CN107207660B - 用于制备支化的聚烯烃的方法 - Google Patents

用于制备支化的聚烯烃的方法 Download PDF

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CN107207660B
CN107207660B CN201580075828.6A CN201580075828A CN107207660B CN 107207660 B CN107207660 B CN 107207660B CN 201580075828 A CN201580075828 A CN 201580075828A CN 107207660 B CN107207660 B CN 107207660B
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hydrocarbyl
bis
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metal
aluminum
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CN107207660A (zh
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D·达查特奥
M·鲍雅伊
L·甲辛斯卡-沃尔克
M·A·祖德维尔德
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SABIC Global Technologies BV
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09Long chain branches

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
CN201580075828.6A 2014-12-23 2015-12-23 用于制备支化的聚烯烃的方法 Active CN107207660B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14200125.4A EP3037438A1 (en) 2014-12-23 2014-12-23 Process for the preparation of a branched polyolefin
EP14200125.4 2014-12-23
PCT/EP2015/081203 WO2016102690A1 (en) 2014-12-23 2015-12-23 Process for the preparation of a branched polyolefin

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CN107207660A CN107207660A (zh) 2017-09-26
CN107207660B true CN107207660B (zh) 2020-02-14

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CN201580075828.6A Active CN107207660B (zh) 2014-12-23 2015-12-23 用于制备支化的聚烯烃的方法

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US (1) US10450388B2 (enExample)
EP (2) EP3037438A1 (enExample)
JP (1) JP6770960B2 (enExample)
KR (1) KR102510436B1 (enExample)
CN (1) CN107207660B (enExample)
SA (1) SA517381805B1 (enExample)
WO (1) WO2016102690A1 (enExample)

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US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
EP3387047B1 (en) 2015-12-09 2020-01-01 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10927196B2 (en) 2016-06-30 2021-02-23 Exxonmobil Chemical Patents Inc. Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent
WO2018160276A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160277A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) * 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
WO2019122455A1 (en) 2017-12-22 2019-06-27 Sabic Global Technologies B.V. Process for preparation of amorphous functionalized olefin copolymer
EP3728351A1 (en) 2017-12-22 2020-10-28 SABIC Global Technologies B.V. Process for preparation of ethylene and propylene ionomer
KR102320012B1 (ko) 2018-01-12 2021-11-02 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
WO2020140064A1 (en) * 2018-12-28 2020-07-02 Dow Global Technologies Llc Organometallic chain transfer agents
CN111116811B (zh) * 2020-01-03 2022-07-05 天津大学 一种1-丁烯/降冰片烯共聚物及其制备方法
WO2022029213A1 (en) * 2020-08-06 2022-02-10 Total Research & Technology Feluy Process for preparing ethylene polymers having long chain branches
JP7697239B2 (ja) * 2021-03-22 2025-06-24 日本ポリエチレン株式会社 エチレン重合用触媒の製造方法および前記エチレン重合用触媒を含むエチレン重合体またはエチレンとα-オレフィンとの共重合体の製造方法。
US20250170805A1 (en) * 2022-02-23 2025-05-29 Sealed Air Corporation (Us) Bulk cheese barrier bag

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JP2018500431A (ja) 2018-01-11
US10450388B2 (en) 2019-10-22
JP6770960B2 (ja) 2020-10-21
SA517381805B1 (ar) 2021-01-14
CN107207660A (zh) 2017-09-26
KR20170108958A (ko) 2017-09-27
EP3037438A1 (en) 2016-06-29
EP3237460A1 (en) 2017-11-01
KR102510436B1 (ko) 2023-03-14
US20170355786A1 (en) 2017-12-14
WO2016102690A1 (en) 2016-06-30

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