CN106866615B - 用于生产三氧杂环己烷的方法 - Google Patents

用于生产三氧杂环己烷的方法 Download PDF

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Publication number
CN106866615B
CN106866615B CN201710109742.1A CN201710109742A CN106866615B CN 106866615 B CN106866615 B CN 106866615B CN 201710109742 A CN201710109742 A CN 201710109742A CN 106866615 B CN106866615 B CN 106866615B
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formaldehyde
reaction mixture
compound
formaldehyde source
catalyst
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CN106866615A (zh
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M·浩博斯
K·库尔兹
J·凌格瑙
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Celanese Sales Germany GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C07D323/04—Six-membered rings
    • C07D323/06—Trioxane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/04—Formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • C07D323/04—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/30—Chemical modification by after-treatment
    • C08G2/36—Chemical modification by after-treatment by depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/28—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/62—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the nature of monomer used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C08J2359/02—Copolyoxymethylenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201710109742.1A 2011-11-24 2012-11-23 用于生产三氧杂环己烷的方法 Active CN106866615B (zh)

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EP11190574.1 2011-11-24
EP11190567 2011-11-24
EP11190586.5 2011-11-24
EP11190567.5 2011-11-24
EP11190586 2011-11-24
EP11190574 2011-11-24
CN201280057571.8A CN103958492A (zh) 2011-11-24 2012-11-23 用于生产三氧杂环己烷的方法

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CN201280057948.XA Expired - Fee Related CN103958493B (zh) 2011-11-24 2012-11-23 用于由含水甲醛来源生产三氧杂环己烷的方法
CN201711457383.5A Active CN108164500B (zh) 2011-11-24 2012-11-23 用于在非均相反应系统中生产环状缩醛的方法
CN201280057572.2A Expired - Fee Related CN103946219B (zh) 2011-11-24 2012-11-23 用于生产环状缩醛的方法
CN201710109742.1A Active CN106866615B (zh) 2011-11-24 2012-11-23 用于生产三氧杂环己烷的方法
CN201280057570.3A Pending CN104024240A (zh) 2011-11-24 2012-11-23 用于在非均相反应系统中生产环状缩醛的方法
CN201280057571.8A Pending CN103958492A (zh) 2011-11-24 2012-11-23 用于生产三氧杂环己烷的方法
CN201280057582.6A Pending CN104105695A (zh) 2011-11-24 2012-11-23 用于在聚合工艺过程中回收甲醛来源的方法

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CN201280057948.XA Expired - Fee Related CN103958493B (zh) 2011-11-24 2012-11-23 用于由含水甲醛来源生产三氧杂环己烷的方法
CN201711457383.5A Active CN108164500B (zh) 2011-11-24 2012-11-23 用于在非均相反应系统中生产环状缩醛的方法
CN201280057572.2A Expired - Fee Related CN103946219B (zh) 2011-11-24 2012-11-23 用于生产环状缩醛的方法

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CN201280057570.3A Pending CN104024240A (zh) 2011-11-24 2012-11-23 用于在非均相反应系统中生产环状缩醛的方法
CN201280057571.8A Pending CN103958492A (zh) 2011-11-24 2012-11-23 用于生产三氧杂环己烷的方法
CN201280057582.6A Pending CN104105695A (zh) 2011-11-24 2012-11-23 用于在聚合工艺过程中回收甲醛来源的方法

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US (8) US9604956B2 (enExample)
EP (5) EP2782907B8 (enExample)
JP (5) JP6192650B2 (enExample)
KR (4) KR101969615B1 (enExample)
CN (7) CN103958493B (enExample)
WO (7) WO2013076287A1 (enExample)

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CN105218513B (zh) * 2014-05-29 2017-12-12 中国石油大学(北京) 一种合成三聚甲醛的方法
FR3024729B1 (fr) 2014-08-07 2018-09-07 Arkema France Procede de preparation du trioxane
CN104478848B (zh) * 2015-01-09 2016-06-29 开封龙宇化工有限公司 一种三聚甲醛脱轻塔分离器加碱水洗装置及使用方法
CN105175389B (zh) * 2015-09-10 2018-09-07 中国石油大学(北京) 一种利用酸和盐催化甲醛合成三聚甲醛的方法
CN107474037A (zh) * 2017-07-03 2017-12-15 湖北三里枫香科技有限公司 一种多级固定床型三聚甲醛生产工艺方法及制备装置
US10829467B2 (en) 2018-03-29 2020-11-10 Celanese Sales Germany Gmbh Process for producing a cyclic acetal in a heterogeneous reaction system
FR3108909A1 (fr) * 2020-04-07 2021-10-08 Arkema Fance Recyclage de polyacétal pour la production de polyoxyméthylènedialkyléthers
WO2021213663A1 (de) * 2020-04-23 2021-10-28 Wacker Chemie Ag Verfahren zur herstellung von aldehyden aus 1,3,5-trioxanen
WO2022036163A1 (en) * 2020-08-14 2022-02-17 Celanese International Corporation Use of biomass to produce polyoxymethylene copolymers
CN112724118B (zh) * 2020-12-08 2023-02-28 中国石油大学(华东) 一种石油基塑料pom的生物质醇解方法
US20220380557A1 (en) * 2021-05-20 2022-12-01 Xerox Corporation Polyoxymethylene microparticles and methods of production and use thereof
TW202413339A (zh) * 2022-06-03 2024-04-01 日商三菱瓦斯化學股份有限公司 組成物、及使用其之三噁烷的製造方法
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EP2782907B8 (en) 2018-06-27
WO2013076290A1 (en) 2013-05-30
US9365537B2 (en) 2016-06-14
KR20140102243A (ko) 2014-08-21
US9499512B2 (en) 2016-11-22
US20140343300A1 (en) 2014-11-20
US9604956B2 (en) 2017-03-28
WO2013076289A1 (en) 2013-05-30
JP6192650B2 (ja) 2017-09-06
KR20140106599A (ko) 2014-09-03
CN103958493B (zh) 2018-02-06
US9546148B2 (en) 2017-01-17
US20140343301A1 (en) 2014-11-20
US20140350216A1 (en) 2014-11-27
US20140316147A1 (en) 2014-10-23
CN108164500A (zh) 2018-06-15
JP2014534254A (ja) 2014-12-18
JP2014534253A (ja) 2014-12-18
EP2782908B1 (en) 2018-07-25
EP2782905B1 (en) 2020-01-01
EP2782909A1 (en) 2014-10-01
CN103946219B (zh) 2019-10-25
EP2782906B1 (en) 2019-05-22
US20140329988A1 (en) 2014-11-06
WO2013076292A1 (en) 2013-05-30
JP6192651B2 (ja) 2017-09-06
EP2782905A1 (en) 2014-10-01
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JP6144272B2 (ja) 2017-06-07
CN106866615A (zh) 2017-06-20
KR20140102241A (ko) 2014-08-21
EP2782906A1 (en) 2014-10-01
US9574061B2 (en) 2017-02-21
CN103958493A (zh) 2014-07-30
JP6192652B2 (ja) 2017-09-06
WO2013076287A1 (en) 2013-05-30
CN103946219A (zh) 2014-07-23
KR101969615B1 (ko) 2019-04-16
EP2782907B1 (en) 2018-04-11
JP2015500894A (ja) 2015-01-08
JP2014534252A (ja) 2014-12-18
EP2782908A1 (en) 2014-10-01
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CN103958492A (zh) 2014-07-30
CN104105695A (zh) 2014-10-15
JP6192653B2 (ja) 2017-09-06
EP2782907A1 (en) 2014-10-01
CN108164500B (zh) 2024-09-03
WO2013076288A1 (en) 2013-05-30
US9469624B2 (en) 2016-10-18
KR20140107309A (ko) 2014-09-04
US20140323686A1 (en) 2014-10-30
US20140343302A1 (en) 2014-11-20
US20160280882A1 (en) 2016-09-29
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WO2013076286A1 (en) 2013-05-30

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