CN106520345A - 一种锌合金冷镦工艺润滑剂组合物 - Google Patents

一种锌合金冷镦工艺润滑剂组合物 Download PDF

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CN106520345A
CN106520345A CN201610966173.8A CN201610966173A CN106520345A CN 106520345 A CN106520345 A CN 106520345A CN 201610966173 A CN201610966173 A CN 201610966173A CN 106520345 A CN106520345 A CN 106520345A
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lubricant compositions
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黄福川
韦开焕
马骁飞
陈彪
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Guangxi University
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Abstract

本发明公开了一种锌合金冷镦工艺润滑剂组合物，采用68号全损耗系统用油作为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、抗乳化剂、防锈剂、抗泡剂、抗氧抗腐剂、分散剂等。本发明的组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤，提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。

Description

一种锌合金冷镦工艺润滑剂组合物
技术领域
本发明一种锌合金冷镦工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
锌合金是以锌为基础加入其他元素组成的合金。常加的合金元素有铝、铜、镁、镉、铅、钛等低温锌合金。锌合金熔点低，流动性好，易熔焊，钎焊和塑性加工，在大气中耐腐蚀，残废料便于回收和重熔；但蠕变强度低，易发生自然时效引起尺寸变化。熔融法制备，压铸或压力加工成材。按制造工艺可分为铸造锌合金和变形锌合金。特点：1.相对比重大。2.铸造性能好，可以压铸形状复杂、薄壁的精密件，铸件表面光滑。3.可进行表面处理：电镀、喷涂、喷漆、抛光、研磨等。4.熔化与压铸时不吸铁，不腐蚀压型，不粘模。5.有很好的常温机械性能和耐磨性。6.熔点低，在385℃熔化，容易压铸成型。锌合金的主要添加元素有铝，铜和镁等。锌合金按加工工艺可分为形变与铸造锌合金两类。铸造锌合金流动性和耐腐蚀性较好，适用于压铸仪表、汽车零件外壳等。不同的锌合金有不同的物理和机械特性，这样为压铸件设计提供了选择的空间。
冷镦加工是利用模具在常温下对金属棒料镦粗(常为局部镦粗)成形的锻造方法。冷镦是另一种形式的镦锻工艺。更具金属型变理论，在常温下对金属坯料施加一定的压力，使之在模腔产生变形。按规定的形状和尺寸成形。冷镦工艺广泛应用于中小零件以及各种类型的标准件。
冷镦工艺的主要特征是无切削加工，材料利用率高，利用率达80～90％，且金属材料流线不会被切断，因此成品强度比切削加工或铸造成型零件强度更高，在一定的批量生产条件下，冷镦加工成本要比其它加工成本低得多，适用于通常需要切削件以及紧固件等形状对称的产品加工。产品的尺寸精度、重量精度及力学性能等都能达到较高的要求。
发明内容
本发明要解决的技术问题是提供一种具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤，提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗的锌合金冷镦工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种锌合金冷镦工艺润滑剂组合物，采用68号全损耗系统用油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.05％～0.2％
金属减活剂 0.05％～0.3％
油性剂 3.0％～8.0％
摩擦改进剂 1.0％～3.0％
极压剂 3.0％～4.0％
抗磨剂 4.0％～6.0％
抗乳化剂 0.05％～0.3％
防锈剂 0.03％～0.5％
抗泡剂 10～50ppm
抗氧抗腐剂 0.5％～1.2％
分散剂 2.0％～4.0％
以上各组分的质量百分比总和是100％。
抗氧剂是质量比50％的2,6二叔丁基混合酚T502和50％的二烷基二苯胺T534复合；
金属减活剂是苯三唑衍生物T551。
油性剂是大豆油；
摩擦改进剂是硬脂酸锌。
极压剂是乙基月桂酸磷酸酯；
抗磨剂是氯化石蜡T301。
抗乳化剂是胺与环氧化合物的缩合物T1001；
防锈剂是质量比67％的环烷酸锌T704和33％的苯并三氮唑T706复合。
抗泡剂是丙烯酸酯与醚共聚物T911；
抗氧抗腐剂是硫磷丁辛基锌盐T202。
分散剂是多烯基丁二酰亚胺T153。
本发明的显著优点：本发明的组合物具有良好的承载抗磨性、挤压性(不拉毛、拉伤、有效延长冲模的使用寿命)、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤，提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性，热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例1产品的主要理化指标：
实施例2产品的主要理化指标：
实施例3产品的主要理化指标：

Claims (7)

1.一种锌合金冷镦工艺润滑剂组合物，其特征在于：采用68号全损耗系统用油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.05％～0.2％ 金属减活剂 0.05％～0.3％ 油性剂 3.0％～8.0％ 摩擦改进剂 1.0％～3.0％ 极压剂 3.0％～4.0％ 抗磨剂 4.0％～6.0％ 抗乳化剂 0.05％～0.3％ 防锈剂 0.03％～0.5％ 抗泡剂 10～50ppm 抗氧抗腐剂 0.5％～1.2％ 分散剂 2.0％～4.0％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于抗氧剂是质量比50％的2,6二叔丁基混合酚T502和50％的二烷基二苯胺T534复合；金属减活剂是苯三唑衍生物T551。
3.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于油性剂是大豆油；摩擦改进剂是硬脂酸锌。
4.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于极压剂是乙基月桂酸磷酸酯；抗磨剂是氯化石蜡T301。
5.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于抗乳化剂是胺与环氧化合物的缩合物T1001；防锈剂是质量比67％的环烷酸锌T704和33％的苯并三氮唑T706复合。
6.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于抗泡剂是丙烯酸酯与醚共聚物T911；抗氧抗腐剂是硫磷丁辛基锌盐T202。
7.如权利要求1所述的一种锌合金冷镦工艺润滑剂组合物，其特征在于分散剂是多烯基丁二酰亚胺T153。
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