CN106614671A - Safe environment-friendly mosquito repellent liquid and preparation method thereof - Google Patents
Safe environment-friendly mosquito repellent liquid and preparation method thereof Download PDFInfo
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- CN106614671A CN106614671A CN201611237745.5A CN201611237745A CN106614671A CN 106614671 A CN106614671 A CN 106614671A CN 201611237745 A CN201611237745 A CN 201611237745A CN 106614671 A CN106614671 A CN 106614671A
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- mosquito
- icaridin
- mosquito repellent
- repellent liquid
- driving liquid
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of daily chemical preparations, and particularly relates to safe environment-friendly mosquito repellent liquid and a preparation method thereof. The mosquito repellent liquid is mainly prepared from the following components in percentage by mass: 4-5% of icaridin, 8-12% of chitosan, 5-7% of sodium lignin sulfonate, 0.5-1.5% of a pH buffering agent, 0.5-1% of rutin, 0.5-1% of citronellol, 1-2% of urea peroxide, 11-15% of ethyl alcohol and 50-75% of water. The mosquito repellent liquid disclosed by the invention is prepared by adding other auxiliary components on the basis of an active substance for eradicating mosquitoes, namely the icaridin, so that the mosquito eradicating effect of the icaridin is better. The mosquito repellent liquid disclosed by the invention has the advantages that the range of eradicating mosquitoes is wide, the time of maintaining the mosquito eradicating effect is prolonged, and the mosquito repellent liquid disclosed by the invention can replace traditional high-concentration mosquito repellent liquid.
Description
Technical field
The invention belongs to daily use chemicals preparation technical field, and in particular to a kind of safety and environmental protection mosquito-driving liquid and its preparation side
Method.
Background technology
Mosquito can propagate various viruses, cause the generation of human diseases, for example cause encephalitis, Hemorrhagic fever, hepatitis, send out
Hot, slight discomfort, arthritis etc., in China, mosquito main propagation dengue fever, epidemic cerebrospinal meningitis B, malaria and hepatitis B etc.
Disease.By taking hepatitis B as an example, the mosquito in Hepatitis B patients room its hepatitis b surface antigen positive recall rate is and healthy up to more than 85%
Mosquito in people room reaches infection rate less than 10%, during the blood of mosquito bite Hepatitis B patients, while also having sucked B-type hepatitis
Poison, then go to bite Healthy People, mosquito will be kept away particularly critical by spreading to healthy human body.
Summer and autumn are mosquito activity most rampant seasons, prevent mosquito and bite, and eliminating mosquito can be effectively pre-
Prevent the generation of above-mentioned disease, at present, common mosquito repellent mode is：1st, physics mosquito repellent, removes rubbish and vegetation, shuts door and window, 2,
Chemical mosquito repellent, often using Metadelphene (DEET), p- terpane -3, the product such as 8- glycol (PMD), but this composition is single use,
It is short to keep away the mosquito time, and temperature is strong, accordingly, it would be desirable to mosquito repellent product needs further improvement.
The Chinese patent application of Publication No. 105997675A discloses a kind of mosquito-repellent water containing pericarpium zanthoxyli schinifolii and its preparation side
Method, main active is the extract of pericarpium zanthoxyli schinifolii, lavender, rose, wrinkled giant hyssop and peppermint, and the invention not only has good drive
Mosquito effect, also with refreshing the mind, refrigerant antipruritic, restraining and sterilizing bacteria, including skin personally instructs effect of insect bites, but, this
The bright plant extracts for using just can be evaporated completely at short notice entirely, and mosquito repellent time is short, and mosquito repellent scope is less.
The Chinese patent application of Publication No. 103860394A discloses a kind of long-acting mosquitos and flies repellent spray liniment of animal specific
And preparation method thereof, parts by weight of raw materials be Metadelphene 10～25, camphor 0.1～0.5, menthol 0.1～0.7, eugenol 0.5～
5th, Permethrin 0.2～3, high molecular polymer 0.2～6, organic solvent 50～80；Described organic solvent is alcohol, tetrahydrochysene furan
One of which in muttering；Described high molecular polymer is in sodium carboxymethylcellulose, polyvinylpyrrolidone, polyvinyl alcohol
One of which.Permethrin can cause environmental pollution, and the invention active ingredient Metadelphene to exist in the composition that the invention is used
More than 10%, it is impossible to as conventional family's composition, belong to agricultural chemicals category, in-convenience in use.
The content of the invention
In order to solve the deficiencies in the prior art, the invention provides a kind of safety and environmental protection mosquito-driving liquid and its preparation side
Method, the mosquito-driving liquid is on the basis of mosquito eradication active material Icaridin, to add other auxiliary elements so as to which mosquito eradication scope is more
Extensively, the time is more lasting.
Concrete technical scheme of the present invention is as follows.
A kind of safety and environmental protection mosquito-driving liquid, mainly by following mass fraction into being grouped into：Icaridin 4-5%, shitosan
8-12%, sodium lignin sulfonate 5-7%, pH buffer 0.5-1.5%, rutin 0.5-1%, citronellol 0.5-1%, peroxidating
Urea 1-2%, ethanol 11-15% and water 50-75%.
Icaridin：Molecular formula C12H23NO3, structural formula：
Icaridin (Icaridin) proves effective pest repellant composition by the World Health Organization, and its form includes spray
Mist agent, mosquito-repellent water etc..According to different consumption levels, active formulation can provide under normal circumstances 3-5 hours (content 10%)
Expelling parasite is protected, and is significantly better than its like product.But the content of Icaridin is no more than in the mosquito-repellent water commonly used due to family
5%, it is therefore desirable to add the auxiliary element of some securities to its further synergy.
Shitosan：Chitosan-phospholipid complex has preferable antibacterial activity, can suppress some fungies, bacterium and virus
Growth and breeding, and shitosan has good flocculation, not only can be sterilized, catharsis can also be played to air,
Importantly, shitosan skin-friendly is good, it is nonirritant.
Rutin (CAS：153-18-4)：Rue is a kind of common mosquito repellent plant, and wherein main active substances are rue
Glucoside.
Citronellol (CAS：106-22-9)：With golden yellow grape and typhoid bacillus activity is suppressed, while being a kind of conventional
Mosquito repellent plant component, but its volatility is high, it is impossible to be used alone, and effect duration is short.
Carbamide peroxide：Urea, H are decomposed in water2O2And elemental oxygen, and slowly release O2, during pH value of water solution is near
Property, good stability, the effectiveness time is long, has no side effect, and Nonpoisonous, non-environmental-pollution can improve the bactericidal effect to bacterium in air.
Sodium lignin sulfonate (CAS in present component：It is 8061-51-6) a kind of surfactant, it is poly- with the use of shell
Sugar can extend the mosquito repellent time of Icaridin.
Further, described safety and environmental protection mosquito-driving liquid, by following mass fraction into being grouped into：Icaridin 4.5%,
Shitosan 10%, sodium lignin sulfonate 6%, pH buffer 1%, rutin 0.7%, citronellol 0.8%, carbamide peroxide
1.5%th, ethanol 13% and water 62.5%.
Preferably, described pH buffer is salicylic acid or sodium salicylate.
Preferably, described pH buffer is salicylic acid.
Present invention also offers the preparation method of described safety and environmental protection mosquito-driving liquid, step is,
S1：After water and ethanol are sufficiently mixed, shitosan and sodium lignin sulfonate are added, be heated to 65-75 DEG C, stirring is equal
It is even, obtain mixed liquor A；
S2：The mixed liquor A that step S1 is obtained is cooled to into 40-45 DEG C, Icaridin, rutin, citronellol, stirring is added
Uniformly, solution B is obtained；
S3：The solution B that step S2 is obtained is down to into 25-35 DEG C, carbamide peroxide is added, is stirred, then using pH
Buffer adjusts pH to 7.0-8.0, obtains final product.
Compared with prior art, the present invention has advantages below：
1st, it is safe：In mosquito-driving liquid when Icaridin content is more than 5%, belong to agricultural chemicals category, toxicity is big, the present invention
Various safe auxiliary elements are with the addition of, the content of Icaridin when the repelling effect of mosquito-driving liquid is ensured, can be reduced.
2nd, bactericidal properties：Shitosan and citronellol have good bactericidal effect in the present invention, can suppress yellow grape ball
Bacterium and colibacillary growth.
3rd, purification of air：Shitosan has good flocculation, is aided with carbamide peroxide, has to air good net
Change effect.
Specific embodiment
By specific embodiment, the present invention is further illustrated, makes those skilled in the art more understand skill of the present invention
Art scheme, but be not the restriction to protection domain.Wherein, present component belongs to conventional products, wherein, shitosan (CAS:
9012-76-4)：Shandong Xi Tang bio tech ltd.
Embodiment 1
A kind of safety and environmental protection mosquito-driving liquid, by following mass fraction into being grouped into：Icaridin 4.5%, shitosan 10%,
Sodium lignin sulfonate 6%, pH buffer salicylic acid 1%, rutin 0.7%, citronellol 0.8%, carbamide peroxide 1.5%, second
Alcohol 13% and water 62.5%.
The preparation method of described safety and environmental protection mosquito-driving liquid, step is,
S1：After water and ethanol are sufficiently mixed, shitosan and sodium lignin sulfonate are added, are heated to 70 DEG C, stirred,
Obtain mixed liquor A；
S2：The mixed liquor A that step S1 is obtained is cooled to into 43 DEG C, Icaridin, rutin, citronellol is added, stirring is equal
It is even, obtain solution B；
S3：The solution B that step S2 is obtained is down to into 30 DEG C, carbamide peroxide is added, is stirred, then buffered using pH
Agent bigcatkin willow acid for adjusting pH is obtained final product to 7.5.
Embodiment 2
A kind of safety and environmental protection mosquito-driving liquid, by following mass fraction into being grouped into：Icaridin 5%, shitosan 8%, wood
Quality sodium sulfonate 7%, pH buffer salicylic acid 0.5%, rutin 1%, citronellol 0.5%, carbamide peroxide 2%, ethanol
11% and water 65%.
The preparation method of described safety and environmental protection mosquito-driving liquid is similar to Example 1.
Embodiment 3
A kind of safety and environmental protection mosquito-driving liquid, by following mass fraction into being grouped into：Icaridin 4%, shitosan 12%, wood
Quality sodium sulfonate 5%, pH buffer sodium salicylate 1.5%, rutin 0.5%, citronellol 1%, carbamide peroxide 1%, ethanol
15% and water 60%.
The preparation method of described safety and environmental protection mosquito-driving liquid is similar to Example 1.
Comparative example 1
A kind of safety and environmental protection mosquito-driving liquid, by following mass fraction into being grouped into：Icaridin 4.5%, shitosan 10%,
Sodium lignin sulfonate 7.5%, pH buffer salicylic acid 1%, rutin 0.7%, citronellol 0.8%, ethanol 13% and water
62.5%.
It is without carbamide peroxide, the content of increase sodium lignin sulfonate with the difference of embodiment 1.
The preparation method of described safety and environmental protection mosquito-driving liquid is similar to Example 1.
The mosquito repellent of test example 1 is tested
Subjects：Embodiment 1-3 and safety and environmental protection mosquito-driving liquid obtained in comparative example 1.
Test method：Take mosquito-driving liquid 3ml, be well mixed with 1g starch, encased using cotton, be suspended on 60cm × 45cm ×
The central point of the mosquito cage of 45cm, is put into 100 female mosquitos, observes the quantity in different distance mosquito, and count first mosquito
Now the time (stopping more than 5 seconds) of cotton bag, anyhow there are 10 thick lines in direction to mosquito cage, there is provided mosquito foothold, mosquito is each
Hour changes a collection of, and concrete outcome is as shown in table 1 below, table 2, table 3.
Table 1 be put into 10 minutes after mosquito repellent data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| In 15cm | 0 | 0 | 0 | 0 |
| Apart from 15-22cm | 3 | 5 | 6 | 10 |
| Beyond 22cm | 97 | 95 | 94 | 90 |
Table 2 be put into 3 hours after mosquito repellent data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| In 15cm | 0 | 0 | 0 | 9 |
| Apart from 15-22cm | 6 | 9 | 10 | 25 |
| Beyond 22cm | 93 | 91 | 90 | 66 |
Table 3 be put into 12 hours after mosquito repellent data
As can be seen that the repelling effect of embodiment of the present invention 1-3 can be reached more than 12 hours from table 1, table 2 and table 3,
Illustrate that instant component cooperates and be effectively increased the repelling effect of Icaridin, be allowed to just to be reached under low concentration
To preferable repelling effect, and simply a kind of helper component is changed in comparative example 1, effect just there occurs change, more illustrate
The compatibility of the present invention, and it can also be seen that the cotton after 10 hours of mosquito-driving liquid obtained in embodiment of the present invention 1-3 from table 3
Cloth wraps just first mosquito of appearance, illustrates that the mosquito-driving liquid repelling effect duration disclosed by the invention is long.
The BA of test example 2
Subjects：Safety and environmental protection mosquito-driving liquid obtained in embodiment 1-3.
Bacterial classification：Staphylococcus aureus, Escherichia coli.
Test method：The mosquito-driving liquid of 1ml is mixed with the water of 100ml, is stirred, be then mixed and made into agar with agar
Culture medium, staphylococcus aureus and Escherichia coli are seeded in respectively on two culture mediums, are put in 37 DEG C of constant temperature incubators
Row culture 10 hours, observes colony counts, calculates sterilizing rate, control group is arranged, without mosquito-driving liquid, 1- sterilizing rates=clump count
Amount/control group colony counts × 100%.
Concrete outcome is as shown in table 4.
The sterilizing rate of table 4
| Product | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Staphylococcus aureus sterilizing rate | 92.1% | 91.0% | 91.2% |
| Escherichia coli sterilizing rate | 100% | 100% | 100% |
As can be seen from Table 4, mosquito-driving liquid disclosed by the invention has good bactericidal effect, wherein Staphylococcus aureus
Bacterium sterilizing rate has reached more than 90%, and Escherichia coli sterilizing rate has reached 100%.
Claims (5)
1. a kind of safety and environmental protection mosquito-driving liquid, it is characterised in that it is main by following mass fraction into being grouped into：Icaridin 4-
5%th, shitosan 8-12%, sodium lignin sulfonate 5-7%, pH buffer 0.5-1.5%, rutin 0.5-1%, citronellol 0.5-
1%th, carbamide peroxide 1-2%, ethanol 11-15% and water 50-75%.
2. safety and environmental protection mosquito-driving liquid according to claim 1, it is characterised in that by following mass fraction into being grouped into：
Icaridin 4.5%, shitosan 10%, sodium lignin sulfonate 6%, pH buffer 1%, rutin 0.7%, citronellol 0.8%,
Carbamide peroxide 1.5%, ethanol 13% and water 62.5%.
3. safety and environmental protection mosquito-driving liquid according to claim 1 and 2, it is characterised in that described pH buffer is salicylic acid
Or sodium salicylate.
4. safety and environmental protection mosquito-driving liquid according to claim 3, it is characterised in that described pH buffer is salicylic acid.
5. the preparation method of the safety and environmental protection mosquito-driving liquid according to any one of claim 1-4, it is characterised in that step is,
S1：After water and ethanol are sufficiently mixed, shitosan and sodium lignin sulfonate are added, are heated to 65-75 DEG C, stirred,
Obtain mixed liquor A；
S2：The mixed liquor A that step S1 is obtained is cooled to into 40-45 DEG C, Icaridin, rutin, citronellol is added, stirring is equal
It is even, obtain solution B；
S3：The solution B that step S2 is obtained is down to into 25-35 DEG C, carbamide peroxide is added, is stirred, then buffered using pH
Agent adjusts pH to 7.0-8.0, obtains final product.
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Applications Claiming Priority (1)
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| CN106614671B CN106614671B (en) | 2019-08-23 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108967434A (en) * | 2018-10-24 | 2018-12-11 | 常州宁录生物科技有限公司 | A kind of highly efficiency compositional mosquito repellent liquid |
| CN116058369A (en) * | 2022-01-19 | 2023-05-05 | 江苏省疾病预防控制中心(江苏省公共卫生研究院) | Skin disinfection mosquito repellent and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1738745A1 (en) * | 2005-06-27 | 2007-01-03 | Beiersdorf AG | Emulsion with insect repellents |
| CN101690502A (en) * | 2009-10-27 | 2010-04-07 | 浙江大学 | Application of torreya essential oil in mosquito repellent |
| CN101786969A (en) * | 2010-01-29 | 2010-07-28 | 河北工业大学 | Method of joint production of urea hydrogen peroxide and sodium percarbonate |
| CN102266270A (en) * | 2010-06-04 | 2011-12-07 | 江苏七洲绿色化工股份有限公司 | Mosquito repelling agent |
| CN104027255A (en) * | 2014-06-20 | 2014-09-10 | 广州立白企业集团有限公司 | Water-based insect expelling aerosol composition |
| CN104705351A (en) * | 2014-05-22 | 2015-06-17 | 宁波职业技术学院 | Mosquito-expelling agent |
| CN105146982A (en) * | 2015-09-17 | 2015-12-16 | 江苏堂皇集团有限公司 | Mosquito-repelling quilt |
| CN106137780A (en) * | 2016-08-24 | 2016-11-23 | 广州睿森生物科技有限公司 | A kind of microcapsule containing dimethyl phthalate, mosquito-repellent water and preparation method thereof |
| CN106172520A (en) * | 2016-07-31 | 2016-12-07 | 黄劼 | Mosquito-repellent water |
-
2016
- 2016-12-28 CN CN201611237745.5A patent/CN106614671B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1738745A1 (en) * | 2005-06-27 | 2007-01-03 | Beiersdorf AG | Emulsion with insect repellents |
| CN101690502A (en) * | 2009-10-27 | 2010-04-07 | 浙江大学 | Application of torreya essential oil in mosquito repellent |
| CN101786969A (en) * | 2010-01-29 | 2010-07-28 | 河北工业大学 | Method of joint production of urea hydrogen peroxide and sodium percarbonate |
| CN102266270A (en) * | 2010-06-04 | 2011-12-07 | 江苏七洲绿色化工股份有限公司 | Mosquito repelling agent |
| CN104705351A (en) * | 2014-05-22 | 2015-06-17 | 宁波职业技术学院 | Mosquito-expelling agent |
| CN104027255A (en) * | 2014-06-20 | 2014-09-10 | 广州立白企业集团有限公司 | Water-based insect expelling aerosol composition |
| CN105146982A (en) * | 2015-09-17 | 2015-12-16 | 江苏堂皇集团有限公司 | Mosquito-repelling quilt |
| CN106172520A (en) * | 2016-07-31 | 2016-12-07 | 黄劼 | Mosquito-repellent water |
| CN106137780A (en) * | 2016-08-24 | 2016-11-23 | 广州睿森生物科技有限公司 | A kind of microcapsule containing dimethyl phthalate, mosquito-repellent water and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108967434A (en) * | 2018-10-24 | 2018-12-11 | 常州宁录生物科技有限公司 | A kind of highly efficiency compositional mosquito repellent liquid |
| CN116058369A (en) * | 2022-01-19 | 2023-05-05 | 江苏省疾病预防控制中心(江苏省公共卫生研究院) | Skin disinfection mosquito repellent and preparation method thereof |
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| Publication number | Publication date |
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| CN106614671B (en) | 2019-08-23 |
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