CN107056248A - 一种建筑物外墙用防火保温陶瓷材料 - Google Patents
一种建筑物外墙用防火保温陶瓷材料 Download PDFInfo
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- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000010453 quartz Substances 0.000 claims abstract description 23
- 239000000853 adhesive Substances 0.000 claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 claims abstract description 22
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003365 glass fiber Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 14
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 8
- 229920002367 Polyisobutene Polymers 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 8
- 239000011118 polyvinyl acetate Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical group O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 3
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical group [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000395 magnesium oxide Substances 0.000 abstract description 4
- 239000005995 Aluminium silicate Substances 0.000 abstract description 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 229910052582 BN Inorganic materials 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 3
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- -1 zirconium alkoxide Chemical class 0.000 description 2
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical group [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
本发明公开了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:70‑90份、氧化铁:10‑20份、氧化镁:5‑12份、硅藻土:1‑9份、玻璃纤维:2‑6份、碳纤维:2‑8份、白云:3‑5份、氮化硼:2‑10份、石英:2‑10份、纳米氧化镁:2‑8份、胶黏剂:3‑10份。本发明陶瓷材料具有防火、保温、使用寿命长等特点,在建筑材料领域具有实用性和应用前景。
Description
技术领域
本发明涉及建筑材料领域,具体涉及一种建筑物外墙用防火保温陶瓷材料。
背景技术
陶瓷作为一种优异的建筑材料,具有多种广泛用途,如在生活用品、建筑材料、机械加工材料等。陶瓷材料具有诸多使用优点,如美观大方、耐酸碱、耐高温等。氧化锆是陶瓷材料中常见的组份,具有良好的抗折强度,被誉为“陶瓷钢”,但其比重较大,通常会增加成品的重量。磷酸锆最为一种新型的陶瓷材料,具有高强度、耐高温、致密稳定、低膨胀等特点,受到了陶瓷界越来越多的重视,但磷酸锆陶瓷也存在一些缺陷,如烧结温度高,通常1600℃也很难烧结,力学强度较低等。CN1844042A报道了一种磷酸锆陶瓷的制备方法,采用氧化镁、氧化铝、氧化硅作为烧结助剂,与磷酸锆粉体混合烧结。化学制备技术是一种将有机材料与无机材料结合的一种有效方法,具有低成本、可调控多种复合材料功能及组份、适于批量生产等诸多优势,涉及无机材料、有机材料、复合材料等众多领域。CN102351532A报道了氧化锆和氧化铝复合陶瓷的制备方法,通过自组装技术合成复合物,经过低温热处理得到复合陶瓷材料。
发明内容
针对现有技术的不足,本发明提供了一种建筑物外墙用防火保温陶瓷材料,具有防火保温,使用寿命长的优点。
为实现以上目的,本发明通过以下技术方案予以实现:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:70-90份、氧化铁:10-20份、氧化镁:5-12份、硅藻土:1-9份、玻璃纤维:2-6份、碳纤维:2-8份、白云:3-5份、氮化硼:2-10份、石英:2-10份、纳米氧化镁:2-8份、胶黏剂:3-10份;
优选的,由以下重量份数的原料制备而成:高岭土:75-88份、氧化铁:12-18份、氧化镁:6-11份、硅藻土:2-8份、玻璃纤维:4-5份、碳纤维:3-6份、白云:3-5份、氮化硼:3-9份、石英:4-8份、纳米氧化镁:3-5份、胶黏剂:6-8份。
优选的,由以下重量份数的原料制备而成:高岭土:75份、氧化铁:14份、Co2O3:6份、硅藻土:3份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:3份、石英:4份、纳米氧化镁:4份、胶黏剂:6份。
优选的,由以下重量份数的原料制备而成:高岭土:88份、氧化铁:12份、氧化镁:10份、硅藻土:5份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:4份、石英:6份、纳米氧化镁:3份、胶黏剂:6份。
优选的,所述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
优选的,所述的石英为颗粒状。
本发明有益效果:
本发明与现有技术相比,其显著优点:其一、在化学合成过程中,有机锆醇盐、钛醇盐、硫酸铝、硫酸镁及硫酸锌经酸解、化学聚合,形成稳定的锆钛铝镁锌基复合前驱体,有助于形成含氧化锆、氧化钛、氧化铝、氧化镁及氧化锌的陶瓷材料;其二、得到的陶瓷材料中,磷酸锆、氧化锆、氧化钛、氧化铝、氧化镁及氧化锌均匀分散于透辉石及高岭土中,具有良好的微观结构;其三、该化学制备技术可推广用于制备其他多功能复合陶瓷。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明的实施例,对本发明实施例中的技术方案进行清楚、完整地描述。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:70份、氧化铁:10份、氧化镁:5份、硅藻土:1份、玻璃纤维:2份、碳纤维:2份、白云:3份、氮化硼:2份、石英:2份、纳米氧化镁:2份、胶黏剂:3份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
实施例2:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:90份、氧化铁:20份、氧化镁:12份、硅藻土:9份、玻璃纤维:6份、碳纤维:8份、白云:5份、氮化硼:10份、石英:10份、纳米氧化镁:8份、胶黏剂:10份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
实施例3:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:75份、氧化铁:12份、氧化镁:6份、硅藻土:2份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:3份、石英:4份、纳米氧化镁:3份、胶黏剂:6份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
实施例4:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:88份、氧化铁:18份、氧化镁:11份、硅藻土:8份、玻璃纤维:5份、碳纤维:6份、白云:5份、氮化硼:9份、石英:8份、纳米氧化镁:5份、胶黏剂:8份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
实施例5:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:75份、氧化铁:14份、氧化镁:6份、硅藻土:3份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:3份、石英:4份、纳米氧化镁:4份、胶黏剂:6份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
实施例6:
本发明提供了一种建筑物外墙用防火保温陶瓷材料,由以下重量份数的原料制备而成:高岭土:88份、氧化铁:12份、氧化镁:10份、硅藻土:5份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:4份、石英:6份、纳米氧化镁:3份、胶黏剂:6份;
上述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
上述的石英为颗粒状。
以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。
Claims (6)
1.一种建筑物外墙用防火保温陶瓷材料,其特征在于,由以下重量份数的原料制备而成:高岭土:70-90份、氧化铁:10-20份、氧化镁:5-12份、硅藻土:1-9份、玻璃纤维:2-6份、碳纤维:2-8份、白云:3-5份、氮化硼:2-10份、石英:2-10份、纳米氧化镁:2-8份、胶黏剂:3-10份。
2.如权利要求1所述的建筑物外墙用防火保温陶瓷材料,其特征在于,由以下重量份数的原料制备而成:高岭土:75-88份、氧化铁:12-18份、Co2O3:6-11份、硅藻土:2-8份、玻璃纤维:4-5份、碳纤维:3-6份、白云:3-5份、氮化硼:3-9份、石英:4-8份、纳米氧化镁:3-5份、胶黏剂:6-8份。
3.如权利要求2所述的建筑物外墙用防火保温陶瓷材料,其特征在于,由以下重量份数的原料制备而成:高岭土:75份、氧化铁:14份、Co2O3:6份、硅藻土:3份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:3份、石英:4份、纳米氧化镁:4份、胶黏剂:6份。
4.如权利要求2所述的建筑物外墙用防火保温陶瓷材料,其特征在于,由以下重量份数的原料制备而成:高岭土:88份、氧化铁:12份、氧化镁:10份、硅藻土:5份、玻璃纤维:4份、碳纤维:3份、白云:3份、氮化硼:4份、石英:6份、纳米氧化镁:3份、胶黏剂:6份。
5.如权利要求1所述的建筑物外墙用防火保温陶瓷材料,其特征在于,所述的胶黏剂为聚乙酸乙烯酯、聚乙烯醇、过氯乙烯、聚异丁烯的一种。
6.如权利要求1所述的建筑物外墙用防火保温陶瓷材料,其特征在于,所述的石英为颗粒状。
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