CN108134117B - 一种燃料电池用液态玻璃复合质子交换膜及制备方法 - Google Patents
一种燃料电池用液态玻璃复合质子交换膜及制备方法 Download PDFInfo
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- CN108134117B CN108134117B CN201711456170.0A CN201711456170A CN108134117B CN 108134117 B CN108134117 B CN 108134117B CN 201711456170 A CN201711456170 A CN 201711456170A CN 108134117 B CN108134117 B CN 108134117B
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- proton exchange
- exchange membrane
- fuel cell
- liquid glass
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- 150000001875 compounds Chemical group 0.000 title claims abstract description 31
- 125000003118 aryl group Chemical group 0.000 claims abstract description 39
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 66
- 238000007731 hot pressing Methods 0.000 claims description 44
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 36
- 239000004925 Acrylic resin Substances 0.000 claims description 34
- -1 silicon ion Chemical class 0.000 claims description 29
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- 229910052710 silicon Inorganic materials 0.000 claims description 25
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 24
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- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 9
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- 238000002791 soaking Methods 0.000 claims description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 8
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- 239000005864 Sulphur Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
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- 241001062009 Indigofera Species 0.000 description 2
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- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
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- 235000007164 Oryza sativa Nutrition 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 238000007598 dipping method Methods 0.000 description 1
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- 238000005755 formation reaction Methods 0.000 description 1
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- 239000002120 nanofilm Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
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- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1086—After-treatment of the membrane other than by polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims (9)
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CN201711456170.0A CN108134117B (zh) | 2017-12-28 | 2017-12-28 | 一种燃料电池用液态玻璃复合质子交换膜及制备方法 |
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CN201711456170.0A CN108134117B (zh) | 2017-12-28 | 2017-12-28 | 一种燃料电池用液态玻璃复合质子交换膜及制备方法 |
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CN108134117B true CN108134117B (zh) | 2018-11-09 |
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CN111193053B (zh) * | 2020-02-28 | 2020-10-09 | 成都新柯力化工科技有限公司 | 一种高热稳定性质子交换膜及制备方法 |
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JP5724164B2 (ja) * | 2009-03-27 | 2015-05-27 | 大日本印刷株式会社 | 燃料電池の膜−電極接合体、電極製造用転写シート及びこれらの製造方法 |
CN101901917B (zh) * | 2010-06-30 | 2013-04-17 | 上海交通大学 | 质子导电复合玻璃膜及其制备方法 |
CN102315463A (zh) * | 2011-08-05 | 2012-01-11 | 上海交通大学 | 一种柔性无机/有机复合质子交换膜制备方法 |
CN103956506A (zh) * | 2014-05-22 | 2014-07-30 | 胡国良 | 用于燃料电池的复合质子交换膜的制备方法 |
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Address after: 26th Floor, Phase 2, Yijing Plaza, 10 Cheung Yu Street, Cheung Sha Wan, Hong Kong, China Patentee after: Austin Technology Co.,Ltd. Address before: 1st Floor, Building 2, No.1 Kechuang Road, Qixia District, Nanjing City, Jiangsu Province, 210046 Patentee before: Austin Technology Co.,Ltd. |
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Application publication date: 20180608 Assignee: Sichuan aohite Electronic Materials Co.,Ltd. Assignor: Austin Technology Co.,Ltd. Contract record no.: X2024990000083 Denomination of invention: A liquid glass composite proton exchange membrane for fuel cells and its preparation method Granted publication date: 20181109 License type: Common License Record date: 20240228 |
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