CN106747332A - 一种高强度高韧性陶瓷材料 - Google Patents
一种高强度高韧性陶瓷材料 Download PDFInfo
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- CN106747332A CN106747332A CN201611143432.3A CN201611143432A CN106747332A CN 106747332 A CN106747332 A CN 106747332A CN 201611143432 A CN201611143432 A CN 201611143432A CN 106747332 A CN106747332 A CN 106747332A
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- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 46
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002657 fibrous material Substances 0.000 claims abstract description 21
- 239000012745 toughening agent Substances 0.000 claims abstract description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 19
- 239000006184 cosolvent Substances 0.000 claims abstract description 18
- 239000006260 foam Substances 0.000 claims abstract description 18
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 14
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 14
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 13
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 13
- 230000000996 additive effect Effects 0.000 claims abstract description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 239000000919 ceramic Substances 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 8
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 5
- 239000005695 Ammonium acetate Substances 0.000 claims description 5
- 235000019257 ammonium acetate Nutrition 0.000 claims description 5
- 229940043376 ammonium acetate Drugs 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 235000011056 potassium acetate Nutrition 0.000 claims description 4
- 239000001632 sodium acetate Substances 0.000 claims description 4
- 235000017281 sodium acetate Nutrition 0.000 claims description 4
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 4
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical class NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000005619 boric acid group Chemical group 0.000 claims description 2
- -1 lead acetate Chemical compound 0.000 claims description 2
- 229940046892 lead acetate Drugs 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229960004109 potassium acetate Drugs 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000004246 zinc acetate Substances 0.000 claims description 2
- 229960000314 zinc acetate Drugs 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims 1
- 239000004872 foam stabilizing agent Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000009776 industrial production Methods 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical group [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GTTYPHLDORACJW-UHFFFAOYSA-N nitric acid;sodium Chemical compound [Na].O[N+]([O-])=O GTTYPHLDORACJW-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229960004249 sodium acetate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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Abstract
本发明提供一种高强度高韧性陶瓷材料，由以下原料制成：锆英石、高岭土、纤维材料、碳化硅、二氧化钛、复合外加剂、氮化铝、碳酸钙、增韧剂、稳泡剂、醋酸盐、助溶剂。本发明高强度高韧性陶瓷材料具有良好的抗弯强度和断裂韧性、抗冲击性优良，且热稳定性能和耐腐蚀性能好，本发明高强度高韧性陶瓷材料还具有优良的耐高温、抗热震性能，因此使钛酸铝陶瓷得到实际应用，使其能够被广泛应用到工业生产中。
Description
技术领域
本发明涉及陶瓷无机非金属材料技术领域，具体涉及一种高强度高韧性陶瓷材料。
背景技术
陶瓷材料是用天然或合成化合物经过成形和高温烧结制成的一类无机非金属材料，具有高的熔点，且在高温下具有极好的化学稳定性；其导热性低于金属材料，还是良好的隔热材料，当温度发生变化时，陶瓷具有良好的尺寸稳定性，陶瓷材料在高温下不易氧化，并对酸、碱、盐具有良好的抗腐蚀能力，且具有高耐磨性、耐氧化等优点，可用作结构材料、刀具材料。 在热和机械性能方面，陶瓷材料有耐高温、隔热、耐磨耗等优势；在化学方面有催化、耐腐蚀、吸附等功能；在生物方面，具有一定生物相容性能，可作为生物结构材料等。
鉴于陶瓷材料的种种特点，因此研究开发新型功能陶瓷是材料科学中的一个重要领域。 但是，经研究发现，陶瓷材料的优势特点很多但还是存在一些欠缺，比如抗拉强度较低，塑性和韧性很差，且性脆，易损坏，这限制了陶瓷材料的应用。
发明内容
针对现有技术不足，本发明提供一种高强度高韧性陶瓷材料，解决了现有技术中陶瓷材料抗拉强度较低、塑性差、韧性差、且性脆的技术问题。
为实现以上目的，本发明的技术方案通过以下技术方案予以实现：
一种高强度高韧性陶瓷材料，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石20-40份、高岭土25-45份、纤维材料10-20份、碳化硅3-10份、二氧化钛3-9份、复合外加剂5-10份、氮化铝3-10份、碳酸钙5-10份、增韧剂6-13份、稳泡剂4-12份、醋酸盐6-15份、助溶剂6-12份。
优选的，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石25-35份、高岭土30-40份、纤维材料11-18份、碳化硅5-8份、二氧化钛4-8份、复合外加剂6-9份、氮化铝5-9份、碳酸钙6-8份、增韧剂7-11份、稳泡剂6-10份、醋酸盐8-13份、助溶剂8-11份。
优选的，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石30份、高岭土35份、纤维材料15份、碳化硅7份、二氧化钛6份、复合外加剂8份、氮化铝7份、碳酸钙8份、增韧剂9份、稳泡剂8份、醋酸盐10份、助溶剂9份。
优选的，所述增韧剂为氧化铝、氧化锆、碳化钛中的一种。
优选的，所述复合外加剂为硫酸钠、三乙醇胺、有机硅中的至少一种。
优选的，所述醋酸盐为乙酸钠、乙酸钾、乙酸铵、乙酸铅、乙酸锌中的至少一种。
优选的，所述助溶剂为碳酸钠、硝酸钠、氟硅酸钠、乙二胺盐中的至少一种。
优选的，所述稳泡剂为硼酸、氧化铁、磷酸钠中的至少一种。
优选的，所述纤维材料为碳纤维、玻璃纤维、矿渣纤维、莫来石纤维中的一种。
本发明提供一种高强度高韧性陶瓷材料，与现有技术相比优点在于：
本发明高强度高韧性陶瓷材料具有良好的抗弯强度和断裂韧性、抗冲击性优良，且热稳定性能和耐腐蚀性能好，其抗弯强度能够达到1500-1598Mpa，断裂韧性能够达到16.2-17.5Mpa·m1/2，本发明高强度高韧性陶瓷材料还具有优良的耐高温、抗热震性能，因此使钛酸铝陶瓷得到实际应用，使其能够被广泛应用到工业生产中；
本发明原料中加入纤维材料，能够增强材料的韧性，纤维的引入不仅提高了陶瓷材料的韧性,更重要的是使陶瓷材料的断裂行为发生了根本性变化，由原来的脆性断裂变成了非脆性断裂；本发明采用锆英石、碳化硅、二氧化钛、氮化铝、碳酸钙、增韧剂再配合其他原料，制成高强度高韧性的陶瓷材料，该材料的硬度高，并且有优良的韧性，耐磨蚀性强，不易碎，不易产生划痕。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面结合本发明实施例对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
本实施例高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石20份、高岭土25份、纤维材料10份、碳化硅3份、二氧化钛3份、复合外加剂5份、氮化铝3份、碳酸钙5份、增韧剂6份、稳泡剂4份、醋酸盐6份、助溶剂6份。
其中增韧剂为氧化铝；醋酸盐为乙酸铵；助溶剂为碳酸钠，稳泡剂为磷酸钠；纤维材料为碳纤维。
实施例2：
本实施例高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石30份、高岭土35份、纤维材料15份、碳化硅7份、二氧化钛6份、复合外加剂8份、氮化铝7份、碳酸钙8份、增韧剂9份、稳泡剂8份、醋酸盐10份、助溶剂9份。
其中增韧剂为碳化钛；醋酸盐为乙酸钠、乙酸钾、乙酸铵混合而成；助溶剂为氟硅酸钠，稳泡剂为氧化铁；纤维材料为碳纤维。
实施例3：
本实施例高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石40份、高岭土45份、纤维材料20份、碳化硅10份、二氧化钛9份、复合外加剂10份、氮化铝10份、碳酸钙10份、增韧剂13份、稳泡剂12份、醋酸盐15份、助溶剂12份。
其中增韧剂为氧化铝；醋酸盐为乙酸钾；助溶剂为碳酸钠，稳泡剂为硼酸和氧化铁混合而成；纤维材料为矿渣纤维。
实施例4：
本实施例高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石25份、高岭土30份、纤维材料11份、碳化硅5份、二氧化钛4份、复合外加剂6份、氮化铝5份、碳酸钙6份、增韧剂7份、稳泡剂6份、醋酸盐8份、助溶剂8份。
其中增韧剂为碳化钛；醋酸盐为乙酸铵；助溶剂为硝酸钠，稳泡剂为氧化铁；纤维材料为玻璃纤维。
实施例5：
本实施例高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石35份、高岭土40份、纤维材料18份、碳化硅8份、二氧化钛8份、复合外加剂9份、氮化铝9份、碳酸钙8份、增韧剂11份、稳泡剂10份、醋酸盐13份、助溶剂11份。
其中增韧剂为氧化锆；醋酸盐为乙酸钠；助溶剂为碳酸钠，稳泡剂为碳酸钠、硝酸钠、氟硅酸钠、乙二胺盐混合而成；纤维材料为莫来石纤维。
将实施例1-实施例5制备的高强度高韧性陶瓷材料和常规配方制得的陶瓷材料进行性能测试，结构见表1。
表1 不同样品材料性能测试结果
| 项目 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 对比例 |
| 抗弯强度/Mpa | 1500 | 1598 | 1580 | 1565 | 1572 | 1203 |
| 断裂韧性/Mpa•m1/2 | 16.2 | 17.5 | 16.5 | 17.0 | 17.1 | 14.2 |
由表1可看出，本发明高强度高韧性陶瓷材料，其抗弯强度能够达到1500-1598Mpa，断裂韧性能够达到16.2-17.5Mpa•m1/2，本发明高强度高韧性陶瓷材料的抗弯强度和断裂韧性均优于对比例。
综上所述，本发明原料中加入纤维材料，能够增强材料的韧性，纤维的引入不仅提高了陶瓷材料的韧性,更重要的是使陶瓷材料的断裂行为发生了根本性变化，由原来的脆性断裂变成了非脆性断裂；本发明采用锆英石、碳化硅、二氧化钛、氮化铝、碳酸钙、增韧剂再配合其他原料，制成高强度高韧性的陶瓷材料，该材料的硬度高，并且有优良的韧性，耐磨蚀性强，不易碎，不易产生划痕。
需要说明的是，以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。
Claims (9)
1.一种高强度高韧性陶瓷材料，其特征在于，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石20-40份、高岭土25-45份、纤维材料10-20份、碳化硅3-10份、二氧化钛3-9份、复合外加剂5-10份、氮化铝3-10份、碳酸钙5-10份、增韧剂6-13份、稳泡剂4-12份、醋酸盐6-15份、助溶剂6-12份。
2.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石25-35份、高岭土30-40份、纤维材料11-18份、碳化硅5-8份、二氧化钛4-8份、复合外加剂6-9份、氮化铝5-9份、碳酸钙6-8份、增韧剂7-11份、稳泡剂6-10份、醋酸盐8-13份、助溶剂8-11份。
3.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于，所述高强度高韧性陶瓷材料由以下重量份的原料制成：锆英石30份、高岭土35份、纤维材料15份、碳化硅7份、二氧化钛6份、复合外加剂8份、氮化铝7份、碳酸钙8份、增韧剂9份、稳泡剂8份、醋酸盐10份、助溶剂9份。
4.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：所述增韧剂为氧化铝、氧化锆、碳化钛中的一种。
5.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：所述复合外加剂为硫酸钠、三乙醇胺、有机硅中的至少一种。
6.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：所述醋酸盐为乙酸钠、乙酸钾、乙酸铵、乙酸铅、乙酸锌中的至少一种。
7.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：
所述助溶剂为碳酸钠、硝酸钠、氟硅酸钠、乙二胺盐中的至少一种。
8.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：所述稳泡剂为硼酸、氧化铁、磷酸钠中的至少一种。
9.根据权利要求1所述的高强度高韧性陶瓷材料，其特征在于：
所述纤维材料为碳纤维、玻璃纤维、矿渣纤维、莫来石纤维中的一种。
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| CN107311623A (zh) * | 2017-09-02 | 2017-11-03 | 佛山市嘉亿艺术陶瓷研究有限公司 | 一种陶制茶具用增韧陶土 |
| CN107686357A (zh) * | 2017-09-29 | 2018-02-13 | 马鞍山松鹤信息科技有限公司 | 一种高强度陶瓷材料及其制备工艺 |
| CN108329009A (zh) * | 2018-01-11 | 2018-07-27 | 柳州市天开企业管理有限公司 | 一种复合陶瓷材料 |
| CN108930005A (zh) * | 2018-07-19 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | 一种高强度陶瓷基复合材料及其制备方法 |
| CN109133954A (zh) * | 2018-11-14 | 2019-01-04 | 福建省德化龙辉陶瓷有限公司 | 一种高韧性耐火日用陶瓷及其制备方法 |
| CN112759402A (zh) * | 2021-03-16 | 2021-05-07 | 福建臻璟新材料科技有限公司 | 一种高强度黑色氮化铝陶瓷的制备工艺 |
| CN116496073A (zh) * | 2023-05-16 | 2023-07-28 | 醴陵千汇实业有限公司 | 一种用于杯耳挤压成型坯体泥料 |
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| CN107151145A (zh) * | 2017-06-08 | 2017-09-12 | 湖州知维技术服务有限公司 | 一种钛酸铝基复合增韧陶瓷及其制备方法 |
| CN107311623A (zh) * | 2017-09-02 | 2017-11-03 | 佛山市嘉亿艺术陶瓷研究有限公司 | 一种陶制茶具用增韧陶土 |
| CN107686357A (zh) * | 2017-09-29 | 2018-02-13 | 马鞍山松鹤信息科技有限公司 | 一种高强度陶瓷材料及其制备工艺 |
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| CN108930005A (zh) * | 2018-07-19 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | 一种高强度陶瓷基复合材料及其制备方法 |
| CN109133954A (zh) * | 2018-11-14 | 2019-01-04 | 福建省德化龙辉陶瓷有限公司 | 一种高韧性耐火日用陶瓷及其制备方法 |
| CN109133954B (zh) * | 2018-11-14 | 2021-10-26 | 福建省德化龙辉陶瓷有限公司 | 一种高韧性耐火日用陶瓷及其制备方法 |
| CN112759402A (zh) * | 2021-03-16 | 2021-05-07 | 福建臻璟新材料科技有限公司 | 一种高强度黑色氮化铝陶瓷的制备工艺 |
| CN116496073A (zh) * | 2023-05-16 | 2023-07-28 | 醴陵千汇实业有限公司 | 一种用于杯耳挤压成型坯体泥料 |
| CN116496073B (zh) * | 2023-05-16 | 2024-04-02 | 醴陵千汇实业有限公司 | 一种用于杯耳挤压成型坯体泥料 |
| CN117264440A (zh) * | 2023-11-14 | 2023-12-22 | 山东陶正新材料科技有限公司 | 一种耐高温氧化铝、氧化锆陶瓷用黑色颜料的制作工艺 |
| CN117264440B (zh) * | 2023-11-14 | 2024-01-30 | 山东陶正新材料科技有限公司 | 一种耐高温氧化铝、氧化锆陶瓷用黑色颜料的制作工艺 |
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