CN108137750A - 制备具有磺酰基侧基的四氟乙烯共聚物的方法 - Google Patents

制备具有磺酰基侧基的四氟乙烯共聚物的方法 Download PDF

Info

Publication number
CN108137750A
CN108137750A CN201680055739.XA CN201680055739A CN108137750A CN 108137750 A CN108137750 A CN 108137750A CN 201680055739 A CN201680055739 A CN 201680055739A CN 108137750 A CN108137750 A CN 108137750A
Authority
CN
China
Prior art keywords
copolymer
ocf
present disclosure
formula
vinyl ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680055739.XA
Other languages
English (en)
Chinese (zh)
Inventor
格雷格·D·达尔克
丹尼斯·杜谢恩
克劳斯·辛策
马库斯·希尔施贝格
卡伊·H·洛哈斯
阿尔内·塔勒
蒂尔曼·C·兹普利斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN108137750A publication Critical patent/CN108137750A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18—Homopolymers or copolymers of tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/22—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C09D127/24—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment halogenated
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668—Binders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN201680055739.XA 2015-09-23 2016-09-22 制备具有磺酰基侧基的四氟乙烯共聚物的方法 Pending CN108137750A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562222296P 2015-09-23 2015-09-23
US62/222,296 2015-09-23
PCT/US2016/053104 WO2017053563A1 (en) 2015-09-23 2016-09-22 Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups

Publications (1)

Publication Number Publication Date
CN108137750A true CN108137750A (zh) 2018-06-08

Family

ID=58387310

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680055739.XA Pending CN108137750A (zh) 2015-09-23 2016-09-22 制备具有磺酰基侧基的四氟乙烯共聚物的方法

Country Status (5)

Country Link
US (1) US11155661B2 (https=)
EP (1) EP3353221B1 (https=)
JP (1) JP6941604B2 (https=)
CN (1) CN108137750A (https=)
WO (1) WO2017053563A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111094438A (zh) * 2017-09-14 2020-05-01 3M创新有限公司 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品
US11820733B2 (en) 2018-03-14 2023-11-21 Asahi Kasei Kabushiki Kaisha Process for producing sulfonic acid group-containing monomer

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108779209A (zh) * 2016-03-07 2018-11-09 3M创新有限公司 具有磺酰侧基的氟化共聚物和制备离聚物的方法
CN108084063A (zh) * 2017-11-25 2018-05-29 山东华夏神舟新材料有限公司 全氟乙烯基醚磺酸盐的制备方法
US20190169338A1 (en) * 2017-12-01 2019-06-06 Honeywell International Inc. Fluoropolymers for coating applications
FR3079834B1 (fr) * 2018-04-10 2021-09-10 Arkema Inc Fluoropolymeres fonctionnels
CN112955494B (zh) * 2018-11-05 2025-09-12 索尔维特殊聚合物意大利有限公司 可分散离聚物粉末和其制作方法
WO2020116645A1 (ja) * 2018-12-07 2020-06-11 Ａｇｃ株式会社 液状組成物、固体高分子電解質膜、膜電極接合体、固体高分子形燃料電池
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
EP4133542A1 (en) * 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
WO2022146967A1 (en) * 2020-12-31 2022-07-07 Hyzon Motors Inc. Fuel cell catalyst coated membrane and method of manufacture
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles
EP4393019A4 (en) * 2021-09-17 2025-07-30 1S1 Energy Inc SOLID PROTON EXCHANGE SUPPORTS FUNCTIONALIZED BY METAL FLUORIDE, MEMBRANES AND IONOMERS
CN118580410A (zh) * 2021-12-17 2024-09-03 济南大学 一类交联氢键增强型全氟共轭阳离子树脂及其合成方法与应用
EP4533574A1 (en) * 2022-06-03 2025-04-09 Celadyne Technologies, Inc. Composite polyelectrolyte-ceramic membranes
CN115109177B (zh) * 2022-06-09 2023-06-20 东风汽车集团股份有限公司 一种mea耐久增强剂及其制备方法和应用
CN115582136A (zh) * 2022-10-14 2023-01-10 国能龙源环保有限公司 一种用于脱硫脱硝的亚砜类催化剂及其制备方法
CN116217780A (zh) * 2022-12-22 2023-06-06 福建科润世纪氢能材料有限公司 一种全氟聚合物制备方法及其在离子交换膜中的应用
WO2025233234A1 (en) * 2024-05-06 2025-11-13 Syensqo Specialty Polymers Italy S.p.A. Monomer composition and use thereof for the preparation of a fluorinated polymer
CN119786670A (zh) * 2024-12-30 2025-04-08 天津大学浙江研究院 一种共价有机框架质子交换膜及其制备方法和高温质子交换膜燃料电池

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1251576A (zh) * 1997-03-31 2000-04-26 大金工业株式会社 全氟乙烯醚磺酸衍生物的制法及由其构成的共聚物
US20030023015A1 (en) * 2000-02-16 2003-01-30 Masayoshi Tatemoto Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation
JP2004010562A (ja) * 2002-06-10 2004-01-15 Asahi Kasei Corp スルホンアミド基含有モノマーの製造方法
CN101023550A (zh) * 2004-09-20 2007-08-22 3M创新有限公司 燃料电池耐久性
WO2008001894A1 (fr) * 2006-06-30 2008-01-03 Daikin Industries, Ltd. Procédé de production de polymère contenant du fluor
CN101772534A (zh) * 2007-07-24 2010-07-07 3M创新有限公司 包含多磺酸聚合物和具有含f阴离子的金属盐的阳离子导电膜
CN103732680A (zh) * 2011-08-04 2014-04-16 3M创新有限公司 低当量重量聚合物

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3560568A (en) * 1968-11-26 1971-02-02 Du Pont Preparation of sulfonic acid containing fluorocarbon vinyl ethers
NL160013C (nl) 1968-11-26 1979-09-17 Du Pont Werkwijze ter bereiding van oplossingen van een sulfonyl- groepen bevattend fluorkoolstofpolymeer.
US3718627A (en) 1968-11-26 1973-02-27 Du Pont Cf{11 {32 cfcf{11 cf{11 so{11 {11 f and derivatives and polymers thereof
US4267364A (en) 1977-04-20 1981-05-12 E. I. Dupont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
US4349650A (en) 1979-03-14 1982-09-14 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4358412A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Preparation of vinyl ethers
US4470889A (en) 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
US4423197A (en) 1981-12-01 1983-12-27 Minnesota Mining And Manufacturing Company Cyclic perfluoroaliphatic-disulfonic acid anhydrides and sulfonamide derivatives thereof
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
JPS62288614A (ja) * 1986-06-06 1987-12-15 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体の製法
JPH027384A (ja) 1988-06-27 1990-01-11 Toshiba Corp 調理器
IT1230718B (it) 1989-02-13 1991-10-29 Ausimont Srl Fluorurazione diretta di fluoro b sultoni ai corrispondenti fluorossi fluorosulfonil fluorocomposti.
US5182342A (en) 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
DE4233824A1 (de) 1992-10-08 1994-04-14 Hoechst Ag Verfahren zur Aufarbeitung wäßriger Dispersionen von Fluorthermoplasten
US5285002A (en) 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
DE4402694A1 (de) 1993-06-02 1995-08-03 Hoechst Ag Verfahren zur Rückgewinnung von fluorierten Carbonsäuren
WO1998016581A1 (en) * 1996-10-15 1998-04-23 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
JPH1167274A (ja) 1997-08-22 1999-03-09 Daikin Ind Ltd リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤
US6388139B1 (en) 1997-11-05 2002-05-14 E. I. Du Pont De Nemours And Company Production of perfluoro (alkyl vinyl) ethers
DE19824614A1 (de) 1998-06-02 1999-12-09 Dyneon Gmbh Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern
US6294627B1 (en) 1998-08-31 2001-09-25 Dyneon Llc Low temperature fluorocarbon elastomers
US6429258B1 (en) 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
DE19933696A1 (de) 1999-07-17 2001-01-18 Dyneon Gmbh Verfahren zur Rückgewinnung fluorierter Emulgatoren aus wässrigen Phasen
US6255536B1 (en) 1999-12-22 2001-07-03 Dyneon Llc Fluorine containing vinyl ethers
US6794550B2 (en) 2000-04-14 2004-09-21 3M Innovative Properties Company Method of making an aqueous dispersion of fluoropolymers
KR100337889B1 (ko) 2000-06-22 2002-05-24 김순택 리튬 2차전지
US20020160272A1 (en) 2001-02-23 2002-10-31 Kabushiki Kaisha Toyota Chuo Process for producing a modified electrolyte and the modified electrolyte
US6861489B2 (en) * 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US20040107869A1 (en) 2002-12-10 2004-06-10 3M Innovative Properties Company Catalyst ink
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005007707A1 (ja) 2003-07-16 2005-01-27 Daikin Industries, Ltd. 含フッ素重合体の製造方法、含フッ素重合体水性分散液、２−アシルオキシカルボン酸誘導体及び界面活性剤
US20050037265A1 (en) 2003-08-14 2005-02-17 Asahi Glass Company, Limited Polymer electrolyte fuel cell, electrolyte material therefore and method for its production
US20070129500A1 (en) 2003-09-10 2007-06-07 Eiji Honda Stabilized fluoropolymer and method for producing same
JP5217090B2 (ja) 2003-10-22 2013-06-19 ダイキン工業株式会社 テトラフルオロエチレン重合体水性分散液、その製造方法、テトラフルオロエチレン重合体粉末及びテトラフルオロエチレン重合体成形体
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7265162B2 (en) 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
EP1561729A1 (en) 2004-02-05 2005-08-10 3M Innovative Properties Company Removal of fluorinated surfactants from waste water
GB0415811D0 (en) 2004-07-15 2004-08-18 Quintel Technology Ltd Antenna system for shared operation
US20060014887A1 (en) * 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
US7304101B2 (en) 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
JP2006036986A (ja) 2004-07-28 2006-02-09 Asahi Glass Co Ltd 含フッ素ポリマーラテックス、その製造方法および含フッ素ポリマー
JP5061446B2 (ja) 2005-03-04 2012-10-31 旭硝子株式会社 含フッ素エラストマーラテックス、その製造方法、含フッ素エラストマーおよび含フッ素ゴム成形品
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
US7671112B2 (en) 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
US8367267B2 (en) 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US20070142513A1 (en) 2005-12-21 2007-06-21 Daikin Industries, Ltd. Surfactant, method of producing a fluoropolymer, fluoropolymer aqueous dispersion
US7575534B2 (en) 2006-12-22 2009-08-18 Torvec, Inc. Transmission with resistance torque control
GB0801194D0 (en) 2008-01-23 2008-02-27 3M Innovative Properties Co Processing aid compositions comprising fluoropolymers having long-chain branches
JP5217708B2 (ja) 2008-07-09 2013-06-19 旭硝子株式会社 ポリマー、その製造方法、固体高分子形燃料電池用電解質膜および膜電極接合体
JP5540681B2 (ja) 2009-07-14 2014-07-02 株式会社豊田中央研究所 改質電解質及びその製造方法、並びに、改質剤
JP5682153B2 (ja) 2010-02-01 2015-03-11 ダイキン工業株式会社 含フッ素共重合体の製造方法、ポリマー電解質、リチウム電池用電極及びリチウム電池
JP5862372B2 (ja) 2012-03-02 2016-02-16 旭硝子株式会社 ポリマーの製造方法、固体高分子形燃料電池用電解質膜の製造方法および膜電極接合体の製造方法
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
US10844152B2 (en) * 2015-02-12 2020-11-24 3M Innovative Properties Company Tetrafluoroethylene and perfluorinated allyl ether copolymers
CN108779209A (zh) 2016-03-07 2018-11-09 3M创新有限公司 具有磺酰侧基的氟化共聚物和制备离聚物的方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1251576A (zh) * 1997-03-31 2000-04-26 大金工业株式会社 全氟乙烯醚磺酸衍生物的制法及由其构成的共聚物
US20030023015A1 (en) * 2000-02-16 2003-01-30 Masayoshi Tatemoto Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation
JP2004010562A (ja) * 2002-06-10 2004-01-15 Asahi Kasei Corp スルホンアミド基含有モノマーの製造方法
CN101023550A (zh) * 2004-09-20 2007-08-22 3M创新有限公司 燃料电池耐久性
WO2008001894A1 (fr) * 2006-06-30 2008-01-03 Daikin Industries, Ltd. Procédé de production de polymère contenant du fluor
CN101772534A (zh) * 2007-07-24 2010-07-07 3M创新有限公司 包含多磺酸聚合物和具有含f阴离子的金属盐的阳离子导电膜
CN103732680A (zh) * 2011-08-04 2014-04-16 3M创新有限公司 低当量重量聚合物

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111094438A (zh) * 2017-09-14 2020-05-01 3M创新有限公司 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品
CN111094438B (zh) * 2017-09-14 2022-11-08 3M创新有限公司 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品
US11820733B2 (en) 2018-03-14 2023-11-21 Asahi Kasei Kabushiki Kaisha Process for producing sulfonic acid group-containing monomer

Also Published As

Publication number Publication date
EP3353221A4 (en) 2019-03-13
US20180273663A1 (en) 2018-09-27
JP2018528316A (ja) 2018-09-27
EP3353221A1 (en) 2018-08-01
US11155661B2 (en) 2021-10-26
EP3353221B1 (en) 2023-06-07
WO2017053563A1 (en) 2017-03-30
JP6941604B2 (ja) 2021-09-29

Similar Documents

Publication Publication Date Title
US11155661B2 (en) Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
CN111094438B (zh) 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品
EP3426701B1 (en) Fluorinated copolymer having sulfonyl pendant groups and method of making an ionomer
CN114901710B (zh) 氟化共聚物以及包括其的组合物和制品
JP7223915B2 (ja) フッ素化アイオノマーの熱分解によるフルオロオレフィンの製造方法
CN115398684A (zh) 包含氟化聚合物和盐纳米粒子的复合材料以及包含其的制品

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180608