CN106746420A - The processing system and its processing method of a kind of oily sludge - Google Patents

The processing system and its processing method of a kind of oily sludge Download PDF

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Publication number
CN106746420A
CN106746420A CN201710136358.0A CN201710136358A CN106746420A CN 106746420 A CN106746420 A CN 106746420A CN 201710136358 A CN201710136358 A CN 201710136358A CN 106746420 A CN106746420 A CN 106746420A
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oil
cylinder
sludge
stirring
water
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CN106746420B (en
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仇霞霞
李艺凡
冷增冰
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/06Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives
    • B02C18/14Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers
    • B02C18/141Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers with axial flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/02Feeding devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C4/00Crushing or disintegrating by roller mills
    • B02C4/02Crushing or disintegrating by roller mills with two or more rollers
    • B02C4/08Crushing or disintegrating by roller mills with two or more rollers with co-operating corrugated or toothed crushing-rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/127Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C10G1/045Separation of insoluble materials
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/365Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Food Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Mechanical Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses the processing system and its processing method of a kind of oily sludge.The processing system includes disintegrating apparatus, vibratory sieve, settler, ejector, high speed reducing mechanism, water storage device and the separation equipment for for oil, water, sludge separate;The disintegrating apparatus, for primary comminution oily sludge, is provided with oil slick space and the first oil slick outlet that can be opened and closed;The vibratory sieve, positioned at settler top;The settler, for precipitating the oily sludge after screening;The high speed reducing mechanism, for oily sludge to be broken into fine particle;The settler is sequentially connected with ejector, high speed reducing mechanism, separation equipment, and the delivery port of the water storage device is connected with the water inlet of ejector.The dehydration of the applicable various types of oily sludges of the processing system, while the oil content of greasy filth can also be removed into less than 3%, can oil recovery to greatest extent, and the present invention will not produce the secondary pollutions such as waste water.

Description

The processing system and its processing method of a kind of oily sludge
Technical field
The present invention relates to the processing system and its processing method of a kind of oily sludge.
Background technology
Greasy filth is primarily referred to as the oily sludge of the formation such as the crude oil caused due to a variety of causes or other oil products and soil, with And the oily sediment that system is taken out of in the normal production in oil field etc., it is a kind of solid waste rich in mineral oil, main component is former Oil, Ni Heshui.Solid particle size can be from not enough micron to several inches, and the composition of oil depends on crude oil species, oil plant structure With operating condition, the composition of sludge may change over time and change.Contain certain crude oil, heavy metal ion in usual sludge (Such as iron, copper, nickel)With inorganic salts compound etc..The materials such as benzene homologues, phenols are typically contained in these greasy filth, and with evil Smelly and toxicity, if directly being contacted with natural environment, can make soil poison, be acidified or alkalize, and cause changing for soil and soil structure Become, hinder plant root growth and larger pollution can be caused to water body and vegetation, while also implying that the waste of petroleum resources.
Oily sludge belongs to heterogeneous system, typically by oil-in-water(O/W), Water-In-Oil(W/O)With suspended solid composition, dirt Suspended solid, colloidal solid in mud is fully emulsified with oil, water, forms the suspension emulsion system of stabilization, and viscosity is larger, it is difficult to Sedimentation.With complicated component, water content is high, volume is big, harmful components it is most more than discharge standard, contain calorific value higher, comprehensive Close the characteristics such as Land use systems are few, intractability is big.
By China Hazardous Waste List, greasy filth is put into《National Hazard waste catalogue》In oily waste water species (HW08 ).Its chronicity and potentiality to environmental hazard, just attracts great attention.Carrying out greasy filth management and Study of Prevention Technology is One vital task of current national environmental protection work.Therefore, how these oily sludges are carried out innoxious and recycling, It is also a pendulum important environmental issue urgently to be resolved hurrily in face of oil refining industry.
The treatment technology of the solid waste such as current oily sludge, mainly there is burning method, biological degradation method, solvent extraction Method, quenched-mechanical phonograph recorder separation, concentration desiccation method, microwave treatment method etc., the weak point of these methods may be summarized to be two classes: One class such as burning method and biological degradation method, put forth effort on control pollutant emission, have ignored the recycling of oil product resource;It is another kind of Such as solvent extraction, quenched-mechanical phonograph recorder separation, hot wash method, pyrolysismethod, oil product resource can be reclaimed, but be difficult to control to waste water, waste residue Secondary pollution to environment, these methods cannot all obtain balance between environment and benefit.
For example, solvent extraction is according to " similar compatibility " principle, suitable organic solvent is chosen come in extracting greasy filth Organic matter, is then recovered by distillation the oil in extract again, solvent is separated from mixture circulation by distillation Use.The advantage of the method is process is simple, and extractant can be reused, and have the disadvantage that extractant is expensive, is recycled During there are a large amount of solvent losses, through the greasy filth oil content after treatment be more than 5% or so, do not reach existing solid pollutant Discharge standard.
Quenched-organizational separation method:Because oily sludge is typically all the suspension emulsion system of stabilization, so before dehydration Oily sludge is carried out quenched.Quenched method is in addition to dosing coagulant, flocculation aid, it is necessary to adds surfactant, break Emulsion, pH adjusting agent etc., while being aided with the reinforcing means such as heating, to improve sludge physical property, change the proterties of oily sludge particle And ordered state, destroy the stability of colloid, so as to improve the dewatering of sludge, then using three-phase centrifuge to treatment after Sludge carry out oil, water, mud three phase separation, with simple to operate, technology it is more ripe, practicality is good the features such as, it is recyclable big Part oil.But its core technology is ultracentrifugal three-phase separating device, monopolized by the country such as America and Europe substantially, China is also difficult to Production such device.The shortcoming of quenched-isolation technics:Due to oily sludge species a lot, existing dewatering machine equipment and medicament Combination can't generally be applicable.Therefore, the research to quenched-mechanical separation technology is limited only to single or a small number of greasy filth samples Product, poor universality, and, it is necessary to redefine coagulant during using different oily sludges(Species, dosage and dosing side Formula), demulsifier(Species, dosage and dosing method), dewatering machine model and operational factor.Furthermore, when oil sludge contains When oil mass is less, centrifugation economic benefit is not good.Because the solids content in centrifuge is higher and Treatment of Sludge can be influenceed to imitate Really, oil-sludge treatment amount in this way it is relatively low, it is impossible to meet the requirement of existing extensive treatment.
Chemico-heating wash method:Cyclic washing is carried out to oily sludge by hydrothermal solution, is added in washing process efficiently, suitably Chemical agent, then it is heated, mix after staticly settle, realize separation of solid and liquid.The oil phase isolated enters after treatment Oil storage tank, the recyclable utilization of cleaning fluid, remaining sludge then carries out recycling after dehydration reprocessing.The sieve of chemical reagent Choosing and using the key for being chemico-heating wash technique, in heating, the separation process of stirring, be mainly concerned with reduction interfacial tension, Emulsification, the change principle such as wetability and rigid interface film.But the method is only applicable to, and oil content is higher, emulsify lighter to fall The crude oil recovery treatment of ground crude oil and oil-sand, it is difficult to which the serious greasy filth for the treatment of emulsification is not applied to but;Need to add substantial amounts of cost Expensive chemical agent, causes high cost;Oil-containing is higher in residue after treatment, and the sludge residue water content after separation is more than 90% and containing substantial amounts of chemical agent, can also cause the secondary pollution such as waste water, waste residue problem, it is necessary to further treatment is utilized.
Also, although the method such as above-mentioned solvent extraction, quenched-mechanical phonograph recorder separation, chemico-heating wash method can reclaim sludge In oil product resource, but because the debris in oily sludge are more, including ratchel, wood, metal object, plastics thing, woven bag Deng, being generally required in removal process first to raw material sieve etc. pretreatment, debris in removal raw material, then just with medicament one Play mixed processing;And because oily sludge viscosity is larger, debris are mutually bonded with soil, pretreatment is difficult to go removal of impurities completely Thing, remaining debris can seriously hinder equipment and facility normally to run.
The content of the invention
In view of the shortcomings of the prior art, the invention provides the processing system and its processing method of a kind of oily sludge.Should The dehydration of the applicable various types of oily sludges of processing system, expands range of application, while can also be by the oil content of greasy filth Be removed to less than 3%, can oil recovery to greatest extent, and the present invention will not produce the sewage sludge waste slag after waste water, and de-oiling to contain Oil is very low, meets the discharge standard of solid pollutant, will not produce secondary pollution to environment, and the scene that is especially suitable for is promoted should With.
The invention provides a kind of processing system of oily sludge, including disintegrating apparatus, vibratory sieve, settler, jet Device, high speed reducing mechanism, water storage device and one or more separation equipments for for oil, water, sludge separate;
The disintegrating apparatus, for primary comminution oily sludge, it includes crushing cylinder, is provided with above the crushing cylinder Oil slick space, crushing cylinder top wall body is provided with the first oil slick outlet that can be opened and closed, the crushing cylinder Bottom be provided with oily sludge outlet;
The vibratory sieve, positioned at settler top, and for sieving the oily sludge of disintegrating apparatus discharge;
The settler, for receiving and precipitating the oily sludge after screening, the settler is provided with can be opened and close The the second oil slick outlet for closing;
The high speed reducing mechanism, for oily sludge further to be broken into fine particle, preferably micron particles;
The settler is sequentially connected with ejector, high speed reducing mechanism, separation equipment, the delivery port of the water storage device with The water inlet connection of ejector.The sludge outlet of i.e. described separation equipment is connected with the sludge import of centrifuge, the centrifuge Delivery port be connected with the water inlet of water storage device, the sludge outlet of the settler is connected with the sludge import of ejector, The sludge outlet of the ejector is connected with the sludge import of high speed reducing mechanism, the sludge outlet of the high speed reducing mechanism with The sludge import connection of separation equipment.
The disintegrating apparatus also includes that import cylinder, pair roller type tear up mechanism, rotary shaft disintegrating mechanism, high-pressure sprayer With the first oil-scraping device;
The bottom of the import cylinder is connected with cylinder is crushed, and the import cylinder is provided with the high pressure spray over or within Water installations, the pair roller type tears up mechanism and is arranged in import cylinder;
The rotary shaft disintegrating mechanism is arranged in pulverization cylinder body;
First oil-scraping device is arranged in the oil slick space and relative with the first oil slick outlet.
The rotary shaft disintegrating mechanism by can the motor of rotating drive, the motor is preferably buncher.Described turn Shaft type disintegrating mechanism is located in pulverization cylinder body, and the disintegrating mechanism includes the rotating shaft being be arranged in parallel with tubular axis, the rotating shaft On be provided with multiple rows of crushing knife tool, the rotating shaft is connected with the drive end of the motor;Preferably, the crushing knife tool and rotating shaft Connection angle be 30 °~90 °, often arrange crushing knife tool include 2 ~ 6 crushing knife tools, crushing knife tool and rotating shaft in same row Connection angle it is identical and along rotating shaft circumferencial direction arrangement;It is further preferred that multiple rows of crushing knife tool includes multiple rows of hanging down Straight crushing knife tool and multiple rows of inclination crushing knife tool, are arranged at intervals with the vertical of 1-3 rows between adjacent two row inclines crushing knife tool Crushing knife tool, the vertical crushing knife tool is 90 ° with the connection angle of rotating shaft, the joint angle for inclining crushing knife tool and rotating shaft Spend is 30 °~80 °.
The first baffle that can be opened and closed is provided with the first oil slick outlet;It is further preferred that described First baffle is hinged with the first oil slick outlet;It is further preferred that the first baffle by first axle with it is described First oil slick outlet is hinged, and the two ends of the first axle are provided with the first crank, and first crank is connected with the first cylinder, institute The first crank handle turns baffle plate described in the first air cylinder driven is stated to be turned on and off;
First oil-scraping device includes the first oil scraping plate and first driving means, and first oil scraping plate and first drive dress The opposite side for being arranged on the first baffle is put, the first driving means are preferably the second cylinder.
The settler includes settling tank and spiral conveying mechanism, and the spiral conveying mechanism is arranged on the bottom of settling tank Portion, the spiral conveying mechanism extends horizontally to the material outlet of settling tank from one end of settling tank;Preferably, the spiral transferring Sending mechanism includes spiral conveying blade, the material outlet of the pitch of the spiral conveying blade from one end of settling tank to settling tank Direction on gradually decrease;
Preferably, the second oil slick outlet is arranged on the top of settling tank, is provided with the second oil slick outlet The second baffle that can be opened and closed;It is further preferred that the second baffle is hinged with the described second oily outlet;More enter one Preferably, the second baffle is hinged step by the second axle with the second oil slick outlet, and the two ends of second axle are provided with Second crank, second crank is connected with the 3rd cylinder, and the second crank handle turns baffle plate described in the 3rd air cylinder driven is opened Or close.
The high speed reducing mechanism includes the multiple rows of crushing knife tool crushed cylinder, rotating shaft, set in rotating shaft, it is preferable that every Row's crushing knife tool includes 2 ~ 8 crushing knife tools, and the crushing knife tool in same row is arranged along the circumferencial direction of rotating shaft.
The sludge inlet of the high speed reducing mechanism is arranged on the one end for crushing cylinder, and the high speed reducing mechanism Sludge outlet is arranged on the bottom for crushing the cylinder other end.
Delivery pump or high-pressure pump are provided with the pipeline that the water inlet of the ejector is connected with the delivery port of water storage device.
When the processing system includes multiple separation equipments, the sludge outlet of one of separation equipment is separated with another The sludge import connection of equipment, and the bottom sludge outlet of the separation equipment connects with the sludge import of next separation equipment again Connect, so as to multiple separation equipments be connected in series.
The separation equipment includes stirring cylinder, agitating shaft, multilayer insulating panel and stirring vane;
The agitating shaft is arranged in mixing drum body, and the multilayer insulating panel is separated into many sheaf spaces, the multilayer by cylinder is stirred Each sheaf space in space is provided with stirring parts, and the stirring parts are connected with agitating shaft, during the multilayer insulating panel is provided with Heart hole, the diameter with diameter greater than agitating shaft of the centre bore, the agitating shaft passes through centre bore;
The bottom of the stirring cylinder is provided with sludge outlet, is provided with for extracting in the bottom or bottom of the stirring cylinder The charging aperture of one or more materials in agent, dissolved air water and solid foam particle;The top of the stirring cylinder is provided with dirt Mud import and the 3rd oil slick outlet that can be opened, close.
The stirring parts include stirring disk and stirring vane, and the stirring disk is provided with center hole and is set in stirring On axle, multiple stirring vanes are provided with the one or both sides of the stirring disk;Preferably, the disk of mixing is with stirring Blade is integrally formed;It is further preferred that being additionally provided with crushing knife tool on the stirring disk.
The multilayer insulating panel extends to the inwall of stirring cylinder;Preferably, the multilayer insulating panel is fixed on stirring cylinder On inwall, or fixed in mixing drum body by many connecting rods, the connecting rod connects through multilayer insulating panel and with multilayer insulating panel Connect fixation, the roof of the connecting rod upper end connection stirring cylinder, the bottom wall of the connecting rod lower end connection stirring cylinder.
The third baffle that can be opened and closed is provided with the 3rd oil slick outlet;It is further preferred that described Third baffle is hinged with the 3rd oil slick outlet;It is further preferred that the third baffle passes through axle and the described 3rd Oil slick outlet is hinged, and the two ends of the 3rd axle are provided with the 3rd crank, and the 3rd crank is connected with the 4th cylinder, and described The 3rd crank handle turns third baffle is turned on and off described in four air cylinder drivens;
The separator also includes the second oil-scraping device, second oil-scraping device be located in mixing drum body top and multilayer every Plate top;Preferably, second oil-scraping device include the second oil scraping plate and the second drive device, second oil scraping plate and Second drive device is arranged on the opposite side of the third baffle, and second drive device is preferably the 5th cylinder.
The charging aperture is connected with air-dissolving apparatus, and the air-dissolving apparatus are preferably air dissolved pump.
The processing system also include one or more Fuel Tanking Units, the Fuel Tanking Unit be used for receive from disintegrating apparatus, The oil that settler and separation equipment are isolated;Preferably, the processing system includes the first Fuel Tanking Unit, the second Fuel Tanking Unit With the 3rd Fuel Tanking Unit, first Fuel Tanking Unit is connected with the first oil slick outlet of disintegrating apparatus, the second oil storage dress Put and be connected with the second oil slick outlet of settler, the 3rd Fuel Tanking Unit connects with the 3rd oil slick outlet of separation equipment Connect;It is further preferred that first Fuel Tanking Unit, the second Fuel Tanking Unit and the 3rd Fuel Tanking Unit are preferably oil storage tank.
The processing system also includes the first conveying device and the second conveying device, the first conveying device, for by oil-containing Sludge is delivered to the import of disintegrating apparatus, and the first conveying device is preferably single bucket elevator;
Second conveying device, for disintegrating apparatus to be processed after oily sludge be delivered to screening machine;Second conveying device is preferred It is bucket elevator, the import of bucket elevator is connected with the sludge outlet for crushing cylinder, the sludge outlet position of bucket elevator In vibratory sieve top.
Present invention also offers a kind of process for treating oil-containing sludge of system processed as described above, comprise the following steps:
(1)Oily sludge is delivered to disintegrating apparatus, is crushed, while with hot water hydro-peening oily sludge, equipment to be comminuted is complete Stood with after hydro-peening into crushing, then open the first oil slick outlet and discharge the oil slick and debris on upper strata, lower floor is contained Greasy dirt is discharged and is transported to vibratory sieve;
(2)The vibratory sieve is sieved to oily sludge, and debris and the big oily sludge of particle diameter are sized out, and particle diameter is small Oily sludge is dropped down onto in the settler of lower section, and oily sludge is staticly settled in settler, and upper strata oil slick is floating through second Oily outlet discharge, bottom oily sludge enters in ejector, while the water of the water storage device enters in ejector, so that shape Into high-speed jet and spray into impact comminution is carried out in high speed reducing mechanism, while high speed reducing mechanism rotation chopping oil-containing is dirty Mud, so as to break into fine particle, preferably micron particles are made mud;Wherein, the water in water storage device is added with demulsification Agent;
(3)Then by slurry transportation to separation equipment, thoroughly realize that oil is separated with water, sludge in the separation equipment, Separate water outlet and return to water storage device, wherein, before separation equipment stirring and/or in whipping process, lead in the bottom of separation equipment Enter one or more in extractant, dissolved air water and solid foam particle.
In step(1)In, the temperature of the water that the high-pressure sprayer sprays is 70 DEG C~90 DEG C, the dress that sprays water with high pressure The part by weight of the water and oily sludge of putting ejection is preferably 1:(1~3).
In step(2)In, the part by weight of water and oily sludge that the water storage device enters ejector is 1:(0.5 ~3), the temperature of water is preferably 70~90 DEG C in water storage device;The demulsifier is neopelex, polyoxyethylene nonyl phenyl One or more in vinethene, OPEO, AEO, the demulsifier is in water storage device Concentration in water is preferably 0.25wt%~2.0wt%.
In step(3)In, the dissolved air water is dissolved with gas;The gas is air or nitrogen;Extractant is petroleum ether, first One or more in benzene, naphtha, gasoline, diesel oil, solvent naphtha, the solid foam particle be polystyrene foam particles, One or more in polyvinyl chloride foam particle, polyurethane foam particles, phenol formaldehyde foam particle.
In step(3)In, the time being stirred in the separation equipment is 5~30 min, is carried out after completion of stirring The time of standing is 5~30min.
Compared with prior art, the processing system and its processing method of oily sludge of the present invention have the following advantages that:
(1)Multi-stage crushing, multilevel oil removal, efficient viscous oil or extraction are combined into a set of efficient, reliability, treatment effect and dashed forward by the present invention The sludge treatment equipment for going out, goes for the oily sludge of different oil contents, is particularly suited for that oil content is relatively low or emulsification is tight The oily sludge sample of weight.
First be transported to oily sludge in disintegrating apparatus by the present invention, bulk oily sludge is crushed, while hot water Also spray punching is carried out to oily sludge, so that first time fragmenting bulk oily sludge, the sludge after disintegrating apparatus treatment is delivered to and shakes Dynamic sieve, screens out debris and crushes the particle of oily sludge, and little particle is fallen into the settling tank of lower section, then in the impact of ejector Crush, then by the rotation chopping at a high speed of high speed reducing mechanism, so as to formed carry out multistage-combination crushing to oily sludge, can be by Oily sludge particle be crushed to 5 microns it is powdered following, the oil in sludge is exposed, be conducive to demulsifier to clean sludge Middle oil, the various oils in depth ground removing sludge, while the emulsification for being formed is very weak, favourable follow-up equipment separates oil Point, while separation equipment can also be graded means using bubble viscous oil, foam solid particle viscous oil or extraction oil, so it is front and rear respectively Technological means cooperate, influence each other, so as to demulsifier consumption very little, do not form strong emulsification in the case of, can Be removed to residual oil content below 3% with by the greasy filth that oil content is more than 30%, can oil recovery to greatest extent, and the present invention will not Produce waste water, the greasy filth after the completion for the treatment of to meet the discharge standard of solid pollutant, secondary pollution will not be produced to environment, very It is adapted to field popularization application.
(2)Processing system of the invention, can tear up mechanism and cut bulk debris and textile bag, rotary shaft by pair roller type Crushing can crush debris, while spray into high-pressure water heating in crushing process, and coordinate can rotating buncher and turn Shaft type disintegrating mechanism particular design(As crushing knife tool is crushed with the connection angle of rotating shaft, especially vertical crushing knife tool and inclination The combination of cutter), can farthest realize that oily sludge is crushed and washed, while can be during crushing and washing Greasy dirt viscosity is reduced, makes debris no longer be bonded with oily sludge or adhesion, after standing oil slick treatment, most of wood can be removed The debris such as head, plastics thing, woven bag, are so conducive to follow-up vibratory sieve to sift out the debris such as remaining stone, metal, so that completely Impurity removing, guarantee equipment and facility is gone normally to run.
(3)Hot water in water storage device enters ejector and forms suction effect, so that can be by settler sludge outlet Greasy filth is suctioned out and high pressure is sprayed into and in the crushing knife tool of impact high speed reducing mechanism, so as to form impact grinding, and is crushed at a high speed Device further shreds mud granule by rotating at a high speed, so as to realize that greasy filth is thoroughly crushed, finally in impact comminution and rotation Under chopping effect, the granularity of greasy filth particle can reach less than 5 microns, and the oil in sludge is exposed, and be conducive to demulsifier clear Oil in sludge is washed, finally can be removed to for the greasy filth that oil content is more than 30% residual by the various oils in depth ground removing sludge Below oil cut rate 3%, the discharge standard of solid pollutant is met, and can oil recovery to greatest extent.
(4)Separation equipment of the invention has a multilayer insulating panel structure, and bottom be provided with for extractant, dissolved air water and The charging aperture of one or more materials in solid foam particle, in such extractant, dissolved air water and solid foam particle one After kind or several materials enter charging aperture, each sheaf space between dividing plate is passed sequentially through, and during stirring parts rise thereon It is sufficiently mixed and is contacted with oily sludge, substantially realize bubble viscous oil, foam solid particle viscous oil or extractant extraction The effect of oil is taken, oil is efficiently separated with water, sludge, it is to avoid existing air-floating apparatus or extraction equipment mixing are uneven, Partial sludge and oil phase are difficult to separate problem.
Bubble viscous oil:The coal tar in greasy filth, mink cell focus are appeared in after being washed to medicament and is configured with a set of air-dissolving apparatus, profit The micro-bubble produced with dissolved air water adheres to oils, it is achieved thereby that thoroughly oil removing.Stirring parts stir during, greasy filth with Bubble is sufficiently mixed and contacts in each layer, and coal tar, mink cell focus are attached on bubble, from hybrid separation equipment upper end row Go out, the multilayer insulating panel design of inside original creation makes bubble and greasy filth mixing more uniformly, and deoiling effect is more excellent.
Extractant is extracted and foam solid particle viscous oil:Coal tar, the heavy in greasy filth are appeared in after being washed for medicament Oil, by adding extractant and/or foam solid particle, the multilayer insulating panel and stirring action created in hybrid separation equipment Under, after extractant and/or foam solid particle and greasy filth are sufficiently mixed, extractant and/or foam solid particle containing oil exist Discharge separation equipment upper end.
(5)The stirring parts of separation equipment of the invention be provided with stirring disk and stirring vane, so stirring disk with it is many Layer dividing plate is formed and is staggered, when one or more materials in extractant, dissolved air water and solid foam particle enter charging aperture Afterwards, the baffling that many sheaf space inner curves rise can be formed in by dividing plate and disk barrier in uphill process, is then coordinated again The rotating of buncher and the regulation of speed, so that further preferably stirring and mixing effect, makes oil with water, sludge fully Separate.
(6)The present invention is dehydrated using centrifuge to the sludge of oil removing, and the water body separated is again introduced into water storage dress In putting, so as to realize the reagents such as demulsifier and water circulation use, so that it is guaranteed that whole processing procedure does not produce waste water.
Brief description of the drawings
Fig. 1 is the schematic diagram of the processing system of oily sludge of the invention;
Fig. 2 is the schematic diagram of disintegrating apparatus of the invention;
Fig. 3 is the schematic diagram of settler of the invention and ejector;
Fig. 4 is the schematic diagram that two stirring separators of the invention are connected with centrifuge;
Fig. 5 is the schematic diagram of stirring separator of the invention;
Reference:1- disintegrating apparatus, the conveying devices of 11- first, 12- import cylinders, 13- crushes cylinder, and 14- pair roller types tear up Mechanism, 15- rotary shaft disintegrating mechanisms, 16- first baffles, 17- flashboards and slide valve, the motors of 18- first, 2- vibratory sieves, 21- Two conveying devices, 3- settlers, 31- settling tanks, 32- spiral conveying mechanisms, the motors of 33- second, 4- ejectors, 5- high speed powder Crushing device, 6- separation equipments, 61- stirring separators, 611- stirring cylinders, 612- agitating shafts, 613- multilayer insulating panels, 614- is stirred Part is mixed, 615- stirs the sludge import of cylinder, and the oil slick outlets of 616- the 3rd, 617- charging apertures, 618- stirs the sludge of cylinder Outlet, the motors of 619- the 3rd, 62- centrifuges, 7- water storage devices, 71- high-pressure pumps, the Fuel Tanking Units of 8- the 3rd.
Specific embodiment
Embodiments of the invention are described below in detail, the example of the embodiment is shown in the drawings, wherein from start to finish Same or similar label represents same or similar element or the element with same or like function.Below with reference to attached It is exemplary to scheme the embodiment of description, it is intended to for explaining the present invention, and be not considered as limiting the invention.
Additionally, term " first ", " second " are only used for describing purpose, and it is not intended that indicating or implying relative importance Or the implicit quantity for indicating indicated technical characteristic.Thus, define " first ", the feature of " second " can express or Implicitly include one or more this feature.In the description of the invention, " multiple " is meant that two or more, Unless otherwise expressly limited specifically.
In the present invention, unless otherwise clearly defined and limited, term " installation ", " connected ", " connection ", " fixation " etc. Term should be interpreted broadly, for example, it may be being fixedly connected, or being detachably connected, or be integrally connected;Can be straight Connect connected, it is also possible to be indirectly connected to by intermediary, can be two connections of element internal.For the common skill of this area For art personnel, above-mentioned term concrete meaning in the present invention can be as the case may be understood.
Technical scheme is further illustrated below by implementation method, but be invention should not be deemed limited to In following implementation method.
According to the first aspect of the invention, as shown in figure 1, the invention provides a kind of processing system of oily sludge, It include disintegrating apparatus 1, vibratory sieve 2, settler 3, ejector 4, high speed reducing mechanism 5, water storage device 7 and for oil, water, The separation equipment 6 that sludge is separate;Disintegrating apparatus 1, for primary comminution oily sludge, it includes crushing cylinder 13, in pulverization cylinder The top of body 13 is provided with oil slick space, crushes the top wall body of cylinder 13 and is provided with the first oil slick outlet that can be opened and closed, The bottom for crushing cylinder 13 is provided with oily sludge outlet;Vibratory sieve 2, positioned at the top of settler 3, and crushes for sieving The oily sludge of the discharge of equipment 1;Settler 3, for receiving and precipitating the oily sludge after screening, settler 3 is provided with The the second oil slick outlet that can be opened and closed;High speed reducing mechanism 5, for oily sludge further to be broken into fine particle, Preferably micron particles;Settler 3 is sequentially connected with ejector 4, high speed reducing mechanism 5, separation equipment 6, water storage device 7 Delivery port be connected with the water inlet of ejector 4.I.e. the sludge outlet of separation equipment 6 is connected with the sludge import of centrifuge 62, The delivery port of centrifuge 62 is connected with the water inlet of water storage device 7, and sludge outlet and the sludge of ejector 4 of settler 3 enter Mouth connection, the sludge outlet of ejector 4 is connected with the sludge import of high speed reducing mechanism 5, the sludge outlet of high speed reducing mechanism 5 It is connected with the sludge import of separation equipment 6.
The the first oil slick outlet and oil slick space that can be opened and closed are provided with for 1 need of disintegrating apparatus, just can be complete Into first time oil removing.As one embodiment of the present invention, in order to more preferable crushing effect and and woven bag torn up, such as Shown in Fig. 2, disintegrating apparatus of the present invention 1 can also include that import cylinder 12, crushing cylinder 13, pair roller type tear up mechanism 14, rotating shaft Formula disintegrating mechanism 15, high-pressure sprayer and the first oil-scraping device;The bottom of import cylinder 12 is connected with cylinder 13 is crushed, high pressure Water injector is arranged on import cylinder 12 over or within, and pair roller type tears up mechanism 14 and is arranged in import cylinder 12;Rotating shaft Formula disintegrating mechanism 15 is arranged in crushing cylinder 13 along the axial direction for crushing cylinder 13, in the top of rotary shaft disintegrating mechanism 15 Oil slick space is set, the first oil-scraping device is provided with oil slick space, being provided with the opposite end of the first oil-scraping device to open The the first oil slick outlet for opening and closing, the bottom for crushing cylinder 13 is provided with the oily sludge outlet that can be opened and closed. In order to realize opening and closing, it is preferable that can be provided with flashboard and flashboard at the oily sludge outlet for crushing cylinder 13 Valve 17.
In one embodiment of the invention, in order to preferably crush the debris such as woven bag and larger plastics, pair roller type Tearing up mechanism 14 includes to roller and is arranged on to the multiple rows of cutting knife on roller that multiple rows of cutting knife is preferably 30 ° with the connection angle to roller ~90 °, so in roller relative rotational motion, cutting knife can play cutting woven bag and the effect of larger plastics, and to roller Formula tears up mechanism 14 can also play a part of extruding crushing.Preferably, the rotating speed to roller is 15~60 revs/min.
In one embodiment of the invention, rotary shaft disintegrating mechanism 15 is located at and crushes in cylinder 13, disintegrating mechanism bag The rotating shaft being be arranged in parallel with tubular axis is included, crushing knife tool is provided with rotating shaft, it is preferable that rotary shaft disintegrating mechanism 15 can be by First motor 18 drives, i.e., one end of rotating shaft is connected with the drive end of the first motor 18.First motor 18 preferably can rotating Buncher.Preferably, crushing knife tool is preferably 30 °~90 ° with the connection angle of rotating shaft.So in rotary shaft disintegrating mechanism In 15 rotation processes, oily sludge particle and some debris can be further smashed, while also make water, oil and mud well mixed, The rotating speed of the rotating shaft of rotary shaft disintegrating mechanism 15 is 50~200 revs/min.
In order to further realize reaching the purpose crushed and wash oily sludge, debris are made to be easily isolated with sludge, it is multiple rows of Crushing knife tool includes multiple rows of vertical crushing knife tool and multiple rows of inclination crushing knife tool, is spaced between adjacent two row inclines crushing knife tool The vertical crushing knife tool of 1-3 rows is provided with, vertical crushing knife tool is 90 ° with the connection angle of rotating shaft, inclines crushing knife tool and turns The connection angle of axle be 30 °~80 ° often row's crushing knife tool include 2 ~ 6 crushing knife tools, crushing knife tool in same row with turn The connection angle of axle it is identical and along rotating shaft circumferencial direction arrangement.So vertical crushing knife tool and inclination crushing knife tool can make oil-containing Sludge can not only be such that oily sludge along the circumferential direction moves, and along the movement of the axial direction of cylinder 13 is crushed sludge can also be made to exist Crush in cylinder 13 and shredded by multi-faceted, crushing effect is very good;After the completion of crushing process neutralization, while multi-faceted Movement can also function well as stirring action, hot water is fully washed oily sludge, oily sludge is no longer mutually glued with debris Connect or adhesion, so as to after oil slick treatment is stood, a part of oil and debris can be removed.
In one embodiment of the invention, import cylinder 12 includes feed hopper and is connected to the square of feed hopper bottom Feed bin, pair roller type tears up mechanism 14 and is arranged in square feed bin.
In order to strengthen crushing effect, pair roller type tears up the axial direction of mechanism 14 and the axial direction side of rotary shaft disintegrating mechanism 15 To can be mutually perpendicular to.
In order to realize the opening and closing of the first oil slick outlet, being provided with the first oil slick outlet to open and close First baffle 16, it is also possible to set other be available for open and close devices.First baffle 16 can cover the discharge of the first oil slick Mouthful, so when disintegrating apparatus 1 is crushed, first baffle 16 is covered in the first oil slick outlet, after crushing completely, opens the One baffle plate 16, can discharge oil slick.Preferably, first baffle 16 is hinged with the first oil slick outlet, it is further preferred that first Baffle plate 16 is hinged by first axle with the first oil slick outlet, and the two ends of first axle are provided with the first crank, the first crank and first Cylinder is connected, and first the first crank handle turns of air cylinder driven first baffle 16 is turned on and off.
After the standing of disintegrating apparatus 1, in order that the oil slick and debris in oil slick space are easily drained, disintegrating apparatus 1 also sets The first oil-scraping device is equipped with, so as to after disintegrating apparatus 1 completes to crush, be stood, polybag, waddy, oily isodensity are less than The debris of water can float to oil slick space, then be scraped by the first oil-scraping device.First oil slick discharge mouth-shaped can be length Bar shaped, extends along the axial direction for crushing cylinder 13.For the first oil-scraping device, the oil slick in oil slick space can be scraped i.e. Can, can be Oil scraper.In one embodiment of the present invention, the first oil-scraping device can include the first oil scraping plate and first Drive device, the first oil scraping plate and first driving means are arranged on the opposite side of first baffle 16, and first driving means are preferably Second cylinder, it is also possible to other drive devices.
As shown in figure 1, in one embodiment of the invention, processing system also includes the first conveying device 11 and second Conveying device 21.First conveying device 11, the import for oily sludge to be delivered to disintegrating apparatus 1;Second conveying device 21, Screening machine is delivered to for the oily sludge after disintegrating apparatus 1 is processed.As preferred embodiment, the first conveying device 11 It can be single bucket elevator;Second conveying device 21 can be bucket elevator, import and the crushing cylinder 13 of bucket elevator Sludge outlet connection, the sludge outlet of bucket elevator is located at the top of vibratory sieve 2.
As shown in figure 1, vibratory sieve 2 can realize that sludge is sieved with debris.As preferred embodiment, vibratory sieve 2 can be provided with bulky grain sludge outlet and miscellaneous object outlet, and bulky grain sludge can return to disintegrating apparatus 1 and proceed to crush, And debris can then be recycled.
Settler 3 can be staticly settled to the oily sludge after screening, can be from storage oily sludge Container, it is also possible to select other devices.As shown in figure 3, in an embodiment of the invention, settler 3 includes heavy Shallow lake case 31.Second oil slick outlet is arranged on the top of settling tank 31, and being provided with the second oil slick outlet can open and close The second baffle for closing;It is further preferred that second baffle is hinged with the second oily outlet;It is further preferred that second baffle It is hinged with the second oil slick outlet by the second axle, the two ends of the second axle are provided with the second crank, and the second crank and the 3rd cylinder connect Connect, the 3rd air cylinder driven the second crank handle turns baffle plate is turned on and off.Set by said structure, oil-containing after the screening of vibratory sieve 2 Sludge and water fall into settler 3 and are staticly settled together, after the completion of staticly settling, open second baffle, by gravity certainly So flow out oil slick or discharged by oil-scraping device.
After precipitation is completed, sludge is more difficult from sludge outlet discharge, in one embodiment of the present invention for settler 3 In, to solve this problem, spiral conveying mechanism 32 being additionally provided with the bottom of settling tank 31, such spiral conveying mechanism 32 can be by Base sludge is delivered to the sludge outlet of settler 3, while the sludge outlet of settler 3 is connected with ejector 4, so penetrates Sludge in settler 3 can be aspirated when flowing device 4 in working order, ensure that the sludge of the bottom of settler 3 Smoothly discharge.Spiral conveying mechanism 32 is connected with the drive end of the second motor 33, the second motor 33 preferably can rotating speed governing Motor.Spiral conveying mechanism 32 can be have screw conveyor shaft structure, or Shaftless screw conveyor structure.As preferable Implementation method, spiral conveying mechanism 32 includes spiral conveying blade, and the pitch of spiral conveying blade is from one end of settling tank 31 Gradually decreased on direction to the material outlet of settling tank 31, extruding is so formed when spiral conveying blade promotes sludge makees With extrusion excessive moisture.
High speed reducing mechanism 5 can be powdered using sludge is crushed to(Especially selection can be crushed to micron order)'s Beating equipment.In one embodiment of the present invention, high speed reducing mechanism 5 includes crushing cylinder, rotating shaft at a high speed, sets in rotating shaft Multiple rows of crushing knife tool, it is preferable that often arranging crushing knife tool includes 2 ~ 8 crushing knife tools, and crushing knife tool in same row is along turning The circumferencial direction arrangement of axle;The sludge inlet of high speed reducing mechanism 5 is arranged on the one end for crushing cylinder at a high speed, and crushes at a high speed The sludge outlet of device 5 is arranged on the bottom for crushing the cylinder other end at a high speed.The rotating speed of high speed reducing mechanism 5 is 100~1000 Rev/min.The external shape of high speed pulverization cylinder is in cylinder, can be horizontal or vertical structure.
Powerful suction effect is formed after ejector 4 for the ease of entering current, water inlet and the water storage of ejector 4 are filled Delivery pump or high-pressure pump 71 are provided with the pipeline of the delivery port connection for putting 7.
In one embodiment of the present invention, separation equipment 6 can include that air-floating apparatus, extraction equipment, foam beads glue One or more separators in oily device, centrifuge 62.Centrifuge 62 can be for three-phase centrifuge or for mud-water separation Centrifuge.When separation equipment 6 uses one or more in air-floating apparatus, extraction equipment, foam beads viscous oil device, then The centrifuge 62 of mud-water separation is connected to after oil removing is completed;Can also separation equipment 6 use three-phase centrifuge, realize Oil, mud, the three phase separation of water.
When separation equipment 6 includes multiple separators, the sludge outlet of one of separator separates dress with another The sludge import connection put, and the bottom sludge outlet of the separator is connected with the sludge import of next separator again, So as to multiple separation apparatuses in series be connected.
As preferred embodiment, as shown in figure 4, the present invention has been sequentially connected in series three separators, two stirrings point First be connected in series from device 61, be then connected in series with a centrifuge 62 again, i.e., first sludge of stirring separator 61 Outlet is connected with the sludge import of second stirring separator 61, second sludge outlet of stirring separator 61 and from The material inlet of scheming 62 is connected, and the delivery port of centrifuge 62 can be connected with the water inlet of water storage device 7.
As shown in figure 5, stirring separator 61 includes stirring cylinder 611, drive device, agitating shaft 612, multilayer insulating panel 613 and stirring parts 614, the axial direction that agitating shaft 612 is arranged in stirring cylinder 611 and along stirring cylinder 611 extends, stirring The lower end of axle 612 is connected through the stirring bottom of cylinder 611 and with the clutch end of drive device.Drive device is preferably the 3rd Motor 619, the buncher that can more preferably rotate and reverse, so can by buncher adjust mixing speed and Turn to.
Multilayer insulating panel 613 is separated into many sheaf spaces by cylinder 611 is stirred, and each sheaf space in many sheaf spaces is provided with and stirs Mix part 614, stirring parts 614 are fixed on agitating shaft 612, multilayer insulating panel 613 is provided with centre bore, centre bore with diameter greater than stirring The diameter of axle 612 is mixed, agitating shaft 612 passes through centre bore;The top for stirring cylinder 611 is provided with the sludge import of stirring cylinder 615 and the 3rd oil slick outlet 616, the bottom for stirring cylinder 611 is provided with the sludge outlet 618 of stirring cylinder, in mixing drum The bottom or bottom of body 611 are provided with entering for one or more materials in extractant, dissolved air water and solid foam particle Material mouth 617.Charging aperture 617 is located at the bottom of multilayer insulating panel 613.Dissolved air water is the water dissolved with gas, and gas is air or nitrogen Deng;Extractant is one or more in petroleum ether, toluene, naphtha, gasoline, diesel oil, solvent naphtha, and solid foam particle is poly- One or more in styrenic foams particle, polyvinyl chloride foam particle, polyurethane foam particles, phenol formaldehyde foam particle.
Stirring parts 614 can only select stirring vane.Alternatively, stirring parts 614 can also include stirring Disk and stirring vane, stirring disk are provided with centre bore and are set on agitating shaft 612, are set on the one or both sides for stirring disk It is equipped with multiple stirring vanes;Preferably, mix disk to be integrally formed with stirring vane, such material flows in stirring separator 61 When can form baffling.If the device crushing sludge before stirring separator 61 is not thorough, particle can also stirred than larger Crushing knife tool is provided with disk, so by stirring disc rotary crushing knife tool can be driven further to crush mud granule, So as to reaching thoroughly crushing, fully washing and being kept completely separate oil phase and the purpose of sludge.
Each layer of dividing plate in multilayer insulating panel 613 all extends to stir the inwall of cylinder 611;Preferably, multilayer insulating panel 613 It is fixed on the inwall of stirring cylinder 611, or is fixed in stirring cylinder 611 by many connecting rods, connecting rod passes through multilayer Dividing plate 613 is simultaneously connected with multilayer insulating panel 613, the roof of connecting rod upper end connection stirring cylinder 611, the connection of connecting rod lower end Stir the bottom wall of cylinder 611.
In another embodiment of the present invention, for can opening and closing is provided with the 3rd oil slick outlet 616 Three baffle plates.Preferably, third baffle is hinged with the 3rd oil slick outlet 616, it is further preferred that third baffle passes through the 3rd axle It is hinged with the 3rd oil slick outlet 616, the two ends of the 3rd axle are provided with the 3rd crank, and the 3rd crank is connected with the 4th cylinder, the 4th The crank handle turns third baffle of air cylinder driven the 3rd is turned on and off.3rd oil slick outlet 616 is strip.
Oil slick after stirring separator 61 stands can lean on gravity to flow out naturally, it is also possible to set the second oil-scraping device, Second oil-scraping device is located at top and the top of multilayer insulating panel 613 in stirring cylinder 611.Second oil-scraping device includes the second frizing Plate and the second drive device, the second oil scraping plate and the second drive device are arranged on the opposite side of third baffle, and second drives dress Put preferably the 5th cylinder.
In another embodiment of the present invention, charging aperture 617 is connected with air-dissolving apparatus, and air-dissolving apparatus are preferably molten gas Pump.Operationally, air and water are sucked together by air dissolved pump import, then through air dissolved pump impeller meet into tiny dissolved air water. After air dissolved pump, the volume concentration of gas phase in dissolved air water can be as high as 15v%, and micro air bubble diameter is smaller than 30 μm.
Processing system also includes one or more Fuel Tanking Units, and Fuel Tanking Unit is used to receive from disintegrating apparatus 1, settler 3 and the oil isolated of separation equipment 6;Preferably, processing system includes the first Fuel Tanking Unit, the second Fuel Tanking Unit and the 3rd oil storage Device 8, the first Fuel Tanking Unit is connected with the first oil slick outlet of disintegrating apparatus 1, and the of the second Fuel Tanking Unit and settler 3 Two oil slick outlets are connected, and the 3rd Fuel Tanking Unit 8 is connected with the 3rd oil slick outlet of separation equipment 6;It is further preferred that the One Fuel Tanking Unit, the second Fuel Tanking Unit and the 3rd Fuel Tanking Unit 8 are preferably oil storage tank.
According to the second aspect of the invention, at present invention also offers a kind of oily sludge of system processed as described above Reason method, comprises the following steps:
(1)Oily sludge is delivered to disintegrating apparatus 1, is crushed, while with hot water hydro-peening oily sludge, equipment to be comminuted 1 Complete to crush and stood with after hydro-peening, then open the first oil slick outlet and discharge the oil slick and debris on upper strata, lower floor Oily sludge is discharged and is transported to vibratory sieve 2;
(2)Vibratory sieve 2 is sieved to oily sludge, and debris and the big oily sludge of particle diameter are sized out, and particle diameter is small to be contained Greasy dirt is dropped down onto in the settler 3 of lower section, and oily sludge is staticly settled in settler 3, and upper strata oil slick is floating through second Oily outlet discharge, bottom oily sludge enters in ejector 4, while the water of water storage device 7 enters in ejector 4, so that shape Into high-speed jet and to spray into and carry out impact comminution in high speed reducing mechanism 5, while the rotation chopping oil-containing of high speed reducing mechanism 5 is dirty Mud, so as to break into fine particle, preferably micron particles are made mud;Wherein, the water in water storage device 7 is added with Demulsifier;
(3)Then by slurry transportation to separation equipment 6, thoroughly realize that oil is separated with water, sludge in separation equipment 6, point Separate out water and return to water storage device 7.
In step(1)In, the temperature of the water that high-pressure sprayer sprays is 70 DEG C~90 DEG C, what high-pressure sprayer sprayed Water is preferably 1 with the part by weight of oily sludge:(1~3).
In step(2)In, the part by weight of water and oily sludge that water storage device 7 enters ejector 4 is 1:(0.5~ 3), the temperature of water is preferably 70~90 DEG C in water storage device 7;Demulsifier is neopelex, Nonyl pheno One or more in ether, OPEO, AEO, demulsifier is in the reclaimed water of water storage device 7 Concentration is preferably 0.25wt%~2.0wt%.
In step(3)In, when separation equipment 6 using stirring separator 61 when, stirring separator 61 stir before and/ Or in whipping process, stirring separator 61 bottom be passed through extractant, dissolved air water and solid foam particle in one kind or It is several, depending on the consumption of gas can be according to the situation of bubble oil slick, all upper strata is floated to until oily;Dissolved air water is dissolved with gas The water of body, gas is air or nitrogen etc., and the consumption of dissolved air water is the 20wt%~40wt% of oily sludge;Extractant is oil One or more in ether, toluene, naphtha, gasoline, diesel oil, solvent naphtha, solid foam particle be polystyrene foam particles, One or more in polyvinyl chloride foam particle, polyurethane foam particles, phenol formaldehyde foam particle.The consumption of extractant is oil-containing 0.2wt%~the 1.0wt% of sludge;Solid foam particle is polystyrene foam particles, polyvinyl chloride foam particle, polyurethane foam One or more in foam particle, phenol formaldehyde foam particle, the consumption of solid foam particle for oily sludge 1.0wt%~ 3.0wt%.The time being stirred in stirring separator 61 is 5~30 min, the time for being stood after completion of stirring It is 5~30min.
Embodiment 1
Reference picture 1-5, by following embodiments, the invention will be further described.
With oil tank bottom greasy filth(Sludge oil-containing is 30wt%, aqueous 35wt%, and remaining is solid matter)As a example by illustrate this hair Bright specific embodiment.
(1)Oily sludge is delivered to disintegrating apparatus 1, is crushed, while spraying into hot water with high-pressure sprayer(Temperature It is 80 DEG C), so as to hydro-peening and crush oily sludge, equipment to be comminuted 1 complete to crush and hydro-peening after stood, then open the One oil slick outlet simultaneously discharges the oil slick and debris on upper strata(Wood chip, grass, plastics etc.), the oily sludge of lower floor discharges and is transported to Vibratory sieve 2;The water that high-pressure sprayer sprays is preferably 1 with the part by weight of oily sludge:1.
(2)Vibratory sieve 2 is sieved to oily sludge, debris(The debris such as brick, stone)The oily sludge big with particle diameter It is sized out, the small oily sludge of particle diameter is dropped down onto in the settler 3 of lower section, and oily sludge is stood in settler 3 Precipitation, upper strata oil slick is discharged through the second oil slick outlet, and bottom oily sludge is pushed into settling tank 31 by spiral conveying mechanism 32 Sludge outlet, ejector 4 suctions out the greasy filth of sludge outlet and high pressure sprays into impact grinding and high speed in high speed reducing mechanism 5 Chopping, the water source of ejector 4 uses the water in water storage device 7(Temperature is 80 DEG C), and high speed reducing mechanism 5 is by rotating at a high speed Mud granule is further crushed, so that greasy filth is thoroughly crushed, the granularity of greasy filth particle reaches less than 5 microns.In water storage device 7 Water is added with demulsifier(Neopelex, concentration is 1.0wt%), the addition of demulsifier is relatively beneficial to the height of ejector 4 Pressure impact grinding and the rotation chopping of the high speed of high speed reducing mechanism 5.Water storage device 7 enters the water and oily sludge of ejector 4 Part by weight be 1:1.
(4)Greasy filth after thoroughly crushing sufficiently is mixed in stirring separator 61 into the two-stage of series connection, In whipping process, the charging aperture 617 in the bottom of stirring separator 61 is passed through dissolved air water(Consumption is oily sludge 30wt%), after dissolved air water enters stirring separator 61, air is discharged and gradually floated by bottom from water, and is stirred and divided Multilayer stirring parts 614 from device 61 are stirred 10min in many sheaf spaces respectively so that greasy filth fills with bubble or solid particle Tap touches mixing, and coal tar, mink cell focus are sticked on bubble or solid particle and float to the top of separation equipment, stands After the 10min times, the 3rd oil-scraping device scrapes oil, and the water of bottom and the mixture of sludge enter centrifuge 62, and system is completed Third time oil phase and water phase and mud are separated.
(5)After the water of bottom and the mixture of sludge enter centrifuge 62, it is centrifuged, completes water phase and mud phase Separate.Water after separation returns to water storage device 7, and the reclaimed water of water storage device 7 is again introduced into ejector 4 and recycles, clean greasy filth Discharged from centrifuge 62, qualified discharge.
Final oil recovery rate is 98.2%, and residual oil content is 1.8%.
Embodiment 2
It is essentially identical with the processing method of embodiment 1 as another embodiment of the present invention, difference in:In step(4)In, Charging aperture 617 in the bottom of separation equipment is passed through extractant, and extractant is toluene, and the consumption of extractant is oily sludge 0.5wt%.Final oil recovery rate is 98.3%, and residual oil content is 1.5%.
It should be noted that each particular technique feature described in above-mentioned specific embodiment, can be by appointing What suitable mode is combined, its equally fall into it is disclosed in this invention within the scope of.In addition, it is of the invention it is various not Can also be combined between same implementation method, as long as it is without prejudice to thought of the invention, it should equally be considered as this Invention disclosure of that.
The preferred embodiment of the present invention is described in detail above in association with accompanying drawing, but, the present invention is not limited to above-mentioned reality The detail in mode is applied, in range of the technology design of the invention, various letters can be carried out to technical scheme Monotropic type, these simple variants belong to protection scope of the present invention.

Claims (10)

1. a kind of processing system of oily sludge, it is characterised in that including disintegrating apparatus, vibratory sieve, settler, ejector, High speed reducing mechanism, water storage device and the separation equipment for for oil, water, sludge separate;
The disintegrating apparatus, for primary comminution oily sludge, it includes crushing cylinder, is provided with above the crushing cylinder Oil slick space, crushing cylinder top wall body is provided with the first oil slick outlet that can be opened and closed, the crushing cylinder Bottom be provided with oily sludge outlet;
The vibratory sieve, positioned at settler top, and for sieving the oily sludge of disintegrating apparatus discharge;
The settler, for receiving and precipitating the oily sludge after screening, the settler is provided with can be opened and close The the second oil slick outlet for closing;
The high speed reducing mechanism, for oily sludge further to be broken into fine particle, preferably micron particles;
The settler is sequentially connected with ejector, high speed reducing mechanism, separation equipment, the delivery port of the water storage device with The water inlet connection of ejector.
2. processing system according to claim 1, it is characterised in that described processing system at least include following feature it One:
(1), the disintegrating apparatus also include that import cylinder, pair roller type tear up mechanism, rotary shaft disintegrating mechanism, high-pressure sprayer With the first oil-scraping device;
The bottom of the import cylinder is connected with cylinder is crushed, and the import cylinder is provided with the high pressure spray over or within Water installations, the pair roller type tears up mechanism and is arranged in import cylinder;
The rotary shaft disintegrating mechanism is arranged in pulverization cylinder body;
First oil-scraping device is arranged in the oil slick space and relative with the first oil slick outlet;
(2), the rotary shaft disintegrating mechanism by can rotating buncher drive, the rotary shaft disintegrating mechanism be located at crush In cylinder, the disintegrating mechanism includes the rotating shaft being be arranged in parallel with tubular axis, and multiple rows of crushing knife tool is provided with the rotating shaft, The rotating shaft is connected with the drive end of the motor;Preferably, the crushing knife tool and the connection angle of rotating shaft are 30 °~90 °, Often row's crushing knife tool includes 2 ~ 6 crushing knife tools, and the crushing knife tool in same row is identical with the connection angle of rotating shaft and edge turns The circumferencial direction arrangement of axle;It is further preferred that multiple rows of crushing knife tool includes multiple rows of vertical crushing knife tool and multiple rows of inclination Crushing knife tool, is arranged at intervals with the vertical crushing knife tool of 1-3 rows, the vertical crushing between adjacent two row inclines crushing knife tool Cutter is 90 ° with the connection angle of rotating shaft, and the crushing knife tool and the connection angle of rotating shaft of inclining is 30 °~80 °;
(3), be provided with the first oil slick outlet the first baffle that can be opened and closed;It is further preferred that described First baffle is hinged with the first oil slick outlet;It is further preferred that the first baffle by first axle with it is described First oil slick outlet is hinged, and the two ends of the first axle are provided with the first crank, and first crank is connected with the first cylinder, institute The first crank handle turns baffle plate described in the first air cylinder driven is stated to be turned on and off;
First oil-scraping device includes the first oil scraping plate and first driving means, and first oil scraping plate and first drive dress The opposite side for being arranged on the first baffle is put, the first driving means are preferably the second cylinder;
(4), the settler include settling tank, the second oil slick outlet is arranged on the top of settling tank, described the The second baffle that can be opened and closed is provided with two oil slick outlets;It is further preferred that the second baffle and described Two oily outlets are hinged;It is further preferred that the second baffle is hinged by the second axle with the second oil slick outlet, The two ends of second axle are provided with the second crank, and second crank is connected with the 3rd cylinder, described in the 3rd air cylinder driven Second crank handle turns baffle plate is turned on and off;
Preferably, the settler also includes spiral conveying mechanism, and the spiral conveying mechanism is arranged on the bottom of settling tank, The spiral conveying mechanism extends horizontally to the material outlet of settling tank from one end of settling tank;It is further preferred that the spiral shell Rotation conveying mechanism includes spiral conveying blade, the material of the pitch of the spiral conveying blade from one end of settling tank to settling tank Gradually decreased on the direction of outlet;
(5), the high speed reducing mechanism include the multiple rows of crushing knife tool crushed cylinder, rotating shaft, set in rotating shaft, it is preferable that it is every Row's crushing knife tool includes 2 ~ 8 crushing knife tools, and the crushing knife tool in same row is arranged along the circumferencial direction of rotating shaft;
(6), the high speed reducing mechanism sludge inlet be arranged on the one end for crushing cylinder, and the high speed reducing mechanism Sludge outlet is arranged on the bottom for crushing the cylinder other end;
(7), be provided with delivery pump or high-pressure pump on the pipeline that is connected with the delivery port of water storage device of the water inlet of the ejector;
(8), the processing system is when including multiple separation equipment, the sludge outlet of one of separation equipment is separated with another The sludge import connection of equipment, and the bottom sludge outlet of the separation equipment connects with the sludge import of next separation equipment again Connect, so as to multiple separation equipments be connected in series.
3. processing system according to claim 1 and 2, it is characterised in that the separation equipment is stirred including one or more Separator and a centrifuge are mixed, the stirring separator is sequentially connected in series with centrifuge, the stirring separator Stirring cylinder, agitating shaft, multilayer insulating panel and stirring vane;
The agitating shaft is arranged in mixing drum body, and the multilayer insulating panel is separated into many sheaf spaces, the multilayer by cylinder is stirred Each sheaf space in space is provided with stirring parts, and the stirring parts are connected with agitating shaft, during the multilayer insulating panel is provided with Heart hole, the diameter with diameter greater than agitating shaft of the centre bore, the agitating shaft passes through centre bore;
The bottom of the stirring cylinder is provided with sludge outlet, is provided with for extracting in the bottom or bottom of the stirring cylinder The charging aperture of one or more materials in agent, dissolved air water and solid foam particle;The top of the stirring cylinder is provided with dirt Mud import and the 3rd oil slick outlet that can be opened, close.
4. processing system according to claim 3, it is characterised in that the stirring parts include stirring disk and paddle Piece, the stirring disk is provided with center hole and is set on agitating shaft, is provided with the one or both sides of the stirring disk Multiple stirring vanes;Preferably, the stirring disk is integrally formed with stirring vane;It is further preferred that the stirring Crushing knife tool is additionally provided with disk.
5. processing system according to claim 3, it is characterised in that the multilayer insulating panel extends to the interior of stirring cylinder Wall;Preferably, the multilayer insulating panel is fixed on the inwall of stirring cylinder, or fixes stirring cylinder by many connecting rods Interior, the connecting rod is connected through multilayer insulating panel and with multilayer insulating panel, the top of the connecting rod upper end connection stirring cylinder Wall, the bottom wall of the connecting rod lower end connection stirring cylinder.
6. processing system according to claim 3, it is characterised in that be provided with and can open at the 3rd oil slick outlet The third baffle for opening and closing;It is further preferred that the third baffle is hinged with the 3rd oil slick outlet;Further Preferably, the third baffle is hinged by axle with the 3rd oil slick outlet, and the two ends of the 3rd axle are provided with the 3rd song Handle, the 3rd crank is connected with the 4th cylinder, described in the 4th air cylinder driven the 3rd crank handle turns third baffle open or Close;
The stirring separator also includes the second oil-scraping device, and second oil-scraping device is located at top and many in mixing drum body Layer dividing plate top;Preferably, second oil-scraping device includes the second oil scraping plate and the second drive device, second frizing Plate and the second drive device are arranged on the opposite side of the third baffle, and second drive device is preferably the 5th cylinder.
7. processing system according to claim 1 and 2, it is characterised in that the charging aperture is connected with air-dissolving apparatus, described Air-dissolving apparatus are preferably air dissolved pump.
8. processing system according to claim 1 and 2, it is characterised in that the processing system at least includes following feature One of:
(1), one or more Fuel Tanking Units,
The Fuel Tanking Unit is used to receive the oil isolated from disintegrating apparatus, settler and separation equipment;Preferably, the place Reason system includes the first Fuel Tanking Unit, the second Fuel Tanking Unit and the 3rd Fuel Tanking Unit, first Fuel Tanking Unit and disintegrating apparatus The connection of the first oil slick outlet, second Fuel Tanking Unit is connected with the second oil slick outlet of settler, the described 3rd Fuel Tanking Unit is connected with the 3rd oil slick outlet of separation equipment;It is further preferred that first Fuel Tanking Unit, the second oil storage Device and the 3rd Fuel Tanking Unit are preferably oil storage tank;
(2), the first conveying device and the second conveying device,
First conveying device, the import for oily sludge to be delivered to disintegrating apparatus, the first conveying device is preferably monobucket and carries The machine of liter;
Second conveying device, for disintegrating apparatus to be processed after oily sludge be delivered to vibratory sieve, the second conveying device is preferred It is bucket elevator, the import of bucket elevator is connected with the sludge outlet for crushing cylinder, the sludge outlet position of bucket elevator In vibratory sieve top.
9. a kind of process for treating oil-containing sludge of the processing system in use claim 1-8 described in any one, its feature exists In comprising the following steps:
(1)Oily sludge is delivered to disintegrating apparatus, is crushed, while with hot water hydro-peening oily sludge, equipment to be comminuted is complete Stood with after hydro-peening into crushing, then open the first oil slick outlet and discharge the oil slick and debris on upper strata, lower floor is contained Greasy dirt is discharged and is transported to vibratory sieve;
(2)The vibratory sieve is sieved to oily sludge, and debris and the big oily sludge of particle diameter are sized out, and particle diameter is small Oily sludge is dropped down onto in the settler of lower section, and oily sludge is staticly settled in settler, and upper strata oil slick is floating through second Oily outlet discharge, bottom oily sludge enters in ejector, while the water of the water storage device enters in ejector, so that shape Into high-speed jet and spray into impact comminution is carried out in high speed reducing mechanism, while high speed reducing mechanism rotation chopping oil-containing is dirty Mud, so as to break into fine particle, preferably micron particles are made mud;Wherein, the water in water storage device is added with demulsification Agent;
(3)Then by slurry transportation to separation equipment, thoroughly realize that oil is separated with water, sludge in the separation equipment, Separate water outlet and return to water storage device.
10. processing method according to claim 9, it is characterised in that described processing method at least includes following feature One of:
A, in step(1)In, the temperature of the water that the high-pressure sprayer sprays is 70 DEG C~90 DEG C, the high-pressure sprayer The water of ejection is preferably 1 with the part by weight of oily sludge:(1~3);
B, in step(2)In, the part by weight of water and oily sludge that the water storage device enters ejector is 1:(0.5~ 3), the temperature of water is preferably 70~90 DEG C in water storage device;The demulsifier is neopelex, polyoxyethylene nonyl phenyl second One or more in alkene ether, OPEO, AEO, the demulsifier is in water storage device reclaimed water In concentration be preferably 0.25wt%~2.0wt%;
C, in step(3)In, when separation equipment using stirring separator when, stirring separator stirring before and/or stir During, stirring separator bottom be passed through extractant, dissolved air water and solid foam particle in one or more;It is described Dissolved air water is the water dissolved with gas;The gas is air or nitrogen;Extractant is petroleum ether, toluene, naphtha, gasoline, bavin Oil, one or more in solvent naphtha, the solid foam particle be polystyrene foam particles, polyvinyl chloride foam particle, One or more in polyurethane foam particles, phenol formaldehyde foam particle;The time being stirred in the separation equipment for 5~ 30 min, the time for being stood after completion of stirring is 5~30min.
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