CN107793027A - A kind of ceramic glaze with self-cleaning function - Google Patents
A kind of ceramic glaze with self-cleaning function Download PDFInfo
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- CN107793027A CN107793027A CN201711242812.7A CN201711242812A CN107793027A CN 107793027 A CN107793027 A CN 107793027A CN 201711242812 A CN201711242812 A CN 201711242812A CN 107793027 A CN107793027 A CN 107793027A
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- cleaning function
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
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Abstract
The present invention relates to a kind of ceramic glaze with self-cleaning function, is made up of melilite, white glass, boric acid powder, calcite, kibushi clay, glaze fruit, green glass, tin frit, cupric silicate barium.The present invention a kind of water resistance, the weatherability of the ceramic glaze with self-cleaning function is good, sustainable permanent antibacterial, moreover it is possible to which that decomposing volatile organic matters, self-cleaning function are strong；The ceramic glaze of the present invention is applicable to construction sanitary ceramic, can be applied in the product surface such as concrete slab, plastic plate, plasterboard, paint, plastics, textile, applied widely, has good promotional value；The ceramic glaze preparation technology of the present invention is simple, stable performance, and it is low to prepare cost.
Description
Technical field
The present invention relates to ceramic fabrication technique field, more particularly to a kind of ceramic glaze with self-cleaning function.
Background technology
Glaze is a kind of silicate, and the glaze applied on ware is typically using quartz, feldspar, clay as raw material, ground plus water
After modulation, coated on billet surface, melted through the roasting of certain temperature, when the temperature drops, forming the nature of glass of ceramic surface
Thin layer.It makes ware increase mechanical strength, heat endurance, dielectric strength and the erosion for preventing liquid, gas.Glaze also has increase
Porcelain is attractive in appearance and is easy to wash and wipes, the effect such as is not sticky with by dust.Substantially can be with according to the classification of product and purposes in ceramic industry
It is divided into following a few classes:Lead glaze and leadless glaze；Raw glaze and fritted glaze, ceramic tile, tableware, sanitary ceramics and electroceramics glaze.According to applying
The method of glaze can be divided into immersion oil, glaze spraying, pour glaze；High-temperature glaze, low temperature glaze；Highly expanded glaze, Low Thermal Expantion Glaze；It is coloured glaze, colourless
Glaze；Bright glaze, mat glaze.During using traditional ceramic glaze, the material for waiting dissolving is easily remained in glaze layer, or silicic acid
Zirconium emulsifying agent is crystallized and appeared on the outermost surface of glaze layer, therefore can not obtain the smooth glaze of the surface aesthetic with gloss
The bed of material, it is also easy to cause ceramic surface to be easily infected with spot.
The content of the invention
It is an object of the invention to：For above-mentioned problem, there is provided one kind has self-cleaning function, preparation technology letter
Ceramic glaze single, manufacturing cost is low.
The present invention is achieved by the following technical solutions：
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：68~70 parts of melilite, white glass
10~15 parts, 20~25 parts of boric acid powder, 20~25 parts of calcite, 15~20 parts of kibushi clay, 15~20 parts of glaze fruit, green glass
15~20 parts, 3~4 parts of tin frit, 1~3 part of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, will be above-mentioned
Raw material add pulverizer, are crushed to the mesh of 300 mesh~320, obtain hybrid particles；B, hybrid particles are stirred, 1350
DEG C~1500 DEG C of fusings, and it is incubated 2h~4h；C, it is put into quench in the water that temperature is 15 DEG C~18 DEG C and frit is made, then ultrasonic wave shake
Dynamic 5min~8min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：Melilite 68
Part, 10 parts of white glass, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, tin frit 3
Part, 1 part of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, crushed
To 300 mesh, hybrid particles are obtained；B, hybrid particles are stirred, in 1350 DEG C of fusings, and is incubated 2h；C, being put into temperature is
Quenched in 15 DEG C of water and frit is made, then vibration of ultrasonic wave 5min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：Melilite 70
Part, 15 parts of white glass, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, tin frit 4
Part, 3 parts of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, crushed
To 320 mesh, hybrid particles are obtained；B, hybrid particles are stirred, in 1500 DEG C of fusings, and is incubated 4h；C, being put into temperature is
Quenched in 18 DEG C of water and frit is made, then vibration of ultrasonic wave 8min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：Melilite 69
Part, 12 parts of white glass, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, tin frit
3.5 parts, 2 parts of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, powder
310 mesh are broken to, obtain hybrid particles；B, hybrid particles are stirred, in 1450 DEG C of fusings, and is incubated 3h；C, it is put into temperature
Frit is made to be quenched in 16 DEG C of water, then vibration of ultrasonic wave 6min, produce the ceramic glaze with self-cleaning function.
The raw material being related in this application can obtain in buying on the market.
The beneficial effects of the invention are as follows：
1. the present invention a kind of water resistance, the weatherability of the ceramic glaze with self-cleaning function is good, sustainable permanent antibacterial, moreover it is possible to
Decomposing volatile organic matters, self-cleaning function are strong.
2. a kind of ceramic glaze with self-cleaning function of the present invention is applicable to construction sanitary ceramic, can be applied in mixed
The product surface such as concrete board, plastic plate, plasterboard, paint, plastics, textile, it is applied widely, there is good promotion price
Value.
3. a kind of ceramic glaze preparation technology with self-cleaning function of the present invention is simple, stable performance, and it is low to prepare cost.
Embodiment
This specification（Including any accessory claim, summary）Disclosed in any feature, unless specifically stated otherwise,
Replaced by other equivalent or with similar purpose alternative features.I.e., unless specifically stated otherwise, each feature is a series of
An example in equivalent or similar characteristics.
Embodiment 1：
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：68 parts of melilite, white glass 10
Part, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, 3 parts of tin frit, cupric silicate barium
1 part；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 300 mesh is crushed to, obtains
Hybrid particles；B, hybrid particles are stirred, in 1350 DEG C of fusings, and is incubated 2h；C, it is put into the water that temperature is 15 DEG C and quenches
Frit, then vibration of ultrasonic wave 5min is made, produces the ceramic glaze with self-cleaning function.
Embodiment 2：
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：70 parts of melilite, white glass 15
Part, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, 4 parts of tin frit, cupric silicate barium
3 parts；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 320 mesh is crushed to, obtains
Hybrid particles；B, hybrid particles are stirred, in 1500 DEG C of fusings, and is incubated 4h；C, it is put into the water that temperature is 18 DEG C and quenches
Frit, then vibration of ultrasonic wave 8min is made, produces the ceramic glaze with self-cleaning function.
Embodiment 3：
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight：69 parts of melilite, white glass 12
Part, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, 3.5 parts of tin frit, cupric silicate
2 parts of barium；Preparation process is as follows：A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 310 mesh is crushed to, obtains
To hybrid particles；B, hybrid particles are stirred, in 1450 DEG C of fusings, and is incubated 3h；C, it is put into the water that temperature is 16 DEG C
Quench and frit is made, then vibration of ultrasonic wave 6min, produce the ceramic glaze with self-cleaning function.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (4)
- A kind of 1. ceramic glaze with self-cleaning function, it is characterised in that：It is made up of the component of following parts by weight：Melilite 68 ~70 parts, 10~15 parts of white glass, 20~25 parts of boric acid powder, 20~25 parts of calcite, 15~20 parts of kibushi clay, glaze fruit 15~ 20 parts, 15~20 parts of green glass, 3~4 parts of tin frit, 1~3 part of cupric silicate barium；Preparation process is as follows：A, according to weight deal Raw material is taken, above-mentioned raw material are added into pulverizer, the mesh of 300 mesh~320 is crushed to, obtains hybrid particles；B, hybrid particles are stirred Mix uniformly, in 1350 DEG C~1500 DEG C fusings, and be incubated 2h~4h；C, be put into temperature be quenched in 15 DEG C~18 DEG C of water be made it is molten Block, then vibration of ultrasonic wave 5min~8min, produce the ceramic glaze with self-cleaning function.
- A kind of 2. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that：It is by following parts by weight Component forms：68 parts of melilite, 10 parts of white glass, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, 3 parts of tin frit, 1 part of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, by above-mentioned former material Material adds pulverizer, is crushed to 300 mesh, obtains hybrid particles；B, hybrid particles are stirred, in 1350 DEG C of fusings, and protected Warm 2h；C, it is to quench that frit is made in 15 DEG C of water to be put into temperature, then vibration of ultrasonic wave 5min, is produced described with self-cleaning function Ceramic glaze.
- A kind of 3. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that：It is by following parts by weight Component forms：70 parts of melilite, 15 parts of white glass, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, 4 parts of tin frit, 3 parts of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, by above-mentioned former material Material adds pulverizer, is crushed to 320 mesh, obtains hybrid particles；B, hybrid particles are stirred, in 1500 DEG C of fusings, and protected Warm 4h；C, it is to quench that frit is made in 18 DEG C of water to be put into temperature, then vibration of ultrasonic wave 8min, is produced described with self-cleaning function Ceramic glaze.
- A kind of 4. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that：It is by following parts by weight Component forms：69 parts of melilite, 12 parts of white glass, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, 3.5 parts of tin frit, 2 parts of cupric silicate barium；Preparation process is as follows：A, raw material is measured according to parts by weight, by above-mentioned original Material adds pulverizer, is crushed to 310 mesh, obtains hybrid particles；B, hybrid particles are stirred, in 1450 DEG C of fusings, and It is incubated 3h；C, it is to quench that frit is made in 16 DEG C of water to be put into temperature, then vibration of ultrasonic wave 6min, and producing described has self-cleaning function Ceramic glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711242812.7A CN107793027A (en) | 2017-11-30 | 2017-11-30 | A kind of ceramic glaze with self-cleaning function |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711242812.7A CN107793027A (en) | 2017-11-30 | 2017-11-30 | A kind of ceramic glaze with self-cleaning function |
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| CN107793027A true CN107793027A (en) | 2018-03-13 |
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| CN201711242812.7A Withdrawn CN107793027A (en) | 2017-11-30 | 2017-11-30 | A kind of ceramic glaze with self-cleaning function |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108911702A (en) * | 2018-09-18 | 2018-11-30 | 龙泉瓯江青瓷有限公司 | A kind of hard high-strength reinforcing porcelain |
| CN108911704A (en) * | 2018-09-18 | 2018-11-30 | 龙泉瓯江青瓷有限公司 | A kind of reinforcing porcelain and its production technology |
| CN111204977A (en) * | 2020-01-23 | 2020-05-29 | 福建省德化县尚品陶瓷有限公司 | Self-cleaning nano ceramic glaze convenient to clean and preparation method thereof |
| CN111204979A (en) * | 2020-01-23 | 2020-05-29 | 林丽品 | Ivory white ceramic glaze with self-cleaning function and preparation method thereof |
| CN112374758A (en) * | 2020-11-30 | 2021-02-19 | 江西省星海电瓷制造有限公司 | Self-cleaning glaze for porcelain insulator and preparation method thereof |
| CN115849868A (en) * | 2022-12-07 | 2023-03-28 | 山东电盾科技股份有限公司 | Self-cleaning dry-hanging silicon porcelain plate curtain wall |
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| JP2000257139A (en) * | 1999-03-11 | 2000-09-19 | Toto Ltd | Flush toilet stool |
| CN103102175A (en) * | 2013-01-22 | 2013-05-15 | 广东尚高科技有限公司 | Self-cleaning glaze and application thereof as well as ceramic sanitary ware |
| CN104478487A (en) * | 2014-12-02 | 2015-04-01 | 王松林 | Lang-kiln red glaze and preparation method thereof |
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| CN106698946A (en) * | 2016-12-05 | 2017-05-24 | 广东泓睿科技有限公司 | Preparation technology of underglaze red glaze |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108911702A (en) * | 2018-09-18 | 2018-11-30 | 龙泉瓯江青瓷有限公司 | A kind of hard high-strength reinforcing porcelain |
| CN108911704A (en) * | 2018-09-18 | 2018-11-30 | 龙泉瓯江青瓷有限公司 | A kind of reinforcing porcelain and its production technology |
| CN108911704B (en) * | 2018-09-18 | 2022-01-11 | 龙泉瓯江青瓷有限公司 | Reinforced porcelain and production process thereof |
| CN111204977A (en) * | 2020-01-23 | 2020-05-29 | 福建省德化县尚品陶瓷有限公司 | Self-cleaning nano ceramic glaze convenient to clean and preparation method thereof |
| CN111204979A (en) * | 2020-01-23 | 2020-05-29 | 林丽品 | Ivory white ceramic glaze with self-cleaning function and preparation method thereof |
| CN112374758A (en) * | 2020-11-30 | 2021-02-19 | 江西省星海电瓷制造有限公司 | Self-cleaning glaze for porcelain insulator and preparation method thereof |
| CN115849868A (en) * | 2022-12-07 | 2023-03-28 | 山东电盾科技股份有限公司 | Self-cleaning dry-hanging silicon porcelain plate curtain wall |
| CN115849868B (en) * | 2022-12-07 | 2023-11-07 | 山东电盾科技股份有限公司 | Self-cleaning dry-hanging silicon porcelain plate curtain wall |
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Application publication date: 20180313 |