CN107700232B - 一种发泡涂层内打灯广告布及其制备工艺 - Google Patents

一种发泡涂层内打灯广告布及其制备工艺 Download PDF

Info

Publication number
CN107700232B
CN107700232B CN201710910907.5A CN201710910907A CN107700232B CN 107700232 B CN107700232 B CN 107700232B CN 201710910907 A CN201710910907 A CN 201710910907A CN 107700232 B CN107700232 B CN 107700232B
Authority
CN
China
Prior art keywords
coating
parts
whitening
foaming
retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710910907.5A
Other languages
English (en)
Other versions
CN107700232A (zh
Inventor
王冰心
马天凤
徐建增
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roushi Intelligent Technology (Shandong) Co.,Ltd.
Original Assignee
Weifang Jiacheng Digital Supplies Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Weifang Jiacheng Digital Supplies Co ltd filed Critical Weifang Jiacheng Digital Supplies Co ltd
Priority to CN201710910907.5A priority Critical patent/CN107700232B/zh
Publication of CN107700232A publication Critical patent/CN107700232A/zh
Application granted granted Critical
Publication of CN107700232B publication Critical patent/CN107700232B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/19—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

本发明涉及一种广告布，尤其涉及一种发泡涂层内打灯广告布，包括基布层，基布层的上、下两面分别涂布有增白防水层，其中一面的增白防水层的表面涂布有发泡阻燃涂层，所述发泡阻燃涂层的表面涂布有墨水接收涂层；本发明还公开了其制备工艺，包括增白防水涂层的涂布、发泡阻燃涂层的涂布和墨水吸收涂层的涂布，本发明中的广告布具有阻燃、抗褶皱、质量轻、手感好、打印画质细腻。

Description

一种发泡涂层内打灯广告布及其制备工艺
技术领域
本发明涉及一种广告布，尤其涉及一种发泡涂层内打灯广告布及其制备工艺。
背景技术
传统广告布，在内打灯灯箱布方面，在实际使用时存在阻燃效果差、容易产生皱褶、柔软性差、打印画质差等问题。而且现有的广告布主要以接触式刮涂或间隙式不发泡涂布为主，在实际生产中采用接触式刮刀涂布，涂布量小，不能一次获得高的涂布量。间隙式不发泡涂布，可以获得较大的涂布量，但干燥慢，而且如果干燥过急，会存在龟裂的弊端。因此针对上述问题，有必要开发一种内打灯用广告布及其制备工艺。
发明内容
本发明所要解决的技术问题是：针对现有技术的不足，提供一种具有高阻燃、抗褶皱、质量轻、手感好、打印画质细腻的发泡涂层内打灯广告布。
为解决上述技术问题，本发明的技术方案是：
一种发泡涂层内打灯广告布，包括基布层，所述基布层的上、下两面分别涂布有增白防水层，其中一面的增白防水层的表面涂布有发泡阻燃涂层，所述发泡阻燃涂层的表面涂布有墨水吸收涂层；
其中所述发泡阻燃涂层为纺织乳液50-80份、发泡剂10-15份、稳泡剂40-60份、滑石粉2-10份、高岭土10-20份、纳米碳酸钙2-10份、钛白粉分散液10-20份、复合型阻燃剂40-80份复合涂布在所述增白防水层的表面所形成的涂层。
作为一种优选的技术方案，所述发泡剂为十二烷基硫酸钠或脂肪醇聚氧乙烯醚硫酸钠；所述稳泡剂为硬脂酸钠或硬脂酸铵；所述复合型阻燃剂为三氧化二锑10-20份、三氧化铝10-30份、聚磷酸铵阻燃剂20-30份中任意两种或三种组合。
作为一种改进的技术方案，所述增白防水涂层为水500-1000份、荧光增白剂5-10份、有机氟防水防油剂40-60份复合分别涂布在所述基布层的上、下两面所形成的涂层。
作为一种优选的技术方案，所述荧光增白剂为双苯乙烯型衍生物。
作为一种改进的技术方案，所述墨水吸收涂层为聚丙烯酸乳液50-80份、聚乙烯蜡2-10份、二氧化硅10-20份、消泡剂0.2-1份复合涂布在所述发泡阻燃涂层的表面所形成的涂层。
作为一种优选的技术方案，所述消泡剂为矿物油类、有机硅类、聚醚类中的任意一种。
本发明要解决的另一个技术问题是：提供一种具有高阻燃、抗褶皱、质量轻、手感好、打印画质细腻的发泡涂层内打灯广告布的制备工艺。
为解决上述技术问题，本发明的技术方案是：
一种发泡涂层内打灯广告布的制备工艺，所述制备工艺包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将500-1000份水、5-10份荧光增白剂、40-60份有机氟防水防油剂,混匀调pH至5-6，得到固含量为0.2-1％的增白防水涂料；采用单次轧液方式，在压辊压力为0.3-0.6MPa条件下将增白防水涂料分别涂布在坯布的上、下两面，经过干燥固化处理，形成增白防水涂层；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液50-80份、发泡剂10-15份、稳泡剂40-60份、滑石粉2-10份、高岭土10-20份、纳米碳酸钙2-10份、钛白粉分散液10-20份、复合型阻燃剂40-80份，混匀调pH至8-10，得到粘度为2000-5000cps，发泡倍率为2-5倍，固含量为40±2％的发泡阻燃涂料；采用辊筒间隙式将发泡阻燃涂料涂布在防水增白处理后的坯布表面，经过干燥固化处理，形成发泡阻燃涂层；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液50-80份、聚乙烯蜡2-10份、二氧化硅10-20份、消泡剂0.2-1份，混匀调pH7-9，得到粘度为5000-10000cps，固含量为50±2％的墨水吸收涂料；采用底板刮刀式将墨水吸收涂料涂布在发泡阻燃处理后的坯布表面，经过干燥固化处理，形成墨水吸收涂层；再经过收卷、质量检验、分切包装得到发泡涂层内打灯广告布。
作为一种优选的技术方案，步骤(1)、步骤(2)和步骤(3)均采用8节烘箱进行干燥固化处理；其中步骤(1)干燥固化处理时，第一节烘箱温度控制在110-128℃，第二节烘箱温度控制在140-160℃，第三节和第四节烘箱的温度控制在150-170℃，第五节烘箱温度控制在160-180℃，第六节和第七节烘箱的温度控制在170-190℃，第八节烘箱温度控制在150-170℃；
步骤(2)干燥固化处理时，第一节烘箱温度设置为110-130℃，第二节烘箱温度控制在140-160℃，第三节至第五节烘箱温度控制在150-170℃，第六节和第七节烘箱的温度控制在160℃-180℃，第八节烘箱的温度控制在140-160℃；
步骤(3)干燥固化处理时，第一节烘箱温度控制在110-130℃，第二节烘箱至第七节烘箱温度分别控制在160-180℃，第八节烘箱温度控制在140-160℃。
作为一种优选的技术方案，步骤(1)中增白防水涂料的涂布湿量为40-50gsm，涂布车速为40-50m/min；
步骤(2)中发泡阻燃涂料的涂布湿量为75-500gsm，涂布车速为10-25m/min；
步骤(3)中墨水吸收涂料的涂布湿量为40-60gsm，涂布车速为20-30m/min。
采用了上述技术方案后，本发明的有益效果是：
(1)本发明提供的内打灯广告布的基布层上涂布有发泡阻燃涂层，且发泡阻燃涂料为纺织乳液、发泡剂、硬脂酸铵、滑石粉、高岭土、纳米碳酸钙、钛白粉分散液、复合型阻燃剂复合而成，采用上述配方中的发泡阻燃涂料可使产品具有较好的阻燃性能；涂料经发泡处理后，涂料密度变小，渗透性变差，涂布时渗入丝线内部的物料变少，涂布出的产品，更加柔软，提高了耐褶皱性；
(2)本发明采用辊筒间隙式涂布，利用5mm“R”型刀涂布，控制发泡涂料粘度及涂布车速，将涂料涂布在基布层表面，与现有技术相比本产品的涂布量容易控制，所以阻燃效果可以通过涂布量来控制；而且产品透光手抓黑痕效果好，抗褶皱、手感好；面涂后，该产品在线进行轧平处理，使表面变得非常平滑，打印画质细腻；
(3)传统底板刮涂涂布量较小，只能采取多次涂布的方式获得更大的涂布量，本申请采用辊筒间隙涂布，只需要涂布一次，便可以涂布较大的克重，而且克重可控制的范围更大；与现有技术相比缩短了大克重涂布的工序，节约了工时；而且大涂布量使产品的阻燃更加好控制；
(4)由于发泡涂布比传统底板刮涂渗透性小，涂布后成品的涂层基本都在基材表面，经在线轧平处理后，在基材表面形成一层很平的膜层，打印后图像更加细腻，颜色更加鲜艳；
(5)发泡后，涂层存在许多微孔结构，相同克重的发泡涂层，显的更加厚实，而且柔软，提高了产品的档次。
附图说明
图1为本发明一种发泡涂层内打灯广告布的剖面结构图；
其中，1-基布层，2，3-增白防水层，4-发泡阻燃涂层，5-墨水吸收涂层。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合附图和实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种发泡涂层内打灯广告布，如图1所示，包括基布层1(涤纶化纤布)，基布层1的上、下两面分别涂布有增白防水层2，其中一面的增白防水层2的表面涂布有发泡阻燃涂层4，发泡阻燃涂层4的表面涂布有墨水吸收涂层5；
其中发泡阻燃涂层为纺织乳液50份、发泡剂10份(十二烷基硫酸钠)、稳泡剂40份(硬脂酸铵)、滑石粉2份、高岭土10份、纳米碳酸钙2份、钛白粉分散液10份、复合型阻燃剂40份(三氧化二锑10份和聚磷酸铵30份)复合涂布在所述增白防水层的表面所形成的涂层。
增白防水涂层为水500份、荧光增白剂5份(双苯乙烯型衍生物)、有机氟防水防油剂40份复合分别涂布在基布层的上、下两面所形成的涂层。
墨水吸收涂层为聚丙烯酸乳液50份、聚乙烯蜡2份、二氧化硅10份、消泡剂0.2份(矿物油类)复合涂布在发泡阻燃涂层的表面所形成的涂层。
其制备工艺，包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将水500份、荧光增白剂5份、有机氟防水防油剂40份,混匀，调pH至5.3，得到固含量为0.2-0.5％的增白防水涂料；采用单次轧液方式，压辊压力为0.4MPa，涂布车速为40-50m/min，按照涂布湿量为40-50gsm的涂布量将增白防水涂料分别涂布在坯布的上、下两面，经过8节烘箱干燥固化处理，形成增白防水涂层；烘箱温度依次设置为110℃、140℃、150℃、150℃、160℃、170℃、170℃和160；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液50份、发泡剂10份、稳泡剂40份、滑石粉2份、高岭土10份、纳米碳酸钙2份、钛白粉分散液10份、复合型阻燃剂40份，混匀调pH至8.5，得到粘度为2000-3000cps/4#,60RPM，25℃，发泡倍率为4-5倍，固含量为的发泡阻燃涂料；采用辊筒间隙式，5mm“R”型刀涂布，涂布车速为15-20m/min，按照涂布湿量为40-60gsm的涂布量将发泡阻燃涂料涂布在防水增白处理后的坯布表面，经过8节烘箱干燥固化处理，形成涂布干量为20-30克的发泡阻燃涂层；烘箱温度依次设置为110℃、140℃、150℃、150℃、150℃、160℃、160℃和140；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液50份、聚乙烯蜡2份、二氧化硅10份、消泡剂0.5份，混匀调pH7.8，得到粘度为5000-6000cps/4#,60RPM，25℃的墨水吸收涂料；选用8mm“E”型刀，按照涂布车速为20-30m/min，涂布湿量为40-50gsm的涂布量将墨水吸收涂料涂布在发泡阻燃处理后的坯布表面，经过8节烘箱干燥固化处理，形成涂布干量20-25gsm的墨水吸收涂层；其中烘箱温度依次设置为110℃、160℃、160℃、160℃、160℃、160℃、160℃和140；
实施例2
一种发泡涂层内打灯广告布，如图1所示，包括基布层1(涤纶化纤布)，基布层1的上、下两面分别涂布有增白防水层2，其中一面的增白防水层2的表面涂布有发泡阻燃涂层4，发泡阻燃涂层5的表面涂布有墨水吸收涂层5；
其中发泡阻燃涂层为纺织乳液65份、发泡剂12份(十二烷基硫酸钠)、稳泡剂45份(硬脂酸铵)、滑石粉4份、高岭土15份、纳米碳酸钙5份、钛白粉分散液15份、复合型阻燃剂50份(三氧化二锑20份和三氧化铝30份)复合涂布在增白防水层的表面所形成的涂层。
增白防水涂层为水650份、荧光增白剂7份(双苯乙烯型衍生物)、有机氟防水防油剂50份复合分别涂布在基布层的上、下两面所形成的涂层。
墨水吸收涂层为聚丙烯酸乳液60份、聚乙烯蜡5份、二氧化硅15份、消泡剂0.5份(有机硅类)复合涂布在发泡阻燃涂层的表面所形成的涂层。
其制备工艺，包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将水650份、荧光增白剂7份、有机氟防水防油剂50份,混匀调pH至5.3，得到固含量为0.2-0.5％的增白防水涂料；采用单次轧液方式，压辊压力为0.4MPa，涂布车速为40-50m/min，按照涂布湿量为40-50gsm的涂布量将增白防水涂料分别涂布在坯布的上、下两面，经过8节烘箱干燥固化处理，形成增白防水涂层；烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、180℃、180℃和180；；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液65份、发泡剂12份、稳泡剂45份、滑石粉4份、高岭土15份、纳米碳酸钙5份、钛白粉分散液15份、复合型阻燃剂50份，混匀调pH至8.5，得到粘度为2000-3000cps，发泡倍率为4-5倍，固含量为40±2％的发泡阻燃涂料；采用辊筒间隙式，5mm“R”型刀涂布，涂布车速为15-20m/min，按照涂布湿量60-100gsm的涂布量将发泡阻燃涂料涂布在防水增白处理后的坯布表面，经过8节烘箱干燥固化处理，形成涂布干量为30-50克的发泡阻燃涂层；烘箱温度依次设置为120℃、150℃、160℃、160℃、160℃、170℃、170℃、150℃；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液60份、聚乙烯蜡5份、二氧化硅15份、消泡剂0.5份，混匀调pH7.8，得到粘度为5000-6000cps/4#,60RPM，25℃，固含量为50±2％的墨水吸收涂料；选用8mm“E”型刀，按照涂布车速为20-30m/min，涂布湿量为40-50gsm的涂布量将墨水吸收涂料涂布在发泡阻燃处理后的坯布表面，经过8节烘箱干燥固化处理，形成涂布干量20-25gsm的墨水吸收涂层；其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、150℃。
实施例3
一种发泡涂层内打灯广告布，如图1所示，包括基布层1(涤纶化纤布)，基布层1的上、下两面分别涂布有增白防水层2，其中一面的增白防水层2的表面涂布有发泡阻燃涂层4，发泡阻燃涂层4的表面涂布有墨水吸收涂层5；
其中发泡阻燃涂层为纺织乳液70份、发泡剂13份(十二烷基硫酸钠)、稳泡剂53份(硬脂酸铵)、滑石粉6份、高岭土18份、纳米碳酸钙8份、钛白粉分散液18份、复合型阻燃剂60份(三氧化铝30份和聚磷酸铵阻燃剂30份)复合涂布在增白防水层的表面所形成的涂层。
增白防水涂层为水800份、荧光增白剂9份(双苯乙烯型衍生物)、有机氟防水防油剂55份复合分别涂布在基布层的上、下两面所形成的涂层。
墨水吸收涂层为聚丙烯酸乳液70份、聚乙烯蜡8份、二氧化硅18份、消泡剂0.8份(聚醚类)复合涂布在发泡阻燃涂层的表面所形成的涂层。
其制备工艺，包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将水800份、9份荧光增白剂、55份有机氟防水防油剂，混匀调pH至5.5，得到固含量为0.5-0.8％的增白防水涂料；采用单次轧液方式，压辊压力为0.5MPa，涂布速度为45m/min，按照涂布湿量为40gsm的涂布量将增白防水涂料分别涂布在坯布的上、下两面，经过8节烘箱干燥固化处理，形成增白防水涂层；其中烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、180℃、180℃和160；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液70份、发泡剂13份、稳泡剂53份、滑石粉6份、高岭土18份、纳米碳酸钙8份、钛白粉分散液18份、复合型阻燃剂70份，混匀调pH至9.3，得到粘度为2000-3000cps，发泡倍率为3-4倍，固含量为40±2％的发泡阻燃涂料；采用辊筒间隙式，用5mm“R”型刀涂布，涂布车速为15-20m/min，按照涂布湿量为100-200gsm的涂布量将发泡阻燃涂料涂布在防水增白处理后的坯布表面，经过8节烘箱干燥固化处理，形成涂布干量为50-100gsm的发泡阻燃涂层；其中烘箱的温度依次设置为120℃、150℃、160℃、160℃、160℃、170℃、170℃、160℃；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液70份、聚乙烯蜡8份、二氧化硅18份、消泡剂0.8份，混匀调pH8.7，得到粘度为6000-8000cps，固含量为50±2％的墨水吸收涂料；采用底板刮刀式选用9mm E型刀，涂布车速为20-30m/min，按照涂布湿量为50-60gsm的涂布量将墨水吸收涂料涂布在发泡阻燃涂层的表面，经过8节烘箱干燥固化处理，形成涂布干量25-30gsm的墨水吸收涂层；其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、160℃。
实施例4
一种发泡涂层内打灯广告布，如图1所示，包括基布层1(涤纶化纤布)，基布层1的上、下两面分别涂布有增白防水层2，其中一面的增白防水层2的表面涂布有发泡阻燃涂层4，发泡阻燃涂层4的表面涂布有墨水吸收涂层5；
其中发泡阻燃涂层为纺织乳液80份、发泡剂(十二烷基硫酸钠)15份、稳泡剂(硬脂酸铵)60份、滑石粉10份、高岭土20份、纳米碳酸钙10份、钛白粉分散液20份、复合型阻燃剂80份(20份三氧化二锑、30份三氧化铝和30份聚磷酸铵的组合)复合涂布在增白防水层的表面所形成的涂层。
增白防水涂层为1000份水、荧光增白剂(双苯乙烯型衍生物)10份、有机氟防水防油剂60份复合分别涂布在基布层的上、下两面所形成的涂层。
墨水吸收涂层为聚丙烯酸乳液80份、聚乙烯蜡10份、二氧化硅20份、消泡剂(有机硅类)1份复合涂布在发泡阻燃涂层的表面所形成的涂层。
一种发泡内打灯广告布的制备工艺，包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将1000份水、10份荧光增白剂、60份有机氟防水防油剂,混匀调pH至6，得到固含量为0.8-1％的增白防水涂料；采用单次轧液方式，压辊压力为0.6MPa，涂布车速为40-50m/min按照涂布湿量为45-50gsm的涂布量将增白防水涂料分别涂布在坯布的上、下两面，经过8节烘箱干燥固化处理，形成增白防水涂层；其中烘箱温度依次设置为120℃、150℃、160℃、160℃、170℃、185℃、185℃和160；；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液80份、发泡剂15份、稳泡剂60份、滑石粉10份、高岭土20份、纳米碳酸钙10份、钛白粉分散液20份、复合型阻燃剂80份，混匀调pH至9.8，得到粘度为3000-4000cps/4#,60RPM，25℃，发泡倍率为2-3倍的发泡阻燃涂料；采用辊筒间隙式，利用5mm“R”型刀涂布，涂布车速10-15m/min，按照涂布湿量为200-400gsm的涂布量将发泡阻燃涂料涂布在防水增白涂层的表面，经过8节烘箱干燥固化处理，形成涂布干量为100-200gsm的发泡阻燃涂层；烘箱温度依次设置为120℃、150℃、160℃、160℃、160℃、170℃、170℃、150℃；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液80份、聚乙烯蜡10份、二氧化硅20份、消泡剂1份，混匀调pH9，得到粘度为8000-10000cps/4#,60RPM，25℃，固含量为50±2％的墨水吸收涂料；采用底板刮刀式选用9mm“E”型刀涂布，涂布车速为20-30m/min，按照涂布湿量为50-60gsm的涂布量将墨水吸收涂料涂布在发泡阻燃涂层的表面，经过8节烘箱干燥固化处理，形成涂布干量为25-30gsm的墨水吸收涂层；其中烘箱温度依次设置为120℃、170℃、170℃、170℃、170℃、170℃、170℃、150℃。
表1
Figure BDA0001424880110000091
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种发泡涂层内打灯广告布，包括基布层，其特征在于：所述基布层的上、下两面分别涂布有增白防水层，其中一面的增白防水层的表面涂布有发泡阻燃涂层，所述发泡阻燃涂层的表面涂布有墨水吸收涂层；
其中所述发泡阻燃涂层为纺织乳液50-80份、发泡剂10-15份、稳泡剂40-60份、滑石粉2-10份、高岭土10-20份、纳米碳酸钙2-10份、钛白粉分散液10-20份、复合型阻燃剂40-80份复合涂布在所述增白防水层的表面所形成的涂层；
所述增白防水涂层为水500-1000份、荧光增白剂5-10份、有机氟防水防油剂40-60份复合分别涂布在所述基布层的上、下两面所形成的涂层；
所述墨水吸收涂层为聚丙烯酸乳液50-80份、聚乙烯蜡2-10份、二氧化硅10-20份、消泡剂0.2-1份复合涂布在所述发泡阻燃涂层的表面所形成的涂层。
2.根据权利要求1所述的一种发泡涂层内打灯广告布，其特征在于:所述发泡剂为十二烷基硫酸钠或脂肪醇聚氧乙烯醚硫酸钠；所述稳泡剂为硬脂酸钠或硬脂酸铵；所述复合型阻燃剂为三氧化二锑10-20份、三氧化铝10-30份、聚磷酸铵阻燃剂20-30份中任意两种或三种组合。
3.根据权利要求1所述的一种发泡涂层内打灯广告布，其特征在于:所述荧光增白剂为双苯乙烯型衍生物。
4.根据权利要求1所述的一种发泡涂层内打灯广告布，其特征在于:所述消泡剂为矿物油类、有机硅类或聚醚类。
5.一种发泡涂层内打灯广告布的制备工艺，其特征在于:所述制备工艺包括以下步骤：
(1)增白防水涂层的涂布
按照重量份计将500-1000份水、荧光增白剂5-10份、有机氟防水防油剂40-60份,混匀调pH至5-6，得到固含量为0.2-1％的增白防水涂料；采用单次轧液方式，在压辊压力为0.3-0.6MPa条件下将增白防水涂料分别涂布在坯布的上、下两面，经过干燥固化处理，形成增白防水涂层；
(2)发泡阻燃涂层的涂布
按照重量份计将纺织乳液50-80份、发泡剂10-15份、稳泡剂40-60份、滑石粉2-10份、高岭土10-20份、纳米碳酸钙2-10份、钛白粉分散液10-20份、复合型阻燃剂40-80份，混匀调pH至8-10，得到粘度为2000-5000cps，发泡倍率为2-5倍，固含量为40±2％的发泡阻燃涂料；采用辊筒间隙式将发泡阻燃涂料涂布在防水增白处理后的坯布表面，经过干燥固化处理，形成发泡阻燃涂层；
(3)墨水吸收涂层的涂布
按照重量份计将聚丙烯酸乳液50-80份、聚乙烯蜡2-10份、二氧化硅10-20份、消泡剂0.2-1份，混匀调pH7-9，得到粘度为5000-10000cps，固含量为50±2％的墨水吸收涂料；采用底板刮刀式将墨水吸收涂料涂布在发泡阻燃处理后的坯布表面，经过干燥固化处理，形成墨水吸收涂层，再经过收卷，质量检验，分切包装得到发泡涂层内打灯广告布。
6.根据权利要求5所述的一种发泡涂层内打灯广告布的制备工艺，其特征在于:步骤(1)、步骤(2)和步骤(3)均采用8节烘箱进行干燥固化处理；其中步骤(1)干燥固化处理时，第一节烘箱温度控制在110-128℃，第二节烘箱温度控制在140-160℃，第三节和第四节烘箱的温度控制在150-170℃，第五节烘箱温度控制在160-180℃，第六节和第七节烘箱的温度控制在170-190℃，第八节烘箱温度控制在150-170℃；
步骤(2)干燥固化处理时，第一节烘箱温度设置为110-130℃，第二节烘箱温度控制在140-160℃，第三节至第五节烘箱温度控制在150-170℃，第六节和第七节烘箱的温度控制在160℃-180℃，第八节烘箱的温度控制在140-160℃；
步骤(3)干燥固化处理时，第一节烘箱温度控制在110-130℃，第二节烘箱至第七节烘箱温度分别控制在160-180℃，第八节烘箱温度控制在140-160℃。
7.根据权利要求5所述的一种发泡涂层内打灯广告布的制备工艺，其特征在于:步骤(1)中增白防水涂料的涂布湿量为40-50gsm，涂布车速为40-50m/min；
步骤(2)中发泡阻燃涂料的涂布湿量为75-500gsm，涂布车速为10-25m/min；
步骤(3)中墨水吸收涂料的涂布湿量为40-60gsm，涂布车速为20-30m/min。
CN201710910907.5A 2017-09-29 2017-09-29 一种发泡涂层内打灯广告布及其制备工艺 Active CN107700232B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710910907.5A CN107700232B (zh) 2017-09-29 2017-09-29 一种发泡涂层内打灯广告布及其制备工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710910907.5A CN107700232B (zh) 2017-09-29 2017-09-29 一种发泡涂层内打灯广告布及其制备工艺

Publications (2)

Publication Number Publication Date
CN107700232A CN107700232A (zh) 2018-02-16
CN107700232B true CN107700232B (zh) 2020-10-30

Family

ID=61175785

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710910907.5A Active CN107700232B (zh) 2017-09-29 2017-09-29 一种发泡涂层内打灯广告布及其制备工艺

Country Status (1)

Country Link
CN (1) CN107700232B (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108728984A (zh) * 2018-05-31 2018-11-02 海宁市硖石迅奇科技信息咨询服务部 一种uv细纺背打光灯布的制备方法
CN110205802A (zh) * 2019-07-05 2019-09-06 江苏辰鸿纺织科技有限公司 一种采用发泡涂层的内打光珍珠布及其制备方法
CN112239555A (zh) * 2020-09-21 2021-01-19 深圳市光科全息技术有限公司 立体打印用薄膜及其制备方法
CN112442903B (zh) * 2020-11-19 2023-08-22 沈阳世纪星纺织品数码科技有限公司 一种使用热升华墨水喷印的内打光纺织品灯箱布
CN115220295B (zh) * 2022-07-22 2023-08-22 潍坊佳诚数码材料有限公司 一种可折叠光学幕布及其制备方法
CN117103802A (zh) * 2022-11-28 2023-11-24 潍坊佳诚数码材料有限公司 一种墙布及其制备方法
CN117328276A (zh) * 2023-11-14 2024-01-02 潍坊佳诚数码材料有限公司 一种双面喷绘内灯广告布及其制备工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805989A (zh) * 2010-01-19 2010-08-18 上海纳尔实业有限公司 纺织品数码打印广告布及其制作工艺
CN102658695A (zh) * 2012-06-05 2012-09-12 江苏泰特尔化工有限公司 纳米环保超轻型喷绘灯箱布
CN102658744A (zh) * 2012-06-05 2012-09-12 江苏泰特尔化工有限公司 水性环保的弱溶剂型喷墨载体材料
CN202448429U (zh) * 2011-12-31 2012-09-26 杭州中亚布艺有限公司 复合涂层面料
CN105648773A (zh) * 2014-11-18 2016-06-08 镇江三鑫科技信息有限公司 一种喷绘广告布

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2839905B2 (ja) * 1989-07-31 1998-12-24 三菱製紙株式会社 写真印画紙用支持体
GB2286616B (en) * 1994-02-16 1997-08-06 Stephen Bernard Murphy A method of laying a road surface

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805989A (zh) * 2010-01-19 2010-08-18 上海纳尔实业有限公司 纺织品数码打印广告布及其制作工艺
CN202448429U (zh) * 2011-12-31 2012-09-26 杭州中亚布艺有限公司 复合涂层面料
CN102658695A (zh) * 2012-06-05 2012-09-12 江苏泰特尔化工有限公司 纳米环保超轻型喷绘灯箱布
CN102658744A (zh) * 2012-06-05 2012-09-12 江苏泰特尔化工有限公司 水性环保的弱溶剂型喷墨载体材料
CN105648773A (zh) * 2014-11-18 2016-06-08 镇江三鑫科技信息有限公司 一种喷绘广告布

Also Published As

Publication number Publication date
CN107700232A (zh) 2018-02-16

Similar Documents

Publication Publication Date Title
CN107700232B (zh) 一种发泡涂层内打灯广告布及其制备工艺
CN102619127B (zh) 一种环保高适印性无纺壁纸原纸
CN107435275B (zh) 一种热升华数码转印纸及生产方法
CN107447534B (zh) 一种数码直喷弱溶剂双面打印广告布及其制备工艺
CN104862966B (zh) 一种宽幅阻燃油画布及其制备方法
CN105926308A (zh) 一种石墨烯改性水性聚氨酯生产合成革的配方及工艺
CN108587425A (zh) 一种抗菌光触媒水性聚氨酯合成革的配方及工艺
CN101448648A (zh) 用于将干涉颜料施涂在基材上的方法
CN103321099B (zh) 一种造纸用表面施胶剂及其制备方法
EP1522629A1 (de) Beschichtetes Papier als Druckstoff
US20020127372A1 (en) Floor and wall coverings employing decorative substrate materials
CN110130142A (zh) 一种低克重数码喷墨转移印花原纸及其生产方法
CN109322158B (zh) 一种单面防水织物及其制备方法
KR101735871B1 (ko) 가볍고 엠보무늬가 깊은 동조 엠보무늬 벽지의 제조방법 및 그 제조방법에 의해 제조된 벽지
CN101581058A (zh) 涂布轻型超感纸的生产方法
CN111270549A (zh) 一种触感充皮纸的生产方法
CN106049084A (zh) 一种天然乳胶与水性聚氨酯发泡合成革的配方及工艺
CN100412269C (zh) 具有改善的印刷或书写特性的型样纸
CN110592960A (zh) 一种环保耐折pvc人造革及其制备方法
CN110093806A (zh) 一种无涂层数码喷墨转移印花原纸及其生产方法
CN110080042A (zh) 环保超防水3d科技纸的生产方法和生产设备
CN103774491A (zh) 涂布纸
CN101250839B (zh) 温变艺术充皮纸的生产方法
CN1289756C (zh) 图案纸
CN105350385B (zh) 数码喷墨无纺基纸

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20230627

Address after: 261000 Room 202, Building 18, No. 4961, Yingqiu Street, Baocheng Street, Changle County, Weifang, Shandong Province

Patentee after: Roushi Intelligent Technology (Shandong) Co.,Ltd.

Address before: 262400 North Xinchang Road, Changle County Economic Development Zone, Weifang City, Shandong Province, 1989

Patentee before: WEIFANG JIACHENG DIGITAL SUPPLIES Co.,Ltd.