CN107335472A - 一种磁性氧化铁杂多酸催化剂及其合成方法 - Google Patents
一种磁性氧化铁杂多酸催化剂及其合成方法 Download PDFInfo
- Publication number
- CN107335472A CN107335472A CN201710627287.4A CN201710627287A CN107335472A CN 107335472 A CN107335472 A CN 107335472A CN 201710627287 A CN201710627287 A CN 201710627287A CN 107335472 A CN107335472 A CN 107335472A
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- Prior art keywords
- iron oxide
- magnetic iron
- heteropolyacid catalyst
- catalyst
- synthetic method
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title claims abstract description 169
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 107
- 239000003054 catalyst Substances 0.000 title claims abstract description 76
- 239000011964 heteropoly acid Substances 0.000 title claims abstract description 74
- 238000010189 synthetic method Methods 0.000 title claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 41
- 238000006243 chemical reaction Methods 0.000 claims abstract description 36
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 238000000975 co-precipitation Methods 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 55
- 239000000243 solution Substances 0.000 claims description 32
- 230000032683 aging Effects 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 12
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 12
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229910001868 water Inorganic materials 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000010494 dissociation reaction Methods 0.000 claims description 3
- 230000005593 dissociations Effects 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 230000005415 magnetization Effects 0.000 claims description 3
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 claims description 3
- 239000002902 ferrimagnetic material Substances 0.000 claims description 2
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims description 2
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 claims description 2
- 238000001291 vacuum drying Methods 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000002028 Biomass Substances 0.000 abstract description 21
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 abstract description 16
- 230000003197 catalytic effect Effects 0.000 abstract description 9
- 230000007062 hydrolysis Effects 0.000 abstract description 6
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 6
- 230000003301 hydrolyzing effect Effects 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000006136 alcoholysis reaction Methods 0.000 abstract description 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 2
- 235000013980 iron oxide Nutrition 0.000 description 56
- 239000000047 product Substances 0.000 description 23
- 230000000694 effects Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 11
- 229910020881 PMo12O40 Inorganic materials 0.000 description 10
- 238000007171 acid catalysis Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 239000011973 solid acid Substances 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 4
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
- 235000009973 maize Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000010902 straw Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000008236 heating water Substances 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 229940040102 levulinic acid Drugs 0.000 description 2
- 238000004451 qualitative analysis Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 229910020628 SiW12O40 Inorganic materials 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- XTLNYNMNUCLWEZ-UHFFFAOYSA-N ethanol;propan-2-one Chemical compound CCO.CC(C)=O XTLNYNMNUCLWEZ-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 229910052603 melanterite Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- UYDPQDSKEDUNKV-UHFFFAOYSA-N phosphanylidynetungsten Chemical compound [W]#P UYDPQDSKEDUNKV-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- WNUPENMBHHEARK-UHFFFAOYSA-N silicon tungsten Chemical compound [Si].[W] WNUPENMBHHEARK-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CN201710627287.4A CN107335472B (zh) | 2017-07-28 | 2017-07-28 | 一种磁性氧化铁杂多酸催化剂及其合成方法 |
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CN201710627287.4A CN107335472B (zh) | 2017-07-28 | 2017-07-28 | 一种磁性氧化铁杂多酸催化剂及其合成方法 |
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CN107335472A true CN107335472A (zh) | 2017-11-10 |
CN107335472B CN107335472B (zh) | 2020-07-24 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913593A (zh) * | 2019-04-01 | 2019-06-21 | 长春工业大学 | 一种基于多酸的磁性纳米复合材料及其制备方法 |
CN113731499A (zh) * | 2021-09-08 | 2021-12-03 | 云南大学 | 一种1d/3d分等级异质结磁性半导体及其制备方法和应用 |
CN113731418A (zh) * | 2021-09-24 | 2021-12-03 | 国网黑龙江省电力有限公司电力科学研究院 | 一种无机结构硅钨系多金属氧酸盐掺杂三氧化二铁复合纳米催化材料及其制备和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01165542A (ja) * | 1987-12-23 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | カルボン酸類の製造方法 |
CN101108361A (zh) * | 2007-07-03 | 2008-01-23 | 浙江大学 | 八面沸石包覆磷钨杂多酸催化剂的制备方法 |
CN101638442A (zh) * | 2009-08-28 | 2010-02-03 | 中国科学院西双版纳热带植物园 | 一种水解木质纤维素的方法 |
CN101733148A (zh) * | 2008-11-21 | 2010-06-16 | 中国科学院化学研究所 | 磁性杂多酸催化剂及其制备方法与应用 |
US20100312006A1 (en) * | 2009-06-09 | 2010-12-09 | Meadwestvaco Corporation | Production of levulinic acid and levulinate esters from biomass |
-
2017
- 2017-07-28 CN CN201710627287.4A patent/CN107335472B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01165542A (ja) * | 1987-12-23 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | カルボン酸類の製造方法 |
CN101108361A (zh) * | 2007-07-03 | 2008-01-23 | 浙江大学 | 八面沸石包覆磷钨杂多酸催化剂的制备方法 |
CN101733148A (zh) * | 2008-11-21 | 2010-06-16 | 中国科学院化学研究所 | 磁性杂多酸催化剂及其制备方法与应用 |
US20100312006A1 (en) * | 2009-06-09 | 2010-12-09 | Meadwestvaco Corporation | Production of levulinic acid and levulinate esters from biomass |
CN101638442A (zh) * | 2009-08-28 | 2010-02-03 | 中国科学院西双版纳热带植物园 | 一种水解木质纤维素的方法 |
Non-Patent Citations (5)
Title |
---|
付云芝 等: "《应用化学综合实验教程》", 31 August 2012, 中国财富出版社 * |
储伟: "《催化剂工程》", 30 September 2006, 四川大学出版社 * |
徐蕾 等: "《负载型多酸光催化材料及应用》", 31 March 2015, 东北师范大学出版社 * |
林宁: "《药剂学》", 31 January 2008, 湖北长江出版集团 * |
许翠霞: ""磁性负载型杂多酸催化剂的制备及其催化噻吩烷基化反应的研究"", 《中国优秀硕士学位论文全文数据库(工程科技I辑)》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913593A (zh) * | 2019-04-01 | 2019-06-21 | 长春工业大学 | 一种基于多酸的磁性纳米复合材料及其制备方法 |
CN113731499A (zh) * | 2021-09-08 | 2021-12-03 | 云南大学 | 一种1d/3d分等级异质结磁性半导体及其制备方法和应用 |
CN113731499B (zh) * | 2021-09-08 | 2022-06-10 | 云南大学 | 一种1d/3d分等级异质结磁性半导体及其制备方法和应用 |
CN113731418A (zh) * | 2021-09-24 | 2021-12-03 | 国网黑龙江省电力有限公司电力科学研究院 | 一种无机结构硅钨系多金属氧酸盐掺杂三氧化二铁复合纳米催化材料及其制备和应用 |
CN113731418B (zh) * | 2021-09-24 | 2023-06-09 | 国网黑龙江省电力有限公司电力科学研究院 | 一种无机结构硅钨系多金属氧酸盐掺杂三氧化二铁复合纳米催化材料及其制备和应用 |
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