CN106635310A - 一种铪及铪合金冷镦工艺润滑剂组合物 - Google Patents

一种铪及铪合金冷镦工艺润滑剂组合物 Download PDF

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CN106635310A
CN106635310A CN201610841102.5A CN201610841102A CN106635310A CN 106635310 A CN106635310 A CN 106635310A CN 201610841102 A CN201610841102 A CN 201610841102A CN 106635310 A CN106635310 A CN 106635310A
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黄福川
陈彪
韦开焕
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Guangxi University
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Abstract

本发明公开了一种铪及铪合金冷镦工艺润滑剂组合物，采用HVI 650基础油作为基础油，配合多种复合添加剂。它们包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、抗泡剂、防锈剂、粘附剂、分散剂、抗氧抗腐剂等。本发明的组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味，不刺激皮肤，能提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，有良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。

Description

一种铪及铪合金冷镦工艺润滑剂组合物
技术领域
本发明属于金属加工润滑剂领域，特别涉及一种铪及铪合金冷镦工艺润滑剂组合物。
背景技术
铪的用途：由于它容易发射电子而很有用处(如用作白炽灯的灯丝)。用作X射线管的阴极，铪可作为很多充气系统的吸气剂。铪的用途还有是制作原子核反应堆的控制棒。纯铪具有可塑性、易加工、耐高温抗腐蚀，是原子能工业重要材料。铪的热中子捕获截面大，是较理想的中子吸收体，可作原子反应堆的控制棒和保护装置。铪粉可作火箭的推进器。铪为银灰色的有光泽金属，熔点2227℃，沸点4602℃，密度13.31克/厘米3；金属铪有较高的中子俘获能力。具有良好的抗腐蚀性，不受一般的酸碱侵蚀；易溶于氢氟酸；高温下可与氧、氮等气体直接化合。金属铪强度适中，可作贱金属的表面包膜。
冷镦加工是利用模具在常温下对金属棒料镦粗(常为局部镦粗)成形的锻造方法。冷镦是另一种形式的镦锻工艺。更具金属型变理论，在常温下对金属坯料施加一定的压力，使之在模腔产生变形。按规定的形状和尺寸成形。冷镦工艺广泛应用于中小零件以及各种类型的标准件。
冷镦工艺的主要特征是无切削加工，材料利用率高，利用率达80～90％，且金属材料流线不会被切断，因此成品强度比切削加工或铸造成型零件强度更高，在一定的批量生产条件下，冷镦加工成本要比其它加工成本低得多，适用于通常需要切削件以及紧固件等形状对称的产品加工。产品的尺寸精度、重量精度及力学性能等都能达到较高的要求。
润滑剂要求具有的特点：良好的承载抗磨性、挤压性(不拉毛、拉伤、有效延长冲模的使用寿命)、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤等。提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。
发明内容
本发明要解决的技术问题是提供一种具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味，不刺激皮肤，能提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，有良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗的铪及铪合金冷镦工艺润滑剂组合物。
本发明采用以下技术方案解决上述技术问题：
一种铪及铪合金冷镦工艺润滑剂组合物，采用HVI 650基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.05％～0.5％
金属减活剂 1％～3％
油性剂 3％～6％
摩擦改进剂 2％～3％
极压剂 2％～3％
抗磨剂 4％～8％
抗泡剂 10～50ppm
防锈剂 0.05％～0.5％
粘附剂 3％～6％
分散剂 1％～3％
抗氧抗腐剂 0.5％～1.2％
以上各组分质量百分比总和等于100％。
抗氧剂是质量比67％的4,4-亚甲基双T511和33％的二烷基二苯胺T534的复合；金属减活剂是苯三唑衍生物T551。
油性剂是硫化猪油。
摩擦改进剂是烷基亚磷酸酯；极压剂是二硫代磷酸酯。
抗磨剂是氯化石蜡T301；抗泡剂是甲基硅油T901。
防锈剂是质量比50％的苯骈三氮唑和50％的烯基丁二酸半酯T747复合。
粘附剂是聚异丁烯T603D。
分散剂是高氮聚异丁烯丁二酰亚胺T154A；抗氧抗腐剂是硫磷丁辛基锌盐T202。
本发明的有益效果在于：本发明组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味，不刺激皮肤，能提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，有良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。
具体实施方式
实施例1：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
HVI 650基础油 余量
质量比67％的4,4-亚甲基双(T511)和33％的二烷基二苯胺(T534)复合 0.3％
苯三唑衍生物(T551) 1％
硫化猪油 3％
烷基亚磷酸酯 3％
二硫代磷酸酯 3％
氯化石蜡(T301) 5％
甲基硅油(T901) 30ppm
质量比50％的苯骈三氮唑和50％的烯基丁二酸半酯(T747)复合 0.3％
聚异丁烯(T603D) 5％
聚异丁烯丁二酰亚胺(高氮)(T154A) 3％
硫磷丁辛基锌盐(T202) 1.2％
以上各组分质量百分比总和等于100％。
实施例2：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
HVI 650基础油 余量
质量比67％的4,4-亚甲基双(T511)和33％的二烷基二苯胺(T534)复合 0.1％
苯三唑衍生物(T551) 3％
硫化猪油 2.5％
烷基亚磷酸酯 2.5％
二硫代磷酸酯 2％
氯化石蜡(T301) 4％
甲基硅油(T901) 20ppm
质量比50％的苯骈三氮唑和50％的烯基丁二酸半酯(T747)复合 0.3％
聚异丁烯(T603D) 5％
聚异丁烯丁二酰亚胺(高氮)(T154A) 1％
硫磷丁辛基锌盐(T202) 1％
以上各组分质量百分比总和等于100％。
实施例3：
将以下各组分按质量百分比调和而成：
组分 质量百分比含量
HVI 650基础油 余量
质量比67％的4,4-亚甲基双(T511)和33％的二烷基二苯胺(T534)复合 0.4％
苯三唑衍生物(T551) 1.5％
硫化猪油 2％
烷基亚磷酸酯 2.5％
二硫代磷酸酯 2.5％
氯化石蜡(T301) 8％
甲基硅油(T901) 50ppm
质量比50％的苯骈三氮唑和50％的烯基丁二酸半酯(T747)复合 0.3％
聚异丁烯(T603D) 5％
聚异丁烯丁二酰亚胺(高氮)(T154A) 2％
硫磷丁辛基锌盐(T202) 0.8％
以上各组分质量百分比总和等于100％。
实施例2产品典型技术指标：
项目 指标
40℃运动粘度mm2/s 212.5
闪点(开口)/℃ 266
倾点/℃ -8
黏度系数 121
腐蚀试验(铜片，100℃，3h)/级 1
摩擦系数 0.07
氧化安定性(旋转氧弹性，150℃)min 251
极压性(四球机试验)Pb/N 925
烧结负荷PD/N 7500
梯姆肯/N 352
FZG，级 14
机械杂质，％ 无
水分，％ 痕迹
水溶性酸和碱 无

Claims (8)

1.一种铪及铪合金冷镦工艺润滑剂组合物，其特征在于：采用HVI 650基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.05％～0.5％ 金属减活剂 1％～3％ 油性剂 3％～6％ 摩擦改进剂 2％～3％ 极压剂 2％～3％ 抗磨剂 4％～8％ 抗泡剂 10～50ppm 防锈剂 0.05％～0.5％ 粘附剂 3％～6％ 分散剂 1％～3％ 抗氧抗腐剂 0.5％～1.2％
以上各组分质量百分比总和等于100％。
2.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于抗氧剂是质量比67％的4,4-亚甲基双T511和33％的二烷基二苯胺T534的复合；金属减活剂是苯三唑衍生物T551。
3.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于油性剂是硫化猪油。
4.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于摩擦改进剂是烷基亚磷酸酯；极压剂是二硫代磷酸酯。
5.如权利要求1所述铪及铪合金冷镦工艺润滑剂组合物，其特征在于抗磨剂是氯化石蜡T301；抗泡剂是甲基硅油T901。
6.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于防锈剂是质量比50％的苯骈三氮唑和50％的烯基丁二酸半酯T747复合。
7.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于粘附剂是聚异丁烯T603D。
8.如权利要求1所述的铪及铪合金冷镦工艺润滑剂组合物，其特征在于分散剂是高氮聚异丁烯丁二酰亚胺T154A；抗氧抗腐剂是硫磷丁辛基锌盐T202。
CN201610841102.5A 2016-09-21 2016-09-21 一种铪及铪合金冷镦工艺润滑剂组合物 Withdrawn CN106635310A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031722A (zh) * 2014-05-22 2014-09-10 丘寿勇 一种润滑油
CN104962368A (zh) * 2015-07-20 2015-10-07 广西大学 铼棒材旋锻润滑剂组合物
CN105238519A (zh) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 润滑油组合物及其用途

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031722A (zh) * 2014-05-22 2014-09-10 丘寿勇 一种润滑油
CN104962368A (zh) * 2015-07-20 2015-10-07 广西大学 铼棒材旋锻润滑剂组合物
CN105238519A (zh) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 润滑油组合物及其用途

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