CN108221371B - 一种以卤胺类化合物及银离子制备抗菌涤纶的方法 - Google Patents
一种以卤胺类化合物及银离子制备抗菌涤纶的方法 Download PDFInfo
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- CN108221371B CN108221371B CN201810101896.0A CN201810101896A CN108221371B CN 108221371 B CN108221371 B CN 108221371B CN 201810101896 A CN201810101896 A CN 201810101896A CN 108221371 B CN108221371 B CN 108221371B
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 28
- -1 silver ions Chemical class 0.000 title claims abstract description 12
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- 239000004332 silver Substances 0.000 title claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 113
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 54
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- 239000007788 liquid Substances 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims abstract description 23
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 18
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
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- 238000002791 soaking Methods 0.000 claims description 15
- 238000005660 chlorination reaction Methods 0.000 claims description 14
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 12
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- 238000005096 rolling process Methods 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
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- 238000003756 stirring Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
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- 229920004933 Terylene® Polymers 0.000 abstract description 14
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 14
- 230000007547 defect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 23
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- 239000004753 textile Substances 0.000 description 12
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- 229920002521 macromolecule Polymers 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 241001333951 Escherichia coli O157 Species 0.000 description 4
- 239000005708 Sodium hypochlorite Substances 0.000 description 4
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- 229910052801 chlorine Inorganic materials 0.000 description 4
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- 230000002209 hydrophobic effect Effects 0.000 description 4
- 238000011081 inoculation Methods 0.000 description 4
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
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- 241001646719 Escherichia coli O157:H7 Species 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
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- 230000001488 breeding effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 238000004134 energy conservation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
- D06M14/30—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M14/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
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CN201810101896.0A CN108221371B (zh) | 2018-02-01 | 2018-02-01 | 一种以卤胺类化合物及银离子制备抗菌涤纶的方法 |
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CN201810101896.0A CN108221371B (zh) | 2018-02-01 | 2018-02-01 | 一种以卤胺类化合物及银离子制备抗菌涤纶的方法 |
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CN114351460B (zh) * | 2020-10-13 | 2024-04-16 | 广州弘海材料科技有限公司 | 一种具抗菌功能的纤维材料、其制备方法及其纤维制品 |
CN113430814A (zh) * | 2021-07-28 | 2021-09-24 | 石狮市中纺学服装及配饰产业研究院 | 一种复合抗菌剂的制备方法及其在聚酯织物上的应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102775353A (zh) * | 2012-08-11 | 2012-11-14 | 河北亚光精细化工有限公司 | 3-烯丙基-5,5-二甲基海因及其制备方法 |
CN102877288A (zh) * | 2012-10-19 | 2013-01-16 | 常州大学 | 一种含卤胺的抗菌聚丙烯腈纤维的制备方法 |
CN104904718A (zh) * | 2015-04-22 | 2015-09-16 | 江南大学 | 一种卤胺双键海因抗菌剂及其制备、应用方法 |
CN106488702A (zh) * | 2014-05-05 | 2017-03-08 | 曹正兵 | 抗菌表面涂层 |
CN106906658A (zh) * | 2017-01-10 | 2017-06-30 | 上海师范大学 | 卤胺接枝天然纤维纺织品及其制备方法与应用 |
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2018
- 2018-02-01 CN CN201810101896.0A patent/CN108221371B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102775353A (zh) * | 2012-08-11 | 2012-11-14 | 河北亚光精细化工有限公司 | 3-烯丙基-5,5-二甲基海因及其制备方法 |
CN102877288A (zh) * | 2012-10-19 | 2013-01-16 | 常州大学 | 一种含卤胺的抗菌聚丙烯腈纤维的制备方法 |
CN106488702A (zh) * | 2014-05-05 | 2017-03-08 | 曹正兵 | 抗菌表面涂层 |
CN104904718A (zh) * | 2015-04-22 | 2015-09-16 | 江南大学 | 一种卤胺双键海因抗菌剂及其制备、应用方法 |
CN106906658A (zh) * | 2017-01-10 | 2017-06-30 | 上海师范大学 | 卤胺接枝天然纤维纺织品及其制备方法与应用 |
Non-Patent Citations (1)
Title |
---|
电子束辐射工艺在乙烯基卤胺单体改性棉织物中的应用研究;李晓林;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20160615;B024-77 * |
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