CN108435247A - 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 - Google Patents

用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 Download PDF

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Publication number
CN108435247A
CN108435247A CN201810264001.5A CN201810264001A CN108435247A CN 108435247 A CN108435247 A CN 108435247A CN 201810264001 A CN201810264001 A CN 201810264001A CN 108435247 A CN108435247 A CN 108435247A
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zeolite
hydroxylation
hours
titanium
crystallization
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Chinese (zh)
Inventor
T.科尔
B.阿尔贝拉
L.博纳维奥
L.加雷尔
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Centre National de la Recherche Scientifique CNRS
Rhodia Operations SAS
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Centre National de la Recherche Scientifique CNRS
Rhodia Operations SAS
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
CN201810264001.5A 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法 Pending CN108435247A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1251496A FR2987046B1 (fr) 2012-02-17 2012-02-17 Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation
FR1251496 2012-02-17
CN201380009890.6A CN104302395A (zh) 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法

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CN201380009890.6A Pending CN104302395A (zh) 2012-02-17 2013-02-15 用于芳香族化合物的羟基化的方法、羟基化催化剂以及用于制备羟基化催化剂的方法

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US (2) US9682909B2 (https=)
EP (1) EP2814606A1 (https=)
JP (2) JP6509561B2 (https=)
CN (2) CN108435247A (https=)
FR (1) FR2987046B1 (https=)
WO (1) WO2013120986A1 (https=)

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CN114634404A (zh) * 2022-04-01 2022-06-17 北京化工大学 一种苯氧化制备苯酚的方法

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UA124030C2 (uk) 2017-01-09 2021-07-07 Евонік Оперейшнс Гмбх Спосіб одержання оксидів металів за допомогою розпилювального піролізу
EP3424883A1 (de) 2017-07-05 2019-01-09 Evonik Degussa GmbH Sprühverdampfung eines flüssigen rohstoffes zur herstellung von siliciumdioxid und metalloxiden
CN107597173B (zh) * 2017-10-11 2020-07-21 中国天辰工程有限公司 一种苯酚羟基化合成苯二酚的催化剂及其制备方法
EP3495321A1 (de) 2017-12-07 2019-06-12 Evonik Degussa GmbH Herstellung von pulverförmigen, porösen kristallinen metallsilikaten mittels flammensprühpyrolyse
FR3075198B1 (fr) * 2017-12-15 2020-04-03 Rhodia Operations Procede d'hydroxylation d'un compose aromatique
WO2019182035A1 (ja) * 2018-03-23 2019-09-26 宇部興産株式会社 芳香族ヒドロキシ化合物の製造方法
EP3798190A4 (en) * 2018-05-21 2022-03-02 Mitsui Chemicals, Inc. METHOD FOR MAKING MODIFIED ALUMINOSILICATE, MODIFIED ALUMINOSILICATE AND METHOD FOR MAKING AN AROMATIC DIHYDROXY COMPOUND USING THE SAME
US11897779B2 (en) * 2018-08-24 2024-02-13 East China Normal University Microporous aluminotitanosilicate crystalline zeolite, method of preparation and applications thereof
EP3628642A1 (en) * 2018-09-25 2020-04-01 Evonik Operations GmbH Process for the manufacture of pulverulent, porous crystalline metal silicates employing flame spray pyrolysis
FR3095199B1 (fr) * 2019-04-19 2021-10-29 Ifp Energies Now Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite
WO2020221683A1 (en) * 2019-04-29 2020-11-05 Basf Se Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst
JP7556686B2 (ja) * 2019-12-26 2024-09-26 日揮触媒化成株式会社 アルコキシ基を含む原料を使用しないチタノシリケートゼオライトの製造方法
CN112717998B (zh) * 2021-01-19 2022-03-11 中国科学院大连化学物理研究所 一种高活性苯酚羟基化钛硅分子筛催化剂及其制备方法
CN112871206B (zh) * 2021-01-19 2022-04-08 中国科学院大连化学物理研究所 一种低成本高活性苯酚羟基化钛硅分子筛催化剂的制备方法
JP2023160591A (ja) * 2022-04-22 2023-11-02 三井化学株式会社 変性アルミノシリケートの製造方法、変性アルミノシリケート及びそれを用いた芳香族ポリヒドロキシド化合物の製造方法

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Publication number Priority date Publication date Assignee Title
CN114634404A (zh) * 2022-04-01 2022-06-17 北京化工大学 一种苯氧化制备苯酚的方法
CN114634404B (zh) * 2022-04-01 2023-09-15 北京化工大学 一种苯氧化制备苯酚的方法

Also Published As

Publication number Publication date
FR2987046A1 (fr) 2013-08-23
JP6509561B2 (ja) 2019-05-08
US9682909B2 (en) 2017-06-20
WO2013120986A1 (fr) 2013-08-22
US20150299076A1 (en) 2015-10-22
US20170253547A1 (en) 2017-09-07
US10173954B2 (en) 2019-01-08
FR2987046B1 (fr) 2014-03-21
CN104302395A (zh) 2015-01-21
JP2019001711A (ja) 2019-01-10
JP2015511945A (ja) 2015-04-23
EP2814606A1 (fr) 2014-12-24

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Application publication date: 20180824