CN109665870A - A kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof - Google Patents
A kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof Download PDFInfo
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- CN109665870A CN109665870A CN201811480325.9A CN201811480325A CN109665870A CN 109665870 A CN109665870 A CN 109665870A CN 201811480325 A CN201811480325 A CN 201811480325A CN 109665870 A CN109665870 A CN 109665870A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/22—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- General Chemical & Material Sciences (AREA)
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Abstract
The present invention relates to a kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof, the preparation method the following steps are included: apparatus there are many texture mold pressing blank；Ground coat enamel, inkjet printing are applied in billet surface, applies the semi-transparent beautiful compound dry granular glaze of matter, firing obtains flexible die line porcelain Antique Imitation Tiles.
Description
Technical field
The invention belongs to ceramic building material fields, and in particular to a kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof.
Background technique
Currently on the market there are many kinds of the tile product preparations with mold effect, still, mostly with plane mould or single table
Based on the male and female mold production in face, plane mould surface is excessively single, is in contrast more imitated by others, leads to homogeneity also very
Seriously.Such as patent document CN 201280805Y discloses a kind of mould ceramic tile, the mould ceramic tile it is main it is outstanding be mold just
Face presents the square ceramic tile ontology of the male and fomale(M&F) being spaced in length and breadth and the superficial layer with respective metal gloss.Secondly for
The product market of plane effect is too many, is easy aestheticly tired.
Summary of the invention
In view of the above-mentioned problems, that the purpose of the present invention is to provide a kind of surface effects is changeable, performance more horn of plenty, level more
Add distinct Ceramic Tiles and preparation method thereof.
On the one hand, the present invention provides a kind of preparation method of flexible die line porcelain Antique Imitation Tiles, comprising the following steps:
There are many mold pressing blanks of texture for apparatus；
Ground coat enamel, inkjet printing are applied in billet surface, applies the semi-transparent beautiful compound dry granular glaze of matter, it is modelled after an antique to obtain flexible die line porcelain for firing
Brick.
According to the present invention, there are many mold pressing blanks of texture for apparatus, therefore billet surface has a variety of mould lines, passes through
It carries out applying ground coat enamel on the adobe surface with a variety of mould lines, inkjet printing pattern color applies the dry granular glaze of special-effect, through height
After temperature firing, different gloss reflecting surface effects is showed at different mould lines, surface effect is changeable, shows more horn of plenty, layer
It is secondary distincter.
Preferably, the mold is obtained and carving a variety of textures on male and female mold, it is preferable that the material of the mold
Matter is resin, and the method for the engraving is laser engraving.
Preferably, the chemical component of the ground coat enamel are as follows: by mass, burn and lose: 6.5~7.5%；SiO2: 45~53%；
Al2O3: 22~26%；Fe2O3: 0.05~0.3%；TiO2: 0.05~0.3%；CaO:6.0~8.5%；MgO:3.1~
3.8%；K2O:3.3~4.4%；Na2O:0.2~0.5%；ZnO:1.2~2.5%；ZrO2: 6~10%.
Preferably, in the ground coat enamel containing partial size be 325~400 mesh calcined alumina.
Preferably, the semi-transparent beautiful compound dry granular glaze of matter include: by mass, it is the transparent dry granular 65~75% of matt, bright
Transparent dry granular 20~30%, wear-resistant antiskid dry-particle 5~10%.
Preferably, the glossiness after the transparent dry granular firing of matt is 10~14 degree, it is preferable that the matt transparent dry
The formula components of grain are as follows: by mass, burn and lose: 0~0.3%；SiO2: 50~60%；Al2O3: 18~24%；CaO:7.0~
10.0%；MgO:2.0~3.5%；K2O:4.1~5.2%；Na2O:0.1~0.5%；ZnO:4.5~5.5%；SrO:1.5~
2.5%.
Preferably, the glossiness after the bright transparent dry granular firing is 50~60 degree, the preferably described bright transparent dry
The formula components of grain are as follows: by mass, burn and lose: 0~0.3%；SiO2: 63.1~71.2%；Al2O3: 9.3~11.9%；CaO:
9.0~11.5%；MgO:1.5~2.5%；K2O:2.6~3.7%；Na2O:2.5~3.5%；ZnO:1.0~2.15%.
Preferably, the formula components of the wear-resistant antiskid dry-particle are as follows: by mass, burn and lose: 0.0~0.3%；SiO2:
45.2~51.05%；Al2O3: 20~25%；CaO:14.0~16.5%；MgO:0.25~1.0%；K2O:3.0~4.5%；
Na2O:0.0~0.2%；ZnO:5.0~8.0%.
Preferably, the fineness of the transparent dry granular of matt, between 90~150 mesh, the fineness of the bright transparent dry granular exists
Between 60~120 mesh, the fineness of the wear-resistant antiskid dry-particle is between 100~160 mesh.
Preferably, dry granular glaze slip, which is made, in the semi-transparent beautiful compound dry granular glaze of matter carries out charity.
Preferably, the dry granular glaze slip includes: 40~50 parts of compound dry granular, 100~110 parts of adhesive by mass.
Preferably, the formula of described adhesive is as follows: by mass, 55~65 parts of water, sodium carboxymethylcellulose 2.0~
3.5 parts, 15~20 parts of ethylene glycol, 4.5~5.5 parts of acrylic copolymer, 3~5 parts of polyurethane, sodium polycarboxylate 3.5~5.
Preferably, the flow velocity of the dry granular glaze slip is 30~36 seconds, specific gravity is 1.32~1.36g/mL, glaze volume 340
~380g/m2。
Second aspect, the present invention provide a kind of flexible die line porcelain Antique Imitation Tiles as made from any of the above-described preparation method.
According to the present invention, mold difference position variation is blended with layout, and can carry out multi-faceted variation combination
Abundant texture color effect, the different surfaces position mold depth, the different combination of texture, if add later period appropriateness sheen, surface
Protrusion there are the bright reflective visual effects of more design textures, make the performance more horn of plenty of product, level is distincter.
Detailed description of the invention
Fig. 1 shows the mold design texture and layout of an embodiment of the present invention.
Fig. 2 shows the inkjet printing patterns of an embodiment of the present invention.
Specific embodiment
The present invention is further illustrated below by way of following embodiments, it should be appreciated that following embodiments are merely to illustrate this
Invention, is not intended to limit the present invention.Following percentage composition refers both to mass percentage unless otherwise instructed.
It is disclosed a kind of preparation method of flexible die line porcelain Antique Imitation Tiles.Flexibility refers to that the product has one kind can the later period
Be cut into different product by different mould lines position size or be cut into as needed identical size with random position variation
Cutting products.
Firstly, preparing green body.In one embodiment, there are many design style textures and the compacting of the mold of location dimension for apparatus
Green body.Different from common lines, bumps, special-shaped texture, in present embodiment, mould line has positioning on same green body, often
Mould line in a location dimension has biggish graphic difference.Mold can have the different depths, texture in different positions, have rich
Rich textured pattern.Adobe surface obtained also has textured pattern abundant as a result, especially can have subtle finishing impression effect
Fruit.The textured pattern on adobe surface can cooperate with inkjet printing pattern.
Mold with a variety of design style textures and location dimension can be by common die or single concave-convex mold
Positioning is carved a variety of textures and is obtained.The method of engraving is preferably laser engraving, it can be incited somebody to action by the contactless cutting of high-power energy
The intact expression of subtle design, section are fine and smooth.The material of mold can be resin material, and the resin material of preferred high strength is resistance to
Temperature and be not easy to soften, good engraving form and details can be kept in this way.
It in one embodiment, combines the mould line figure of multi-effect element in a sheet mold, distributes each member by aesthetics
The proportional sizes of element.Different element mould lines select different artistic carving and depth, and mould line texture mould point height is of different sizes, can
Ink is set to adsorb and disperse different, formation pattern disconnection depth variation.Mould line difference of height can be 0.2 to 1.5mm.Number of modules can be
4~10.Each module area ratio can be between 1~10.Entire module area can be between 0.36~2.88 square metre.Fig. 1 shows
The mold design texture and layout of an embodiment of the present invention out.In the embodiment, mold is combined using five formulas, has five
The different design effect of kind.
Then, ground coat enamel is applied on green body.To avoid influencing the subtle finishing impression effect of billet surface, ground coat enamel is preferably glaze volume
Low, covering is strong, and color development is beautiful.
Aluminium, potassium content in ground coat enamel can be made higher, to help to widen firing range, in identical glaze volume
Under, covering steady change is small, and color development variation is small.For example, alumina content can be 22~26% in ground coat enamel, potassium oxide content can
It is 3.3~4.4%.In one preferred embodiment, the formula chemical component of ground coat enamel are as follows: by mass, burn and lose (IL): 6.5~
7.5%；SiO2: 45~53%；Al2O3: 22~26%；Fe2O3: 0.05~0.3%；TiO2: 0.05~0.3%；CaO:6.0~
8.5%；MgO:3.3~3.8%；K2O:3.3~4.4%；Na2O:0.2~0.5%；ZnO:1.2~2.5%；ZrO2: 6~
10%.The ground coat enamel can play the role of stronger covering under lower glaze volume and color development is beautiful.
Ultra-fine aluminium is preferably comprised in ground coat enamel to enhance color development.Ultra-fine aluminium refers to the ultra-fine aluminum-containing raw material of partial size.For example, super
The partial size of thin aluminium can stop purpose calcined alumina for 325~400.
Ground coat enamel can be made ground coat enamel slurry and carry out charity.Charity mode can be glaze spraying, leaching glaze etc..In preferred embodiment, adopt
With high pressure glaze spraying, glaze spraying pressure can be 8~12MPa.The specific gravity of ground coat enamel slurry can be 1.40~1.46g/mL.Glaze volume preferably compared with
It is low, such as the applied amount of ground coat enamel slurry can be 360~380g/m2。
Then, the inkjet printing on ground coat enamel.Inkjet printing pattern color can be suitable for changing, and cooperate with green body mould line,
Such as shown in Figure 2.It can be printed using digital ink-jet printer.The ceramic ink used can have blue, brown, orange colour,
Lemon yellow, black, red etc..Preferably, ink-jet 3D printing can be carried out.
After drying ink, the compound dry granular glaze of the semi-transparent beautiful matter of charity (referred to as compound dry granular).Ink drying mode may be, for example,
Electric seasoning etc..
The semi-transparent jade compound dry granular glaze of matter is translucent shape after referring to burning, is the dry of beautiful matter surface in soft throwing rear surface effect class
Grain.The semi-transparent jade compound dry granular glaze of matter may include three kinds of dry granulars: the transparent dry granular of matt, bright transparent dry granular and wear-resistant antiskid dry-particle.
The transparent dry granular of matt refer to firing after in matt, transparent dry granular (glossiness of matt generally at 25 degree hereinafter, have
There is sub-translucent property).In one embodiment, the transparent dry granular of matt is the transparent dry granular of high temperature matt, and formula components are for example as follows: pressing
Quality meter burns and loses: 0~0.3%；SiO2: 50~60%；Al2O3: 18~24%；CaO:7.0~10.0%；MgO:2.0~
3.5%；K2O:4.1~5.2%；Na2O:0.1~0.5%；ZnO:4.5~5.5%；SrO:1.5~2.5%.The matt is transparent
Dry granular firing temperature is at 1180~1200 DEG C, 10~14 degree of gloss after burning, and beginning melting point is high, is easily vented, can promote product surface
Bright sub-layer time effect, reduces stomata, improves anti-pollution.
Content of the transparent dry granular of matt in the compound dry granular glaze of semi-transparent beautiful matter is preferably higher, for example, 65~75wt%.Such as
Its too high levels of fruit, then it is relatively low to will lead to brick face glossiness, and the transparency is poor.
Bright transparent dry granular refers to burn after issue the visual effect of bright sudden strain of a muscle, the good dry granular of permeability.Bright transparent dry granular can
To adjust the semi-transparent beautiful texture of compound dry granular.In one embodiment, the formula components of bright transparent dry granular are as follows: by mass, burn
It loses: 0~0.3%；SiO2: 63.1~71.2%；Al2O3: 9.3~11.9%；CaO:9.0~11.5%；MgO:1.5~
2.5%；K2O:2.6~3.7%；Na2O:2.5~3.5%；ZnO:1.0~2.15%.
Content of the bright transparent dry granular in the compound dry granular glaze of semi-transparent beautiful matter is preferably 20~30wt%.If its content mistake
It is low, then it is on the weak side to will lead to the low color colour generation of brick face transparency；If its too high levels, it is higher to will lead to brick face glossiness, soft
It is thrown after throwing and not throw contrast grade inadequate, gloss level is unintelligible.
Wear-resistant antiskid dry-particle can promote product surface wear-resisting antiskid ability.In one embodiment, wear-resistant antiskid dry-particle
Formula components are as follows: by mass, burn and lose: 0.0~0.3%；SiO2: 45.2~51.05%；Al2O3: 20~25%；CaO:14.0
~16.5%；MgO:0.25~1.0%；K2O:3.0~4.5%；Na2O:0.0~0.2%；ZnO:5.0~8.0%.Using this
Wear-resistant antiskid dry-particle can make the wearability of product reach 4 grades, and product is made to have durability and anti-skidding effect.
Content of the wear-resistant antiskid dry-particle in the compound dry granular glaze of semi-transparent beautiful matter is preferably 5~10wt%.If its content mistake
It is low, then it is insufficient to will lead to product surface wear-resisting antiskid performance；If its too high levels, it is excessively rough to will lead to product.
The selection principle of the fineness of the transparent dry granular of matt, bright transparent dry granular and wear-resistant antiskid dry-particle these three dry granulars can
To enable wear-resistant antiskid dry-particle to be scattered among the transparent dry granular of dry granular matt and bright transparent dry granular, dry granular face had both been kept in this way
Texture, and increase anti-skidding power.For example, in an embodiment, the fineness of the transparent dry granular of matt between 90~150 mesh,
The fineness of the bright transparent dry granular is between 60~120 mesh, and the fineness of the wear-resistant antiskid dry-particle is between 100~160 mesh.
It, can be with by being used cooperatively for the transparent dry granular of matt, bright transparent dry granular and wear-resistant antiskid dry-particle in the present invention
Make brick face that there is light matt level effect, it is few to burn posterior spiracle, and there is semi-transparent beautiful texture, and there is wear-resisting, skid resistance.This is multiple
It closes dry granular effect to be overlapped mutually with green body mould line effect and ink-jetting pattern effect, tile color and level can be made to show more
It is rich and changeful.
In one embodiment, slurry (dry granular slurry) is made in the semi-transparent beautiful compound dry granular glaze of matter and carrys out charity.Preferred embodiment
In, using thin method leaching sizing process come glazing, the die surface and level effect of product can be kept in this way, color development is beautiful, colour generation
By force, while production and application cost is reduced.Thin method leaching sizing process, which refers to, applies one layer of relatively thin uniform glaze layer in a manner of glaze to drench, and applies
Glaze amount is lower, small to the influential effect below glaze layer.The main purpose of thin method leaching sizing process keeps glaze layer relatively thin, reduces glaze volume,
And surface evenness is kept, it can be deteriorated according to the glaze spraying mode glaze layer uniformity.
It keeping dry granular to starch good mobile performance when to make low glaze volume, adhesive can be added in compound dry granular, increase
Add the dispersibility and mobility between dry granular.In one embodiment, dry granular slurry includes: that by mass, 40~50 parts of compound dry granular glues
100~110 parts of mixture.Wherein adhesive formula ratio is as follows: by mass, 55~65 parts of water, sodium carboxymethylcellulose 2.0~
3.5 parts, 15~20 parts of ethylene glycol, 4.5~5.5 parts of acrylic copolymer, 3~5 parts of polyurethane, 3.5~5 parts of sodium polycarboxylate.It should
Adhesive has excellent mobility and dispersion dry granular effect.
The flow velocity of dry granular slurry can be 30~36 seconds/glass.Here flow velocity, which refers to, expires determinand for 100ml flow velocity cup, beats
Open aperture (bore 0.5mm) below flow velocity cup, by determinand from starting to flowing to end after time be denoted as the flow velocity of determinand.
The specific gravity of dry granular slurry can be 1.32~1.36g/mL.The applied amount of dry granular slurry can be 340~380g/m2。
It is dry after applying the compound dry granular glaze of semi-transparent beautiful matter, firing.Firing period can be 55~60 minutes, maximum sintering temperature
It can be 1200~1225 DEG C.
After firing, the thickness of ground glaze layer can be 0.08~0.12mm, and the thickness of the compound dry granular glaze layer of semi-transparent jade matter can be
0.10~0.15mm.
Soft throwing is preferably carried out after firing, so that the gloss of the beautiful crystal grain thoroughly in surface be made effectively to be promoted.In one embodiment, with height
Mesh number elastic module carries out soft throwing, and the mesh number of elastic module can be 2000~3000.
In the disclosure, is designed by the use of flexible die and the pattern color of mating suitable variation, drenched and starched by thin method
Dry granular slurry with semi-transparent beautiful matter is applied in brick face, by soft throwing technique, promotes the gloss of the beautiful crystal grain thoroughly in surface effectively.
After soft throwing brick face dried at grain it is sparkling and crystal-clear it is beautiful hide oneself thoroughly like frozen beads in brick face different location, it is either large or small or long or
It is short.
The defects of Imitation Rock Porcelain Tiles of the disclosure integrate anti-skidding without rough, and surface is without obvious pin hole, glaze bubble.And it is resistance to
Mill property reaches 4 grades, has excellent durability.
The Imitation Rock Porcelain Tiles of the disclosure have the characteristics that four directions mixing paving and cutting any combination paving, are suitble to various using field
It closes.Not by such environmental effects, various inner-outer walls and ground decoration can be widely used in.
The Imitation Rock Porcelain Tiles of the disclosure are fully sintered, and water absorption rate controls within 0.5%, and pass through the use of fine melt block dry granular,
The gas vent of firing is reduced, surface soiling effect is good, easy to clean.
The Imitation Rock Porcelain Tiles performance of the disclosure is stablized, smaller by time, environmental impact factor, and wear resistance is high, can keep for a long time such as
New to feel, long service life has a vast market economic benefit.
Enumerate embodiment further below with the present invention will be described in detail.It will similarly be understood that following embodiment is served only for this
Invention is further described, and should not be understood as limiting the scope of the invention, those skilled in the art is according to this hair
Some nonessential modifications and adaptations that bright above content is made all belong to the scope of protection of the present invention.Following examples are specific
Technological parameter etc. is also only an example in OK range, i.e. those skilled in the art can be done properly by the explanation of this paper
In the range of select, and do not really want to be defined in hereafter exemplary specific value.
Embodiment 1
Brick face effect requirements are produced by flexible die line porcelain Antique Imitation Tiles, high covering color development ground coat enamel formula components: IL:
6.82%；SiO2: 45.85%；Al2O3: 24.44%；Fe2O3: 0.12%；TiO2: 0.08%；CaO:6.95%；MgO:
3.21%；K2O:3.55%；Na2O:0.33%；ZnO:1.29%；ZrO2: 7.56%.
Compound dry granular formula is made of 3 parts, the transparent dry granular of high temperature matt, bright transparent dry granular, wear-resistant antiskid dry-particle,
Three kinds of dry granulars mix composition in proportion.
The transparent dry granular formula components of its high temperature matt are as follows: IL:0.15%；SiO2: 57.02%；Al2O3: 20.43%；
CaO:8.2%；MgO:2.83%；K2O:4.58%；Na2O:0.39%；ZnO:4.63%；SrO:1.77%.
Bright transparent dry granular formula components are as follows: IL:0.27%；SiO2: 69.49%；Al2O3: 10.86%；CaO:
9.91%；MgO:1.77%；K2O:2.84%；Na2O:2.93%；ZnO:1.37%.
Wear-resistant antiskid dry-particle formula components are as follows: IL:0.26%；SiO2: 49.54%；Al2O3: 22.06%；CaO:16.05；
MgO:0.46%；K2O:3.89%；Na2O:0.11%；ZnO:7.0%.
Thin method leaching slurry dry granular glaze formula is as follows.
Compound dry granular proportion is as follows: by mass, the transparent dry granular 66% of high temperature matt, bright transparent siccative 26%, wear-resisting
Anti-skidding dry granular 8%.
Dry granular glaze slip charge ratio is as follows: by mass, compound dry granular: 48 parts, adhesive: 104 parts, 33 second/glass of flow velocity.Add
Work mode is stirring.
Wherein adhesive formula ratio is as follows: by mass, 65 parts of water, low-viscosity sodium carboxymethyl cellulose are (purchased from well-off
New macromolecular fibre Co., Ltd, model FH9.00464) 3.0 parts, 19 parts of ethylene glycol, acrylic copolymer it is (solid new purchased from connection
Material Science and Technology Ltd., model 4005) 5.0 parts, polyurethane (be purchased from Lian Gu new material Science and Technology Ltd., model
2148H) 4 parts, 3.5 parts of sodium polycarboxylate (being purchased from Daewoo's new material Science and Technology Ltd., model DSX2000).
Specific preparation process is as follows.
It prepares green body: will change with the mold that flexible design is made in press, suppress flexible die green body.
By the dry rear high covering color development ground coat enamel of spray of body drying kiln drying (specific gravity 1.46 sprays 130-135g/ piece).
Multiple color inkjet printing.
The semi-transparent beautiful compound dry granular glaze of matter (specific gravity 1.33,110-120g/ piece) of leaching slurry.
After kiln firing, edging classification is packaged after carrying out soft throwing.The area of gained Imitation Rock Porcelain Tiles is 600*600mm.
Water absorption rate is by the following method: its principle is that dry brick is placed in water and absorbs water to saturation by test, with the drying of brick
Quality characterisitic parameter relevant with quality after water suction saturation and in water Mass Calculation.Usually using boiling method, had using instrument:
Drying box, heating device, heat source, balance, deionized water, drier.Wearability is tested by the following method: by putting on glaze
It sets medium and rotates, the observation of worn-out sample Yu unworn sample is compared, Ceramic Tiles wearability is evaluated.Common instrument
Have: abrasive media, abrasion wear test machine, drying box, balance.Stain resistance is tested by the following method: by test solution and material (pollution
Agent) with brick front face, make its act on certain time, then by defined cleaning method clean brick face, observation brick surface can
Variation is seen to determine the stain resistance of brick.Common instrument has: drying box.Product rationality energy part of detecting data are as follows: water absorption rate
0.03%, wear-resisting 2100 brick, 5 grades of stain resistance.
Embodiment 2
Difference from example 1 is that the transparent dry granular formula components of high temperature matt are as follows: IL:0.10%；SiO2:
53.02%；Al2O3: 22.43%；CaO:8.9%；MgO:3.23%；K2O:4.58%；Na2O:0.35%；ZnO:5.13%；
SrO:2.27%；Bright transparent dry granular formula components are as follows: IL:0.24%；SiO2: 67.88%；Al2O3: 11.82%；CaO:
10.55%；MgO:1.97%；K2O:3.24%；Na2O:2.73%；ZnO:1.55%；Wear-resistant antiskid dry-particle formula components are as follows:
IL:0.26%；SiO2: 47.98%；Al2O3: 23.16%；CaO:15.85%；MgO:0.55%；K2O:4.22%；Na2O:
0.15%；ZnO:7.88%.
After tested, product rationality energy part of detecting data are as follows: water absorption rate 0.06%, wear-resisting 2100 brick, 5 grades of stain resistance.
Claims (10)
1. a kind of preparation method of flexible die line porcelain Antique Imitation Tiles, which comprises the following steps:
There are many mold pressing blanks of texture for apparatus；
Ground coat enamel, inkjet printing are applied in billet surface, applies the semi-transparent beautiful compound dry granular glaze of matter, it is modelled after an antique to obtain flexible die line porcelain for firing
Brick.
2. preparation method according to claim 1, which is characterized in that the mold be by resin die laser carve
It carves and obtains.
3. preparation method according to claim 1 or 2, which is characterized in that the chemical component of the ground coat enamel are as follows: press quality
Meter burns and loses: 6.5~7.5%；SiO2: 45~53%；Al2O3: 22~26%；Fe2O3: 0.05~0.3%；TiO2: 0.05~0.3%；
CaO:6.0~8.5%；MgO:3.1~3.8%；K2O:3.3~4.4%；Na2O:0.2~0.5%；ZnO:1.2~2.5%；ZrO2: 6
~10%.
4. preparation method according to any one of claim 1 to 3, which is characterized in that be containing partial size in the ground coat enamel
The calcined alumina of 325~400 mesh.
5. preparation method according to any one of claim 1 to 4, which is characterized in that the compound dry granular of the semi-transparent beautiful matter
Glaze includes: the transparent dry granular 65~75% of matt, bright transparent dry granular 20~30%, wear-resistant antiskid dry-particle 5~10% by mass.
6. preparation method according to any one of claim 1 to 5, which is characterized in that
Glossiness after the transparent dry granular firing of the matt is 10~14 degree, it is preferable that the formula of the transparent dry granular of matt at
It is divided into: by mass, burns and lose: 0~0.3%；SiO2: 50~60%；Al2O3: 18~24%；CaO:7.0~10.0%；MgO:2.0~
3.5%；K2O:4.1~5.2%；Na2O:0.1~0.5%；ZnO:4.5~5.5%；SrO:1.5~2.5%；
Glossiness after the bright transparent dry granular firing is 50~60 degree, it is preferable that the formula of the bright transparent dry granular at
It is divided into: by mass, burns and lose: 0~0.3%；SiO2: 63.1~71.2%；Al2O3: 9.3~11.9%；CaO:9.0~11.5%；
MgO:1.5~2.5%；K2O:2.6~3.7%；Na2O:2.5~3.5%；ZnO:1.0~2.15%；
The formula components of the wear-resistant antiskid dry-particle are as follows: by mass, burn and lose: 0.0~0.3%；SiO2: 45.2~51.05%；
Al2O3: 20~25%；CaO:14.0~16.5%；MgO:0.25~1.0%；K2O:3.0~4.5%；Na2O:0.0~0.2%；ZnO:
5.0~8.0%.
7. preparation method according to any one of claim 1 to 6, which is characterized in that the transparent dry granular of matt it is thin
Degree between 90~150 mesh, the fineness of the bright transparent dry granular between 60~120 mesh, the wear-resistant antiskid dry-particle it is thin
Degree is between 100~160 mesh.
8. preparation method according to any one of claim 1 to 7, which is characterized in that by the compound dry granular glaze of semi-transparent beautiful matter
Dry granular glaze slip is made and carries out charity,
The dry granular glaze slip includes: 40~50 parts of compound dry granular, 100~110 parts of adhesive by mass,
The formula of described adhesive is as follows: by mass, 55~65 parts of water, 2.0~3.5 parts of sodium carboxymethylcellulose, ethylene glycol
15~20 parts, 4.5~5.5 parts of acrylic copolymer, 3~5 parts of polyurethane, sodium polycarboxylate 3.5~5.
9. preparation method according to claim 8, which is characterized in that the flow velocity of the dry granular glaze slip is 30~36 seconds, than
Weight is 1.32~1.36g/mL, and glaze volume is 340~380g/m2。
10. flexible die line porcelain Antique Imitation Tiles made from a kind of preparation method as described in any one of claims 1 to 9.
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| CN110642521A (en) * | 2019-12-02 | 2020-01-03 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof |
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