CN104027255A - Water-based insect expelling aerosol composition - Google Patents
Water-based insect expelling aerosol composition Download PDFInfo
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Abstract
The invention discloses a water-based insect expelling aerosol composition which comprises the following components in percentage by weight: 0.2%-20% of insect expelling active component, 0.01%-5% of phosphate surface active agent, 0.003%-5.5% of pH regulating agent, 5%-60% of ethanol, 30%-80% of deionized water and 5%-30% of propelling agent, wherein the phosphate surface active agent is phosphomonoester or phosphodiester or a mixture of the phosphomonoester and the phosphodiester, and the phosphomonoester or the phosphodiester or the mixture of the phosphomonoester and the phosphodiester is in a chemical structure which contains more than 12 carbon atoms; the pH range of the water-based insect expelling aerosol composition is 6-8. The water-based insect expelling aerosol composition disclosed by the invention can effectively prevent the mosquito bite. According to the water-based insect expelling aerosol composition, the pH value of an aerosol content system is neutral, so that the degradation of active component and the corrosion to a tank body can be well prevented.
Description
Technical field
The invention belongs to anthelmintic aerosol products technical field, be specifically related to have a kind of water base anthelmintic aerosol combination and method that prevents water base anthelmintic aerosol container corrosion of anthelmintic activity.
Background technology
Anthelmintic aerosol products comprises insect aerosol and skin repellent aerosol.In insect aerosol product, formula is still taking oil base as main flow at present, major part is to dissolve active insecticidal components with alkane solvent, the type aerosol products cost is high, the solvent naphtha using mostly is non-renewable resources, and product is inflammable and explosive, poor stability, and volatile organic content (VOC) is higher in this type of oil base aerosol, use in the large pollution of domestic environment moderate stimulation not environmental protection by force.Water-base pesticide aerosols has the not available feature of many oil bases, comprises environmental protection, and cost is low, pollution-free, renewable etc., but because water base aerosol formulations causes that the risk that inner tank wall gets rusty is higher, to a certain degree limit its use and the occupation rate on existing market.
Chinese patent CN1513323 and patent CN101554175B all disclose water-base pesticide aerosols, and their common feature is to utilize the effect of emulsifying agent that the content of water-base pesticide aerosols is prepared into emulsion, and can add auxiliary antirust agent.The also main flow of existing water-base pesticide aerosols just of this type of formula system, but in this class formula system, still can use alkane solvent or kerosene, use the puzzlement that still can be subject to abnormal smells from the patient or oil stain in domestic environment.
Skin is actually rare on market at home with repellent aerosol, many products that are used for mosquito repellent are designed to water preparation or Emulsion more, in plastic containers, sell, for easy to use, large multi-product is designed to normal pressure spray type product, needs user to take a long time and smear when this series products use.Skin can the good feature of the atomizing effect of utilization own with the packaged form of repellent aerosol, spraying evenly, without smearing or dab, use lightly, adopt the packaged form of aerosol, good airproof performance, the risk that leakage can not occur, very convenient user goes out to carry.But skin is with generally all having high level water in repellent aerosol products formula, the container that aerosol uses is canister mostly, this makes the risk of corrosion tank body become large, inhalator jar major part is to be made up of zinc-plated tinplate, zinc-plated can also can carry out resin spraying so that Additional Protection to be provided in inner side, but these resin-coated uses there are certain requirements aerosol content tool, this content can not contain soluble resin coating maybe can destroy resin-coated raw material, but the effective ingredient that is applied to anthelmintic class all has certain dissolved destruction to resinous coat as dimethyl phthalate or Icaridin, using resinous coat tank just to limit to a great extent these anophelifuge effective ingredient is applied in aerosol products, other also has aluminum to make, but aluminium price is comparatively expensive.
For meeting the Anticorrosion Problems of water base aerosol, many antirust systems are worked out, in these systems, contain benzoate, borate, organic borate, molybdate, nitrite, morpholine etc., these antirust agent parts are to belong to dangerous type antirust agent, once underdosage, corrosion will be more serious.A part is not suitable for being applied in family product or skin product; The acid-base value that adds membership change system of part antirust agent, general system can be alkalescence, has promoted the degraded of many esters active component, thereby cannot reach guaranteeing the quality of long period.Much antirust agent is used in water base anthelmintic aerosol system and is identified simultaneously, and they all can not well stop the corrosion of zinc-plated inhalator jar or guaranteeing the quality of two-year effective ingredient.
Summary of the invention
For above-mentioned problems and shortcomings, the object of the present invention is to provide a kind of water base anthelmintic aerosol combination, said composition can effectively prevent mosquito bite, aerosol content system pH is neutral, can finely prevent the corrosion of active component degraded and tank body.
Another object of the present invention is to provide a kind of above-mentioned water base anthelmintic aerosol combination to prevent the method for aerosol container corrosion.
The object of the invention to solve the technical problems realizes by the following technical solutions.The water base anthelmintic aerosol combination of one proposing according to the present invention, the each component that comprises following percentage by weight:
Anthelmintic activity composition 0.2～20%;
Phosphoric acid ester surfactant 0.01～5%; Described phosphoric acid ester surfactant is in chemical constitution, to contain the phosphate monoester of 12 above structures of carbon or the mixture of phosphate diester or phosphate monoester and phosphate diester;
The pH scope of described water base anthelmintic aerosol combination is 6～8.
Described anthelmintic activity composition is the one of pyrethroid, skin repellant; Described pyrethroid is one or both in prallethrin, tetramethrin, Permethrin, d-phenothrin, d-phenothrin, cypermethrin, and this quasi-chrysanthemum ester is safe, all belongs to domestic environment and can use effective ingredient.
Described skin repellant is one or both of chemosynthesis repellant, natural plants repellent composition, wherein chemosynthesis repellant is any one of diethyltoluamide, dimethyl phthalate, Icaridin, natural plants repellent composition is p-menthyl-3,8-glycol, lemon eucalyptus oil, eucalyptus oil, citronella oil, Oleum Cinnamomi, Oleum Caryophylli, Indian oil of verbena, oil of rosemary, Oleum lavandula angustifolia two or more, above chemosynthesis repellent composition or natural plants repellent composition are the safety anophelifuge effective ingredient that can be used in skin, can effectively prevent mosquito bite.
Described water base anophelifuge aerosol combination preferably comprises weight 0.01～1% phosphoric acid ester surfactant; In described phosphoric acid ester surfactant and after be dissolvable in water in water.
Described phosphoric acid ester surfactant is selected from C12-13 alcohol phosphate ester, hexadecanyl phosphate, Phosphoric acid monohexadecyl ester, C22 alkyl phosphate, oleyl alcohol phosphate ester, two oleyl alcohol phosphate esters, dicetyl phosphate, dodecanol amidophosphoric acid ester, tetradecanol amidophosphoric acid ester, hexadecanol amidophosphoric acid ester, octadecanol amidophosphoric acid ester, oleth kind phosphate ester, spermol polyethers phosphate ester, glycerin polyether kind phosphate ester.Such surfactant materials all has good safety, all can directly contact skin, phosphoric acid ester surfactant can promote the solubilization of anthelmintic activity composition in aqueous based systems on the one hand, on the one hand due to its special bipolar structure, can make polarity hold more by force and be adsorbed on metallic tin or iron surface, there is chemisorbed, and after phosphate ester end neutralizes, this adsorption is stronger, other end long chain hydrocarbon groups can help this phosphoric acid ester material to form absorption bilayer, more than the carbon chain lengths of long chain hydrocarbon groups is more than or equal to 12 carbon length, this absorption bilayer can form complete and firm thin film, the corrosion that can well prevent inhalator jar occurs.
Described water base anthelmintic aerosol combination preferably comprises the pH adjusting agent of weight 0.003～1%.
Described pH adjusting agent is the one in monoethanolamine, diethanolamine, triethanolamine, sodium hydroxide, potassium hydroxide, aminomethyl propanol.
Described water base anthelmintic aerosol combination preferably comprises the propellant of weight 5～20%, and described propellant is the third butane mixture or dimethyl ether.Propellant content is less than 20%, can effectively reduce the release of VOC.
Another aspect of the present invention provides a kind of method that prevents water base anthelmintic aerosol container corrosion, and described method relates to be introduced above-mentioned water base anthelmintic aerosol combination of the present invention in described aerosol container, can well stop the corrosion of aerosol tank.
By technique scheme, advantage and beneficial effect that the present invention has are:
1) water base anthelmintic aerosol combination Environmental Safety of the present invention, easy to use, and anthelmintic aerosol uses safety non-pollution in domestic environment;
2) the present invention uses at skin surface, due to the uniqueness of aerosol packaging form, product utilizes the atomization dispersion effect that aerosol is good while use, use on skin without smearing or dab, to skin safe, aerosol products self seal is good, can prevent leakage, is convenient for carrying.
3) water base anthelmintic aerosol combination of the present invention can finely prevent the corrosion of tank body, and in said composition system, the antirust composition of phosphoric acid ester can well form firm thin film in metal surface, thereby prevents the corrosion to tank body.
Detailed description of the invention
By concrete embodiment, technical scheme of the present invention is further illustrated below, following examples only do not have restricted for the present invention is described.
embodiment 1
A kind of water base anthelmintic aerosol, wherein the percentage by weight of each component is as follows:
D-phenothrin 0.3%;
Permethrin 0.2%;
PPG-5 phosphate ester spermol polyethers-10 phosphoesterase 30 .01%;
Aminomethyl propanol 0.003%;
Ethanol 40%;
Deionized water 34.487%;
Dimethyl ether 25%.
Preparation method: under normal temperature condition, d-phenothrin, Permethrin, PPG-5 phosphate ester spermol polyethers-10 phosphate ester are added in stirred tank and stirred, then after adding ethanol to be uniformly mixed, slowly add deionized water, keep stirring, finally add aminomethyl propanol and add gross weight 2% ethanol, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then dimethyl ether is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 2
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
Prallethrin 0.1%;
Cypermethrin 0.1%;
Stearyl alcohol polyethers-2 phosphate ester 3.8%;
Oleth-5 phosphoesterase 30 .1%;
Triethanolamine 1%;
Ethanol 60%;
Deionized water 29.9%;
The third butane 5%.
Preparation method: under normal temperature condition, prallethrin, cypermethrin, stearyl alcohol polyethers-2 phosphate ester, oleth-5 phosphate ester, ethanol are added in stirred tank and stirred, to be mixed evenly after, slowly add deionized water, keep stirring, finally add triethanolamine and add gross weight 2% ethanol, mix homogeneously, makes medicinal liquid., described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 3
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
Tetramethrin 0.25%;
Dicetyl phosphate 0.5%;
Dodecanol amidophosphoric acid ester 0.01%;
Triethanolamine 0.25%;
Ethanol 5%;
Deionized water 80%;
The third butane 13.99%.
Preparation method: tetramethrin, dicetyl phosphate, dodecanol amidophosphoric acid ester, ethanol are added in stirred tank and stirred, then slowly add deionized water, keep stirring, finally add triethanolamine, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 4
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
D-phenothrin 0.4%;
Spermol polyethers-5 phosphoesterase 30 .3%;
Triethanolamine 0.25%;
Ethanol 5%;
Deionized water 79.8%;
The third butane 14.25%.
Preparation method: d-phenothrin, spermol polyethers-5 phosphate ester, ethanol are added in stirred tank and stirred, then slowly add deionized water, keep stirring, finally add triethanolamine, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 5
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
Diethyltoluamide 10%;
C12-13 alcohol phosphoesterase 30 .02%;
Triethanolamine 0.02%;
Ethanol 50%;
Deionized water 19.96%;
The third butane 20%.
Preparation method: diethyltoluamide, C12-13 alcohol phosphate ester, ethanol are added in stirred tank and stirred, then slowly add deionized water, keep stirring, finally add triethanolamine and add gross weight 2% ethanol, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 6
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
Dimethyl phthalate 20%;
Hexadecanol amidophosphoric acid ester 4.5%;
O-3-P 0.5%;
Triethanolamine 5.5%;
Ethanol 40%;
Deionized water 21.5%;
The third butane 8%.
Preparation method: dimethyl phthalate, hexadecanol amidophosphoric acid ester, ethanol are added in stirred tank and stirred, then slowly add deionized water, keep stirring, finally add triethanolamine to add gross weight 2% ethanol, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 7
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
To menthyl-3,8-glycol 4%;
Oleum Cinnamomi 0.5%;
Indian oil of verbena 0.6%;
Oil of rosemary 0.4%;
Glycerin polyether-26 phosphate ester 3%;
Sodium hydroxide 0.5%;
Ethanol 55%;
Deionized water 16%;
The third butane 20%.
Preparation method: will be to menthyl-3,8-glycol, Oleum Cinnamomi, Indian oil of verbena, oil of rosemary, glycerin polyether-26 phosphate ester, ethanol add in stirred tank and stir, then slowly add part deionized water, keep stirring, finally add sodium hydrate aqueous solution and add gross weight 2% ethanol, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then the third butane is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
embodiment 8
A kind of water base anthelmintic aerosol, wherein each weight percentages of components is:
Icaridin 15%;
Two oleyl alcohol phosphoesterase 30 .3%;
Triethanolamine 0.3%;
Ethanol 30%;
Deionized water 24.4%;
Dimethyl ether 30%.
Preparation method: Icaridin, two oleyl alcohol phosphate esters, ethanol are added in stirred tank and stirred, then slowly add part deionized water, keep stirring, finally add triethanolamine, mix homogeneously, makes medicinal liquid.Described medicinal liquid is poured in iron flask with filling machine according to conventional method, plug in valve, sealing, then dimethyl ether is filled with in iron flask with filling machine.Finally, use the water-bath leak detection machine test of hunting leak, and certified products are pressed to aerosol lid, enter case packing, obtain anthelmintic aerosol products.
effect test example
1, the heat of water base anthelmintic aerosol combination storage effect
Above-described embodiment 1-8 component is packed into in zinc-plated inhalator jar, and a DEG C explosion-proof baking oven interior-heat stores up eight weeks in (50 ± 2), observe the corrosion condition of atomize variation and inhalator jar every surrounding can opening, weight-loss ratio and the pH value of test composition simultaneously, test result is as following table 1.
The heat storage effect of the water base anthelmintic aerosol combination of table 1 embodiment 1-8
From table 1, result can be found out, in above-described embodiment, anthelmintic composition all has good anticorrosion ability, and in whole storage process the stable in properties of compositions, there is good using value.
2, the anthelminthic effect of water base anthelmintic aerosol combination
According to GB/T 13917.2-2009, the killing effect of embodiment 1-4 is tested, carried out evaluating drug effect according to indoor KT50,24h mortality rate, in triplicate, the results are shown in Table 2.KT50 is KT, refers under rated condition, 50% examination worm is gone down (facing upward down) required time.
According to GB/T 13917.9-2009, the repellent effect of embodiment 5-8 is tested, according to effective protecting time, drug effect is evaluated, the results are shown in Table 3; Before test, first anthelmintic aerosol is done and process: before test, sample is shaken up; slowly anthelmintic aerosol is sprayed into the about 20mL of small beaker with the shower nozzle of carrying pipe; return to room temperature placement 2h left and right to propellant and discharge (without obvious bubble) completely, get processed sample and carry out effective protecting time test.
Table 2 embodiment 1-4 efficacy testing result
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| KT50 (mosquito, min) | ≤2 | ≤2 | ≤2 | ≤2 |
| Mortality rate (mosquito, 24h, %) | 100 | 100 | 100 | 100 |
From table 2, data can be found out, the parasite killing drug effect of the anthelmintic aerosol of above-described embodiment 1-4 all can reach A grade standard, has good insecticidal effect.
Table 3 embodiment 5-8 efficacy testing result
| ? | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 |
| Effective protecting time (h) | 5 | 8 | 4 | 8 |
From table 3, data are known, and the anthelmintic aerosol of above-described embodiment 5-8 is surveyed repellent effect and all reached the above standard of B level, uses and can finely prevent mosquito bite at skin surface.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, do not depart from technical solution of the present invention content therefore every, any simple modification, equivalent variations and the modification above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.
Claims (9)
1. a water base anthelmintic aerosol combination, is characterized in that each component that it comprises following percentage by weight:
Anthelmintic activity composition 0.2～20%;
Phosphoric acid ester surfactant 0.01～5%; Described phosphoric acid ester surfactant is in chemical constitution, to contain the phosphate monoester of 12 above structures of carbon or the mixture of phosphate diester or phosphate monoester and phosphate diester;
The pH scope of described water base anthelmintic aerosol combination is 6～8.
2. water base anthelmintic aerosol combination according to claim 1, is characterized in that: described anthelmintic activity composition is the one of pyrethroid, skin repellant.
3. water base anthelmintic aerosol combination according to claim 2, is characterized in that: described pyrethroid is one or both in prallethrin, tetramethrin, Permethrin, d-phenothrin, d-phenothrin, cypermethrin; Described skin repellant is one or both of chemosynthesis repellant, natural plants repellent composition.
4. water base anthelmintic aerosol combination according to claim 3, is characterized in that: described chemosynthesis repellant is any one of diethyltoluamide, dimethyl phthalate, Icaridin; Described natural plants repellent composition is p-menthyl-3, any two or more the mixture in 8-glycol, lemon eucalyptus oil, eucalyptus oil, citronella oil, Oleum Cinnamomi, Oleum Caryophylli, Indian oil of verbena, oil of rosemary, Oleum lavandula angustifolia.
5. water base anthelmintic aerosol combination according to claim 1, is characterized in that: described compositions comprises 0.01～1% phosphoric acid ester surfactant; In described phosphoric acid ester surfactant and after be dissolvable in water in water.
6. water base anthelmintic aerosol combination according to claim 1 or 5, it is characterized in that: described phosphoric acid ester surfactant is selected from C12-13 alcohol phosphate ester, hexadecanyl phosphate, Phosphoric acid monohexadecyl ester, C22 alkyl phosphate, oleyl alcohol phosphate ester, two oleyl alcohol phosphate esters, dicetyl phosphate, dodecanol amidophosphoric acid ester, tetradecanol amidophosphoric acid ester, hexadecanol amidophosphoric acid ester, octadecanol amidophosphoric acid ester, oleth kind phosphate ester, spermol polyethers phosphate ester, any one or more mixture in glycerin polyether kind phosphate ester.
7. water base anthelmintic aerosol combination according to claim 1, it is characterized in that: described compositions comprises 0.003～1% pH adjusting agent, described pH adjusting agent is any in monoethanolamine, diethanolamine, triethanolamine, sodium hydroxide, potassium hydroxide or aminomethyl propanol.
8. water base anthelmintic aerosol combination according to claim 1, is characterized in that: described compositions comprises 5～20% propellant, and described propellant is the third butane mixture or dimethyl ether.
9. a method that prevents water base anthelmintic aerosol container corrosion, is characterized in that: the method right to use requires the water base anthelmintic aerosol combination described in any one in 1-8, and is introduced in described aerosol container.
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| CN112442779A (en) * | 2020-11-12 | 2021-03-05 | 汪爱国 | Stretch-proof and fracture-resistant blended fabric and preparation method thereof |
| CN115530178A (en) * | 2022-10-31 | 2022-12-30 | 原上科技(河南)有限公司 | Composition for repelling ticks and killing ticks as well as preparation method and application of composition |
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| CN104027255B (en) | 2018-02-23 |
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