CN107108957A - 具有二氧化硅的天然橡胶化合物及在轮胎中的使用 - Google Patents
具有二氧化硅的天然橡胶化合物及在轮胎中的使用 Download PDFInfo
- Publication number
- CN107108957A CN107108957A CN201680005462.XA CN201680005462A CN107108957A CN 107108957 A CN107108957 A CN 107108957A CN 201680005462 A CN201680005462 A CN 201680005462A CN 107108957 A CN107108957 A CN 107108957A
- Authority
- CN
- China
- Prior art keywords
- rubber
- silica
- rubber composition
- phr
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 56
- 244000043261 Hevea brasiliensis Species 0.000 title claims abstract description 50
- 229920003052 natural elastomer Polymers 0.000 title claims abstract description 27
- 229920001194 natural rubber Polymers 0.000 title claims abstract description 27
- 150000001875 compounds Chemical class 0.000 title claims description 76
- 229920001971 elastomer Polymers 0.000 claims abstract description 112
- 239000005060 rubber Substances 0.000 claims abstract description 103
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 claims abstract description 34
- 241001495453 Parthenium argentatum Species 0.000 claims abstract description 30
- LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 claims abstract description 26
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 12
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 6
- 239000005061 synthetic rubber Substances 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 239000006229 carbon black Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 7
- 241001441571 Hiodontidae Species 0.000 claims description 5
- 241000341871 Taraxacum kok-saghyz Species 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 108060000307 allene oxide cyclase Proteins 0.000 claims description 2
- 241000221020 Hevea Species 0.000 claims 6
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims 2
- 229920001195 polyisoprene Polymers 0.000 claims 2
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 claims 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 claims 1
- 241000219793 Trifolium Species 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 18
- 239000011593 sulfur Substances 0.000 description 17
- 229910052717 sulfur Inorganic materials 0.000 description 17
- 239000000945 filler Substances 0.000 description 16
- 239000005077 polysulfide Substances 0.000 description 13
- 229920001021 polysulfide Polymers 0.000 description 13
- 150000008117 polysulfides Polymers 0.000 description 13
- 238000009472 formulation Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- -1 guayule compound Chemical class 0.000 description 10
- 239000000806 elastomer Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000000306 component Substances 0.000 description 6
- 238000004073 vulcanization Methods 0.000 description 6
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 238000000518 rheometry Methods 0.000 description 5
- 125000004434 sulfur atom Chemical group 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
- 238000011066 ex-situ storage Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 2
- 208000007811 Latex Hypersensitivity Diseases 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 244000197975 Solidago virgaurea Species 0.000 description 2
- 235000000914 Solidago virgaurea Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 102000007641 Trefoil Factors Human genes 0.000 description 2
- 235000015724 Trifolium pratense Nutrition 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine group Chemical group NC(=N)N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000010058 rubber compounding Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- HRBGPDOPANSWHU-UHFFFAOYSA-N 2-(triethoxy-lambda4-sulfanyl)ethylsilane Chemical compound C(C)OS(OCC)(OCC)CC[SiH3] HRBGPDOPANSWHU-UHFFFAOYSA-N 0.000 description 1
- JMTSYRHCTRYKHH-UHFFFAOYSA-N 3-(triethoxy-lambda4-sulfanyl)propylsilane Chemical compound CCOS(OCC)(OCC)CCC[SiH3] JMTSYRHCTRYKHH-UHFFFAOYSA-N 0.000 description 1
- OUDROXNVPSWFCG-UHFFFAOYSA-N 3-methoxysulfanylpropyl(dimethyl)silane Chemical compound COSCCC[SiH](C)C OUDROXNVPSWFCG-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- 241001071161 Asclepias Species 0.000 description 1
- RWWBMFHMBPHCLJ-UHFFFAOYSA-N CCCCCCCCCCCCCCCCO[S+](CCC[SiH2]OCC)OCCCCCCCCCCCCCCCC Chemical compound CCCCCCCCCCCCCCCCO[S+](CCC[SiH2]OCC)OCCCCCCCCCCCCCCCC RWWBMFHMBPHCLJ-UHFFFAOYSA-N 0.000 description 1
- USSWDCUBGJSFSD-UHFFFAOYSA-N CCCCCCCCCCCCO[S+](CCC[SiH2]OCC)OCCCCCCCCCCCC Chemical compound CCCCCCCCCCCCO[S+](CCC[SiH2]OCC)OCCCCCCCCCCCC USSWDCUBGJSFSD-UHFFFAOYSA-N 0.000 description 1
- UIFNCFXNSYKDME-UHFFFAOYSA-N CCO[SiH2]CCC[S+](OC)OC Chemical compound CCO[SiH2]CCC[S+](OC)OC UIFNCFXNSYKDME-UHFFFAOYSA-N 0.000 description 1
- KXALBLJBEDOYEY-UHFFFAOYSA-N COS(OC)(OC)CCC[SiH3] Chemical compound COS(OC)(OC)CCC[SiH3] KXALBLJBEDOYEY-UHFFFAOYSA-N 0.000 description 1
- GPVHICUANZWBLF-UHFFFAOYSA-N CO[S+](CCC[SiH2]C)OC Chemical compound CO[S+](CCC[SiH2]C)OC GPVHICUANZWBLF-UHFFFAOYSA-N 0.000 description 1
- 241000041806 Cacalia Species 0.000 description 1
- 235000009503 Cacalia atriplicifolia Nutrition 0.000 description 1
- 244000108253 Cacalia atriplicifolia Species 0.000 description 1
- 241000703226 Campanula americana Species 0.000 description 1
- 241000703121 Campanula rotundifolia Species 0.000 description 1
- 240000009275 Cryptostegia grandiflora Species 0.000 description 1
- 241001232454 Ericameria nauseosa Species 0.000 description 1
- 244000207543 Euphorbia heterophylla Species 0.000 description 1
- 229930185597 Euphorbia lathyris Natural products 0.000 description 1
- 241001553700 Euphorbia lathyris Species 0.000 description 1
- 244000286663 Ficus elastica Species 0.000 description 1
- 241000201986 Galenia Species 0.000 description 1
- 235000017396 Menta cendrata Nutrition 0.000 description 1
- 235000010672 Monarda didyma Nutrition 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241001003282 Parthenium incanum Species 0.000 description 1
- 102000002508 Peptide Elongation Factors Human genes 0.000 description 1
- 108010068204 Peptide Elongation Factors Proteins 0.000 description 1
- 241001062991 Pycnanthemum Species 0.000 description 1
- 244000178112 Pycnanthemum incanum Species 0.000 description 1
- 235000012230 Pycnanthemum incanum Nutrition 0.000 description 1
- 206010039251 Rubber sensitivity Diseases 0.000 description 1
- 101710149959 Small rubber particle protein Proteins 0.000 description 1
- 241000607059 Solidago Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000245665 Taraxacum Species 0.000 description 1
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 1
- 241001154912 Teucrium canadense Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- PYSAMOQTNZQMIN-UHFFFAOYSA-N ethoxy(propan-2-yl)silane Chemical compound CCO[SiH2]C(C)C PYSAMOQTNZQMIN-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 201000005391 latex allergy Diseases 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229940032017 n-oxydiethylene-2-benzothiazole sulfenamide Drugs 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000006235 reinforcing carbon black Substances 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C4/00—Treatment of rubber before vulcanisation, not provided for in groups C08C1/00 - C08C3/02
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
- B60C2001/0058—Compositions of the bead apexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C2200/00—Tyres specially adapted for particular applications
- B60C2200/02—Tyres specially adapted for particular applications for aircrafts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Life Sciences & Earth Sciences (AREA)
- Genetics & Genomics (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Tires In General (AREA)
- Molecular Biology (AREA)
- Biomedical Technology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562102211P | 2015-01-12 | 2015-01-12 | |
| US62/102,211 | 2015-01-12 | ||
| PCT/US2016/013043 WO2016115132A1 (en) | 2015-01-12 | 2016-01-12 | Natural rubber compounds with silica and use with tires |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107108957A true CN107108957A (zh) | 2017-08-29 |
Family
ID=56406291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680005462.XA Pending CN107108957A (zh) | 2015-01-12 | 2016-01-12 | 具有二氧化硅的天然橡胶化合物及在轮胎中的使用 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10538600B2 (enExample) |
| EP (1) | EP3245250A4 (enExample) |
| JP (1) | JP6842426B2 (enExample) |
| KR (1) | KR102472476B1 (enExample) |
| CN (1) | CN107108957A (enExample) |
| BR (1) | BR112017014870B1 (enExample) |
| CA (1) | CA2972933C (enExample) |
| MX (1) | MX389436B (enExample) |
| WO (1) | WO2016115132A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201600131325A1 (it) * | 2016-12-27 | 2018-06-27 | Pirelli | Composizioni elastomeriche comprendenti gomme naturali da Guayule per componenti di pneumatici e pneumatici che le comprendono |
| ES2994255T3 (en) * | 2017-01-24 | 2025-01-21 | Smarterials Tech Gmbh | Damage-resistant gloves with breach-indicator function |
| US20180229553A1 (en) * | 2017-02-13 | 2018-08-16 | Cooper Tire & Rubber Company | Tire tread compound |
| WO2018148725A1 (en) * | 2017-02-13 | 2018-08-16 | Cooper Tire & Rubber Company | Guayule tire tread compound |
| JP7243036B2 (ja) * | 2018-04-24 | 2023-03-22 | 横浜ゴム株式会社 | 空気入りタイヤ |
| EP3788103A4 (en) | 2018-05-04 | 2022-01-12 | Bridgestone Americas Tire Operations, LLC | RUBBER COMPOSITION FOR TIRE TREAD |
| WO2019213233A1 (en) | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| WO2019213226A1 (en) * | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| US12370830B2 (en) | 2018-05-04 | 2025-07-29 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| US20210237510A1 (en) * | 2018-05-04 | 2021-08-05 | Bridgestone Americas Tire Operations, Llc | Tire Tread Rubber Composition |
| JP7445681B2 (ja) | 2019-05-29 | 2024-03-07 | ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー | タイヤトレッドゴム組成物及び関連方法 |
| WO2020243304A1 (en) | 2019-05-29 | 2020-12-03 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| WO2020243308A1 (en) | 2019-05-29 | 2020-12-03 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| DE102019213148A1 (de) * | 2019-08-30 | 2021-03-04 | Continental Reifen Deutschland Gmbh | Kautschukmischung für Zweiradreifenlaufstreifen |
| EP3800066B1 (en) | 2019-10-06 | 2025-11-05 | Silpara Technologies, Inc. | Molecular composites of functional silica and natural rubber |
| EP4263621A1 (en) * | 2020-12-18 | 2023-10-25 | Bridgestone Corporation | Tire rubber compositions combining bagasse-containing guayule rubber with silane and related methods |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102083892A (zh) * | 2008-07-24 | 2011-06-01 | 内格罗梅克斯工业可变动资本额公司 | 制造硅烷、疏水化的二氧化硅、二氧化硅母料及橡胶产品的方法 |
| US20130203940A1 (en) * | 2012-02-02 | 2013-08-08 | Lion Copolymer, Llc | Preparation of styrene butadiene rubber masterbatch using polyamide and an epoxidized silica |
| US20130203915A1 (en) * | 2012-02-02 | 2013-08-08 | Lion Copolymer, Llc | Compatibilized silica with a plurality of silanes and a polymer silica-reinforced masterbatch |
| US20130253088A1 (en) * | 2012-03-06 | 2013-09-26 | Bridgestone Corporation | Cured guayule rubber containing compositions and method for preparing same |
| WO2013173625A1 (en) * | 2012-05-16 | 2013-11-21 | Bridgestone Corporation | Compositions containing purified non-hevea rubber and related purification methods |
| CN103772760A (zh) * | 2014-01-23 | 2014-05-07 | 怡维怡橡胶研究院有限公司 | 一种以天然橡胶/炭黑、合成聚异戊二烯橡胶/白炭黑为母胶的橡胶组合物及其加工工艺 |
| US20140357803A1 (en) * | 2013-05-30 | 2014-12-04 | Arindam Mazumdar | Functionalized elastomer |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1004558B (it) | 1972-08-31 | 1976-07-20 | Ppg Industries Inc | Agente copulante silanato per gomma |
| US3814160A (en) | 1972-09-18 | 1974-06-04 | Ppg Industries Inc | Tread wear indicator |
| US4621118A (en) * | 1985-03-21 | 1986-11-04 | The Firestone Tire & Rubber Company | Sulfurized guayule resin and rubber |
| JP4679312B2 (ja) * | 2002-03-28 | 2011-04-27 | 株式会社ブリヂストン | 天然ゴム、ゴム組成物及び空気入りタイヤ |
| BR0313418A (pt) | 2002-08-03 | 2005-07-05 | Degussa | ácido silìcico precipitado altamente disperso com alta superfìcie |
| US7923039B2 (en) | 2005-01-05 | 2011-04-12 | Yulex Corporation | Biopolymer extraction from plant materials |
| US7259231B2 (en) | 2004-10-12 | 2007-08-21 | Yulex Corporation | Extraction and fractionation of biopolymers and resins from plant materials |
| US7594528B2 (en) | 2007-03-08 | 2009-09-29 | The Goodyear Tire & Rubber Company | Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber |
| JP5570153B2 (ja) * | 2009-07-22 | 2014-08-13 | 株式会社ブリヂストン | タイヤ |
| JP5545102B2 (ja) * | 2010-07-30 | 2014-07-09 | 戸田工業株式会社 | 疎水性シリカ粒子粉末及びその製造法並びに該疎水性シリカ粒子粉末を用いたゴム組成物 |
| US9833037B2 (en) * | 2013-11-11 | 2017-12-05 | Nike, Inc. | Natural rubber outsoles and footwear |
| US20150159001A1 (en) * | 2013-12-05 | 2015-06-11 | The Goodyear Tire & Rubber Company | Rubber composition and pneumatic tire |
-
2016
- 2016-01-12 MX MX2017009165A patent/MX389436B/es unknown
- 2016-01-12 CA CA2972933A patent/CA2972933C/en active Active
- 2016-01-12 BR BR112017014870-6A patent/BR112017014870B1/pt active IP Right Grant
- 2016-01-12 US US15/542,528 patent/US10538600B2/en active Active
- 2016-01-12 WO PCT/US2016/013043 patent/WO2016115132A1/en not_active Ceased
- 2016-01-12 KR KR1020177022644A patent/KR102472476B1/ko active Active
- 2016-01-12 JP JP2017555447A patent/JP6842426B2/ja active Active
- 2016-01-12 EP EP16737732.4A patent/EP3245250A4/en active Pending
- 2016-01-12 CN CN201680005462.XA patent/CN107108957A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102083892A (zh) * | 2008-07-24 | 2011-06-01 | 内格罗梅克斯工业可变动资本额公司 | 制造硅烷、疏水化的二氧化硅、二氧化硅母料及橡胶产品的方法 |
| US20130203940A1 (en) * | 2012-02-02 | 2013-08-08 | Lion Copolymer, Llc | Preparation of styrene butadiene rubber masterbatch using polyamide and an epoxidized silica |
| US20130203915A1 (en) * | 2012-02-02 | 2013-08-08 | Lion Copolymer, Llc | Compatibilized silica with a plurality of silanes and a polymer silica-reinforced masterbatch |
| US20130253088A1 (en) * | 2012-03-06 | 2013-09-26 | Bridgestone Corporation | Cured guayule rubber containing compositions and method for preparing same |
| WO2013173625A1 (en) * | 2012-05-16 | 2013-11-21 | Bridgestone Corporation | Compositions containing purified non-hevea rubber and related purification methods |
| US20140357803A1 (en) * | 2013-05-30 | 2014-12-04 | Arindam Mazumdar | Functionalized elastomer |
| CN103772760A (zh) * | 2014-01-23 | 2014-05-07 | 怡维怡橡胶研究院有限公司 | 一种以天然橡胶/炭黑、合成聚异戊二烯橡胶/白炭黑为母胶的橡胶组合物及其加工工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102472476B1 (ko) | 2022-11-29 |
| US20180265601A1 (en) | 2018-09-20 |
| US10538600B2 (en) | 2020-01-21 |
| BR112017014870A2 (pt) | 2018-03-13 |
| BR112017014870B1 (pt) | 2022-09-27 |
| CA2972933A1 (en) | 2016-07-21 |
| EP3245250A1 (en) | 2017-11-22 |
| CA2972933C (en) | 2023-03-14 |
| MX2017009165A (es) | 2017-10-16 |
| WO2016115132A1 (en) | 2016-07-21 |
| EP3245250A4 (en) | 2018-07-25 |
| JP2018502980A (ja) | 2018-02-01 |
| KR20170103954A (ko) | 2017-09-13 |
| JP6842426B2 (ja) | 2021-03-17 |
| MX389436B (es) | 2025-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107108957A (zh) | 具有二氧化硅的天然橡胶化合物及在轮胎中的使用 | |
| CN105579247B (zh) | 硫可交联的橡胶共混物以及车辆轮胎 | |
| US10273351B2 (en) | Rubber mixture and vehicle tires | |
| CN102884120B (zh) | 轮胎胎面用橡胶组合物 | |
| CN103201335B (zh) | 用于公用车辆的充气轮胎 | |
| JP6429883B2 (ja) | 硫黄架橋可能なゴム混合物および自動車両用タイヤ | |
| CN103958592B (zh) | 二氧化硅填充的橡胶组合物及其制备方法 | |
| CN105801936B (zh) | 用于二氧化硅增强的橡胶配制物的添加剂 | |
| US9556331B2 (en) | Rubber composition containing pre-hydrophobated silica with zinc salt fatty acid processing aid and tire with tread | |
| EP2452831B1 (en) | Tire with tread containing carboxylated styrene/butadiene rubber | |
| WO2013001826A1 (ja) | タイヤ用ゴム組成物、空気入りタイヤ、及びタイヤ用ゴム組成物の製造方法 | |
| JP2002293994A (ja) | シリカ強化材、およびジエン／ヒドロキシル側基含有ビニル芳香族化合物の乳化重合由来三元共重合体ゴムを含むゴム組成物の構成部材を有するタイヤ | |
| CN105829370B (zh) | 橡胶混合物及车辆轮胎 | |
| US11999854B2 (en) | Rubber composition | |
| CN111491998B (zh) | 硫可交联的橡胶混合物、橡胶混合物的硫化橡胶和车辆轮胎 | |
| US20220220288A1 (en) | A rubber composition | |
| CN114787201A (zh) | 硫可交联的橡胶混合物和充气车辆轮胎 | |
| CN116209712A (zh) | 可交联橡胶混合物及充气车辆轮胎 | |
| CN102596591A (zh) | 胎面混炼胶 | |
| US20180086900A1 (en) | Preparation of silica reinforced rubber composition, rubber composition and tire with component |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20230417 Address after: Ohio, USA Applicant after: THE GOODYEAR TIRE & RUBBER Co. Address before: Ohio, USA Applicant before: COOPER TIRE & RUBBER Co. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170829 |