CN108471738A - 粒状农药组合物 - Google Patents
粒状农药组合物 Download PDFInfo
- Publication number
- CN108471738A CN108471738A CN201680076610.7A CN201680076610A CN108471738A CN 108471738 A CN108471738 A CN 108471738A CN 201680076610 A CN201680076610 A CN 201680076610A CN 108471738 A CN108471738 A CN 108471738A
- Authority
- CN
- China
- Prior art keywords
- rice
- agrichemical composition
- granular agrichemical
- granular
- seed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000010899 nucleation Methods 0.000 claims abstract description 22
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
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Abstract
本发明提供减小药害发生的危险性、能省力的粒状农药组合物及其散布方法。上述粒状农药组合物是与稻的稻种混合并在播种时散布使用、且含有农药活性成分的粒状农药组合物,该粒状农药组合物的短径为稻种的宽度的50~320%、长径为稻种的长度的50~230%、比重为1~4g/cm3。另外,本发明提供粒状农药组合物的散布方法等,该方法具备:将上述粒状农药组合物和稻的稻种混合的混合工序;以及将上述混合工序中得到的混合物散布的散布工序。
Description
技术领域
本发明涉及粒状农药组合物,更详细而言,涉及减小药害发生的危险性、能省力的粒状农药组合物。
背景技术
在稻的栽培中需要防治病害、害虫、杂草等,另外,为了培育健康的苗、防止抽穗后的倒伏,需要降低植物高度等对生长进行调节。因此,通常使用杀菌剂、杀虫剂、除草剂、植物生长调节剂等农药。
农药的使用方法有各种,在稻的栽培中,主要采用:将农药组合物悬浮于水中而用喷雾器散布的方法、将粉状的农药组合物与送风机的风一起吹送至稻株的方法、向栽培有稻的水田的田面水散布粒状或液状的农药组合物的方法、使用育苗箱培育稻的苗后,在苗或育苗培土上散布农药组合物后移植至水田的方法等。另外,最近还实施了如下方法:在上述的向水田的田面水散布粒状农药组合物的方法中,使用在水面边使有效成分扩散至广范围边崩解的大粒的粒状农药组合物的方法(例如参照专利文献1);在使用了育苗箱的育苗中,与播种同时地向稻种周边的育苗培土中散布粒状农药组合物的方法(例如参照专利文献2)。
其中,对于使农药组合物悬浮于水中并用喷雾器散布的方法,为了向广阔的水田散布,必须准备大量的水,进而一边拉拽与水田外的药液罐(tank)连接的长软管一边遍布水田内地进行散布这样的作业负担大,因此近年来基本未实施。代替它而实施的是利用有人直升机、无人直升机的药液散布,但由于器材昂贵、操作需要高度的专业技术、对于向近邻的药液飞散的社会批判等理由,只不过在一部分地域中实施。
将粉状农药组合物与送风机的风一起向稻株吹送的方法、向栽培有稻的水田的田面水散布粒状或液状的农药组合物的方法出于省力而普及,但前者因散布作业者自身的农药暴露、向邻近的飞散而被回避,后者在散布时适当耗费管理田面水的时间和劳力。另外,均必须向广阔的水田全面均匀地散布,期望更省力。使用在水面边使有效成分扩散至广范围边崩解的大粒的粒状农药组合物的方法为该省力的一个方法,但是仅仅为了农药散布而去水田,不能省略边在各水田的周围散布边来回走动的劳力。
使用育苗箱培育稻的苗后、在苗或育苗培土上散布农药组合物后移植至水田的方法在不必仅仅为了农药散布而到水田的方面是省力的、进行了普及,但向苗密生的育苗箱均匀地散布农药组合物的作业并不那么容易,尤其是在极其繁忙的插秧时期,该作业变为大的负担。作为满足更省力化的要求的技术,开发了在与播种同时向稻种周边的育苗培土中散布粒状农药组合物的方法,但使得在稻种的周围存在高浓度的农药活性成分下进行发芽及苗的生长,药害发生的危险性高,该方法仅能够用于极其有限的一部分农药活性成分。另外,向育苗箱散布的方法当然不能用于在水田直接播种稻种的直播栽培。
此外,作为其它省力的农药处理法,还开发了使农药组合物覆盖/附着于稻的稻种的表面,并一次完成播种和农药散布的技术(例如参照专利文献3、4)。但是,使一定量的农药组合物附着于稻种的作业耗费时间和劳力,此外,在该方法中,也在稻种的周围存在高浓度的农药活性成分,药害发生的危险性高、仅仅能够用于极其有限的一部分农药活性成分。
现有技术文献
专利文献
专利文献1:日本特开2000-302602号公报
专利文献2:日本特开2003-321310号公报
专利文献3:日本特开平8-275620号公报
专利文献4:日本特开平10-33014号公报
发明内容
发明所要解决的问题
本发明是在上述状况下作出的,其目的在于,提供减小药害发生的危险性、能省力的粒状农药组合物及其散布方法。
解决问题的方法
为了达到上述目的,本发明人等进行了深入研究,结果发现,通过将具有与稻的稻种类似的特定大小及某特定比重的粒状农药组合物与稻的稻种混合并在播种时散布,无论农药活性成分的种类为哪一种,均能减小药害发生的危险性、另外不仅在利用育苗箱的育苗、在直播栽培中也能够使农药散布作业省力,从而完成了本发明。
即本发明如下。
(1)一种粒状农药组合物,其是与稻的稻种混合并在播种时散布使用、且含有农药活性成分的粒状农药组合物,该粒状农药组合物的短径为稻种的宽度的50~320%、长径为稻种的长度的50~230%、比重为1~4g/cm3。
(2)根据上述(1)所述的粒状农药组合物,其短径为2~8mm。
(3)根据上述(1)或(2)所述的粒状农药组合物,其用于水稻的直播栽培。
(4)根据上述(3)所述的粒状农药组合物,其中,上述直播栽培为湛水直播栽培或旱田直播栽培。
(5)根据上述(1)~(4)中任一项所述的粒状农药组合物,其含有具有防治病害的作用的成分作为上述农药活性成分。
(6)根据上述(1)~(5)中任一项所述的粒状农药组合物,其含有具有防治害虫的作用的成分作为上述农药活性成分。
(7)根据上述(1)~(6)中任一项所述的粒状农药组合物,其含有具有防治杂草的作用的成分作为上述农药活性成分。
(8)根据上述(1)~(7)中任一项所述的粒状农药组合物,其含有具有调节生长的作用的成分作为上述农药活性成分。
(9)一种粒状农药组合物的散布方法,该方法具备:将上述(1)~(8)中任一项所述的粒状农药组合物和稻的稻种混合的混合工序;以及将上述混合工序中得到的混合物散布的散布工序。
(10)根据上述(9)所述的粒状农药组合物的散布方法,其中,上述稻为水稻,在上述散布工序中,通过散布上述混合物来播种上述水稻的稻种。
(11)根据上述(9)或(10)所述的粒状农药组合物的散布方法,其中,在上述散布工序中,通过散布上述混合物来直播上述水稻的稻种。
(12)根据上述(9)~(11)中任一项所述的粒状农药组合物的散布方法,其中,在上述散布工序中,用动力散粒机散布上述混合物。
(13)根据上述(9)~(11)中任一项所述的粒状农药组合物的散布方法,其中,在上述散布工序中,用乘坐式水田管理机散布上述混合物。
(14)根据上述(9)~(11)中任一项所述的粒状农药组合物的散布方法,其中,在上述散布工序中,用飞机、有人直升机、或无人直升机散布上述混合物。
(15)权利要求(9)~(14)中任一项所述的粒状农药组合物的散布方法,其中,上述混合物中的上述粒状农药组合物的混合量相对于稻种1质量份为0.001~10质量份。
(16)一种稻的病害的防治方法,其包括下述工序:将上述(5)所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
(17)一种稻的害虫的防治方法,其包括下述工序:将上述(6)所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
(18)一种稻田的杂草的防治方法,其包括下述工序:将上述(7)所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
(19)一种稻的生长的调节方法,其包括下述工序:在稻的播种时,将上述(8)所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
发明的效果
根据本发明,能够提供减小药害发生的危险性、能省力的粒状的农药组合物及其散布方法。
具体实施方式
以下,对本发明的粒状农药组合物、散布方法及防治方法详细地进行说明。
本发明的粒状农药组合物是与稻的稻种混合并在播种时散布使用、且含有农药活性成分的粒状农药组合物,该粒状农药组合物的短径为稻种的宽度的50~320%、长径为稻种的长度的50~230%、比重为1~4g/cm3。
此处,粒状农药组合物的长径是指粒子的最长的长轴方向的长度,短径是指在与上述长径正交的方向(以下称为“短轴方向”)的长度中最长的长度。在球体、立方体那样无法区别长轴方向与短轴方向的形状的情况下,是指任意轴向的粒子的长度,该情况下,长径和短径为同一长度。另外,本发明中的稻可以为旱稻,也可以为水稻,此外,还可以为通过基因重组等技术进行了转化的稻。稻的稻种还包括催芽稻种、用铁粉、过氧化钙、钼化合物那样的种子包衣剂进行了包衣的稻种。
重要的是将本发明的粒状农药组合物的粒径及比重设为上述范围。即,如果以混合并播种的稻种的尺寸为基准,将稻种的宽度设为100%时,本发明的粒状农药组合物的粒子的短径为稻种的宽度的50~320%。上述短径相对于稻种的宽度优选50~240%、进一步优选80~200%的范围,由于能够进一步防止与稻种的分级,因此对与稻种均匀地进行混合处理是有利的。另外,将稻种的长度设为100%时,本发明的粒状农药组合物的粒子的长径为稻种的长度的50~230%,优选为60~160%、进一步优选为60~130%。
另外,本发明的粒状农药组合物的粒子的比重设为1~4g/cm3、优选1~3g/cm3的范围,更优选根据使用的稻种的种类、有无使用种子包衣剂来适宜选择比重,与未包衣的稻种、过氧化钙粉粒剂包衣稻谷混合使用的情况下,使用1~2g/cm3为宜,与铁包衣稻谷混合使用的情况下,使用2~3g/cm3为宜。另外,将混合并播种的稻种的比重设为100%而作为基准时,本发明的粒状农药组合物的粒子的比重使用60~350%、优选70~260%、进一步优选80~150%者为宜。
根据本发明,通过将粒状农药组合物的粒径及比重调整至上述范围,从而在与稻种混合时很少分级,然后,直到播种作业为止的期间也很少分级。另外,能够使稻栽培中的农药散布作业与稻种的播种同时进行,并且不需要向育苗箱散布农药、走到水田来散布农药这样的时间和劳力,因此极其省力。另外,由于本发明的粒状农药组合物的散布方法也仅仅是与稻种混合并散布,因此能够在与仅进行播种的时间和劳力相比基本没有变化下实施。
此外,在本发明中,稻种与粒状农药组合物是分开的,因此在例如直播栽培中的播种那样以低密度播种的情况下,稻种与粒状农药组合物分离并落下,与农药活性成分的接触带来的药害所产生的危险性低。在育苗箱中进行播种的情况下也是,通过对本发明的粒状农药组合物利用使农药活性成分的溶出缓慢的公知技术,即使直接在稻种与本发明的粒状农药组合物接触的状态下发芽,也能够降低产生药害的危险性。这样一来,对于以往因产生药害的危险性而不能在育苗箱中播种的同时散布、不能对稻种进行覆盖/附着处理的农药活性成分,本发明中也能够在不产生药害下实施,因此是极其有益的技术。
对于本发明的粒状农药组合物,根据需要在农药活性成分中适宜加入固体载体、表面活性剂、其它辅助剂并制成粒状制剂即可。本发明的粒状农药组合物的形状只要为粒状,就没有特别限定,例如可以为球形、大致球状形、橄榄球状的椭圆球体形、蛋形、茧形、圆柱状形、具有带圆弧的两端的圆柱状形、围棋子状椭圆球体形、医药经口给药用的明胶胶囊状形、草袋状形、立方体、或长方体中任意形状,也可以具有多种形状,更优选球形、椭圆球体形、蛋形、或长径与短径的比率接近稻种的长度与宽度的比率的圆柱状形。
本发明的粒状农药组合物中可以使用的农药活性成分可以举出具有防治病害的作用的成分、具有防治害虫的作用的成分、具有防治杂草的作用的成分、具有调节对象作物的生长的作用的成分等。这些农药活性成分只要是通常用作农药的成分,就没有特别限定,可以单独使用或混合使用2种以上。上述农药有杀菌剂、杀虫剂、除草剂、植物生长调节剂等,但本发明的粒状农药组合物不限定于这些中的任一者。
作为本发明的粒状农药组合物中可以使用的公知的杀菌剂成分的例子,可以举出阿扎康唑(azaconazole)、噻二唑素-S-甲基(acibenzolar-S-methyl)、腈嘧菌酯(azoxystrobin)、敌菌灵(anilazine)、吲唑磺菌胺(amisulbrom)、唑嘧菌胺(ametoctradin)、艾敌吗啉(aldimorph)、异噻菌胺(isotianil)、吡唑萘菌胺(isopyrazam)、异丙噻菌胺(isofetamid)、稻瘟灵(isoprothiolane)、环戊唑醇(ipconazole)、异菌脲(iprodione)、异丙菌胺(iprovalicarb)、异稻瘟净(iprobenfos)、抑霉唑(imazalil)、双胍三辛烷基苯磺酸盐(iminoctadine-tris-albesilate)、双胍辛胺三乙酸盐(iminoctadine-triacetate)、亚胺唑(imibenconazole)、敌瘟磷(edifenphos)、乙环唑(etaconazole)、噻唑菌胺(ethaboxam)、乙嘧酚(ethirimol)、乙氧基喹(ethoxyquin)、氯唑灵(etridiazole)、烯肟菌酯(enestroburin)、烯肟菌酯(enoxastrobin)、氟环唑(epoxiconazole)、有机油(organic oils)、恶霜灵(oxadixyl)、曙嗪唑(oxazinylazole)、氟噻唑吡乙酮(oxathiapiprolin)、氧化萎锈灵(oxycarboxin)、喹啉铜(oxine-copper)、土霉素(oxytetracycline)、咪唑富马酸盐(oxpoconazole-fumarate)、奥索利酸(oxolinic acid)、辛酸铜(copperdioctanoate)、辛噻酮(octhilinone)、甲呋酰胺(ofurace)、肟醚菌胺(orysastrobin)、邻苯基苯酚(o-phenylphenol)、春雷霉素(kasugamycin)、敌菌丹(captafol)、氯环丙酰胺(carpropamid)、多菌灵(carbendazim)、萎锈灵(carboxin)、香芹酮(carvone)、喹氧灵(quinoxyfen)、灭螨猛(chinomethionat)、克菌丹(captan)、唑喹菌酮(quinconazole)、五氯硝基苯(quintozene)、双辛胍胺(guazatine)、硫杂灵(cufraneb)、丁香菌酯(coumoxystrobin)、苯氧菊酯(kresoxim-methyl)、克拉康(clozylacon)、乙菌利(chlozolinate)、百菌清(chlorothalonil)、氯苯甲醚(chloroneb)、氰霜唑(cyazofamid)、乙霉威(diethofencarb)、双氯氰菌胺(diclocymet)、抑菌灵(dichlofluanid)、哒菌酮(diclomezine)、氯硝胺(dicloran)、双氯酚(dichlorophen)、二氰蒽醌(dithianon)、烯唑醇(diniconazole)、烯唑醇(diniconazole-M)、代森锌(zineb)、敌螨普(dinocap)、dipymetitrone、二苯胺(diphenylamine)、苯醚甲环唑(difenoconazole)、环氟菌胺(cyflufenamid)、二氟林(diflumetorim)、环丙唑醇(cyproconazole)、嘧菌环胺(cyprodinil)、硅氟唑(simeconazole)、二甲嘧酚(dimethirimol)、二甲基二硫醚(dimethyl disulfide)、烯酰吗啉(dimethomorph)、霜脲氰(cymoxanil)、醚菌胺(dimoxystrobin)、福美锌(ziram)、硫硅菌胺(silthiofam)、链霉素(streptomycin)、螺环菌胺(spiroxamine)、环苯吡菌胺(sedaxane)、苯酰菌胺(zoxamide)、棉隆(dazomet)、噻酰菌胺(tiadinil)、噻苯唑(thiabendazole)、福美双(thiram)、托布津(thiophanate)、甲基托布津(thiophanate-methyl)、噻呋酰胺(thifluzamide)、四氯硝基苯(tecnazene)、叶枯酞(tecloftalam)、氟醚唑(tetraconazole)、咪菌威(debacarb)、戊唑醇(tebuconazole)、异丁乙氧喹啉(tebufloquin)、特比萘芬(terbinafine)、多果定(dodine)、十二环吗啉(dodemorph)、三唑醇(triadimenol)、三唑酮(triadimefon)、咪唑嗪(triazoxide)、水杨菌胺(trichlamide)、氯啶菌酯(triclopyricarb)、三环唑(tricyclazole)、灭菌唑(triticonazole)、十三吗啉(tridemorph)、氟菌唑(triflumizole)、肟菌酯(trifloxystrobin)、嗪胺灵(triforine)、对甲抑菌灵(tolylfluanid)、甲基立枯磷(tolclofos-methyl)、甲磺菌胺(tolnifanide)、甲苯氟磺胺(tolprocarb)、代森钠(nabam)、那他霉素(natamycin)、萘替芳(naftifine)、三氯甲基吡啶(nitrapyrin)、酞菌酯(nitrothal-isopropyl)、氟苯嘧啶醇(nuarimol)、壬基酚磺酸铜(copper nonyl phenol sulphonate)、枯草芽胞杆菌(Bacillus subtilis)(strain:QST713)、有效霉素(validamycin)、缬菌胺(valifenalate)、picarbutrazox、联苯吡菌胺(bixafen)、啶氧菌酯(picoxystrobin)、氟唑菌酰羟胺(pydiflumetofen)、联苯三唑醇(bitertanol)、乐杀螨(binapacryl)、联苯(biphenyl)、哌丙灵(piperalin)、恶霉灵(hymexazol)、唑菌酯(pyraoxystrobin)、吡唑醚菌酯(pyraclostrobin)、pyraziflumid、定菌磷(pyrazophos)、唑胺菌酯(pyrametostrobin)、派瑞芬酮(pyriofenone)、氯啶菌酯(pyrisoxazole)、比芬诺(pyrifenox)、稗草畏(pyributicarb)、吡菌苯威(pyribencarb)、嘧霉胺(pyrimethanil)、咯喹酮(pyroquilon)、乙烯菌核利(vinclozolin)、福美铁(ferbam)、唑酮(famoxadone)、叶枯净(phenazine oxide)、咪唑菌酮(fenamidone)、烯肟菌胺(fenaminstrobin)、氯苯嘧啶醇(fenarimol)、氰菌胺(fenoxanil)、嘧菌腙(ferimzone)、拌种咯(fenpiclonil)、胺苯吡菌酮(fenpyrazamine)、腈苯唑(fenbuconazole)、甲呋酰胺(fenfuram)、苯锈啶(fenpropidin)、丁苯吗啉(fenpropimorph)、环酰菌胺(fenhexamid)、灭菌丹(folpet)、苯酞(phthalide)、乙嘧酚磺酸酯(bupirimate)、麦穗宁(fuberidazole)、稻瘟净(blasticidin-S)、福拉比(furametpyr)、呋霜灵(furalaxyl)、呋喃甲酸(furancarboxylic acid)、氟啶胺(fluazinam)、3-(二氟甲基)-N-(7-氟-2,3-二氢-1,1,3-三甲基-1H-茚-4-基)-1-甲基-1H-吡唑-4-甲酰胺(fluindapyr)、氟嘧菌酯(fluoxastrobin)、氟吡菌胺(fluopicolide)、氟吡菌酰胺(fluopyram)、氟酰亚胺(fluoroimide)、氟唑菌酰胺(fluxapyroxad)、氟喹唑(fluquinconazole)、呋菌唑(furconazole)、呋醚唑(furconazole-cis)、咯菌腈(fludioxonil)、氟硅唑(flusilazole)、磺菌胺(flusulfamide)、氟噻唑菌腈(flutianil)、氟酰胺(flutolanil)、粉唑醇(flutriafol)、氟菌螨酯(flufenoxystrobin)、氟联苯菌(flumetover)、氟吗啉(flumorph)、丙氧喹啉(proquinazid)、咪鲜胺(prochloraz)、腐霉利(procymidone)、胺丙威(prothiocarb)、丙硫菌唑(prothioconazole)、溴硝丙二醇(bronopol)、霜霉威盐酸盐(propamocarb-hydrochloride)、丙环唑(propiconazole)、丙森锌(propineb)、噻菌灵(probenazole)、糠菌唑(bromuconazole)、flometoquin、己唑醇(hexaconazole)、苯霜灵(benalaxyl)、精苯霜灵(benalaxyl-M)、麦锈灵(benodanil)、苯菌灵(benomyl)、稻瘟酯(pefurazoate)、戊菌唑(penconazole)、戊菌隆(pencycuron)、苯并烯氟菌唑(benzovindiflupyr)、苯噻硫氰(benthiazole)、苯噻菌胺(benthiavalicarb-isopropyl)、吡噻菌胺(penthiopyrad)、氟唑菌苯胺(penflufen)、啶酰菌胺(boscalid)、福赛得(fosetyl)(铝(alminium)、钙(calcium)、钠(sodium))、多抗霉素(polyoxin)、福美锌(polycarbamate)、波尔多液(Bordeaux mixture)、代森锰锌(mancozeb)、双炔酰菌胺(mandipropamid)、mandestrobin、代森锰(maneb)、腈菌唑(myclobutanil)、矿物油(mineral oils)、灭粉霉素(mildiomycin)、磺菌威(methasulfocarb)、威百亩(metam)、甲霜灵(metalaxyl)、精甲霜灵(metalaxyl-M)、代森联(metiram)、叶菌唑(metconazole)、苯氧菌胺(metominostrobin)、苯菌酮(metrafenone)、嘧菌胺(mepanipyrim)、消螨多(meptyldinocap)、灭锈胺(mepronil)、碘代丙炔基丁基甲胺酸酯(iodocarb)、昆布多糖(laminarin)、亚磷酸及盐(phosphorous acid and salts)、碱式氯化铜(copperoxychloride)、银(silver)、氧化亚铜(cuprous oxide)、氢氧化铜(copper hydroxide)、碳酸氢钾(potassium bicarbonate)、碳酸氢钠(sodium bicarbonate)、硫(sulfur)、羟喹啉硫酸盐(oxyquinoline sulfate)、硫酸铜(copper sulfate)、(3,4-二氯异噻唑-5-基)甲基4-(tert-丁基)苯甲酸酯(化学名称、CAS注册号:1231214-23-5)、3-((3,4-二氯异噻唑-5-基)甲氧基)苯并[d]异噻唑-1、1-二氧化物(化学名称、CAS注册号:957144-77-3)、BAF-045(code number)、BAG-010(code number)、UK-2A(code number)、DBEDC(十二烷基苯磺酸双乙烯二胺铜络盐[II])、MIF-1002(code number)、TPTA(三苯基乙酸锡)、TPTC(三苯基氯化锡)、TPTH(三苯基氢氧化锡)、非病原性胡萝卜软腐欧文氏等。
作为本发明的粒状农药组合物中可以使用的公知的杀虫剂成分的例子,可以举出氟丙菊酯(acrinathrin)、印楝素(azadirachtin)、甲基吡啶磷(azamethiphos)、乙基谷硫磷(azinphos-ethyl)、保棉磷(azinphos-methyl)、灭螨醌(acequinocyl)、啶虫脒(acetamiprid)、乙酰虫腈(acetoprole)、乙酰甲胺磷(acephate)、三唑锡(azocyclotin)、阿巴克丁(abamectin)、afidopyropen、阿福拉纳(afoxolaner)、磺胺螨酯(amidoflumet)、阿米曲士(amitraz)、棉铃威(alanycarb)、涕灭威(aldicarb)、涕灭砜威(aldoxycarb)、丙烯除虫菊(allethrin)[包含d-cis-trans-体、d-trans-体]、异丙三唑硫磷(isazophos)、异酰胺磷(isamidofos)、水胺硫磷(isocarbophos)、异唑磷(isoxathion)、甲基异柳磷(isofenphos-methyl)、异丙威(isoprocarb)、伊维菌素(ivermectin)、氰咪唑硫磷(imicyafos)、吡虫啉(imidacloprid)、炔咪菊酯(imiprothrin)、茚虫威(indoxacarb)、高效氰戊菊酯(esfenvalerate)、乙硫苯威(ethiofencarb)、乙硫磷(ethion)、乙虫腈(ethiprole)、二溴乙烷(ethylene dibromide)、乙螨唑(etoxazole)、依芬普司(etofenprox)、灭线磷(ethoprophos)、乙嘧硫磷(etrimfos)、因灭汀(emamectinbenzoate)、硫丹(endosulfan)、右旋烯炔菊酯(empenthrin)、杀线威(oxamyl)、砜吸磷(oxydemeton-methyl)、亚异砜磷(oxydeprofos)、氧乐果(omethoate)、硫线磷(cadusafos)、kappa-tefluthrin、kappa-bifenthrin、水黄皮素(karanjin)、杀螟丹(cartap)、胺甲萘(carbaryl)、丁硫克百威(carbosulfan)、虫螨威(carbofuran)、γ-BHC(gamma-BHC)、灭杀威(xylylcarb)、喹硫磷(quinalphos)、烯虫炔酯(kinoprene)、灭螨猛(chinomethionat)、蝇毒磷(coumaphos)、冰晶石(cryolite)、噻虫胺(clothianidin)、四螨嗪(clofentezine)、环虫酰肼(chromafenozide)、氯虫苯甲酰胺(chlorantraniliprole)、氯氧磷(chlorethoxyfos)、氯丹(chlordane)、氯化苦(chloropicrin)、毒死蜱(chlorpyrifos)、甲基毒死蜱(chlorpyrifos-methyl)、溴虫腈(chlorfenapyr)、毒虫畏(chlorfenvinphos)、氟啶脲(chlorfluazuron)、氯甲磷(chlormephos)、氯丙炔菊酯(chloroprallethrin)、杀螟腈(cyanophos)、丁醚脲(diafenthiuron)、除线特(diamidafos)、氰虫酰胺(cyantraniliprole)、除螨灵(dienochlor)、腈吡螨酯(cyenopyrafen)、蔬果磷(dioxabenzofos)、苯虫醚(diofenolan)、环溴虫酰胺(cyclaniliprole)、百治磷(dicrotophos)、除线磷(dichlofenthion)、乙氰菊酯(cycloprothrin)、敌敌畏(dichlorvos)、1,3-二氯丙烯(1,3-dichloropropene)、dichloromezotiaz、开乐散(dicofol)、地昔尼尔(dicyclanil)、乙拌磷(disulfoton)、呋虫胺(dinotefuran)、消螨通(dinobuton)、氯氟氰虫酰胺(cyhalodiamide)、三氟氯氰菊酯(cyhalothrin)[包含gamma-体、lambda-体]、苯醚氰菊酯(cyphenothrin)[包含(1R)-trans-体]、氟氯氰菊酯(cyfluthrin)[包含beta-体]、除虫脲(diflubenzuron)、丁氟螨酯(cyflumetofen)、氟螨嗪(diflovidazin)、杀螨锡(cyhexatin)、氯氰菊酯(cypermethrin)[包含alpha-体、beta-体、theta-体、zeta-体]、甲基毒虫畏(dimethylvinphos)、四氟甲醚菊酯(dimefluthrin)、乐果(dimethoate)、硅白灵(silafluofen)、环丙马秦(cyromazine)、乙基多杀菌素(spinetoram)、赐诺杀(spinosad)、螺螨酯(spirodiclofen)、螺虫乙酯(spirotetramat)、螺甲螨酯(spiromesifen)、sulcofuron-sodium、氟虫胺(sulfluramid)、氟啶虫胺腈(sulfoxaflor)、治螟磷(sulfotep)、二嗪农(diazinon)、噻虫啉(thiacloprid)、噻虫嗪(thiamethoxam)、tioxazafen、硫双威(thiodicarb)、杀虫环(thiocyclam)、杀虫双(thiosultap)、硫磷嗪(thionazin)、久效威(thiofanox)、甲基乙拌磷(thiometon)、杀虫畏(tetrachlorvinphos)、三氯杀螨砜(tetradifon)、氟氰虫酰胺(tetraniliprole)、四氟醚菊酯(tetramethylfluthrin)、胺菊酯(tetramethrin)、丁基嘧啶磷(tebupirimfos)、虫酰肼(tebufenozide)、吡螨胺(tebufenpyrad)、七氟菊酯(tefluthrin)、伏虫隆(teflubenzuron)、甲基内吸磷(demeton-S-methyl)、双硫磷(temephos)、溴氰菊酯(deltamethrin)、特丁磷(terbufos)、四溴菊酯(tralomethrin)、四氟苯菊酯(transfluthrin)、唑蚜威(triazamate)、三唑磷(triazophos)、三氯磷酸酯(trichlorfon)、杀铃脲(triflumuron)、三氟苯嘧啶(triflumezopyrim)、混灭威(trimethacarb)、唑虫酰胺(tolfenpyrad)、二溴磷(naled)、烯啶虫胺(nitenpyram)、双苯氟脲(novaluron)、多氟脲(noviflumuron)、蜡蚧轮枝菌(Verticillium lecanii)、烯虫乙酯(hydroprene)、穿刺巴斯德氏柄菌胞子(Pasteuriapenetrans)、蚜灭磷(vamidothion)、对硫磷(parathion)、对硫磷甲酯(parathion-methyl)、溴氟醚菊酯(halfenprox)、氯虫酰肼(halofenozide)、生物烯丙菊酯(bioallethrin)、2-环戊烯基生物烯丙菊酯(bioallethrin S-cyclopentenyl)、除虫菊酯(bioresmethrin)、双三氟虫脲(bistrifluron)、氟蚁腙(hydramethylnon)、联苯肼酯(bifenazate)、联苯菊酯(bifenthrin)、pyflubumide、胡椒基丁醚(piperonyl butoxide)、吡蚜酮(pymetrozine)、吡唑硫磷(pyraclofos)、吡嗪氟虫腈(pyrafluprole)、哒嗪硫磷(pyridaphenthion)、哒螨灵(pyridaben)、啶虫丙醚(pyridalyl)、吡氟喹虫唑(pyrifluquinazon)、吡唑虫啶(pyriprole)、蚊蝇醚(pyriproxyfen)、抗蚜威(pirimicarb)、嘧螨醚(pyrimidifen)、嘧螨胺(pyriminostrobin)、甲基嘧啶磷(pirimiphos-methyl)、除虫菊内酯(pyrethrine)、氨磺磷(famphur)、氟虫清(fipronil)、喹螨醚(fenazaquin)、苯线磷(fenamiphos)、杀螟松(fenitrothion)、苯氧威(fenoxycarb)、苯硫威(fenothiocarb)、酚丁灭宁(phenothrin)[包含(1R)-trans-体]、仲丁威(fenobucarb)、倍硫磷(fenthion)、稻丰散(phenthoate)、氰戊菊酯(fenvalerate)、唑螨酯(fenpyroximate)、苯丁锡(fenbutatin oxide)、甲氰菊酯(fenpropathrin)、地虫膦(fonofos)、硫酰氟(sulfurylfluoride)、丁酮威(butocarboxim)、丁酮砜威(butoxycarboxim)、噻嗪酮(buprofezin)、呋线威(furathiocarb)、丙炔菊酯(prallethrin)、嘧螨酯(fluacrypyrim)、三氟咪啶酰胺(fluazaindolizine)、氟佐隆(fluazuron)、联氟砜(fluensulfone)、氟乙酸钠(sodiumfluoroacetate)、fluxametamide、氟环脲(flucycloxuron)、氟氰戊菊酯(flucythrinate)、磺菌胺(flusulfamide)、氟胺氰菊酯(fluvalinate)[包含tau-体]、氟吡呋喃酮(flupyradifurone)、吡氟硫磷(flupyrazofos)、丁虫腈(flufiprole)、嘧虫胺(flufenerim)、氟菌螨酯(flufenoxystrobin)、氟虫脲(flufenoxuron)、fluhexafon、氟虫双酰胺(flubendiamide)、氟氯苯菊酯(flumethrin)、氟雷拉纳(fluralaner)、丙硫磷(prothiofos)、protrifenbute、氟啶虫酰胺(flonicamid)、丙虫磷(propaphos)、快螨特(propargite)、丙溴磷(profenofos)、broflanilide、丙氟菊酯(profluthrin)、胺丙畏(propetamphos)、残杀威(propoxur)、flometoquin、溴螨酯(bromopropylate)、噻满酮(hexythiazox)、氟铃脲(hexaflumuron)、细脚拟青霉(Paecilomyces tenuipes)、蝉拟青霉菌(Paecilomyces fumosoroceus)、heptafluthrin、蚜螨磷(heptenophos)、氯菊酯(permethrin)、benclothiaz、杀虫磺(bensultap)、苯螨特(benzoximate)、恶虫威(bendiocarb)、丙硫克百威(benfuracarb)、纤细白僵菌(Beauveria tenella)、巴西安白僵菌(Beauveriabassiana)、布氏白僵菌(Beauveria brongniartii)、辛硫磷(phoxim)、伏杀磷(phosalone)、噻唑磷(fosthiazate)、噻线膦(fosthietan)、磷胺(phosphamidon)、亚胺硫磷(phosmet)、杀螨菌素(polynactins)、灭蚜磷(formetanate)、甲拌磷(phorate)、马拉硫磷(malathion)、密灭汀(milbemectin)、灭蚜磷(mecarbam)、甲亚砜磷(mesulfenfos)、灭多威(methomyl)、氰氟虫腙(metaflumizone)、甲胺磷(methamidophos)、威百亩(metham)、灭虫威(methiocarb)、杀扑磷(methidathion)、异硫氰酸甲酯(methyl isothiocyanate)、溴甲烷(methyl bromide)、甲氧氯(methoxychlor)、灭芬诺(methoxyfenozide)、甲醚菊酯(methothrin)、甲氧苄氟菊酯(metofluthrin)、ε-甲氧苄氟菊酯(epsilon-metofluthrin)、蒙五一五(methoprene)、速灭威(metolcarb)、速灭磷(mevinphos)、氯氟醚菊酯(meperfluthrin)、两栖单顶孢菌(Monacrosporium phymatophagum)、久效磷(monocrotophos)、甲氧苄氟菊酯(momfluorothrin)、epsilon-momfluorothrin、诱杀酯A(litlure-A)、诱杀酯B(litlure-B)、磷化铝(aluminium phosphide)、磷化锌(zincphosphide)、磷化氢(phosphine)、虱螨脲(lufenuron)、红圆蚧引诱剂(rescalure)、灭虫菊(resmethrin)、雷皮菌素(lepimectin)、鱼藤酮(rotenone)、苯丁锡(fenbutatin oxide)、氰化钙(calcium cyanide)、硫酸烟碱(nicotinesulfate)、(Z)-11-十四烯基=乙酸酯、(Z)-11-十六烯醛、(Z)-11-十六烯基=乙酸酯、(Z)-9,12-十四碳二烯基=乙酸酯、(Z)-9-十四碳烯-1-醇、(Z,E)-9,11-十四碳二烯基=乙酸酯、(Z,E)-9,12-十四碳二烯基=乙酸酯、日本甲虫芽孢杆菌(Bacillus popilliae)、枯草芽胞杆菌(Bacillus subtillis)、球形芽孢杆菌(Bacillus sphaericus)、苏云金芽孢杆菌鲇泽亚种(Bacillus thuringiensissubsp.Aizawai)、苏云金杆菌以色列亚种(Bacillus thuringiensissubsp.Israelensis)、苏云金芽孢杆菌库斯塔克亚种(Bacillus thuringiensissubsp.Kurstaki)、苏云金芽胞杆菌拟步行亚种(Bacillus thuringiensissubsp.Tenebrionis)、Bt蛋白质(Cry1Ab、Cry1Ac、Cry1Fa、Cry2Ab、mCry3A、Cry3Ab、Cry3Bb、Cry34/35Ab1)、CL900167(code number)、DCIP(双-(2-氯-1-甲基乙基)醚)、DDT(1,1,1-三氯-2,2-双(4-氯苯基)乙烷)、DEP(二甲基-2,2,2-三氯-1-羟基乙基膦酸酯)、DNOC(4,6-二硝基-o-甲酚)、DSP(O,O-二乙基-O-[4-(二甲基氨基磺酰基)苯基]-硫代磷酸酯)、EPN(O-乙基-O-4-(硝基苯基)苯硫磷酯、核多角体病病毒包埋体、NA-85(code number)、NA-89(codenumber)、NC-515(code number)、RU15525(code number)、ZDI-2501(code number)、XMC、Z-13-二十碳-10-酮、ZXI8901(code number)、ME5382(code number)等。
作为本发明的粒状农药组合物中可以使用的公知的除草剂成分的例子,可以举出碘苯腈(ioxynil)、苯草醚(aclonifen)、丙烯醛(acrolein)、唑啶草酮(azafenidin)、三氟羧草醚(acifluorfen)(包含与钠等的盐)、四唑嘧磺隆(azimsulfuron)、磺草灵(asulam)、乙草胺(acetochlor)、阿特拉嗪(atrazine)、莎稗磷(anilofos)、氨唑草酮(amicarbazone)、酰嘧磺隆(amidosulfuron)、杀草强(amitrole)、氯丙嘧啶酸(aminocyclopyrachlor)、氯氨吡啶酸(aminopyralid)、甲胺草磷(amiprofos-methyl)、莠灭净(ametryn)、甲草胺(alachlor)、禾草灭(alloxydim)、异隆(isouron)、异氯草酮(isoxachlortole)、异唑草酮(isoxaflutole)、异酰草胺(isoxaben)、异丙隆(isoproturon)、三唑酰草胺(ipfencarbazone)、灭草喹(imazaquin)、甲基咪草烟(imazapic)(包含与胺等的盐)、灭草烟(imazapyr)(包含异丙胺等盐)、咪草酯(imazamethabenz-methyl)、咪草啶酸(imazamox)、咪草烟(imazethapyr)、唑吡嘧磺隆(imazosulfuron)、三嗪茚草胺(indaziflam)、茚草酮(indanofan)、草止津(eglinazine-ethyl)、禾草畏(esprocarb)、胺苯磺隆(ethametsulfuron-methyl)、丁氟消草(ethalfluralin)、磺噻隆(ethidimuron)、乙氧嘧磺隆(ethoxysulfuron)、氟乳醚乙酯(ethoxyfen-ethyl)、乙氧呋草黄(ethofumesate)、乙氧苯草胺(etobenzanid)、茵多酸-二钠(endothal-disodium)、恶草灵(oxadiazon)、丙炔草酮(oxadiargyl)、嗪草酮(oxaziclomefone)、环氧嘧磺隆(oxasulfuron)、乙氧氟草醚(oxyfluorfen)、黄草消(oryzalin)、嘧苯胺磺隆(orthosulfamuron)、坪草丹(orbencarb)、唑草胺(cafenstrole)、唑草酮酯(carfentrazone-ethyl)、卡灵草(karbutilate)、长杀草(carbetamide)、喹禾灵乙酯(quizalofop-ethyl)、精喹禾灵乙酯(quizalofop-P-ethyl)、喹禾糠酯(quizalofop-P-tefuryl)、灭藻醌(quinoclamine)、二氯喹啉酸(quinclorac)、氯甲喹啉酸(quinmerac)、苄草隆(cumyluron)、氯酰草膦(clacyfos)、甘草膦(glyphosate)(包含钠、钾、铵、胺、丙胺、异丙胺、二甲胺或三甲基硫等的盐)、草铵膦(glufosinate)(包含胺或钠等的盐)、精草铵膦-钠(glufosinate-P-sodium)、烯草酮(clethodim)、炔草酯(clodinafop-propargyl)、二氯吡啶酸(clopyralid)、异草酮(clomazone)、甲氧除草醚(chlomethoxyfen)、氯甲酰草胺(clomeprop)、氯酯磺草胺(cloransulam-methyl)、草灭平(chloramben)、氯草敏(chloridazon)、氯嘧磺隆(chlorimuron-ethyl)、氯磺隆(chlorsulfuron)、氯酞酸甲酯(chlorthal-dimethyl)、赛草青(chlorthiamid)、氯酞亚胺(chlorphthalim)、整形素(chlorflurenol-methyl)、氯普芬(chlorpropham)、氯溴隆(chlorbromuron)、枯草隆(chloroxuron)、绿麦隆(chlorotoluron)、ketospiradox、苯嘧磺草胺(saflufenacil)、氰草津(cyanazine)、氰胺(cyanamide)、敌草隆(diuron)、乙酰甲草胺(diethatyl-ethyl)、麦草畏(dicamba)(包含胺、二乙胺、异丙胺、二甘醇胺、钠或锂等的盐)、草灭特(cycloate)、噻草酮(cycloxydim)、双氯磺草胺(diclosulam)、环胺磺隆(cyclosulfamuron)、cyclopyrimorate、敌草腈(dichlobenil)、精禾草灵(diclofop-P-methyl)、禾草灵(diclofop-methyl)、2,4-滴丙酸(dichlorprop)、精2,4-滴丙酸(dichlorprop-P)、敌草快(diquat)、氟硫草定(dithiopyr)、环草隆(siduron)、敌乐胺(dinitramine)、吲哚酮草酯(cinidon-ethyl)、醚磺隆(cinosulfuron)、特乐酚(dinoterb)、氰氟草酯(cyhalofop-butyl)、草乃敌(diphenamid)、野燕枯(difenzoquat)、吡氟酰草胺(diflufenican)、二氟吡隆(diflufenzopyr)、西玛津(simazine)、二甲草胺(dimethachlor)、异戊乙净(dimethametryn)、二甲吩草胺(dimethenamid)、精二甲吩草胺(dimethenamid-P)、西草净(simetryn)、哌草丹(dimepiperate)、唑隆(dimefuron)、环庚草醚(cinmethylin)、灭草灵(swep)、磺草酮(sulcotrione)、甲磺草胺(sulfentrazone)、磺酰磺隆(sulfosulfuron)、甲嘧磺隆(sulfometuron-methyl)、烯禾啶(sethoxydim)、特草定(terbacil)、杀草隆(daimuron)、茅草枯(dalapon)、噻唑烟酸(thiazopyr)、tiafenacil、噻酮磺隆(thiencarbazone)(包含钠盐、甲酯等)、仲草丹(tiocarbazil)、禾草丹(thiobencarb)、噻二唑草胺(thidiazimin)、噻吩磺隆甲酯(thifensulfuron-methyl)、甜菜安(desmedipham)、敌草净(desmetryne)、噻吩草胺(thenylchlor)、牧草胺(tebutam)、丁噻隆(tebuthiuron)、吡喃草酮(tepraloxydim)、特糠酯酮(tefuryltrione)、环磺酮(tembotrione)、特丁津(terbuthylazine)、去草净(terbutryn)、甲氧去草净(terbumeton)、苯吡唑草酮(topramezone)、脱莠定(tralkoxydim)、三嗪氟草胺(triaziflam)、醚苯磺隆(triasulfuron)、氟酮磺草胺(triafamone)、野麦畏(tri-allate)、草达津(trietazine)、定草酯(triclopyr)、三氯吡氧乙酸丁氧基乙酯(triclopyr-butotyl)、三氟甲磺隆(tritosulfuron)、三氟草嗪(trifludimoxazin)、氟胺磺隆甲酯(triflusulfuron-methyl)、氟乐灵(trifluralin)、三氟啶磺隆钠盐(trifloxysulfuron-sodium)、苯磺隆(tribenuron-methyl)、tolpyralate、抑草生(naptalam)(包含与钠等的盐)、萘丙胺(naproanilide)、敌草胺(napropamide)、敌草胺-M(napropamide-M)、烟嘧磺隆(nicosulfuron)、草不隆(neburon)、达草灭(norflurazon)、灭草猛(vernolate)、氟氯吡啶苄酯(halauxifen-benzyl)、百草枯(paraquat)、氟氯吡啶酯(halauxifen-methyl)、氟吡禾灵(haloxyfop)、精氟吡禾灵(haloxyfop-P)、氟吡乙禾灵(haloxyfop-etotyl)、氯吡嘧磺隆(halosulfuron-methyl)、毒莠定(picloram)、氟吡酰草胺(picolinafen)、双环吡喃酮(bicyclopyrone)、双草醚钠盐(bispyribac-sodium)、唑啉草酯(pinoxaden)、甲羧除草醚(bifenox)、哌草磷(piperophos)、双唑草腈(pyraclonil)、磺酰草吡唑(pyrasulfotole)、苄草唑(pyrazoxyfen)、吡嘧磺隆乙酯(pyrazosulfuron-ethyl)、吡唑特(pyrazolynate)、双丙氨膦(bilanafos)、吡草醚乙酯(pyraflufen-ethyl)、氯苯哒醇(pyridafol)、嘧草硫醚钠盐(pyrithiobac-sodium)、哒草特(pyridate)、环酯草醚(pyriftalid)、稗草畏(pyributicarb)、嘧啶肟草醚(pyribenzoxim)、嘧磺草胺(pyrimisulfan)、肟啶草(pyriminobac-methyl)、砜吡草唑(pyroxasulfone)、甲氧磺胺(pyroxsulam)、棉胺宁(phenisopham)、非草隆(fenuron)、fenoxasulfone、精唑禾草灵(fenoxaprop-P-ethyl)、酚醌草酮(fenquinotrione)、噻唑禾草灵(fenthiaprop-ethyl)、四唑酰草胺(fentrazamide)、苯敌草(phenmedipham)、甲酰氨嘧磺隆(foramsulfuron)、丁草胺(butachlor)、氟丙嘧草酯(butafenacil)、丁胺磷(butamifos)、丁草敌(butylate)、丁烯草胺(butenachlor)、地禾安(butralin)、丁氧环酮(butroxydim)、啶嘧磺隆(flazasulfuron)、氟燕灵(flamprop)(包含甲基、乙基、异丙酯)、精氟燕灵M(flamprop-M)(包含甲基、乙基、异丙酯)、氟嘧磺隆(primisulfuron-methyl)、吡氟禾草灵丁酯(fluazifop-butyl)、精吡氟禾草灵丁酯(fluazifop-P-butyl)、异丙吡草酯(fluazolate)、氟草隆(fluometuron)、乙羧氟草醚乙酯(fluoroglycofen-ethyl)、氟酮磺隆钠盐(flucarbazone-sodium)、氟消草(fluchloralin)、氟吡磺隆(flucetosulfuron)、嗪草酸甲酯(fluthiacet-methyl)、甲基氟啶嘧磺隆钠盐(flupyrsulfuron-methyl-sodium)、氟噻草胺(flufenacet)、氟哒嗪草酯(flufenpyr-ethyl)、四氟丙酸(flupropanate)、氟胺草唑(flupoxame)、丙炔氟草胺(flumioxazin)、氟烯草酸(flumiclorac-pentyl)、唑嘧磺草胺(flumetsulam)、氟啶草酮(fluridone)、呋草酮(flurtamone)、氟草烟(fluroxypyr)、氟咯草酮(flurochloridone)、丙草胺(pretilachlor)、丙苯磺隆(procarbazone-sodium)、氨氟乐灵(prodiamine)、氟磺隆(prosulfuron)、苄草丹(prosulfocarb)、恶草酸(propaquizafop)、毒草胺(propachlor)、扑灭津(propazine)、敌稗(propanil)、炔苯酰草胺(propyzamide)、异丙草胺(propisochlor)、嗪咪唑嘧磺隆(propyrisulfuron)、苯胺灵(propham)、氟唑草胺(profluazol)、丙苯磺隆钠(propoxycarbazone-sodium)、环苯草酮(profoxydim)、除草定(bromacil)、溴莠敏(brompyrazon)、扑草净(prometryn)、扑灭通(prometon)、溴苯腈(bromoxynil)(包含丁酸、辛酸或庚酸等的酯体)、杀草肟(bromofenoxim)、溴丁酰草胺(bromobutide)、双氟磺草胺(florasulam)、烯草胺(pethoxamid)、草除灵(benazolin)、五氟磺草胺(penoxsulam)、胺苯吡菌酮(heptamaloxyloglucan)、氟丁酰草胺(beflubutamid)、克草猛(pebulate)、bencarbazone、二甲戊灵(pendimethalin)、双苯嘧草酮(benzfendizone)、地散磷(bensulide)、苄嘧磺隆(bensulfuron-methyl)、双环磺草酮(benzobicyclon)、吡草酮(benzofenap)、苯达松(bentazone)、蔬草灭(pentanochlor)、嗪酮(pentoxazone)、氟落灵(benfluralin)、呋草黄(benfuresate)、杀木膦(fosamine)、氟磺胺草醚(fomesafen)、2-甲-4-氯丙酸(mecoprop)(包含钠、钾、异丙胺、三乙醇胺、二甲胺等的盐)、2-甲-4-氯丙酸-P-钾(mecoprop-P-potassium)、甲磺胺磺隆(mesosulfuron-methyl)、硝磺草酮(mesotrione)、吡草胺(metazachlor)、嗪吡嘧磺隆(metazosulfuron)、冬播宁(methabenzthiazuron)、苯嗪草酮(metamitron)、唑酰草胺(metamifop)、methiozolin、苯丙隆(methyldymuron)、甲氧隆(metoxuron)、磺草唑胺(metosulam)、甲磺隆(metsulfuron-methyl)、溴谷隆(metobromuron)、吡喃隆(metobenzuron)、异丙甲草胺(metolachlor)、嗪草酮(metribuzin)、苯噻酰草胺(mefenacet)、绿谷隆(monolinuron)、禾草敌(molinate)、碘甲磺隆(iodosulfuron)、甲基碘磺隆钠盐(iodosulfulon-methyl-sodium)、碘嗪磺隆(iofensulfuron)、碘嗪磺隆钠(iofensulfuron-sodium)、乳氟禾草灵(lactofen)、利谷隆(linuron)、玉嘧磺隆(rimsulfuron)、环草定(lenacil)、2,3,6-TBA(2,3,6-三氯苯甲酸)、2,4,5-T(2,4,5-三氯苯氧基醋酸)、2,4-D(2,4-二氯苯氧基醋酸)(包含胺、二乙胺、三乙醇胺、异丙胺、钠或锂等的盐)、2,4-DB(4-(2,4-二氯苯氧基)丁酸)、AE-F-150944(codenumber)、DNOC(4,6-二硝基-O-甲酚)(包含胺或钠等的盐)、EPTC(S-乙基二丙基硫代氨基甲酸酯)、MCPA(2-甲基-4-氯苯氧基醋酸)、MCPA·硫代乙基(MCPA-thioethyl)、MCPB(2-甲基-4-氯苯氧基丁酸)(包含钠盐、乙酯等)、SYP-298(code number)、SYP-300(code number)、精异丙甲草胺(S-metolachlor)、TCA(2,2,2-三氯醋酸)(包含钠、钙或氨等的盐)等。
作为本发明的粒状农药组合物中可以使用的公知的植物生长调节剂成分的例子,可以举出1-萘基乙酰胺(1-naphthylacetamide)、1-甲基环丙烯(1-methylcyclopropene)、2,6-二异丙基萘(2,6-diisopropylnaphthalene)、4-CPA(4-氯苯氧基乙酸)、4-氧-4-(2-苯基乙基)氨基丁酸(化学名、CAS注册号:1083-55-2)、正癸醇(n-decanol)、艾维激素(aviglycine)、环丙嘧啶醇(ancymidol)、抗倒胺(inabenfide)、吲哚乙酸(indole aceticacid)、吲哚丁酸(indolebutyric acid)、烯效唑(uniconazole)、精烯效唑-P(uniconazole-P)、吲唑酯(ethychlozate)、乙烯利(ethephon)、丙酰芸苔素内酯(epocholeone)、香芹酮(carvone)、坐果酸(cloxyfonac)、坐果酸钾(cloxyfonac-potassium)、调果酸(cloprop)、矮壮素(chlormequat)、细胞激肽(cytokinins)、环烷基酰苯胺(cyclanilide)、敌草克(dikegulac)、赤霉素(gibberellins)、噻节因(dimethipin)、杀雄啉(sintofen)、丁酰肼(daminozide)、噻苯隆(thidiazuron)、三十烷醇(triacontanol)、抗倒酯(trinexapac-ethyl)、多效唑(paclobutrazol)、氟节胺(flumetralin)、调嘧醇(flurprimidol)、调嘧醇(flurenol)、茉莉酮(prohydrojasmon)、调环酸钙(prohexadione-calcium)、苄基氨基嘌呤(benzylaminopurine)、氯吡脲(forchlorfenuron)、马来酰肼(maleic hydrazide)、缩节胺(mepiquat chloride)、氟草磺(mefluidide)、过氧化钙等。
本发明的粒状农药组合物中的农药活性成分的含量根据该农药活性成分的种类而异,通常在0.01~99.9%、优选0.1~50%、进一步优选0.1~35%的范围中进行适宜选择。此处,%表示质量百分比。
此外,本发明的粒状农药组合物中,作为药害减轻剂已知的化合物也可以根据需要与上述的农药活性成分混合来使用。作为本发明的粒状农药组合物中可以使用的公知的药害减轻剂成分的例子,可以举出双苯唑酸(isoxadifen)、双苯唑酸(isoxadifen-ethyl)、解草腈(oxabetrinil)、cloquintcet-mexyl、解草胺腈(cyometrinil)、二氯丙烯胺(dichlormid)、dicyclonone、环丙磺酰胺(cyprosulfamide)、萘二甲酸酐(1,8-NaphthalicAnhydride)、解草唑(fenchlorazole-ethyl)、解草啶(fenclorim)、解草唑(furilazole)、氟草肟(fluxofenim)、解草胺(flurazole)、解草酮(benoxacor)、吡咯二酸(mefenpyr)、吡咯二酸乙酯(mefenpyr-ethyl)、吡咯二酸二乙酯(mefenpyr-diethyl)、低级烷基取代苯甲酸、PPG-1292(2,2-二氯-N-(1,3-二烷-2-基甲基)-N-(2-丙烯基)乙酰胺)、MG-191(2-二氯甲基-2-甲基-1,3-二烷)、R-29148(3-二氯乙酰基-2,2,5-三甲基-1,3-唑烷)、AD-67(4-二氯乙酰基-1-氧杂-4-氮杂螺[4.5]癸烷)、MON4660(codenumber)、N-(2-甲氧基苯甲酰基)-4-[(甲基氨基羰基)氨基]苯磺酰胺(化学名、CAS注册号:129531-12-0)、DKA-24(N1,N2-二烯丙基-N2-二氯乙酰基甘氨酰胺)、TI-35(code number)等。这些药害减轻剂成分可以单独使用或混合使用2种以上。
这些农药活性成分及药害减轻剂成分的配合比例的合计相对于本发明的粒状农药组合物100质量份通常为0.1~70质量份,优选为1~50质量份。
以上,示例出了本发明的粒状农药组合物中可以使用的公知的杀菌剂、杀虫剂、除草剂、植物生长调节剂、药害减轻剂的成分,但本发明的粒状农药组合物中可以使用的农药活性成分及药害减轻剂成分并不限定于这些。
本发明的粒状农药组合物除了上述的农药活性成分以外,还可以含有有用微生物、肥料、土壤改良剂等农业上允许的成分。
本发明的粒状农药组合物中可以使用的固体载体可以举出水溶性载体或非水溶性载体,也可以将它们组合使用。作为水溶性载体,例如可以举出硫酸铵、碳酸氢铵、硝酸铵、氯化铵、氯化钾、硫酸钠、硫酸镁、柠檬酸钠、碳酸钠、碳酸氢钠等有机或无机酸盐类、柠檬酸、琥珀酸等有机酸类、蔗糖、乳糖等糖类、尿素等。另外,作为非水溶性载体,通常使用矿物质微粉,例如可以举出粘土类、碳酸钙、膨润土、滑石、硅藻土、硬脂酸钙、白炭黑等。这些固体载体的配合比例相对于本发明的粒状农药组合物100质量份通常为5~80质量份,优选为10~75质量份。
作为本发明的粒状农药组合物中可以使用的表面活性剂,使用农药制剂中通常的表面活性剂即可,例如可以举出聚乙二醇高级脂肪酸酯、聚氧乙烯烷基醚、聚氧乙烯烷基芳基醚、聚氧乙烯芳基苯基醚、山梨糖醇酐单烷基化物、乙炔醇及乙炔二醇以及它们的环氧烷烃加成物等非离子性表面活性剂、烷基芳基磺酸盐、而烷基磺酸盐、木质素磺酸盐、萘磺酸盐及其缩合物、烷基硫酸酯盐、烷基磷酸酯盐、烷基芳基硫酸酯盐、烷基芳基磷酸酯盐、聚氧乙烯烷基醚硫酸酯盐、聚氧乙烯烷基芳基醚硫酸酯盐、聚氧乙烯芳基苯基醚磷酸酯盐、聚羧酸型高分子活性剂等阴离子性表面活性剂等、以及有机硅系表面活性剂、氟系表面活性剂。这些表面活性剂可以单独使用或混合使用2种以上。这些表面活性剂的配合比例相对于本发明的粒状农药组合物100质量份通常为0.1~30质量份,优选为0.5~20质量份、进一步优选为2~10质量份。
此外,本发明的粒状农药组合物中,为了将其比重调整为适当的比重,根据需要可以配混如下所述的低比重的材料。作为这样的材料的例子,可以举出由真珠岩、黑曜石构成的珠光体、由白砂构成的发泡白砂、由硅酸铝系进行煅烧而成的铝硅酸镁盐(fillite)、使硅酸钠或硼砂发泡而成的微珠(microballoon)、浮石、粒状硅藻土、粒状活性炭、木粉、软木粉、由酚醛树脂构成的酚醛微珠、由环氧树脂构成的生态球(ecosphere)、由聚氨酯构成的聚氨酯泡沫、由聚丙烯腈构成的微球等。配合这些低比重的材料的情况下,相对于本发明的粒状农药组合物100质量份可含有0.1~20质量份,优选可含有0.3~10质量份。
此外,本发明的粒状农药组合物中根据需要可以配合结合剂、有机溶剂等作为其它辅助剂。
结合剂为农药粒状组合物中通常使用的结合剂即可,优选水溶性的物质。例如可以举出羧甲基纤维素钠盐、糊精、水溶性淀粉、黄原胶、瓜尔豆胶、蔗糖、聚乙烯基吡咯烷酮、聚乙烯醇、聚丙烯酸钠盐、平均分子量6000~20000的聚乙二醇、平均分子量10万~500万的聚环氧乙烷等。这些结合剂的配合比例相对于本发明的粒状农药组合物100质量份通常为0.01~10质量份,优选为0.1~5质量份。
另外,有机溶剂用于使农药活性成分溶解的情况下,例如可以使用邻苯二甲酸二辛酯、甲基萘、烷基吡咯烷酮、苯基二甲苯基乙烷、甘油、亚烷基二醇等,优选高沸点溶剂。这些有机溶剂的配合比例相对于农药活性成分100质量份通常为10~200质量份。
本发明的粒状农药组合物通过除了含有以上说明的农药活性成分、根据需要使用的固体载体及表面活性剂以外,还含有其它辅助剂和/或其它有效成分,进而向其中加入水而成形为粒状来制备。对成形的方法没有特别限定,优选在将全部原料混合后加入水进行混炼,从开有一定大小的孔的板挤出并进行造粒的方法。在本发明中,在板上开的孔的大小通常为2~8mm。优选使得到的造粒物干燥以使水分相对于组合物100质量份成为0.3~6质量份的范围。另外,可以在使农药活性成分成为液状或溶解于有机溶剂而成为液状后,通过同样的方法对除农药活性成分以外的原料进行造粒、成形、干燥,并使其吸附上述液状的农药活性成分。
本发明的粒状农药组合物通常成形为:粒子的短径成为2~8mm、优选成为2~6mm。另外,为了进一步防止与稻种的分级并均匀地进行混合处理,粒子的长径为5~15mm、优选为6~10mm的范围更好。粒子的形状为球形状、立方体时,优选成形为粒子的直径即粒径、一边的长度在2~8mm、优选在2~6mm的范围内均匀或基本均匀。粒子的形状为除球形、立方体以外的粒子形态时,优选成形为:粒子的短径在2~8mm、优选在2~6mm的范围内均匀或基本均匀,并且粒子的长径在5~15mm、优选在6~10mm的范围内均匀或基本均匀。此外,更优选还根据使用的稻种的种类、有无使用种子包衣剂来适宜选择粒径,具体而言,使用的稻种的种类为短粒种的情况下,粒子的长径为5~10mm者更好,为长粒种的情况下,粒子的长径为8~15mm者更好。另外,在使用包衣有过氧化钙粉粒剂等产氧剂、铁粉等的稻种的情况下也是,优选使用粒径稍微大的粒状农药组合物,具体而言,使用粒子的短径为3~6mm、优选为4~6mm者为宜。
本发明的粒状农药组合物可以用于将稻种播种于育苗箱等并在育苗后移植至水田的移植栽培、将稻的稻种直接播种于水田并进行栽的直播栽培中的任一种,可以适当地用于稻、特别是水稻的直播栽培。作为直播栽培,湛水直播栽培或旱田直播栽培无论哪一种均可。
本发明的粒状农药组合物的施用量根据农药活性成分的种类、要防治的对象、使用方法、使用时期等来适宜决定即可,通常以相对于未包衣的稻种1质量份为0.001~10质量份、优选为0.01~10质量份、更优选为0.1~3质量份、进一步优选为0.3~1质量份的范围使用为宜。对于进行了包衣的稻种的质量,必须进行与使用的包衣剂的质量相应的校正,例如在对稻种1质量份包衣过氧化钙粉粒剂2质量份的情况下,在相对于包衣稻种1质量份为0.003~3质量份、优选为0.03~1质量份、进一步优选为0.1~0.3质量份的范围中使用为宜。
本发明的粒状农药组合物的散布方法具备:将上述的粒状农药组合物和稻的稻种混合的混合工序;以及将上述混合工序中得到的混合物散布的散布工序。
混合工序利用人力或机械以期望的比率对稻种和本发明的粒状农药组合物进行即可。此时,进行混合直到稻种和本发明的粒状农药组合物尽可能变得均匀。
上述混合物中的本发明的粒状农药组合物的混合量根据农药活性成分的种类、要防治的对象、使用方法、使用时期等来适宜决定即可,优选相对于稻种1质量份为0.001~10质量份。
对于散布工序,以成为期望的播种密度的方式、通过播种通常的稻种并散布上述混合工序中得到的混合物的方法进行即可。在移植栽培中使用育苗箱的情况下,将上述混合工序中得到的混合物散布于育苗介质上,并进行如以往那样的播种及育苗作业即可。在直播栽培中,可以按照湛水直播栽培法将上述混合工序中得到的混合物在湛水状态下散布于稻田的表面,另外,也可以按照旱田直播栽培法在排水状态下散布后进行湛水。
另外,对于上述混合物的散布,除了使用人手、动力散粒机、乘坐式水田管理机等以外,还可以使用飞机、有人直升机、无人直升机来进行。
本发明的粒状农药组合物的散布方法优选用于直播栽培、即在上述散布工序中通过散布上述混合物来直播水稻的稻种时。
通过上述那样将稻种和本发明的粒状农药组合物混合并散布,可同时进行播种和采用农药的防治,此外,根据需要可以在将其它农药、有用微生物、肥料、土壤改良剂等混合来使用或在前后使用。
本发明的稻的病害的防治方法是,将本发明的粒状农药组合物与稻的稻种混合并在播种时散布。粒状农药组合物中含有具有防治病害的作用的成分作为农药活性成分。作为这样的成分,可以举出上述杀菌剂成分,可以单独使用或组合使用两种以上。另外,还可以含有除杀菌剂成分以外的上述的农药活性成分、药害减轻剂成分、农业上允许的成分。
本发明的稻的害虫的防治方法是,将本发明的粒状农药组合物与稻的稻种混合并在播种时散布。粒状农药组合物中含有具有防治害虫的作用的成分作为农药活性成分。作为这样的成分,可以举出上述杀虫剂成分,可以单独使用或组合使用两种以上。另外,还可以含有除杀虫剂成分以外的上述的农药活性成分、药害减轻剂成分、农业上允许的成分。
本发明的稻田的杂草的防治方法是,将本发明的粒状农药组合物与稻的稻种混合并在播种时散布。粒状农药组合物中含有具有防治杂草的作用的成分作为农药活性成分。作为这样的成分,可以举出上述除草剂成分,可以单独使用或组合使用两种以上。另外,还可以含有除除草剂成分以外的上述的农药活性成分、药害减轻剂成分、农业上允许的成分。
本发明的稻的生长的调节方法为,将本发明的粒状农药组合物与稻的稻种混合并在播种时散布。粒状农药组合物中含有具有调节对象作物的生长的作用的成分作为农药活性成分。作为这样的成分,可以举出上述植物生长调节剂成分,可以单独使用或组合使用两种以上。另外,还可以含有除植物生长调节剂成分以外的上述的农药活性成分、药害减轻剂成分、农业上允许的成分。
实施例
以下,对本发明的实施例进行叙述,但本发明不仅限定于这些实施例。
(实施例1)制剂例1
将肟啶草1.2份、苄嘧磺隆2.1份、苯噻酰草胺9份、吸附于白炭黑4份的聚氧乙烯芳基苯基醚4份、吸附于白炭黑2.5份的乙炔醇2.5份、聚乙烯醇1份、膨润土6份、氯化钾10份及硫酸钠57.7份均匀混合后,进行冲击式粉碎。将得到的粉末在高速搅拌机中均匀混合,加入适量的水进行混炼后,进行从4mm的孔的挤出造粒。对得到的造粒物进行干燥,得到粒状农药组合物。得到的粒状农药组合物的粒子的短径为4mm、长径为8mm、比重为1.6g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种(Japonica rice)的越光稻种的宽度的100%、长径为稻种的长度的114%。另外,是未包衣的粳稻种的越光稻种的宽度及长度的125%及123%。此外,为籼稻种(Indica rice)的Suphanburi No.1的催芽稻种的宽度及长度的160%及80%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的100%及114%。
(实施例2)制剂例2
将咯喹酮30份、木质素磺酸钠盐2份、吸附于白炭黑3份的聚氧乙烯芳基苯基醚磷酸酯盐3份、糊精3份及硫酸铵54份均匀混合后,进行冲击式粉碎。将得到的粉末和发泡白砂5份在高速搅拌机中均匀混合,加入适量的水进行混炼后,进行从3mm的孔的挤出造粒。对得到的造粒物进行干燥,得到粒状农药组合物。得到的粒状农药组合物的粒子的短径为3mm、长径为6mm、比重为1.4g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种的越光稻种的宽度的75%、长径为稻种的长度的86%。另外,是未包衣的粳稻种的越光的宽度及长度的94%及92%。此外,为籼稻种的Suphanburi No.1的催芽稻种的宽度及长度的120%及60%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的75%及86%。
(实施例3)制剂例3
将嘧磺草胺1质量份、碳酸钙290质量份、硫酸钡100质量份在乳钵内混合,用少量的自来水搅拌好并进行造粒。对得到的造粒物进行干燥,得到米粒状的农药组合物。得到的粒状农药组合物的粒子的短径为5mm、长径为8mm、比重为2.3g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种的越光稻种的宽度的125%、长径为稻种的长度的114%。另外,是未包衣的粳稻种的越光的宽度及长度的156%及123%。此外,为籼稻种的Suphanburi No.1的催芽稻种的宽度及长度的200%及80%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的125%及114%。
(比较例1)制剂例4
将肟啶草1.2份、苄嘧磺隆2.1份、苯噻酰草胺9份、吸附于白炭黑4份的聚氧乙烯芳基苯基醚4份、吸附于白炭黑2.5份的乙炔醇2.5份、聚乙烯醇1份、膨润土5份、氯化钾10份及硫酸钠56.7份均匀混合后,进行冲击式粉碎。将得到的粉末和微球2份在高速搅拌机中均匀混合,加入适量的水进行混炼后,进行从4mm的孔的挤出造粒。对得到的造粒物进行干燥,得到粒状农药组合物。得到的粒状农药组合物的粒子的短径为4mm、长径为8mm、比重为0.8g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种的越光稻种的宽度的100%、长径为稻种的长度的114%。另外,是未包衣的粳稻种的越光的宽度及长度的125%及123%。此外,为籼稻种的Suphanburi No.1的催芽稻种的宽度及长度的160%及80%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的100%及114%。
(比较例2)制剂例5
将肟啶草1.2份、苄嘧磺隆2.1份、苯噻酰草胺9份、吸附于白炭黑4份的聚氧乙烯芳基苯基醚4份、吸附于白炭黑2.5份的乙炔醇2.5份、聚乙烯醇1份、膨润土6份、氯化钾10份及硫酸钠57.7份均匀混合后,进行冲击式粉碎。将得到的粉末在高速搅拌机中均匀混合,加入适量的水进行混炼后,进行从0.8mm的孔的挤出造粒。对得到的造粒物进行干燥,得到粒状农药组合物。得到的粒状农药组合物的粒子的短径为0.8mm、长径为5mm、比重为1.6g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种的越光稻种的宽度的20%、长径为稻种的长度的71%。另外,是未包衣的粳稻种的越光的宽度及长度的25%及77%。此外,为籼稻种的SuphanburiNo.1的催芽稻种的宽度及长度的32%及50%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的20%及71%。
(比较例3)制剂例6
将咯喹酮30份、木质素磺酸钠盐2份、吸附于白炭黑3份的聚氧乙烯芳基苯基醚磷酸酯盐3份、糊精3份及硫酸铵54份均匀混合后,进行冲击式粉碎。将得到的粉末和发泡白砂5份在高速搅拌机中均匀混合,加入适量的水进行混炼后,进行从1.2mm的孔的挤出造粒。对得到的造粒物进行干燥,得到粒状农药组合物。得到的粒状农药组合物的粒子的短径为1.2mm、长径为为6mm、比重为1.4g/cm3。该短径为以下的试验例1及2中使用的进行了包衣的粳稻种的越光稻种的宽度的30%、长径为稻种的长度的86%。另外,是未包衣的粳稻种的越光的宽度及长度的38%及92%。此外,为籼稻种的Suphanburi No.1的催芽稻种的宽度及长度的48%及60%。另外,为试验例3中使用的进行了包衣的粳稻种的Hitomebore稻种的宽度及长度的30%及86%。
(试验例1)与稻种的混合试验
将实施例1及比较例1、2的粒状农药组合物的各300g放入桶中,在催芽后将包衣有过氧化钙粉粒剂的粳稻种的越光稻种各2kg(包括包衣剂的质量在内)放入各自的桶中后,用手将各桶摇晃5分钟而将粒状农药组合物和稻种充分混合。然后,将全部桶排列在1个容器内,通过使该容器在沙砾上滑动而使其振动10分钟。同样地,在装有实施例2及比较例3的粒状农药组合物的各300g的各桶中分别放入未包衣的粳稻种的越光或籼稻种的Suphanburi No.1的催芽稻种各1kg并混合后,使其振动。将目视观察使其振动后的各桶内的粒状农药组合物和稻种的分级的程度的结果示于表1。需要说明的是,这里使用的用过氧化钙粉粒剂进行了包衣的粳稻种的越光稻种的粒长为7mm、粒宽为4mm、粒厚为3.5mm,未包衣的粳稻种的越光稻种的粒长为6.5mm、粒宽为3.2mm、粒厚为2mm、未包衣的籼稻种的SuphanburiNo.1的催芽稻种的粒长为10mm、粒宽为2.5mm、粒厚为2mm。
[表1]
如表1所示,本发明的粒状农药组合物容易与稻种均匀混合,即使通过混合后的振动也不分级,因此适于与稻种混合使用时的处理。
(试验例2)散布试验
再次用手将装入有试验例1中得到的实施例1及2以及比较例1~3的各混合物的桶摇晃5分钟而将粒状农药组合物和稻种混合后,用背负式动力散粒机分别将这些混合物散布1分钟,测量落入配置于距离散布地点10m、7m、4m、2m的距离的50cm四方的容器的粒状农药组合物和稻种的数量,将其结果示于表2。
[表2]
(试验例3)生物效果与药害的比较试验
使用粳稻种的Hitomebore稻种,制作包衣比0.5(稻谷:铁粉=1:0.5)的铁包衣稻谷。铁包衣稻谷的制作中使用的材料的数量比率如表3所示。铁包衣稻谷的粒长为7mm、粒宽为4mm、粒厚为3.5mm。
在200cm2的盆中填充水田土壤,进行了耕种后,将稗草(Echinochloa oryzicola)及萤蔺(Scirpus juncoides)的种子播种于土壤表面。以4粒/盆播种上述铁包衣稻谷,之后立即将实施例3中制作的粒状农药组合物1粒施用于土壤表面。作为比较例4,将BestPartner(注册商标)颗粒剂(Kumiai Chemical Industry Co.,Ltd.制造:包括0.67%的嘧磺草胺)20mg同样地施用于土壤表面。在播种后轻轻地灌水,进行湛水至4cm。在播种后第7天用管将水排走,在水稻成为1叶期的时刻再次进行湛水至4cm。在播种后15天后判定水稻种子的发芽率及杂草的生长抑制效果。将其结果示于表4。需要说明的是,使用的BestPartner颗粒剂的短径及长径分别为使用的稻种的宽度及长度的30%及14~57%。另外,水稻发芽率用%表示,杂草生长抑制率基于下述判定基准来表示。
(判定基准)0:无抑制~100:完全枯死
[表3]
[表4]
本发明的粒状农药组合物即使在与稻种混合下用动力散粒机进行散布,也能够没有偏重地、均匀地散布,不会成为稻种的散布的障碍。此外可明确,表现出与市售的粒状农药组合物同样的生物效果,也没有药害。
Claims (19)
1.一种粒状农药组合物,其是与稻的稻种混合并在播种时散布使用、且含有农药活性成分的粒状农药组合物,
该粒状农药组合物的短径为稻种的宽度的50~320%、长径为稻种的长度的50~230%、比重为1~4g/cm3。
2.根据权利要求1所述的粒状农药组合物,其短径为2~8mm。
3.根据权利要求1或2所述的粒状农药组合物,其用于水稻的直播栽培。
4.根据权利要求3所述的粒状农药组合物,其中,所述直播栽培为湛水直播栽培或旱田直播栽培。
5.根据权利要求1~4中任一项所述的粒状农药组合物,其含有具有防治病害的作用的成分作为所述农药活性成分。
6.根据权利要求1~5中任一项所述的粒状农药组合物,其含有具有防治害虫的作用的成分作为所述农药活性成分。
7.根据权利要求1~6中任一项所述的粒状农药组合物,其含有具有防治杂草的作用的成分作为所述农药活性成分。
8.根据权利要求1~7中任一项所述的粒状农药组合物,其含有具有调节生长的作用的成分作为所述农药活性成分。
9.一种粒状农药组合物的散布方法,该方法具备:
将权利要求1~8中任一项所述的粒状农药组合物和稻的稻种混合的混合工序;以及
将所述混合工序中得到的混合物散布的散布工序。
10.根据权利要求9所述的粒状农药组合物的散布方法,其中,所述稻为水稻,在所述散布工序中,通过散布所述混合物来播种所述水稻的稻种。
11.根据权利要求9或10所述的粒状农药组合物的散布方法,其中,在所述散布工序中,通过散布所述混合物来直播所述水稻的稻种。
12.根据权利要求9~11中任一项所述的粒状农药组合物的散布方法,其中,在所述散布工序中,用动力散粒机散布所述混合物。
13.根据权利要求9~11中任一项所述的粒状农药组合物的散布方法,其中,在所述散布工序中,用乘坐式水田管理机散布所述混合物。
14.根据权利要求9~11中任一项所述的粒状农药组合物的散布方法,其中,在所述散布工序中,用飞机、有人直升机、或无人直升机散布所述混合物。
15.根据权利要求9~14中任一项所述的粒状农药组合物的散布方法,其中,所述混合物中的所述粒状农药组合物的混合量相对于稻种1质量份为0.001~10质量份。
16.一种稻的病害的防治方法,其包括下述工序:将权利要求5所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
17.一种稻的害虫的防治方法,其包括下述工序:将权利要求6所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
18.一种稻田的杂草的防治方法,其包括下述工序:将权利要求7所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
19.一种稻的生长的调节方法,其包括下述工序:在稻的播种时,将权利要求8所述的粒状农药组合物与稻的稻种混合,并在播种时散布。
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