CN104987135A - Production method for travertine-like ceramic tiles - Google Patents

Production method for travertine-like ceramic tiles Download PDF

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Publication number
CN104987135A
CN104987135A CN201510354864.8A CN201510354864A CN104987135A CN 104987135 A CN104987135 A CN 104987135A CN 201510354864 A CN201510354864 A CN 201510354864A CN 104987135 A CN104987135 A CN 104987135A
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China
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low temperature
brick
production
temperature glaze
glaze
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CN201510354864.8A
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CN104987135B (en
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丘云灵
金国庭
周燕
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Fengcheng Dongpeng Ceramic Co., Ltd.
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
Qingyuan Nafuna Ceramics Co Ltd
Original Assignee
FENGCHENG DONGPENG CERAMIC Co Ltd
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
Guangdong Dongpeng Ceramic Co Ltd
Qingyuan Nafuna Ceramics Co Ltd
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Priority to CN201510354864.8A priority Critical patent/CN104987135B/en
Publication of CN104987135A publication Critical patent/CN104987135A/en
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Abstract

The invention provides a production method for travertine-like ceramic tiles. The production method includes the following steps: A, manufacturing polished green tiles, wherein the surfaces of formed and dried green tiles are polished through a green tile polishing machine, and then green tile surfaces with clear pattern textures are obtained; B, applying low-temperature glaze, wherein the low-temperature glaze is applied on the polished green tiles obtained in the step A; C, applying transparent glaze, wherein the transparent glaze is applied on the polished green tiles obtained in the step B; D, performing firing and polishing to obtain the finished products. According to the production method for the travertine-like ceramic tiles, the simulation degree is high, the color and luster of the produced travertine-like ceramic tiles are rich and changeable, and the controllability of the travertine effect is high.

Description

The production method of a kind of imitative hole feldspar brick
Technical field
The present invention relates to building material technical field, particularly relate to the production method of a kind of imitative hole feldspar brick.
Background technology
Hole stone, formal name used at school is called Tufa, English name: (Travertine) is a kind of rock of porous, so people are also its hole stone usually.Hole stone belongs to nonmarine deposit rock, and it is a kind of settling of calcium carbonate.Hole stone is formed at rich Wingdale landform calciferous mostly, is formed in the ground such as riverbed, lakebed by calcium calcium carbonate soluble in water and other mineral deposition.Owing to there is hole sometimes in the process of heavily piling up, simultaneously because the main component of himself is again calcium carbonate, self be just easy to be corroded by water dissolution, so there will be many natural random holes in these storess.Natural cavity stone clean mark, gentle abundant texture, be derived from natural, but surmount natural.Finished product out, reasonable organization, concavo-convex harmony, just come back to life from earth seemingly, in the texture of lines tendency, texture, the dark vestige hiding prehistoric civilization, but its total figure modelling can describe with " modern trend " again, shows a kind of design demeanour divisional greatly especially, rank and honour, elegance, top product speciality are showed incisively and vividly, because dark doting on by numerous architects.
In natural travertine stone-imitated tile, two kinds can be divided into, a kind of have true hole, ceramic tile deliberately generates hole in process of production, such as application number 200610167363.X natural cavity stone imitation ceramic tile, adopt polishing residue material as a part for fabric, when firing, material is by thermogenesis gas, and gas distributes thus the hole on surface from fabric.This natural travertine stone-imitated tile and natural cavity stone are relatively.Another natural travertine stone-imitated tile, then on the basis of the first, use transparency material to fill the hole produced, thus formation one appears to have hole, but touch up the ceramic tile not having hole to feel, the benefit of this ceramic tile is, can as ground tile paving, and be filled due to hole, can not shelter evil people and countenance evil practices, convenient for cleaning, remain again the natural aesthetic feeling of hole stone simultaneously.But existing natural travertine stone-imitated tile is generally polished tile, its color and luster texture variations is few, and the design of brick face can not be enriched changeable, has certain limitation, and not as good as ornamental brick texture, true and pattern enriches fine and smooth feature.
Summary of the invention
The object of the invention is to the production method proposing the high imitative hole feldspar brick of a kind of emulator, its color and luster enriches changeable, and hole stone effect controllability is high.
For reaching this object, the present invention by the following technical solutions:
A production method for imitative hole feldspar brick, comprises the following steps:
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to the adobe after shaping and drying, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains;
C, charity transparent: transparent is executed to the throwing grey cloth that step B obtains;
D, fire polishing, obtain finished product.
Preferably, the softening temperature of described low temperature glaze is lower than 850 DEG C.
Preferably, the cloth applying method of described low temperature glaze is one or more combinations in silk screen printing or ink-jet glaze spraying.
Preferably, in step B, low temperature glaze correspondence is printed on the pattern texture of throwing base surface design of steps A.
Preferably, the glaze of low temperature glaze described in step B comprises following component: 30-40%SiO 2, 55-65%PbO, 3-8%Al 2o 3, 1-3% (Na 2o, K 2and 0.2-1%MgO O).
Preferably, the adobe preparation of steps A: through press compression moulding after the powder of different colours, different texture is gone out with effects such as micro mist lines pattern according to design requirements cloth.
Preferably, before step C charity transparent, also comprise stamp program, carry out stamp by the mode of one or more combinations in locating ink-jet or silk screen printing.
Preferably, in step B, the position of printed design its stamp corresponding that low temperature glaze is established surely according to brick face is printed.
Preferably, in described stamp program, its decalcomania is designed by the spelling group of two or more pattern, and printed design its position that is a kind of or multiple patterns corresponding that in step B, low temperature glaze is established surely according to brick face is printed, or in step B, low temperature glaze stochastic print is surperficial in the throwing base of steps A.
Preferably, the unfired brick structure that step D obtains comprises initial bed and transparent layer from bottom to top, also arranges low temperature glaze layer between described initial bed and described transparent layer.
Preferably, be also provided with printed layer between described low temperature glaze layer and described transparent layer, the layout that the design of described printed layer corresponds to described low temperature glaze layer designs.
Beneficial effect of the present invention: 1, use low temperature glaze to obtain hole stone effect, form hole stone effect after firing polishing on brick face, the ceramic tile bottom the stone of hole with decorative pattern or textured pattern can be obtained; 2, its color and luster can change the technologic change such as bed material or transparent according to the different demand of people, and abundanter than polished tile color and luster, emulator is higher; 3, by interval or the Random Design of imitative hole stone, the stereoscopic visual effect in brick face is strengthened.
Accompanying drawing explanation
Fig. 1 is the preparation flow schematic diagram of the blank structure of one embodiment of the present of invention;
Fig. 2 is the preparation flow schematic diagram of the blank structure of an alternative embodiment of the invention;
Fig. 3 is the preparation flow schematic diagram of the blank structure of an alternative embodiment of the invention;
Fig. 4 is the brick face schematic diagram of the imitative hole feldspar brick burnt till of one embodiment of the present of invention;
Fig. 5 is the preparation flow schematic diagram of the blank structure of an alternative embodiment of the invention;
Fig. 6 is the brick face schematic diagram of the imitative hole feldspar brick burnt till of an alternative embodiment of the invention.
Wherein: initial bed 1, low temperature glaze layer 2, printed layer 3, transparent layer 4.
Embodiment
Technical scheme of the present invention is further illustrated by embodiment below in conjunction with accompanying drawing 1-6.
A production method for imitative hole feldspar brick, is characterized in that: comprise the following steps:
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to the adobe after shaping and drying, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains;
C, charity transparent: transparent is executed to the throwing grey cloth that step B obtains;
D, fire polishing, obtain finished product.
The present invention uses low temperature glaze to obtain hole stone effect, on brick face, hole stone effect is formed after firing polishing, the ceramic tile bottom the stone of hole with decorative pattern or textured pattern can be obtained, low temperature glaze refers to that firing temperature is lower than the glaze of 1120 DEG C, its color and luster can change the technologic change such as bed material or transparent according to the different demand of people, abundanter than polished tile color and luster, emulator is higher.In step D, sintering procedure is that the throwing base that pouring glaze completes is sent into kiln kiln roasting, and firing temperature is 1100-1250 DEG C.In steps A, the design of pattern texture can according to the diversified design of the market requirement, the spray of transparent in step C, every square metre of 150-1200g.Adopt soft rubbing down tool to carry out polishing in step D, the soft rubbing down tool of resin can be selected to carry out polishing, cavitation after polishing.
Preferably, the softening temperature of described low temperature glaze is lower than 850 DEG C.
Preferably, the cloth applying method of described low temperature glaze is one or more combinations in silk screen printing or ink-jet glaze spraying.The present invention uses low temperature glaze to obtain hole stone effect, and decide by the order number size of silk screen and the viscosity of low temperature glaze the quantity that low temperature glaze is printed on billet surface, low temperature glaze is printed on quantity and the size of the quantity decision cavitation of billet surface, cavitation effect controllability is high, low temperature glaze can according to the design of stamp, spaced design in printed surface or stamp prints, interval printing can fire cavitation, be randomly distributed in compared with the natural cavity stone imitation polished tile on brick face with existing hole stone, effect is more diversified, has larger market.
Preferably, in step B, low temperature glaze correspondence is printed on the pattern texture of throwing base surface design of steps A.To occur that the place of hole stone is corresponding with the position that steps A throws the pattern texture that base is provided with by location, low temperature glaze is made to correspond to pattern texture printing, on texture, good hole stone effect is formed after burning till, hole stone effect can be more obvious on pattern texture, and the structure of hole stone makes stamp at the bottom of hole to the visual effect of people's solid.
Preferably, the glaze of low temperature glaze described in step B comprises following component: 30-40%SiO 2, 55-65%PbO, 3-8%Al 2o 3, 1-3% (Na 2o, K 2and 0.2-1%MgO O).Under about 900 DEG C, plumbous oxide watery fusion, can be enclosed in melting layer by all or part of for base substrate expellant gas, form bubble, the transparent layer and part bubble can rise brokenly, form the hole exposed, hole is left in the position making brick face be printed on low temperature glaze, polishing rear section or CAB also expose on brick face, form good hole stone effect.The range of viscosities value of low temperature glaze is 6000-11000mpa.s, and specific gravity range value is 1.5-1.8.
Containing a certain amount of constitution water and organic and decomposable carbonate in blank raw material, these components all can produce gas when burning till and discharge.Because it is lower to produce gas temperature, be about 800-1000 DEG C, for the not melting at this temperature of traditional glaze, gas is easy to discharge, containing low temperature flux in low temperature glaze provided by the invention, melting at the temperature that can produce at base substrate gas, the gas produced by base substrate is all or part of to be enclosed in wherein, forms bubble.
Preferably, the adobe preparation of steps A: through press compression moulding after the powder of different colours, different texture is gone out with effects such as micro mist lines pattern according to design requirements cloth.By throwing the design of base, enrich the brick face effect of ceramic tile, combine the low temperature glaze layer imitating hole stone, compared with existing natural cavity stone imitation polished tile, its color and luster texture variations is many, brick face establish enrich changeable.
Preferably, before step C charity transparent, also comprise stamp program, carry out stamp by the mode of one or more combinations in locating ink-jet or silk screen printing.Carry out stamp before charity transparent, its decalcomania is formed by the spelling group of two or more pattern, designs unrestricted, and range of choice is wide, enriches the effect in brick face.
Preferably, in step B, the position of printed design its stamp corresponding that low temperature glaze is established surely according to brick face is printed.
Preferably, in described stamp program, its decalcomania is designed by the spelling group of two or more pattern, and printed design its position that is a kind of or multiple patterns corresponding that in step B, low temperature glaze is established surely according to brick face is printed, or in step B, low temperature glaze stochastic print is surperficial in the throwing base of steps A.The throwing base surface that in step B, low temperature glaze correspondence is printed in steps A or printed design its position that is a kind of or multiple patterns corresponding of surely establishing according to brick face, the part decalcomania in brick face is made to have hole stone effect, enrich the decorative effect in brick face, and pass through interval or the Random Design of imitative hole stone, strengthen the stereoscopic visual effect in brick face.
Preferably, the unfired brick structure that step D obtains comprises initial bed and transparent layer from bottom to top, also arranges low temperature glaze layer between described initial bed and described transparent layer.
Preferably, be also provided with printed layer between described low temperature glaze layer and described transparent layer, the layout that the design of described printed layer corresponds to described low temperature glaze layer designs.
Embodiment 1
The unfired brick structure used in Examples below, the powder chemical composition (wt%) of its green body layer is: SiO 2: 70%, Al 2o 3: 21%, CaO:1%, MgO:2%, K 2o:2%, Na 2o:3%, Fe 2o 3: 0.5%, TiO 2: 0.5%, prepare powder by said ratio, dry, for subsequent use after the powder pressing prepared being become adobe;
The chemical composition of its low temperature glaze: SiO 2: 30%, PbO:65%, Al 2o 3: 3%, (Na 2o, K 2o): 1%, MgO:1%, the low temperature glaze viscosity prepared by mixing and ball milling is 9000mpa.s, and proportion is 1.7, and the softening temperature of described low temperature glaze is 850 DEG C.
The chemical composition (wt%) of its transparent is: NaO:1.5%; KO:2%; AlO:11%; CaO:8%; MgO:5%; ZnO:2%; ZrO:4%; High temperature frit: 15%; Loss on ignition: 6%; SiO is 45.5%.Flow velocity is 40s, proportion 1.75.It should be noted that, transparent can select the formula of the transparent used in existing production.
A production method for imitative hole feldspar brick, comprises the following steps (flow process can as shown in Figure 1):
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to adobe, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains, wherein low temperature glaze adopts silk screen to carry out charity corresponding to the pattern texture on adobe surface, and meshcount is 60;
C, charity transparent: transparent is executed to the throwing grey cloth that step B obtains;
D, fire polishing, obtain finished product, brick face effect as shown in Figure 4, is provided with textured pattern at the bottom of hole, make textured pattern to the visual effect of people 3D, hole stone emulator is high, and the visibility of hole stone is 6-7m, the hole length of hole stone is 15-40mm, and width is 2-10mm, and the degree of depth is 3-6mm.
Embodiment 2
Use the adobe identical with embodiment 1 and transparent;
The chemical composition of its low temperature glaze: SiO 2: 40%, PbO:55%, Al 2o 3: 3%, (Na 2o, K 2o): 1%, MgO:1%, the low temperature glaze viscosity prepared by mixing and ball milling is 10000mpa.s, and proportion is 1.63, and the softening temperature of described low temperature glaze is 800 DEG C.
The production method of another kind of imitative hole feldspar brick, comprises the following steps (flow process can as shown in Figure 5):
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to adobe, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains, low temperature glaze corresponds to adobe surface and does not establish veined position to adopt ink-jet printer to print, and thickness is 5mm;
C, carry out stamp: adopt silk screen printing to carry out stamp, wherein stamp position is consistent with the position of low temperature glaze charity;
D, charity transparent: transparent is executed to the throwing grey cloth that step C obtains;
E, fire polishing, obtain finished product, as shown in Figure 6, hole is provided with stamp textured pattern to brick face effect, make decalcomania to the visual effect of people 3D, hole stone emulator is high, and the visibility of hole stone is 5-6m, the hole length of hole stone is 5-20mm, and width is 2-6mm, and the degree of depth is 3-5mm.
Embodiment 3
Use the adobe identical with embodiment 1 and transparent;
The chemical composition of its low temperature glaze: SiO 2: 35%, PbO:60%, Al 2o 3: 3%, (Na 2o, K 2o): 1%, MgO:1%, the low temperature glaze viscosity prepared by mixing and ball milling is 9850mpa.s, and proportion is 1.83, and the softening temperature of described low temperature glaze is 780 DEG C.
A production method for imitative hole feldspar brick, comprises the following steps (flow process can as shown in Figure 2):
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to adobe, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains, the pattern texture that low temperature glaze corresponds to adobe surface adopts silk screen to carry out charity, and meshcount is 160;
C, carry out stamp: adopt silk screen printing to carry out stamp, wherein stamp position is consistent with the position of low temperature glaze charity, and decalcomania is the stamp of imitating natural stone texture;
D, charity transparent: transparent is executed to the throwing grey cloth that step C obtains;
E, fire polishing, obtain finished product, hole is provided with imitating natural stone texture, makes imitating natural stone texture to the visual effect of people 3D, and hole stone emulator is high, and the visibility of hole stone is 3-4m, and the hole length of hole stone is 5-15mm, and width is 2-5mm, and the degree of depth is 2-3mm.
Embodiment 4
Use the adobe identical with embodiment 1 and transparent;
The chemical composition of its low temperature glaze: SiO 2: 33.8%, PbO:55%, Al 2o 3: 8%, (Na2O, K2O): 3%, MgO:0.2%, the low temperature glaze viscosity prepared by mixing and ball milling is 8500mpa.s, and proportion is 1.63, and the softening temperature of described low temperature glaze is 820 DEG C.
A production method for imitative hole feldspar brick, comprises the following steps (flow process can as shown in Figure 2):
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to adobe, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains, the pattern texture that low temperature glaze corresponds to adobe surface adopts silk screen to carry out charity, and meshcount is 120;
C, carry out stamp: adopt silk screen printing to carry out stamp, wherein stamp position is consistent with the position of low temperature glaze charity, and decalcomania is the stamp of imitating natural stone texture;
D, charity transparent: transparent is executed to the throwing grey cloth that step C obtains;
E, fire polishing, obtain finished product, hole is provided with imitating natural stone texture, makes imitating natural stone texture to the visual effect of people 3D, as being piled up the stone structure formed by magma natural flow, meticulous true to nature, hole stone emulator is high, and the visibility of hole stone is 5-6m, and the hole length of hole stone is 5-15mm, width is 3-6mm, and the degree of depth is 2-5mm.
Embodiment 5
Use the adobe identical with embodiment 1 and transparent;
The chemical composition of its low temperature glaze: SiO2:40%, PbO:50%, Al2O3:7.5%, (Na2O, K2O): 2%, MgO:0.5%, the low temperature glaze viscosity prepared by mixing and ball milling is 8470mpa.s, proportion is 1.60, and the softening temperature of described low temperature glaze is 900 DEG C.
A production method for imitative hole feldspar brick, comprises the following steps:
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to adobe, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains, the pattern texture that low temperature glaze corresponds to adobe surface adopts silk screen to carry out charity, and meshcount is 120;
C, carry out stamp: adopt silk screen printing to carry out stamp, wherein stamp position is consistent with the position of low temperature glaze charity, and decalcomania is the stamp of imitating natural stone texture;
D, charity transparent: transparent is executed to the throwing grey cloth that step C obtains;
E, fire polishing, obtain finished product, hole is provided with imitating natural stone texture, makes imitating natural stone texture to the visual effect of people 3D, as being piled up the stone structure formed by magma natural flow, meticulous true to nature, hole stone emulator is high, and the visibility of hole stone is 5-6m, and the hole length of hole stone is 5-10mm, width is 3-4mm, and the degree of depth is 2-3mm.The softening temperature of described low temperature glaze is 900 DEG C, because it is lower to produce gas temperature, is about 800-1000 DEG C, 900 DEG C time, low temperature glaze just forms the words of melting layer, the gas of a part can be run away before 900 DEG C, the formation of hole is diminished, be unfavorable for the formation controlling hole.
Below know-why of the present invention is described in conjunction with specific embodiments.These describe just in order to explain principle of the present invention, and can not be interpreted as limiting the scope of the invention by any way.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present invention, and these modes all will fall within protection scope of the present invention.

Claims (10)

1. a production method for imitative hole feldspar brick, is characterized in that: comprise the following steps:
Base is thrown in A, preparation: utilize throwing base machine to carry out grinding process to its surface to the adobe after shaping and drying, obtain pattern texture adobe clearly surface;
B, charity low temperature glaze: charity low temperature glaze on the throwing base that steps A obtains;
C, charity transparent: transparent is executed to the throwing grey cloth that step B obtains;
D, fire polishing, obtain finished product.
2. a kind of natural cavity stone imitation according to claim 1 throws the production method of glazed brick, it is characterized in that: the softening temperature of described low temperature glaze is lower than 850 DEG C.
3. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: the cloth applying method of described low temperature glaze is one or more combinations in silk screen printing or ink-jet glaze spraying.
4. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: in step B, low temperature glaze correspondence is printed on the pattern texture of throwing base surface design of steps A.
5. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: the glaze of low temperature glaze described in step B comprises following component: 30-40%SiO 2, 55-65%PbO, 3-8%Al 2o 3, 1-3% (Na 2o, K 2and 0.2-1%MgO O).
6. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: the adobe of steps A preparation: through press compression moulding after the powder of different colours, different texture is gone out with effects such as micro mist lines pattern according to design requirements cloth.
7. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: before step C charity transparent, also comprise stamp program, carries out stamp by the mode of one or more combinations in locating ink-jet or silk screen printing.
8. the production method of a kind of imitative hole according to claim 7 feldspar brick, is characterized in that: in step B, the position of printed design its stamp corresponding that low temperature glaze is established surely according to brick face is printed.
9. the production method of a kind of imitative hole according to claim 8 feldspar brick, it is characterized in that: in described stamp program, its decalcomania is designed by the spelling group of two or more pattern, printed design its position that is a kind of or multiple patterns corresponding that in step B, low temperature glaze is established surely according to brick face is printed, or in step B, low temperature glaze stochastic print is surperficial in the throwing base of steps A.
10. the production method of a kind of imitative hole according to claim 1 feldspar brick, is characterized in that: the unfired brick structure that step D obtains comprises initial bed and transparent layer from bottom to top, also arranges low temperature glaze layer between described initial bed and described transparent layer.
CN201510354864.8A 2015-06-24 2015-06-24 A kind of production method of imitative hole feldspar brick Active CN104987135B (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN105541343A (en) * 2015-12-18 2016-05-04 蒙娜丽莎集团股份有限公司 Method for preparing inkjet-penetrated travertine polished tiles
CN106242527A (en) * 2016-08-09 2016-12-21 佛山欧神诺陶瓷股份有限公司 A kind of high emulation entire body throws glaze marble ceramic tile and production method thereof entirely
CN108972839A (en) * 2018-08-10 2018-12-11 佛山市东鹏陶瓷有限公司 A kind of preparation process and its ceramic tile of thin layer cloth solid Ceramic Tiles

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CN1519213A (en) * 2003-01-22 2004-08-11 强 王 Method for producing blackboard and whiteboard made from enamel in super strength, and glaze of enamel
CN101168489A (en) * 2007-09-30 2008-04-30 成伟 Method for producing crack under glaze at low-temperature
CN101323539A (en) * 2007-06-15 2008-12-17 余敬镇 Method for making stone matrix colored glaze face brick
CN101367642A (en) * 2007-08-17 2009-02-18 郭春森 Double firing manufacturing method of under-glaze decoration ceramic

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Publication number Priority date Publication date Assignee Title
JP2003093197A (en) * 2001-09-26 2003-04-02 Showa Nishikawa Co Ltd Collapsible bed
CN1519213A (en) * 2003-01-22 2004-08-11 强 王 Method for producing blackboard and whiteboard made from enamel in super strength, and glaze of enamel
CN101323539A (en) * 2007-06-15 2008-12-17 余敬镇 Method for making stone matrix colored glaze face brick
CN101367642A (en) * 2007-08-17 2009-02-18 郭春森 Double firing manufacturing method of under-glaze decoration ceramic
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105541343A (en) * 2015-12-18 2016-05-04 蒙娜丽莎集团股份有限公司 Method for preparing inkjet-penetrated travertine polished tiles
CN105541343B (en) * 2015-12-18 2018-01-26 蒙娜丽莎集团股份有限公司 A kind of preparation method of ink-jet infiltration hole stone polished brick
CN106242527A (en) * 2016-08-09 2016-12-21 佛山欧神诺陶瓷股份有限公司 A kind of high emulation entire body throws glaze marble ceramic tile and production method thereof entirely
CN108972839A (en) * 2018-08-10 2018-12-11 佛山市东鹏陶瓷有限公司 A kind of preparation process and its ceramic tile of thin layer cloth solid Ceramic Tiles

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