CN107522892B - 碳酸氢有机胺盐类化合物及其作为发泡剂的用途 - Google Patents
碳酸氢有机胺盐类化合物及其作为发泡剂的用途 Download PDFInfo
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- CN107522892B CN107522892B CN201710872094.5A CN201710872094A CN107522892B CN 107522892 B CN107522892 B CN 107522892B CN 201710872094 A CN201710872094 A CN 201710872094A CN 107522892 B CN107522892 B CN 107522892B
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- blowing agent
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- organic amine
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- -1 amine bicarbonate compound Chemical class 0.000 title claims abstract description 163
- 239000004088 foaming agent Substances 0.000 title claims abstract description 82
- 239000000203 mixture Substances 0.000 claims abstract description 88
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- 150000001412 amines Chemical class 0.000 claims abstract description 45
- 239000004814 polyurethane Substances 0.000 claims abstract description 43
- 150000001768 cations Chemical class 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 181
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 111
- 238000005187 foaming Methods 0.000 claims description 99
- 239000004604 Blowing Agent Substances 0.000 claims description 90
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- 239000011496 polyurethane foam Substances 0.000 claims description 69
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- 239000006260 foam Substances 0.000 claims description 61
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 40
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 39
- 229910052736 halogen Chemical group 0.000 claims description 33
- 150000002367 halogens Chemical group 0.000 claims description 33
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- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 21
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 19
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
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- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims description 2
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- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 6
- ZVAKZVDJIUFFFP-UHFFFAOYSA-N 2-chlorooxolane Chemical compound ClC1CCCO1 ZVAKZVDJIUFFFP-UHFFFAOYSA-N 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 41
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- 229910002091 carbon monoxide Inorganic materials 0.000 description 32
- 150000003839 salts Chemical class 0.000 description 32
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 26
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 26
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 24
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 22
- 238000009413 insulation Methods 0.000 description 22
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- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 19
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| CN109679130B (zh) * | 2017-10-19 | 2021-09-07 | 山东理工大学 | 包含六氟丁烯和有机醇胺盐化合物的复合发泡剂 |
| CN109867767B (zh) * | 2017-12-05 | 2021-08-10 | 补天新材料技术有限公司 | 二氧化碳与有机胺相结合使用的聚氨酯发泡方法 |
| JP7327904B2 (ja) * | 2018-03-30 | 2023-08-16 | マツダ株式会社 | 2液反応型ウレタン樹脂組成物を用いたポリウレタンフォームの形成方法 |
| CN110396212A (zh) * | 2018-04-25 | 2019-11-01 | 北京市建筑工程研究院有限责任公司 | 一种硬质聚氨酯泡沫辅助发泡剂 |
| CN109021281B (zh) * | 2018-07-04 | 2021-11-26 | 广西斯佰祥科技产业有限公司 | 一种复合发泡剂及其制备聚氨酯泡沫的用途 |
| CN109021280B (zh) * | 2018-07-04 | 2021-11-12 | 淮北市星光新材料科技有限公司 | 一种聚氨酯泡沫的制备方法及聚氨酯泡沫 |
| CN109762136B (zh) * | 2019-01-25 | 2021-05-25 | 海信容声(广东)冰箱有限公司 | 一种聚氨酯发泡组合物、聚氨酯泡沫及其制备方法和应用 |
| US11603444B2 (en) | 2019-12-31 | 2023-03-14 | Industrial Technology Research Institute | Foaming composition and method of forming foam material |
| TWI717959B (zh) * | 2019-12-31 | 2021-02-01 | 財團法人工業技術研究院 | 發泡組成物與發泡材料的形成方法 |
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|---|---|
| AU2017275049A1 (en) | 2018-12-06 |
| US20190152899A1 (en) | 2019-05-23 |
| KR20190004693A (ko) | 2019-01-14 |
| KR20210028751A (ko) | 2021-03-12 |
| CN107089927A (zh) | 2017-08-25 |
| WO2017206692A1 (zh) | 2017-12-07 |
| CA3025030A1 (en) | 2017-12-07 |
| JP6800320B2 (ja) | 2020-12-16 |
| JP2019523810A (ja) | 2019-08-29 |
| EP3466924A4 (en) | 2020-04-15 |
| EP3466924A1 (en) | 2019-04-10 |
| CN107089927B (zh) | 2017-11-21 |
| CN107522892A (zh) | 2017-12-29 |
| AU2017275049B2 (en) | 2019-12-19 |
| CA3025030C (en) | 2021-05-04 |
| KR102346512B1 (ko) | 2021-12-31 |
| RU2708457C1 (ru) | 2019-12-09 |
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