf+150 DEG C to T1-50 DEG C to the green body after charity ground coat enamel to be sintered, wherein described
Tf is the decomposition temperature of the organic binder, and the T1 is first sintering temperature；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 150-200 microns, ink ejection amount 50-80g/m2mm, the m2 are billet surface area, and the mm is ground coat enamel thickness；
5) green body completed to ink-jet carries out that infiltration is helped to handle.
Preferably, the organic adhesive include one of acrylic resin, epoxy resin, Pioloform, polyvinyl acetal with
On.
Preferably, the component of the ground coat enamel further include SiO2 55~65%, Al3O2 10-15%, 0.05 Fe2O3~
0.1%, K2O 1.5-3.5%, 2 Na2O~3%, MgO 1-4%.
Preferably, described to help infiltration processing to carry out longitudinal electric field processing, the electricity of the longitudinal electric field processing to layer of ink surface
Pressure is 2-5V, and the processing time is 20-40 minutes.
It is further preferred that second of sintering temperature control is at 700-800 DEG C.
It is further preferred that the boundary Control of the ink pigments is corresponding in Texture Boundaries 180-200 microns away from green body
Place.
The present invention can make ground coat enamel cloth by adding a small amount of organic adhesive, one side bonding agent in ground coat enamel well
It applies in adobe, on the other hand after double sintering, the organic adhesive in ground coat enamel forms hole by decomposing volatilization, helps
In the infiltration of subsequent ink pigments.In addition, being also required to reasonably be controlled for the dosage of organic adhesive, when dosage is too low
When the through-hole rate that is formed it is too low unobvious to the infiltration facilitation of ink pigments, through-hole rate is excessively high if dosage is excessively high and hole
Diameter is excessive, and the infiltration direction and depth that thus will lead to ink pigments are difficult to control therefore ground coat enamel texture caused to be distorted, and is based on
Ground coat enamel component of the invention controls the content of organic adhesive within the scope of 8-14%, by logical in follow-up sintering ground coat enamel
Porosity is 35-42%, and average pore size provides good basic condition at 15-20 μm, for the infiltration control of subsequent ink pigments.
Sintering temperature control by carrying out double sintering to the adobe after charity ground coat enamel and is being higher than organic glue by the present invention
150 DEG C of agent decomposition temperature or more are connect lower than more than once sintered temperature 50 C, on the one hand promotes organic adhesive well
Decomposition makes in ground coat enamel that there are the infiltrations of the subsequent ink pigments of reasonable voidage to provide condition well, another aspect, will be warm
Degree control is in above range it is possible to prevente effectively from occurring mutually to seep between green and ground coat enamel to be distorted so as to cause texture on section.
The present invention reasonably controlled by the region to ink-jet and cooperate it is subsequent help infiltration treatment process, can be effective
Diffusion energy while ground controls ink pigments longtitudinal dispersion to rational position in transverse direction effectively arrives at green body and corresponds to Texture Boundaries
Place, so that ceramic tile be made to have ideal three-dimensional sense and high fidelity, ink ejection amount and ink-jet boundary method of determination is then
Calculated according to the porosity of ground coat enamel after the sintering of aforementioned charity ground coat enamel and average pore size, is based on charity ground coat enamel above-mentioned and two
Secondary sintering process, the present invention determined by ink-jet boundary be corresponded in Texture Boundaries at 150-200 microns away from green body, ink ejection amount is
50-80g/m2·mm。
The present invention helps cementation process that can effectively facilitate the infiltration of ink pigments in the longitudinal direction by using what longitudinal electric field was handled
Thoroughly, and the relevant parameter of electric field treatment should with required osmotic effect be adapted, if electric field strength crosses reduction process, the time is too short,
Then ideal position, which is not achieved, in ink pigments infiltration causes to be distorted；If the excessive processing overlong time of electric field strength, ink pigments
Depth and width have exceeded ideal range, thereby result in the texture of ground coat enamel and green body unlike adapting to, ceramic tile longitudinal profile texture
Distortion is obvious.For these reasons, what the present invention finally determined through a large number of experiments is suitable for helping cementation process condition for longitudinal electricity
The voltage control of field processing handles time control at 20-40 minutes in 2-5V.
Compared with prior art, carrying out ink-jet the invention has the following beneficial effects: technical solution according to the present invention can
The degree of ink pigments infiltration is efficiently controlled, the texture goodness of fit is high on green body and ground coat enamel longitudinal profile, greatly improves ceramic tile
Three-dimensional sense and fidelity.
Specific embodiment
It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 850 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), for the ground coat enamel with a thickness of 2mm, the ground coat enamel includes acrylic acid tree
Rouge 8%, SiO260%, Al3O2 10%, Fe2O3 0.05%, K2O 1.5%, Na2O 2%, MgO 2%；
3) second is carried out within the scope of 680 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 150 microns, ink ejection amount 158g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 4V is applied to the green body that ink-jet is completed, the processing time is 30 minutes.
According to ceramic tile manufactured in the present embodiment, the porosity measured after double sintering is 36%, 5 μm of average pore size, ground coat enamel
Ink-jet texture and blank Texture Boundaries goodness of fit height, ceramic tile three-dimensional sense are strong.
Embodiment 2
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 1000 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes asphalt mixtures modified by epoxy resin with a thickness of 1.8mm, the ground coat enamel
Rouge 12%, SiO255%, Al3O2 12%, Fe2O3 0.1%, K2O2.8%, Na2O 3%, MgO 3.6%；
3) second is carried out within the scope of 800 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 180 microns, ink ejection amount 126g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 3.5V is applied to the green body that ink-jet is completed, the processing time is 25 minutes.
According to ceramic tile manufactured in the present embodiment, the porosity measured after double sintering is 40%, 7 μm of average pore size, ground coat enamel
Ink-jet texture and blank Texture Boundaries goodness of fit height, ceramic tile three-dimensional sense are strong.
Embodiment 3
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 1000 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes epoxy resin with a thickness of 2mm, the ground coat enamel
14%, SiO2 65%, Al3O2 15%, Fe2O3 0.1%, K2O 1.5%, Na2O 2%, MgO 2%；
3) second is carried out within the scope of 800 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 200 microns, ink ejection amount 104g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 2V is applied to the green body that ink-jet is completed, the processing time is 20 minutes.
According to ceramic tile manufactured in the present embodiment, the porosity measured after double sintering is 42%, 10 μm of average pore size, ground coat enamel
Ink-jet texture and blank Texture Boundaries goodness of fit height, ceramic tile three-dimensional sense are strong.
Embodiment 4
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 950 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes polyethylene with a thickness of 1.5mm, the ground coat enamel
Acetal 10%, SiO262%, Al3O215%, Fe2O30.07%, K2O 3.5%, Na2O3%, MgO 4%；
3) second is carried out within the scope of 750 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 170 microns, ink ejection amount 148g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 3V is applied to the green body that ink-jet is completed, the processing time is 28 minutes.
According to ceramic tile manufactured in the present embodiment, the porosity measured after double sintering is 38%, 6 μm of average pore size, ground coat enamel
Ink-jet texture and blank Texture Boundaries goodness of fit height, ceramic tile three-dimensional sense are strong.
Comparative example 1
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is sintered at 850 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes SiO2 with a thickness of 2mm, the ground coat enamel
60%, Al3O2 10%, Fe2O3 0.05%, K2O 1.5%, Na2O 2%, MgO 2%；
3) ink-jet is carried out to green body obtained by step 2), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 150 microns, ink ejection amount 158g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 4V is applied to the green body that ink-jet is completed, the processing time is 30 minutes.
According to ceramic tile prepared by this comparative example, ceramic tile cross-sectional direction ground coat enamel ink-jet texture differs bright with blank Texture Boundaries
Aobvious, not enough, longitudinal texture fidelity is low for the infiltration of ground glaze layer ink pigments on naked eyes visible texture border-differential, longitudinal cross-section, stands
Body-sensing is poor.
Comparative example 2
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 850 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), for the ground coat enamel with a thickness of 2mm, the ground coat enamel includes acrylic acid tree
Rouge 4%, SiO2 60%, Al3O2 10%, Fe2O3 0.05%, K2O 1.5%, Na2O 2%, MgO 2%；
3) second is carried out within the scope of 680 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 150 microns, ink ejection amount 158g/m2mm, the m2 are billet surface area；
5) longitudinal electric field that voltage is 4V is applied to the green body that ink-jet is completed, the processing time is 30 minutes.
According to ceramic tile prepared by this comparative example, the porosity measured after double sintering is 18%, 5 μm of average pore size, ceramic tile
There are ground glaze layer inks on naked eyes visible borders difference, longitudinal cross-section with blank Texture Boundaries for cross-sectional direction ground coat enamel ink-jet texture
There are apparent phantoms with cladding layer texture for pigment penetration layer, and longitudinal texture fidelity is lower, and three-dimensional sense is bad.
Comparative example 3
A kind of ink ejecting method of high Scagliola ceramic tile, described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 1000 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes epoxy resin with a thickness of 2mm, the ground coat enamel
25%, SiO255%, Al3O2 12%, Fe2O3 0.1%, K2O 1.5%, Na2O 2%, MgO 2%；
3) second is carried out within the scope of 1600 DEG C to the green body after charity ground coat enamel to be sintered；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments corresponds in Texture Boundaries away from green body
At 200 microns, ink ejection amount 104g/m2, the m2 are billet surface area；
5) longitudinal electric field that voltage is 2V is applied to the green body that ink-jet is completed, the processing time is 20 minutes.
According to ceramic tile manufactured in the present embodiment, the porosity measured after double sintering is 55%, 32 μm of average pore size, ceramic tile
Cross-sectional direction ground glaze layer ink pigments dispersal direction is mixed and disorderly, obvious with blank material layer Texture Boundaries difference, cladding on longitudinal interface
Layer mutually seeps obviously with ground glaze layer, and the distortion factor is high, three-dimensional sense is poor.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (7)
1. a kind of ink ejecting method of high Scagliola ceramic tile, it is characterised in that: described method includes following steps:
1) ceramic tile blank is subjected to first sintering at 850-1000 DEG C；
2) to the sintered green body charity ground coat enamel of step 1), the ground coat enamel includes the organic adhesive of 8-14%；
3) second is carried out within the scope of Tf+150 DEG C to T1-50 DEG C to the green body after charity ground coat enamel to be sintered, wherein the Tf is
The decomposition temperature of the organic binder, the T1 are first sintering temperature；
4) ink-jet is carried out to green body obtained by step 3), the boundary Control of ink pigments is corresponding to 150- in Texture Boundaries away from green body
At 200 microns, ink ejection amount 50-80g/m2mm, the m2 are billet surface area, and the mm is ground coat enamel thickness；
5) green body completed to ink-jet carries out that infiltration is helped to handle.
2. ink ejecting method according to claim 1, it is characterised in that: the organic adhesive includes acrylic resin, ring
One or more of oxygen resin, Pioloform, polyvinyl acetal.
3. according to the method described in claim 1, it is characterized by: the component of the ground coat enamel further include SiO2 55~65%,
Al3O2 10-15%, 0.05 Fe2O3~0.1%, K2O 1.5-3.5%, 2 Na2O~3%, MgO 1-4%.
4. ink ejecting method according to claim 1, it is characterised in that: described to help infiltration processing to carry out longitudinal direction to layer of ink surface
Electric field treatment.
5. ink ejecting method according to claim 4, it is characterised in that: the voltage of the longitudinal electric field processing is 2-5V, place
Managing the time is 20-40 minutes.
6. ink ejecting method according to claim 1-5, it is characterised in that: second of sintering temperature control exists
700-800℃。
7. ink ejecting method as described in any one in claim 1-5, it is characterised in that: the boundary Control of the ink pigments away from
Green body corresponds in Texture Boundaries at 180-200 microns.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910142811.8A CN109704814B (en) | 2019-02-26 | 2019-02-26 | Ink-jet method for high-simulation marble tile |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910142811.8A CN109704814B (en) | 2019-02-26 | 2019-02-26 | Ink-jet method for high-simulation marble tile |
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| CN109704814B CN109704814B (en) | 2022-03-15 |
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Cited By (1)
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| CN113372136A (en) * | 2021-07-08 | 2021-09-10 | 广东博智林机器人有限公司 | Inorganic artificial stone plate and preparation method thereof |
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