CN107635925B - 用于锂离子电池组的混合过渡金属氧化物 - Google Patents

用于锂离子电池组的混合过渡金属氧化物 Download PDF

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CN107635925B
CN107635925B CN201580060415.0A CN201580060415A CN107635925B CN 107635925 B CN107635925 B CN 107635925B CN 201580060415 A CN201580060415 A CN 201580060415A CN 107635925 B CN107635925 B CN 107635925B
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transition metal
particle
concentration
radius
mixed oxide
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CN107635925A (zh
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C·埃尔克
T·M·里尔
J·兰伯特
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BASF SE
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/80Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/30Particle morphology extending in three dimensions
    • C01P2004/32Spheres
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/50Agglomerated particles
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN201580060415.0A 2014-11-07 2015-10-30 用于锂离子电池组的混合过渡金属氧化物 Active CN107635925B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462076545P 2014-11-07 2014-11-07
US62/076,545 2014-11-07
PCT/EP2015/075222 WO2016071219A1 (de) 2014-11-07 2015-10-30 Übergangsmetall-mischoxide für lithiumionen-batterien

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CN107635925A CN107635925A (zh) 2018-01-26
CN107635925B true CN107635925B (zh) 2020-06-12

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US (1) US10526212B2 (https=)
EP (1) EP3215462A1 (https=)
JP (1) JP2017538649A (https=)
KR (1) KR20170083573A (https=)
CN (1) CN107635925B (https=)
WO (1) WO2016071219A1 (https=)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
KR20200051931A (ko) * 2018-11-06 2020-05-14 주식회사 포스코 리튬 화합물, 니켈계 양극 활물질, 산화 리튬의 제조 방법, 니켈계 양극 활물질의 제조 방법, 및 이를 이용한 이차 전지
CN112969666A (zh) * 2018-11-09 2021-06-15 巴斯夫欧洲公司 制备镍复合氢氧化物的方法
CN112619571B (zh) * 2020-11-18 2022-06-14 东南大学 一种调控过渡金属磷化物晶面相对暴露强度的方法
DE202022102465U1 (de) 2022-04-29 2022-05-12 Hte Gmbh The High Throughput Experimentation Company Vorrichtung zur Herstellung von Feststoffpartikeln
WO2023208742A1 (de) 2022-04-29 2023-11-02 Hte Gmbh The High Throughput Experimentation Company Vorrichtung und verfahren zur herstellung von feststoffpartikeln
WO2023229354A1 (ko) * 2022-05-24 2023-11-30 주식회사 엘지화학 전구체 제조장치 및 전구체 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1708867A (zh) * 2002-10-31 2005-12-14 Lg化学株式会社 具有金属组成梯度的锂过渡金属氧化物
WO2007114557A1 (en) * 2006-03-30 2007-10-11 Industry-University Cooperation Foundation Hanyang University Positive active material for lithium battery, method of preparing the same, and lithium battery including the same
CN101616870A (zh) * 2007-01-29 2009-12-30 尤米科尔公司 岛覆盖锂砷钴矿氧化物
CN104521039A (zh) * 2012-06-08 2015-04-15 汉阳大学校产学协力团 用于锂二次电池的正极活性材料前体,由其制造的正极活性材料,以及包括该材料的锂二次电池

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100752703B1 (ko) * 2006-06-29 2007-08-29 한양대학교 산학협력단 리튬 이차 전지용 양극 활물질, 그 제조 방법 및 그를사용한 리튬 이차 전지
CA2676390C (en) 2007-01-29 2013-07-16 Umicore Island-covered lithium cobaltite oxides
JP5638232B2 (ja) * 2009-12-02 2014-12-10 住友金属鉱山株式会社 非水系電解質二次電池正極活物質用ニッケルコバルトマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池
KR101292756B1 (ko) * 2011-01-05 2013-08-02 한양대학교 산학협력단 입자 전체 농도 구배 리튬이차전지용 양극활물질, 이의 제조 방법, 및 이를 포함하는 리튬이차전지
US20140308584A1 (en) * 2011-11-09 2014-10-16 Gs Yuasa International Ltd. Active material for nonaqueous electrolyte secondary battery, method for manufacturing active material, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
KR101521178B1 (ko) * 2012-03-31 2015-05-19 한양대학교 산학협력단 리튬 이차 전지용 양극활물질 전구체의 제조 방법, 이에 의하여 제조된 리튬 이차 전지용 양극활물질 전구체, 및 이를 포함하는 리튬 이차 전지용 양극활물질
KR102223214B1 (ko) * 2013-05-08 2021-03-04 바스프 에스이 구형 입자들, 그것의 제조 및 용도
KR101568263B1 (ko) * 2014-08-07 2015-11-11 주식회사 에코프로 리튬 이차 전지용 양극활물질 및 이를 포함하는 리튬 이차 전지

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1708867A (zh) * 2002-10-31 2005-12-14 Lg化学株式会社 具有金属组成梯度的锂过渡金属氧化物
WO2007114557A1 (en) * 2006-03-30 2007-10-11 Industry-University Cooperation Foundation Hanyang University Positive active material for lithium battery, method of preparing the same, and lithium battery including the same
CN101616870A (zh) * 2007-01-29 2009-12-30 尤米科尔公司 岛覆盖锂砷钴矿氧化物
CN104521039A (zh) * 2012-06-08 2015-04-15 汉阳大学校产学协力团 用于锂二次电池的正极活性材料前体,由其制造的正极活性材料,以及包括该材料的锂二次电池

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Cathode Material with Nanorod Structure-An Application for Advanced High-Energy and Safe Lithium Batteries;Hyung-Joo Noh等;《Chem. Mater.》;20130502;2109-2115 *
Comparison of Nanorod-Structured Li[Ni0.54Co0.16Mn0.30]O2 with Conventional Cathode Materials for Li-Ion Batteries;Hyung-Joo Noh等;《ChemSusChem》;20131011;第246页左栏第2-3段以及图2和图3b,第251页Experimental Section *
Nanostructured high-energy cathode materials for advanced lithium batteries;Yang-Kook Sun等;《NATURE MATERIALS》;20121007;942-947页 *

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EP3215462A1 (de) 2017-09-13
WO2016071219A1 (de) 2016-05-12
CN107635925A (zh) 2018-01-26
KR20170083573A (ko) 2017-07-18
US10526212B2 (en) 2020-01-07
JP2017538649A (ja) 2017-12-28
US20170355614A1 (en) 2017-12-14

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