CN107793027A - A kind of ceramic glaze with self-cleaning function - Google Patents

A kind of ceramic glaze with self-cleaning function Download PDF

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Publication number
CN107793027A
CN107793027A CN201711242812.7A CN201711242812A CN107793027A CN 107793027 A CN107793027 A CN 107793027A CN 201711242812 A CN201711242812 A CN 201711242812A CN 107793027 A CN107793027 A CN 107793027A
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CN
China
Prior art keywords
parts
self
glaze
cleaning function
ceramic glaze
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711242812.7A
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Chinese (zh)
Inventor
符绩承
吴锡银
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Nanning Shengrun Technology Co Ltd
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Nanning Shengrun Technology Co Ltd
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Priority to CN201711242812.7A priority Critical patent/CN107793027A/en
Publication of CN107793027A publication Critical patent/CN107793027A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form

Abstract

The present invention relates to a kind of ceramic glaze with self-cleaning function, is made up of melilite, white glass, boric acid powder, calcite, kibushi clay, glaze fruit, green glass, tin frit, cupric silicate barium.The present invention a kind of water resistance, the weatherability of the ceramic glaze with self-cleaning function is good, sustainable permanent antibacterial, moreover it is possible to which that decomposing volatile organic matters, self-cleaning function are strong;The ceramic glaze of the present invention is applicable to construction sanitary ceramic, can be applied in the product surface such as concrete slab, plastic plate, plasterboard, paint, plastics, textile, applied widely, has good promotional value;The ceramic glaze preparation technology of the present invention is simple, stable performance, and it is low to prepare cost.

Description

A kind of ceramic glaze with self-cleaning function
Technical field
The present invention relates to ceramic fabrication technique field, more particularly to a kind of ceramic glaze with self-cleaning function.
Background technology
Glaze is a kind of silicate, and the glaze applied on ware is typically using quartz, feldspar, clay as raw material, ground plus water After modulation, coated on billet surface, melted through the roasting of certain temperature, when the temperature drops, forming the nature of glass of ceramic surface Thin layer.It makes ware increase mechanical strength, heat endurance, dielectric strength and the erosion for preventing liquid, gas.Glaze also has increase Porcelain is attractive in appearance and is easy to wash and wipes, the effect such as is not sticky with by dust.Substantially can be with according to the classification of product and purposes in ceramic industry It is divided into following a few classes:Lead glaze and leadless glaze;Raw glaze and fritted glaze, ceramic tile, tableware, sanitary ceramics and electroceramics glaze.According to applying The method of glaze can be divided into immersion oil, glaze spraying, pour glaze;High-temperature glaze, low temperature glaze;Highly expanded glaze, Low Thermal Expantion Glaze;It is coloured glaze, colourless Glaze;Bright glaze, mat glaze.During using traditional ceramic glaze, the material for waiting dissolving is easily remained in glaze layer, or silicic acid Zirconium emulsifying agent is crystallized and appeared on the outermost surface of glaze layer, therefore can not obtain the smooth glaze of the surface aesthetic with gloss The bed of material, it is also easy to cause ceramic surface to be easily infected with spot.
The content of the invention
It is an object of the invention to:For above-mentioned problem, there is provided one kind has self-cleaning function, preparation technology letter Ceramic glaze single, manufacturing cost is low.
The present invention is achieved by the following technical solutions:
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:68~70 parts of melilite, white glass 10~15 parts, 20~25 parts of boric acid powder, 20~25 parts of calcite, 15~20 parts of kibushi clay, 15~20 parts of glaze fruit, green glass 15~20 parts, 3~4 parts of tin frit, 1~3 part of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, will be above-mentioned Raw material add pulverizer, are crushed to the mesh of 300 mesh~320, obtain hybrid particles;B, hybrid particles are stirred, 1350 DEG C~1500 DEG C of fusings, and it is incubated 2h~4h;C, it is put into quench in the water that temperature is 15 DEG C~18 DEG C and frit is made, then ultrasonic wave shake Dynamic 5min~8min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:Melilite 68 Part, 10 parts of white glass, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, tin frit 3 Part, 1 part of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, crushed To 300 mesh, hybrid particles are obtained;B, hybrid particles are stirred, in 1350 DEG C of fusings, and is incubated 2h;C, being put into temperature is Quenched in 15 DEG C of water and frit is made, then vibration of ultrasonic wave 5min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:Melilite 70 Part, 15 parts of white glass, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, tin frit 4 Part, 3 parts of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, crushed To 320 mesh, hybrid particles are obtained;B, hybrid particles are stirred, in 1500 DEG C of fusings, and is incubated 4h;C, being put into temperature is Quenched in 18 DEG C of water and frit is made, then vibration of ultrasonic wave 8min, produce the ceramic glaze with self-cleaning function.
Preferably, a kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:Melilite 69 Part, 12 parts of white glass, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, tin frit 3.5 parts, 2 parts of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, powder 310 mesh are broken to, obtain hybrid particles;B, hybrid particles are stirred, in 1450 DEG C of fusings, and is incubated 3h;C, it is put into temperature Frit is made to be quenched in 16 DEG C of water, then vibration of ultrasonic wave 6min, produce the ceramic glaze with self-cleaning function.
The raw material being related in this application can obtain in buying on the market.
The beneficial effects of the invention are as follows:
1. the present invention a kind of water resistance, the weatherability of the ceramic glaze with self-cleaning function is good, sustainable permanent antibacterial, moreover it is possible to Decomposing volatile organic matters, self-cleaning function are strong.
2. a kind of ceramic glaze with self-cleaning function of the present invention is applicable to construction sanitary ceramic, can be applied in mixed The product surface such as concrete board, plastic plate, plasterboard, paint, plastics, textile, it is applied widely, there is good promotion price Value.
3. a kind of ceramic glaze preparation technology with self-cleaning function of the present invention is simple, stable performance, and it is low to prepare cost.
Embodiment
This specification(Including any accessory claim, summary)Disclosed in any feature, unless specifically stated otherwise, Replaced by other equivalent or with similar purpose alternative features.I.e., unless specifically stated otherwise, each feature is a series of An example in equivalent or similar characteristics.
Embodiment 1:
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:68 parts of melilite, white glass 10 Part, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, 3 parts of tin frit, cupric silicate barium 1 part;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 300 mesh is crushed to, obtains Hybrid particles;B, hybrid particles are stirred, in 1350 DEG C of fusings, and is incubated 2h;C, it is put into the water that temperature is 15 DEG C and quenches Frit, then vibration of ultrasonic wave 5min is made, produces the ceramic glaze with self-cleaning function.
Embodiment 2:
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:70 parts of melilite, white glass 15 Part, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, 4 parts of tin frit, cupric silicate barium 3 parts;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 320 mesh is crushed to, obtains Hybrid particles;B, hybrid particles are stirred, in 1500 DEG C of fusings, and is incubated 4h;C, it is put into the water that temperature is 18 DEG C and quenches Frit, then vibration of ultrasonic wave 8min is made, produces the ceramic glaze with self-cleaning function.
Embodiment 3:
A kind of ceramic glaze with self-cleaning function, is made up of the component of following parts by weight:69 parts of melilite, white glass 12 Part, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, 3.5 parts of tin frit, cupric silicate 2 parts of barium;Preparation process is as follows:A, raw material is measured according to parts by weight, above-mentioned raw material is added into pulverizer, 310 mesh is crushed to, obtains To hybrid particles;B, hybrid particles are stirred, in 1450 DEG C of fusings, and is incubated 3h;C, it is put into the water that temperature is 16 DEG C Quench and frit is made, then vibration of ultrasonic wave 6min, produce the ceramic glaze with self-cleaning function.
Although above the present invention is described in detail with a general description of the specific embodiments, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (4)

  1. A kind of 1. ceramic glaze with self-cleaning function, it is characterised in that:It is made up of the component of following parts by weight:Melilite 68 ~70 parts, 10~15 parts of white glass, 20~25 parts of boric acid powder, 20~25 parts of calcite, 15~20 parts of kibushi clay, glaze fruit 15~ 20 parts, 15~20 parts of green glass, 3~4 parts of tin frit, 1~3 part of cupric silicate barium;Preparation process is as follows:A, according to weight deal Raw material is taken, above-mentioned raw material are added into pulverizer, the mesh of 300 mesh~320 is crushed to, obtains hybrid particles;B, hybrid particles are stirred Mix uniformly, in 1350 DEG C~1500 DEG C fusings, and be incubated 2h~4h;C, be put into temperature be quenched in 15 DEG C~18 DEG C of water be made it is molten Block, then vibration of ultrasonic wave 5min~8min, produce the ceramic glaze with self-cleaning function.
  2. A kind of 2. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that:It is by following parts by weight Component forms:68 parts of melilite, 10 parts of white glass, 20 parts of boric acid powder, 20 parts of calcite, 15 parts of kibushi clay, 15 parts of glaze fruit, 15 parts of green glass, 3 parts of tin frit, 1 part of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, by above-mentioned former material Material adds pulverizer, is crushed to 300 mesh, obtains hybrid particles;B, hybrid particles are stirred, in 1350 DEG C of fusings, and protected Warm 2h;C, it is to quench that frit is made in 15 DEG C of water to be put into temperature, then vibration of ultrasonic wave 5min, is produced described with self-cleaning function Ceramic glaze.
  3. A kind of 3. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that:It is by following parts by weight Component forms:70 parts of melilite, 15 parts of white glass, 25 parts of boric acid powder, 25 parts of calcite, 20 parts of kibushi clay, 20 parts of glaze fruit, 20 parts of green glass, 4 parts of tin frit, 3 parts of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, by above-mentioned former material Material adds pulverizer, is crushed to 320 mesh, obtains hybrid particles;B, hybrid particles are stirred, in 1500 DEG C of fusings, and protected Warm 4h;C, it is to quench that frit is made in 18 DEG C of water to be put into temperature, then vibration of ultrasonic wave 8min, is produced described with self-cleaning function Ceramic glaze.
  4. A kind of 4. ceramic glaze with self-cleaning function according to claim 1, it is characterised in that:It is by following parts by weight Component forms:69 parts of melilite, 12 parts of white glass, 22 parts of boric acid powder, 23 parts of calcite, 18 parts of kibushi clay, 18 parts of glaze fruit, 17 parts of green glass, 3.5 parts of tin frit, 2 parts of cupric silicate barium;Preparation process is as follows:A, raw material is measured according to parts by weight, by above-mentioned original Material adds pulverizer, is crushed to 310 mesh, obtains hybrid particles;B, hybrid particles are stirred, in 1450 DEG C of fusings, and It is incubated 3h;C, it is to quench that frit is made in 16 DEG C of water to be put into temperature, then vibration of ultrasonic wave 6min, and producing described has self-cleaning function Ceramic glaze.
CN201711242812.7A 2017-11-30 2017-11-30 A kind of ceramic glaze with self-cleaning function Withdrawn CN107793027A (en)

Priority Applications (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108911704A (en) * 2018-09-18 2018-11-30 龙泉瓯江青瓷有限公司 A kind of reinforcing porcelain and its production technology
CN108911702A (en) * 2018-09-18 2018-11-30 龙泉瓯江青瓷有限公司 A kind of hard high-strength reinforcing porcelain
CN111204977A (en) * 2020-01-23 2020-05-29 福建省德化县尚品陶瓷有限公司 Self-cleaning nano ceramic glaze convenient to clean and preparation method thereof
CN111204979A (en) * 2020-01-23 2020-05-29 林丽品 Ivory white ceramic glaze with self-cleaning function and preparation method thereof
CN112374758A (en) * 2020-11-30 2021-02-19 江西省星海电瓷制造有限公司 Self-cleaning glaze for porcelain insulator and preparation method thereof
CN115849868A (en) * 2022-12-07 2023-03-28 山东电盾科技股份有限公司 Self-cleaning dry-hanging silicon porcelain plate curtain wall

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000257139A (en) * 1999-03-11 2000-09-19 Toto Ltd Flush toilet stool
CN103102175A (en) * 2013-01-22 2013-05-15 广东尚高科技有限公司 Self-cleaning glaze and application thereof as well as ceramic sanitary ware
CN104478487A (en) * 2014-12-02 2015-04-01 王松林 Lang-kiln red glaze and preparation method thereof
CN104496554A (en) * 2014-12-03 2015-04-08 张幼兰 Jun red glaze and preparation method thereof
CN106518164A (en) * 2016-12-05 2017-03-22 广东泓睿科技有限公司 Preparation technology for glaze surface of Jun red glaze
CN106698946A (en) * 2016-12-05 2017-05-24 广东泓睿科技有限公司 Preparation technology of underglaze red glaze
CN106746663A (en) * 2016-12-05 2017-05-31 广东泓睿科技有限公司 A kind of preparation technology of ox-blood glaze glaze paint
CN107311619A (en) * 2017-07-06 2017-11-03 董孟富 The production method of novel antibacterial ceramics

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000257139A (en) * 1999-03-11 2000-09-19 Toto Ltd Flush toilet stool
CN103102175A (en) * 2013-01-22 2013-05-15 广东尚高科技有限公司 Self-cleaning glaze and application thereof as well as ceramic sanitary ware
CN104478487A (en) * 2014-12-02 2015-04-01 王松林 Lang-kiln red glaze and preparation method thereof
CN104496554A (en) * 2014-12-03 2015-04-08 张幼兰 Jun red glaze and preparation method thereof
CN106518164A (en) * 2016-12-05 2017-03-22 广东泓睿科技有限公司 Preparation technology for glaze surface of Jun red glaze
CN106698946A (en) * 2016-12-05 2017-05-24 广东泓睿科技有限公司 Preparation technology of underglaze red glaze
CN106746663A (en) * 2016-12-05 2017-05-31 广东泓睿科技有限公司 A kind of preparation technology of ox-blood glaze glaze paint
CN107311619A (en) * 2017-07-06 2017-11-03 董孟富 The production method of novel antibacterial ceramics

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108911704A (en) * 2018-09-18 2018-11-30 龙泉瓯江青瓷有限公司 A kind of reinforcing porcelain and its production technology
CN108911702A (en) * 2018-09-18 2018-11-30 龙泉瓯江青瓷有限公司 A kind of hard high-strength reinforcing porcelain
CN108911704B (en) * 2018-09-18 2022-01-11 龙泉瓯江青瓷有限公司 Reinforced porcelain and production process thereof
CN111204977A (en) * 2020-01-23 2020-05-29 福建省德化县尚品陶瓷有限公司 Self-cleaning nano ceramic glaze convenient to clean and preparation method thereof
CN111204979A (en) * 2020-01-23 2020-05-29 林丽品 Ivory white ceramic glaze with self-cleaning function and preparation method thereof
CN112374758A (en) * 2020-11-30 2021-02-19 江西省星海电瓷制造有限公司 Self-cleaning glaze for porcelain insulator and preparation method thereof
CN115849868A (en) * 2022-12-07 2023-03-28 山东电盾科技股份有限公司 Self-cleaning dry-hanging silicon porcelain plate curtain wall
CN115849868B (en) * 2022-12-07 2023-11-07 山东电盾科技股份有限公司 Self-cleaning dry-hanging silicon porcelain plate curtain wall

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Application publication date: 20180313