CN106520315A - 一种锡合金冷镦工艺润滑剂组合物 - Google Patents

一种锡合金冷镦工艺润滑剂组合物 Download PDF

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CN106520315A
CN106520315A CN201610963531.XA CN201610963531A CN106520315A CN 106520315 A CN106520315 A CN 106520315A CN 201610963531 A CN201610963531 A CN 201610963531A CN 106520315 A CN106520315 A CN 106520315A
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tin alloy
alloy cold
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黄福川
陈帆
陈一帆
唐弓斌
肖锋
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Guangxi University
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Abstract

本发明公开了一种锡合金冷镦工艺润滑剂组合物，采用MVI 400作为基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、抗磨剂、摩擦改进剂、极压剂、防锈剂、抗乳化剂、抗泡剂、抗氧抗腐剂、分散剂等。本发明组合物具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤等。提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗，延长模具使用寿命。

Description

一种锡合金冷镦工艺润滑剂组合物
技术领域
本发明一种锡合金冷镦工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
金属锡柔软，易弯曲，熔点231.89℃，沸点2260℃。有三种同素异形体：白锡为四方晶系，密度7.28克/厘米&sup3，硬度2，延展性好；灰锡为金刚石形立方晶系，密度5.75克/厘米&sup3；脆锡为正交晶系，密度6.54克/厘米&sup3。锡是人类使用的最古老的金属之一，随着锡的工业用途不断拓展，锡的开采、选矿、冶炼和加工得到了快速发展，逐步形成了门类齐全的锡产业。古老的锡仍然是现代工业不可缺少的关键稀有金属，号称“工业味精”，广泛应用于电子、信息、电器、化工、冶金、建材、机械、食品包装等行业。
冷镦加工是利用模具在常温下对金属棒料镦粗(常为局部镦粗)成形的锻造方法。冷镦是另一种形式的镦锻工艺。更具金属型变理论，在常温下对金属坯料施加一定的压力，使之在模腔产生变形。按规定的形状和尺寸成形。冷镦工艺广泛应用于中小零件以及各种类型的标准件。
冷镦工艺的主要特征是无切削加工，材料利用率高，利用率达80～90％，且金属材料流线不会被切断，因此成品强度比切削加工或铸造成型零件强度更高，在一定的批量生产条件下，冷镦加工成本要比其它加工成本低得多，适用于通常需要切削件以及紧固件等形状对称的产品加工。产品的尺寸精度、重量精度及力学性能等都能达到较高的要求。
发明内容
本发明要解决的技术问题是提供一种具有良好的承载抗磨性、挤压性、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤，提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗的锡合金冷镦工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种锡合金冷镦工艺润滑剂组合物，采用MVI 400基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
以上各组分的质量百分比总和是100％。
抗氧剂是质量比50％的2,6二叔丁基对甲酚T501和50％的对羟基二苯胺复合；
金属减活剂是苯三唑衍生物T551。
油性剂是牛脂；抗磨剂是氯化石蜡T301。
摩擦改进剂是油酸乙基酯；极压剂是酸性磷酸酯胺盐T308。
防锈剂是质量比50％的环烷酸锌T704和50％的苯并三氮唑(T706)复合；
抗乳化剂是聚醚类高分子化合物DL32。
抗泡剂是甲基硅油T901；
抗氧抗腐剂是二烷基二硫代氨基甲酸锡。
分散剂是双烯基丁二酰亚胺T152。
本发明的优点在于：本发明组合物具有良好的承载抗磨性、挤压性(不拉毛、拉伤、有效延长冲模的使用寿命)、低温流动扩散性、润滑性、冷却性，油膜强度大、油膜厚度保持稳定，无异味、不刺激皮肤等。提高光洁度，保护被加工零件表面不锈蚀和氧化，减少动力能耗，低温流动性好，良好的抗泡性、抗乳化性、热氧化定性好，减少沉淀物和漆膜的产生，成型件易清洗。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI 400基础油 余量
质量比50％的2,6二叔丁基对甲酚(T501)和50％的对羟基二苯胺复合 0.1％
苯三唑衍生物(T551) 0.2％
牛脂 4.0％
氯化石蜡(T301) 3.0％
油酸乙基酯 2.0％
酸性磷酸酯胺盐(T308) 2.0％
质量比50％的环烷酸锌(T704)和50％的苯并三氮唑(T706)复合 0.1％
聚醚类高分子化合物(DL32) 0.15％
甲基硅油(T901) 30ppm
二烷基二硫代氨基甲酸锡 0.7％
双烯基丁二酰亚胺(T152) 2.5％
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI 400基础油 余量
质量比50％的2,6二叔丁基对甲酚(T501)和50％的对羟基二苯胺复合 0.2％
苯三唑衍生物(T551) 0.15％
牛脂 5.0％
氯化石蜡(T301) 3.5％
油酸乙基酯 2.0％
酸性磷酸酯胺盐(T308) 1.5％
质量比50％的环烷酸锌(T704)和50％的苯并三氮唑(T706)复合 0.15％
聚醚类高分子化合物(DL32) 0.2％
甲基硅油(T901) 35ppm
二烷基二硫代氨基甲酸锡 0.6％
双烯基丁二酰亚胺(T152) 2.5％
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
组分 质量百分比含量
MVI 400基础油 余量
质量比50％的2,6二叔丁基对甲酚(T501)和50％的对羟基二苯胺复合 0.25％
苯三唑衍生物(T551) 0.25％
牛脂 5.0％
氯化石蜡(T301) 3.5％
油酸乙基酯 1.5％
酸性磷酸酯胺盐(T308) 2.5％
质量比50％的环烷酸锌(T704)和50％的苯并三氮唑(T706)复合 0.1％
聚醚类高分子化合物(DL32) 0.15％
甲基硅油(T901) 30ppm
二烷基二硫代氨基甲酸锡 0.6％
双烯基丁二酰亚胺(T152) 2.5％
以上各组分质量百分比含量总和为100％。
实施例1产品的主要理化指标：
实施例2产品的主要理化指标：
实施例3产品的主要理化指标：

Claims (7)

1.一种锡合金冷镦工艺润滑剂组合物，其特征在于：采用MVI 400基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.03％～0.3％ 金属减活剂 0.03％～0.3％ 油性剂 3.0％～6.0％ 抗磨剂 2.0％～4.0％ 摩擦改进剂 1.0％～3.0％ 极压剂 1.0％～3.0％ 防锈剂 0.08％～0.2％ 抗乳化剂 0.05％～0.3％ 抗泡剂 10～50ppm 抗氧抗腐剂 0.5％～0.8％ 分散剂 2.0％～3.0％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于抗氧剂是质量比50％的2,6二叔丁基对甲酚T501和50％的对羟基二苯胺复合；金属减活剂是苯三唑衍生物T551。
3.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于油性剂是牛脂；抗磨剂是氯化石蜡T301。
4.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于摩擦改进剂是油酸乙基酯；极压剂是酸性磷酸酯胺盐T308。
5.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于防锈剂是质量比50％的环烷酸锌T704和50％的苯并三氮唑T706复合；抗乳化剂是聚醚类高分子化合物DL32。
6.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于抗泡剂是甲基硅油T901；抗氧抗腐剂是二烷基二硫代氨基甲酸锡。
7.如权利要求1所述的一种锡合金冷镦工艺润滑剂组合物，其特征在于分散剂是双烯基丁二酰亚胺T152。
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Publication number Priority date Publication date Assignee Title
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Publication number Priority date Publication date Assignee Title
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Application publication date: 20170322