CN107848918B - 使Z-1336mzz催化异构化为E-1336mzz - Google Patents

使Z-1336mzz催化异构化为E-1336mzz Download PDF

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Publication number
CN107848918B
CN107848918B CN201680046175.3A CN201680046175A CN107848918B CN 107848918 B CN107848918 B CN 107848918B CN 201680046175 A CN201680046175 A CN 201680046175A CN 107848918 B CN107848918 B CN 107848918B
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1336mzz
halide
hfo
fluorides
catalyst
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Chinese (zh)
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CN107848918A (zh
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M.J.纳帕
彭晟
V.A.佩特罗夫
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Chemours Co FC LLC
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Chemours Co FC LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/358—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00029—Batch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201680046175.3A 2015-08-07 2016-08-04 使Z-1336mzz催化异构化为E-1336mzz Active CN107848918B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562202382P 2015-08-07 2015-08-07
US62/202382 2015-08-07
PCT/US2016/045573 WO2017027323A1 (en) 2015-08-07 2016-08-04 Catalytic isomerization of z-1,1,1,4,4,4-hexafluoro-2-butene to e-1,1,1,4,4,4-hexafluoro-2-butene

Publications (2)

Publication Number Publication Date
CN107848918A CN107848918A (zh) 2018-03-27
CN107848918B true CN107848918B (zh) 2021-12-21

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US (1) US10479745B2 (enExample)
EP (2) EP3663274B1 (enExample)
JP (1) JP6930962B2 (enExample)
KR (1) KR102664130B1 (enExample)
CN (1) CN107848918B (enExample)
MX (2) MX2018001489A (enExample)
WO (1) WO2017027323A1 (enExample)

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CN111094503B (zh) * 2017-09-11 2022-04-01 科慕埃弗西有限公司 包含氟化氢和含氟烃的共沸组合物
CA3077388C (en) * 2017-10-10 2024-04-09 The Chemours Company Fc, Llc Process for the manufacture of thermoplastic foam containing hfo-1336mzz(z) and hfo-1336mzz(e)
CN107602340B (zh) * 2017-10-17 2020-05-15 北京宇极科技发展有限公司 气相异构化制备全氟二烯烃和全氟炔烃的方法
WO2019113052A1 (en) * 2017-12-04 2019-06-13 The Chemours Company Fc, Llc Process and intermediates for preparing 1,1,3-trichloro-4,4,4-trifluorobut-1-ene and (e)-1,1,1,4,4,4-hexafluorobut-2-ene
CN108727155B (zh) * 2018-06-19 2021-01-01 北京宇极科技发展有限公司 E-1，1，1，4，4，4-六氟-2-丁烯的制备方法
EP3947327B1 (en) * 2019-04-05 2023-05-31 The Chemours Company FC, LLC Processes for producing z-1,1,1,4,4,4-hexafluorobut-2-ene and intermediates for producing same
WO2022080276A1 (ja) * 2020-10-15 2022-04-21 昭和電工株式会社 フルオロ－２－ブテンの保管方法
JPWO2022080275A1 (enExample) * 2020-10-15 2022-04-21
EP4230608A4 (en) * 2020-10-15 2024-11-27 Resonac Corporation PROCESS FOR STORING FLUORO-2-BUTENE
CN112811975B (zh) * 2021-04-22 2021-07-30 泉州宇极新材料科技有限公司 气相异构化制备z-1-r-3,3,3-三氟丙烯的方法
KR20240088766A (ko) * 2021-10-06 2024-06-20 가부시끼가이샤 레조낙 (e)-1,1,1,4,4,4-헥사플루오로-2-부텐의 제조 방법
CN114292158B (zh) * 2021-12-01 2024-01-02 西安近代化学研究所 一种制备顺式-1,1,1,4,4,4-六氟-2-丁烯的方法
CN114262255B (zh) * 2021-12-01 2023-10-20 西安近代化学研究所 一种合成反式-1,1,1,4,4,4-六氟-2-丁烯的方法
TW202346449A (zh) 2022-04-22 2023-12-01 美商科慕Ｆｃ有限責任公司 包含ｅ－１，１，１，４，４，４－六氟－２－丁烯之氟丁烯組成物及其用途
WO2025019749A1 (en) 2023-07-20 2025-01-23 The Chemours Company Fc, Llc Hexafluoro-2-butene compositions, storage and handling
WO2025019753A2 (en) 2023-07-20 2025-01-23 The Chemours Company Fc, Llc Heat mitigation in cf3ccl3 (cfc-113a) coupling reaction
WO2025160037A2 (en) * 2024-01-22 2025-07-31 The Chemours Company Fc, Llc Process for the preparation of e-isomer of 1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene (hfo-153-10mczz; cf3cf2ch=chc2cf3)
WO2025174926A1 (en) 2024-02-16 2025-08-21 The Chemours Company Fc, Llc Purification of e-1,1,1,4,4,4-hexafluoro-2-butene by adsorption

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WO2011158790A1 (ja) * 2010-06-14 2011-12-22 独立行政法人産業技術総合研究所 フッ素化合物の製造方法
CN102884030A (zh) * 2010-03-26 2013-01-16 霍尼韦尔国际公司 制备六氟-2-丁烯的方法
CN102892736A (zh) * 2010-03-26 2013-01-23 霍尼韦尔国际公司 六氟-2-丁烯的制造方法
FR2989374A1 (fr) * 2012-04-11 2013-10-18 Arkema France Procede de preparation d'un compose olefinique sous forme d'un isomere specifique.
CN103755519A (zh) * 2014-02-24 2014-04-30 山东联创节能新材料股份有限公司 六氟丁烯的合成方法
WO2015059500A1 (en) * 2013-10-25 2015-04-30 Mexichem Amanco Holding S.A. De C.V. Process for the isomerisation of c3-7 (hydro)(halo)fluoroalkenes

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US5136113A (en) 1991-07-23 1992-08-04 E. I. Du Pont De Nemours And Company Catalytic hydrogenolysis
US7485760B2 (en) * 2006-08-24 2009-02-03 Honeywell International Inc. Integrated HFC trans-1234ze manufacture process
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GB0721991D0 (en) * 2007-11-09 2007-12-19 Ineos Fluor Holdings Ltd Preparation method
EP2399892A3 (en) 2008-03-19 2012-06-13 E.I. Du Pont De Nemours And Company Process for making 1,1,1,4,4,4-hexafluoro-2-butene
JP5828761B2 (ja) * 2008-05-23 2015-12-09 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ ジヒドロフルオロアルケンを製造するための高選択性方法
CA2743670C (en) * 2008-11-19 2016-04-12 Arkema Inc. Process for the manufacture of hydrochlorofluoroolefins
US8399721B2 (en) 2008-12-22 2013-03-19 E I Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
JP5620478B2 (ja) * 2009-06-03 2014-11-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ ２，３，３，３−テトラフルオロプロペンを製造するための触媒および方法
US8822739B2 (en) 2012-03-22 2014-09-02 E I Du Pont De Nemours And Company Catalytic isomerization of 2,3,3,3-tetrafluoropropene
KR20230031374A (ko) 2014-02-07 2023-03-07 더 케무어스 컴퍼니 에프씨, 엘엘씨 Z-1,1,1,4,4,4-헥사플루오로-2-부텐의 생산을 위한 통합 공정
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CN102884030A (zh) * 2010-03-26 2013-01-16 霍尼韦尔国际公司 制备六氟-2-丁烯的方法
CN102892736A (zh) * 2010-03-26 2013-01-23 霍尼韦尔国际公司 六氟-2-丁烯的制造方法
WO2011158790A1 (ja) * 2010-06-14 2011-12-22 独立行政法人産業技術総合研究所 フッ素化合物の製造方法
FR2989374A1 (fr) * 2012-04-11 2013-10-18 Arkema France Procede de preparation d'un compose olefinique sous forme d'un isomere specifique.
WO2015059500A1 (en) * 2013-10-25 2015-04-30 Mexichem Amanco Holding S.A. De C.V. Process for the isomerisation of c3-7 (hydro)(halo)fluoroalkenes
CN103755519A (zh) * 2014-02-24 2014-04-30 山东联创节能新材料股份有限公司 六氟丁烯的合成方法

Also Published As

Publication number Publication date
CN107848918A (zh) 2018-03-27
JP2018522908A (ja) 2018-08-16
KR102664130B1 (ko) 2024-05-10
MX2023009585A (es) 2023-08-23
KR20180038006A (ko) 2018-04-13
WO2017027323A1 (en) 2017-02-16
MX2018001489A (es) 2018-04-24
EP3331846B1 (en) 2020-10-28
EP3331846A1 (en) 2018-06-13
US20180215690A1 (en) 2018-08-02
EP3663274B1 (en) 2025-02-19
EP3663274A1 (en) 2020-06-10
US10479745B2 (en) 2019-11-19
JP6930962B2 (ja) 2021-09-01

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