CN107673749A - A kind of production technology of ceramics modelled after an antique - Google Patents

A kind of production technology of ceramics modelled after an antique Download PDF

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Publication number
CN107673749A
CN107673749A CN201710699919.8A CN201710699919A CN107673749A CN 107673749 A CN107673749 A CN 107673749A CN 201710699919 A CN201710699919 A CN 201710699919A CN 107673749 A CN107673749 A CN 107673749A
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China
Prior art keywords
ceramics
antique
modelled
production technology
dry granular
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Inventor
林家生
王志强
石颍
李宣营
熊国峰
谢扬光
刘丰
朱志明
张来根
陈炒
涂伟明
吴云平
赵英
黄金保
李继新
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BOHUA CERAMIC Co Ltd GUANGDONG
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BOHUA CERAMIC Co Ltd GUANGDONG
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Priority to CN201710699919.8A priority Critical patent/CN107673749A/en
Publication of CN107673749A publication Critical patent/CN107673749A/en
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
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    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/963Surface properties, e.g. surface roughness

Abstract

Embodiment of the present invention discloses a kind of production technology of ceramics modelled after an antique, and product level and third dimension are more prominent;Compared with traditional ceramics, this ceramics surface modelled after an antique can stamp various patterns modelled after an antique, and surface is in sand shape, there is the natural texture of sandstone, and comparison of light and shade is strong, and third dimension is strong, has adapted to the requirement of a variety of decorative effects;This ceramics modelled after an antique is designed as matte effect, and the sight protectio and pre- light pollution preventive to people have certain protective effect.This production technology includes step:A, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;B, mould is compressing, and the slurry of preparation is sent into press die and suppressed, is then dried, biscuiting;C, glazing, the surface of adobe is carried out adding glaze;D, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;E, dry granular is applied, dry granular is modulated and adds dry granular in the adobe for be printed on glaze paint;F, fire, the product that step E is obtained is sent into kiln and fired, and ceramics modelled after an antique is obtained after oversintering.

Description

A kind of production technology of ceramics modelled after an antique
Technical field
The present invention relates to ceramic tile field, more particularly to a kind of production technology of ceramics modelled after an antique.
Background technology
Existing market mainstream ceramics is that have light brick face, and there is the defects of some pin holes and water ripples on surface, the easy scratching of glaze paint, It is not wear-resisting, and water absorption rate is big, and easy moisture expantion is deformed.In the serious industry of current production capacity surplus, product homogeneity Under background, many pottery enterprises face sale predicament.
Although ceramics possesses fairly good pattern advantage, but the effect that it is used as independent decorative is unsatisfactory, from application On from the point of view of be also not well suited for as independent decorative material for wall surface, and wall difficulty of construction is also bigger on ceramics, is doing one When a little personalized designs, certain influence can be produced, so in the scope used or can be restricted.It is common at present Most of ceramics is light, produces harmful effect to the eyesight of people to a certain extent under bright environment for a long time.
Innovation becomes the widespread consensus of ceramic industry with lifting.Ceramics modelled after an antique is a new production just risen in nearly 2 years Product, have traditional internal wall brick and Antique Imitation Tiles double grading concurrently.Due to the classic flavor with uniqueness, it embodies long ceramics modelled after an antique History and years, time brings great changes to the world, style, tone and the texture rendering atmosphere missed old times or old friends, be more suitable for classic decoration and pastoralism and Various decorated styles.
Ceramics is improved it can be seen that those skilled in the art needs badly to be adapted to present market.
The content of the invention
Embodiment of the present invention provides a kind of production technology of ceramics modelled after an antique, the ceramics phase with traditional smooth texture Than this ceramics modelled after an antique, plus the improvement of kiln sintering curve, reaches glaze paint by the way that the formula of blank and glaze is adjusted A kind of dumb light glaze paint, low so as to lower the water absorption rate of ceramics, brick shape and thermostabilization all can be more preferable, using be not in after the later stage inhale Hygral expansion deforms and split brick phenomenon.Meanwhile print upper various figures modelled after an antique using the concave-convex effect of different moulds, then with ink jet printer Case, it is in sand shape to make product surface, there is the natural texture of sandstone, and comparison of light and shade is strong, and third dimension protrudes, and is more imbued with dicoration..
To solve the above problems, a kind of production technology of ceramics modelled after an antique provided by the invention, including step:
A, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B, mould is compressing, and the slurry of preparation is sent into press die and suppressed, is then dried, biscuiting;
C, glazing, the surface of adobe is carried out adding glaze;
D, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E, dry granular is applied, dry granular is modulated and adds dry granular in the adobe for be printed on glaze paint;
F, fire, the product that step E is obtained is sent into kiln and fired, and ceramics modelled after an antique is obtained after oversintering.
Preferably, the surface band of the press die described in step B is textured, and the texture is in lines, bumps and abnormity One or more.
Preferably, the compressing pressing pressure of mould described in step B is 22000MPa.
Preferably, the procedure calls dried described in step B are moisture content in adobe 0.1%~0.5%, described biscuiting Firing temperature be at 1100 °~1120 °, firing the time be 40min.
Preferably, the glaze described in step C, specially frit, raw material, diamond spar powder and burning aluminium earth burning.
Preferably, glazing described in step C includes ground-coat enamel and cover-coat enamel, and specific embodiment is glaze spraying or leaching glaze.
Preferably, the technological parameter of the ground-coat enamel is specially:It was 250 mesh sieves to sieve, and tails over and is for 0.3g/ml, proportion 1.78 ± 0.01g/ml, flow velocity are 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces;
The technological parameter of the cover-coat enamel is specially:It was 250 mesh sieves to sieve, and was tailed over as 0.3g/ml, proportion is 1.90 ± 0.01g/ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
Preferably, the ink-jet described in step D is sprayed using ceramic ink jet printer or 3D code ink jet printing machines Ink.
Preferably, the mesh of grain composition 100~200 of the dry granular described in step E, is shaped as spheric granules, the dry granular For the one or more in dumb light dry granular, light dry granular, colored dry granular and metal dry granular.
Preferably, the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that step F firing temperature Spend at 1100 °~1120 °, firing the time be 35min.
As can be seen from the above technical solutions, embodiment of the present invention has advantages below:
The production technology of the ceramics modelled after an antique of the present invention, water absorption rate is low, and brick shape and thermostabilization all can be more preferable, will not using the later stage There is moisture expantion deformation and split brick phenomenon, different textures and effect are showed by different moulds, effectively embody abundant Color and strong third dimension, the ceramics modelled after an antique manufactured by this production technology can effectively solve common ceramics glaze paint and easily draw Flower, it is not wear-resisting, and water absorption rate is big, and easy moisture expantion is deformed the problem of.
Embodiment
Embodiment of the present invention provides a kind of production technology of ceramics modelled after an antique, and product level and third dimension are more prominent;With Traditional ceramics is compared, and this ceramics surface modelled after an antique can stamp various patterns modelled after an antique, and surface is in sand shape, the natural matter for having sandstone Sense, comparison of light and shade is strong, and third dimension is strong, has adapted to the requirement of a variety of decorative effects.
A kind of production technology of ceramics modelled after an antique provided by the invention, including step:
A, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B, mould is compressing, and the slurry of preparation is sent into press die and suppressed, is then dried, biscuiting;
C, glazing, the surface of adobe is carried out adding glaze;
D, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E, dry granular is applied, dry granular is modulated and adds dry granular in the adobe for be printed on glaze paint;
F, fire, the product that step E is obtained is sent into kiln and fired, and ceramics modelled after an antique is obtained after oversintering.
The present invention uses raw material to produce required raw material sodium that is identical, including calculating in parts by weight with traditional ceramics base substrate Stone flour 5~10, feldspar 40~45, clay 10~15, talcum 2~4, barium carbonate 5~8, calcite 3~7, it is contained therein chemistry into It is divided into:SiO2 60~65, Al2O3 14~16, Fe2O3 0.1~0.3, TiO2 0.1~0.3, CaO 1.3~1.6, MgO 0.8~1.2, K2O 5.0~5.5, Na2O 2.0~2.5, BaO3~6, I.L 3.0~3.5.
Preferably, the surface band of the press die described in step B is textured, and the texture is in lines, bumps and abnormity One or more.
Using lines, bumps and special-shaped texture caused by different moulds, with reference to antique matte, it is in sand grains to make product surface Shape, there is the natural texture of sandstone, comparison of light and shade is strong, and third dimension protrudes.
Preferably, the compressing pressing pressure of mould described in step B is 22000MPa.
Preferably, the requirement of drying process described in step B is that moisture content is 0.1%~0.5% in adobe, described biscuiting Firing temperature be at 1100 °~1120 °, firing the time be 40min.
Preferably, the glaze described in step C, specially frit, raw material, diamond spar powder and burning aluminium earth burning.
Special frit, raw material are added in the formula of glaze, burn aluminium earth burning, burns till and aoxidizes with kiln high temperature, producing Product surface forms the touch feeling of similar lithotome.
Preferably, glazing described in step C includes ground-coat enamel and cover-coat enamel, and specific embodiment is glaze spraying or leaching glaze.
Preferably, the technological parameter of the ground-coat enamel is specially:It was 250 mesh sieves to sieve, and tails over and is for 0.3g/ml, proportion 1.78 ± 0.01g/ml, flow velocity are 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
The technological parameter of the cover-coat enamel is specially:It was 250 mesh sieves to sieve, and was tailed over as 0.3g/ml, proportion is 1.90 ± 0.01g/ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
Preferably, the ink-jet described in step D is sprayed using ceramic ink jet printer or 3D code ink jet printing machines Ink.
Preferably, the mesh of grain composition 100~200 of the dry granular described in step E, is shaped as spheric granules, the dry granular For the one or more in dumb light dry granular, light dry granular, colored dry granular and metal dry granular.
In dry granular selection, according to different surface sandstone or stone effect, dry granular grain composition need to be controlled 100~200 mesh, are shaped as spheric granules, if sheet or other shapes, may result in and stick together, can not show sandstone Or stone effect.Different dry granulars is sprayed on inside product glaze paint at a high speed by high pressure glaze spraying cabinet, sand is formed by high temperature sintering Rock or stone effect.
By the utilization of heterogeneity dry granular, dumb light dry granular effect, light dry granular effect, colored dry granular effect can be realized And metal dry granular effect.
Preferably, the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that step F firing temperature Spend at 1100 °~1120 °, firing the time be 35min.
Adjusted repeatedly by the change to frit, raw material and firing temperature in glaze, by adjustment, it is determined that firing temperature Spend at 1100 °~1120 °, the dumb light luminosity of glaze paint is controlled below 20 degree, make product glaze paint luminosity be in integrally sheen, be mute Light state.
The production technology of the present invention is described in detail below by embodiment:
Embodiment 1
The production technology of ceramics modelled after an antique, including step:
A1, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B1, mould are compressing, and the slurry of preparation is sent into press die and suppressed under conditions of 22000MPa, so Dry afterwards, biscuiting;
The firing temperature of biscuiting is 1100 °, and the time is 40min during firing;
C1, glazing, the surface of adobe is carried out adding glaze;
The technological parameter of ground-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.78 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces;
The technological parameter of cover-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.90 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
D1, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E1, dry granular is applied, modulate dry granular and add dry granular, the mesh of grain composition 100 of dry granular, shape in the adobe for be printed on glaze paint For spheric granules;
F1, firing, the product that above-mentioned steps are obtained are sent into kiln and fired, and firing temperature is at 1100 °, and the firing time is 35min obtains ceramics modelled after an antique after oversintering.
Embodiment 2
The production technology of ceramics modelled after an antique, including step:
The production technology of ceramics modelled after an antique, including step:
A2, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B2, mould are compressing, and the slurry of preparation is sent into press die and suppressed under conditions of 22000MPa, so Dry afterwards, biscuiting;
The firing temperature of biscuiting is 1120 °, and the time is 40min during firing;
C2, glazing, the surface of adobe is carried out adding glaze;
The technological parameter of ground-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.78 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces;
The technological parameter of cover-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.90 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
D2, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E2, dry granular is applied, modulate dry granular and add dry granular, the mesh of grain composition 200 of dry granular, shape in the adobe for be printed on glaze paint For spheric granules;
F2, firing, the product that above-mentioned steps are obtained are sent into kiln and fired, and firing temperature is at 1120 °, and the firing time is 35min obtains ceramics modelled after an antique after oversintering.
Embodiment 1 and embodiment 2 produce two batch Imitative Ancient Porcelains pieces, and 10 pieces of ceramics, numbering batch are randomly selected from embodiment 1 Secondary 1,10 pieces of ceramics are randomly selected from embodiment 2, numbering batch 2, are compared, observation ceramics outward appearance, hardness test:
Those skilled in the art observe:10 pieces of ceramics of batch 1, color and luster is basically identical, and decorative pattern is similar;
Those skilled in the art observe:10 pieces of ceramics of batch 2, color and luster is basically identical, and decorative pattern is similar;
Those skilled in the art observe:Each 1 piece of ceramics for choosing batch 1 and batch 2 is compared, and color and luster is basically identical, surface Bumps and sandstone texture it is slightly different.
Non- those skilled in the art's observation:20 pieces of ceramics of batch 1 and batch 2 are basically identical.
Water absorption rate test:The water absorption rate of batch 1 and the ceramics of batch 2 meets Standard.
Reference examples
The production technology of ceramics, including step:
A3, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B3, plane mould mould are compressing, then dry, biscuiting, and biscuiting temperature is 1100 °;
The firing temperature of biscuiting is 1100 °, and the time is 40min during firing;
C3, glazing, the surface of adobe is carried out adding glaze;
The technological parameter of ground-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.78 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces;
The technological parameter of cover-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.90 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
D3, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E3, dry granular is applied, modulate dry granular and add dry granular, the mesh of grain composition 100 of dry granular, shape in the adobe for be printed on glaze paint For spheric granules;
F3, firing, the product that above-mentioned steps are obtained are sent into kiln and fired, and firing temperature is at 1100 °, and the firing time is 35min obtains ceramics modelled after an antique after oversintering.
10 pieces of ceramics in reference examples are randomly selected, are named as batch 3, randomly select 10 pieces of ceramics in embodiment 1, are named For batch 4.
Observe ceramics outward appearance, hardness test:
Those skilled in the art observe:10 pieces of ceramics of batch 3, color and luster is basically identical, and decorative pattern is similar;
Those skilled in the art observe:10 pieces of ceramics of batch 4, color and luster is basically identical, and decorative pattern is similar;
Those skilled in the art observe:Each 1 piece of ceramics for choosing batch 3 and selection batch 4 is compared, color and luster and decorative pattern difference It is larger.
Non- those skilled in the art's observation:Batch 3 and the ceramics color and luster of batch 4 and decorative pattern differ greatly, wherein the ceramics matter of batch 3 Ground is smooth, and smooth surface is careful, and stereovision is relatively low, and the ceramics concave-convex surface sense of batch 4 is strong, there is the natural texture of sandstone, batch 3 It is more excellent from color and luster and decorative pattern arranging effect, batch 4 with batch 4.
Water absorption rate test:The ceramics water absorption rate of batch 3 and batch 4 meets Standard.
It can be seen that the production technology of ceramics modelled after an antique of the invention, by the effect of different mould and dry granular, shows difference Texture and texture, effectively embody abundant color and strong third dimension, meanwhile, the ceramics modelled after an antique manufactured by this production technology can It is not wear-resisting effectively to solve the common easy scratching of ceramics glaze paint, and water absorption rate is big, and what easy moisture expantion was deformed asks Topic.
Described above, embodiment of above and embodiment are merely illustrative of the technical solution of the present invention, rather than its limitations; Although the present invention is described in detail with reference to aforementioned embodiments and embodiment, one of ordinary skill in the art should Understand:It can still modify to the technical scheme described in foregoing embodiments, or to which part technical characteristic Carry out equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is departed from each embodiment of the present invention With the spirit and scope of embodiment technical scheme.

Claims (10)

1. a kind of production technology of ceramics modelled after an antique, it is characterised in that including step:
A, raw material is taken, progress slurry ball milling, powder by spraying, powder cabin are old;
B, mould is compressing, and the slurry of preparation is sent into press die and suppressed, is then dried, biscuiting;
C, glazing, the surface of adobe is carried out adding glaze;
D, ink-jet, by deployed ink in a manner of inkjet printing, it is printed on adobe surface;
E, dry granular is applied, dry granular is modulated and adds dry granular in the adobe for be printed on glaze paint;
F, fire, the product that step E is obtained is sent into kiln and fired, and ceramics modelled after an antique is obtained after oversintering.
2. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that press die described in step B Surface band is textured, and the texture is the one or more in lines, bumps and abnormity.
3. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that the mould described in step B is pressed into The pressing pressure of type is 22000MPa.
4. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that the process dried described in step B will Ask is moisture content in adobe 0.1%~0.5%;
The firing temperature of described biscuiting be at 1100 °~1120 °, firing the time be 40min.
5. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that the glaze described in step C, it is specially molten Block, raw material, diamond spar powder and burning aluminium earth burning.
6. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that glazing described in step C includes bottom Glaze and cover-coat enamel, specific embodiment are glaze spraying or leaching glaze.
7. the production technology of ceramics modelled after an antique according to claim 6, it is characterised in that the technological parameter of the ground-coat enamel is specific For:It was 250 mesh sieves to sieve, and it is 1.78 ± 0.01g/ml to tail over as 0.3g/ml, proportion, and flow velocity is 30 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces;
The technological parameter of the cover-coat enamel is specially:It was 250 mesh sieves to sieve, and it is 1.90 ± 0.01g/ to tail over as 0.3g/ml, proportion Ml, flow velocity are 35 ± 2 seconds, and glaze volume is 150 ± 1g/ pieces.
8. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that the ink-jet described in step D uses Ceramic ink jet printer or 3D code ink jet printing machines carry out ink-jet.
9. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that of the dry granular described in step E Grade matches somebody with somebody 100~200 mesh, is shaped as spheric granules, and the dry granular is that dumb light dry granular, light dry granular, colored dry granular and metal are done One or more in grain.
10. the production technology of ceramics modelled after an antique according to claim 1, it is characterised in that step F firing temperature exists 1100 °~1120 °, firing time 35min.
CN201710699919.8A 2017-08-16 2017-08-16 A kind of production technology of ceramics modelled after an antique Pending CN107673749A (en)

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CN111499396A (en) * 2020-04-27 2020-08-07 德清诺贝尔陶瓷有限公司 Metal texture porcelain plate with prominent bright/matte contrast and manufacturing method thereof
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CN109665870B (en) * 2018-12-05 2021-08-10 蒙娜丽莎集团股份有限公司 Flexible pattern porcelain archaized brick and preparation method thereof
CN109665870A (en) * 2018-12-05 2019-04-23 蒙娜丽莎集团股份有限公司 A kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof
CN109456035A (en) * 2018-12-11 2019-03-12 佛山欧神诺陶瓷有限公司 A kind of Ceramic Tiles and preparation method thereof with bright mute effect
CN109912293A (en) * 2019-04-15 2019-06-21 广东宏威陶瓷实业有限公司 Granite texture ceramic tile and preparation method thereof
CN112441812A (en) * 2019-08-31 2021-03-05 广东强辉陶瓷有限公司 Preparation method of whole-body granite ceramic tile
CN110526744B (en) * 2019-09-03 2021-03-30 广东新润成陶瓷有限公司 Spot archaized brick and manufacturing method thereof
CN110526744A (en) * 2019-09-03 2019-12-03 广东新润成陶瓷有限公司 A kind of spot Antique Imitation Tiles and preparation method thereof
CN111499396A (en) * 2020-04-27 2020-08-07 德清诺贝尔陶瓷有限公司 Metal texture porcelain plate with prominent bright/matte contrast and manufacturing method thereof
CN111499396B (en) * 2020-04-27 2022-04-01 德清诺贝尔陶瓷有限公司 Metal texture porcelain plate with prominent bright/matte contrast
CN111646786A (en) * 2020-06-03 2020-09-11 广东清远蒙娜丽莎建陶有限公司 Ceramic brick prepared by micro powder composite ink-jet positioning dry particle process and preparation method thereof
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CN114536524A (en) * 2022-03-15 2022-05-27 肇庆市来德利陶瓷有限公司 Rock plate relief production process
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