CN105999342A - Water-based air freshening aerosol and preparation method thereof - Google Patents
Water-based air freshening aerosol and preparation method thereof Download PDFInfo
- Publication number
- CN105999342A CN105999342A CN201610479680.9A CN201610479680A CN105999342A CN 105999342 A CN105999342 A CN 105999342A CN 201610479680 A CN201610479680 A CN 201610479680A CN 105999342 A CN105999342 A CN 105999342A
- Authority
- CN
- China
- Prior art keywords
- aerosol
- pure
- aqueous
- based air
- propellant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a water-based air freshening aerosol and a preparation method thereof, and belongs to the technical field of air fresheners. The aerosol is prepared from, by weight, 0.1%-0.5% of menthol, 0.1%-0.5% of thymol, 1.0%-1.5% of hydrogenated castor oil, 1.0%-1.5% of cosolvent, 0.5%-0.8% of essence, 0.2%-0.5% of corrosion inhibitor, 20%-25% of propellant and the balance deionized water. The preparation method of the water-based air freshening aerosol comprises the steps that menthol, thymol and essence are added into the cosolvent to be dissolved, the hydrogenated castor oil is added, all the materials are mixed to be uniform, and a transparent emulsion is obtained; the corrosion inhibitor is added into the deionized water and mixed to be uniform, and a transparent solution is obtained; the prepared transparent emulsion and the prepared transparent solution are mixed, the propellant is added, and all the materials are prepared into the aerosol. The aerosol is good in use effect, foam cannot be generated when the aerosol is used, the usage environment is more refreshing, and the sterilizing and acarus killing effects are achieved.
Description
Technical field
The invention belongs to air freshener technical field, be specifically related to a kind of pure and fresh aerosol of aqueous-based air and preparation method thereof, particularly relate to a kind of pure and fresh aerosol of aqueous-based air with bactericidal effect and preparation method thereof.
Background technology
Empty freshener is commonly called as again environment perfume, uses air freshener can be effectively improved air quality.Typically mainly there are solid, liquid, aerial fog type three kinds, presently commercially available air freshener is of a great variety, and great majority are all with traditional ether, essence as raw material, utilize the low boiling of ether, volatile characteristic, essence is driven to fill the air in atmosphere, to hide the unpleasant thing in air.Though this freshener can effective covering smell, but can not really improve air quality, because its composition can not resolving harmful gas, it is difficult to be really achieved the purpose of fresh air.And after human body sucks the volatility ether with certain fragrance gas, easily produce calmness sense.If life-time service can cause chronic poisoning.In order to solve the problems referred to above, having a lot of freshener with pure natural plant extract as raw material at present, but this kind of additive still suffers from fresh air DeGrain, effective time is shorter waits deficiency.
As the Chinese patent of Application No. 201110462819.6 discloses a kind of air freshener, the composition of following weight percents mix and form: Mentholum 0.3-0.4%, Borneolum Syntheticum 0.2-0.3%, ethanol 10-20% and Fructus Citri Limoniae essence 0.5-0.7%；Surplus is eucalyptus leaves plant extraction liquid.Although this freshener has the effect of certain fresh air, but its effectiveness time and bactericidal properties are more weak, still need to be improved further.
As the Chinese patent of Application No. 201110417810.3 discloses a kind of air freshener, it is made up of super absorbent resin, coloring agent, essence, surfactant, ethylene glycol, white carbon and Herba Menthae.But this freshener is because containing super absorbent resin in formula, can absorb the moisture in air in a large number and cause air to be dried in actual applications, and the effect of fresh air is poor.
The deficiencies in the prior art the most how are overcome to become the technical barrier that existing field is urgently to be resolved hurrily.
Summary of the invention
In order to solve upper problem, an object of the present invention is to provide a kind of pure and fresh aerosol of aqueous-based air, this aerosol has bactericidal effect and has bigger ejection pressure and emission rate, the most also has the effect of humidification, and each raw material all uses environment amenable material；The two of the purpose of the present invention there is provided the preparation method of aforementioned aerosol, and described technical scheme is as follows:
On the one hand, embodiments provide a kind of pure and fresh aerosol of aqueous-based air, being made up of the raw material of following weight percent content: Mentholum 0.1%-0.5%, thymol 0.1%-0.5%, castor oil hydrogenated 1.0%-1.5%, cosolvent 1.0%-1.5%, essence 0.5%-0.8%, corrosion inhibiter 0.2%-0.5% and propellant 20%-25%, surplus is deionized water.
Wherein, thymol and Mentholum are respectively provided with bactericidal effect and all have pleasant aromatic odor；Thymol is major antibacterial component, and it has the strongest acaricidal action, 1% solution mortality rate half an hour 100%, and the solution 24h of 0.03% kills 100%；Thymol 0.05%-0.2% solution also has and stronger kills protoscolex effect, can reach 100% effect killing protoscolex in 5-10min, and effect is the most reliable, and toxicity is little；Thymol and Mentholum synergism have preferably sterilization and insecticidal action；Meanwhile, Mentholum and essence have the effect providing novel aroma；Castor oil hydrogenated is emulsifying agent, makes effective ingredient dispersion more uniform, and effect is more lasting, and it environmentally friendly also will not produce foam；Cosolvent is for increasing the dissolubility of effective ingredient；Power when propellant is for providing spraying, makes effective ingredient atomization uniformly, more disperses；Corrosion inhibiter is used for anticorrosion；Deionized water not only can also have humidification as solvent, primary solvent in the present invention is water rather than the organic solvent such as propane of the prior art or ethanol, decreases the pollution to environment, improves air quality, reduce the effects such as air-borne dust, it is also possible to make delicate fragrance more lasting.
Preferably, the pure and fresh aerosol of aqueous-based air that the embodiment of the present invention provides, being made up of the raw material of following weight percent content: Mentholum 0.2%, thymol 0.2%, castor oil hydrogenated 1.0%, cosolvent 1.0%, essence 0.6%, corrosion inhibiter 0.4% and propellant 20%, surplus is deionized water.
Preferably, one or more in ethanol, propandiol butyl ether, dipropylene glycol methyl ether and hexylene glycol etc. of the cosolvent that the embodiment of the present invention provides.
It is highly preferred that the cosolvent that the embodiment of the present invention provides is ethanol；Specifically, ethanol can use the medical ethanol of 95%.
Wherein, one or more in ring ethylamine, sodium benzoate, sodium nitrite, ammonium benzoate and sodium molybdate etc. of the corrosion inhibiter that the embodiment of the present invention provides.
Wherein, one or more in dimethyl ether, propane, normal butane and iso-butane etc. of the propellant that the embodiment of the present invention provides.
Preferably, the propellant that the embodiment of the present invention provides is dimethyl ether；Dimethyl ether is the polar compound that a kind of hydrophilic is extremely strong, can reduce product flame intensity with water excellent dissolution, reduce combustibility；In addition dimethyl ether destruction lossless to ozone layer, can degrade under photochemical effect, water environment not exist any hazardness.
The embodiment of the present invention make spray have bigger ejection pressure and emission rate by control castor oil hydrogenated, propellant and the content of water and ratio.
Preferably, the embodiment of the present invention provide castor oil hydrogenated be numbered AA220(hydrogenation value index).
On the other hand, the embodiment of the present invention additionally provides the preparation method of the pure and fresh aerosol of aforementioned aqueous-based air, and the method comprises the following steps:
(1) Mentholum, thymol and essence addition cosolvent will dissolve by proportioning, then add castor oil hydrogenated by proportioning, after mixing, obtain transparency emulsion.
(2) by proportioning, corrosion inhibiter is joined in deionized water, after mixing, obtain clear solution.
(3) after the clear solution that transparency emulsion step (1) obtained by proportioning obtains with step (2) mixes, then aerosol is made by proportioning addition propellant.
Wherein, step (3) specifically includes: load in inhalator jar after the clear solution mixing that transparency emulsion step (1) obtained by proportioning and step (2) obtain, and after sealed cans, then makes aerosol by proportioning addition propellant.
Specifically, the method comprises the following steps:
(1) Mentholum, thymol and essence are added dissolving in cosolvent, add castor oil hydrogenated, after mixing, obtain transparency emulsion；Wherein, the consumption of Mentholum, thymol, essence, castor oil hydrogenated and cosolvent is respectively 0.1%-0.5%, 0.1%-0.5%, 0.5%-0.8%, 1.0%-1.5% and 1.0%-1.5% of aerosol gross mass；Wherein, one or more in ethanol, propandiol butyl ether, dipropylene glycol methyl ether and hexylene glycol etc. of cosolvent, preferably ethanol.
(2) corrosion inhibiter is joined in deionized water, after mixing, obtain clear solution；Wherein, the consumption of corrosion inhibiter and water is 0.2%-0.5% and 60%-80% of aerosol gross mass；Wherein, one or more in ring ethylamine, sodium benzoate, sodium nitrite, ammonium benzoate and sodium molybdate etc. of corrosion inhibiter.
(3) loading in inhalator jar after the clear solution mixing that transparency emulsion step (1) obtained and step (2) obtain, after aerosol valve sealed cans, the propellant adding aerosol gross mass 20%-25% makes aerosol；Wherein, one or more in dimethyl ether, propane, normal butane and iso-butane etc. of propellant, preferably dimethyl ether.
Wherein, in above-mentioned preparation process, the percentage composition sum of each material gathers together enough 100%.
Embodiments providing a kind of pure and fresh aerosol of aqueous-based air and preparation method thereof, this aqueous-based air pure and fresh aerosol using effect is good, is not only better than using the product of common emulsifying agent at emission rate, pressure (safety index) aspect.And due to the emulsifying agent castor oil hydrogenated of the effective ingredient contained and environmental protection, environmentally friendly, foam will not be produced during use and make use environment salubriouser, more have effect of disinfecting mite-removing concurrently.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below the present invention is described in further detail.
Embodiment 1
Embodiment 1 provides a kind of pure and fresh aerosol of aqueous-based air and preparation method thereof, and the method comprises the following steps:
(1) Mentholum 2g, thymol 2g and essence 6g are added in the medical ethanol of 10g95% and dissolve, add 10g castor oil hydrogenated (being numbered AA220), after mixing, obtain transparency emulsion.
(2) 4g sodium benzoate is joined in 770g deionized water, after mixing, obtain clear solution.
(3) load in inhalator jar after the clear solution mixing that transparency emulsion step (1) obtained and step (2) obtain, after aerosol valve sealed cans, add 200g dimethyl ether and make aerosol.
Embodiment 2
Embodiment 2 provides another kind of pure and fresh aerosol of aqueous-based air and preparation method thereof, and the method comprises the following steps:
(1) Mentholum 2g, thymol 2g and essence 6g are added in the medical ethanol of 6g95% and the mixed solvent of 4g propandiol butyl ether composition and dissolve, add 10g castor oil hydrogenated (being numbered AA220), after mixing, obtain transparency emulsion.
(2) 1g sodium benzoate and 3g sodium nitrite are added sequentially in 770g deionized water, after mixing, obtain clear solution.
(3) load in inhalator jar after the clear solution mixing that transparency emulsion step (1) obtained and step (2) obtain, after aerosol valve sealed cans, add 200g dimethyl ether and make aerosol.
Embodiment 3-6
Embodiment 3-6 is identical with the preparation method of embodiment 1, and difference is: raw material and the proportioning of use are had any different, and its composition is as shown in table 1:
Table 1
Wherein, in upper table, in each component, deionized water gathers together enough 1000g.
Comparative example
By the aerosol obtained by embodiment 2 and the existing air freshener containing common emulsifying agent (commodity conventional on market, formula composition (mass percentage content) is: essence 0.6%, Isopar M 7%, span-80 0.5%, sodium nitrite 0.8%, deionized water 61.1%, propane 6%, iso-butane 24%) detect by QB2548 2002 requirement, result is as shown in table 2:
Table 2
As can be seen from Table 2, all technical of the pure and fresh aerosol of aqueous-based air that the present invention provides all meets the technology requirement of national standard, is not only better than using the product of common emulsifying agent at emission rate, pressure (safety index) aspect.And due to the effective ingredient contained and the emulsifying agent of environmental protection, environmentally friendly, foam will not be produced during use and make use environment salubriouser, more have effect of disinfecting mite-removing concurrently.
Additionally, the aerosol obtaining embodiment 1 and 3-6 is detected by QB2548 2002 requirement, and its result is similar with table 2, has bigger ejection pressure and emission rate relative to existing air freshener, also having mite killing and bactericidal effect, the present embodiment omits detailed data.
Meanwhile, embodiment 1,2 and normal air freshener are carried out subjective appreciation experiment (olfactory sensation and lasting using effect), takes 60 volunteers, it is randomly divided into 3 groups, often organize 20 people, it is ensured that often in group, sex ratio and age distribution do not have significant difference, coincidence statistics standard.Its result is: the subjective appreciation index of the aerosol that embodiment 1,2 provides is slightly above normal air freshener, it is characterized in: the delicate fragrance of the aerosol of the present invention is lasting, its perfume (or spice) is slightly better than normal air freshener, and (essence of the aerosol of the present invention more disperses, formula is reasonable, organic solvent usage amount is few), and bottom note is better than normal air freshener (normal air freshener continues for some time the fragrance of rear essence and cannot cover the abnormal smells from the patient of organic solvent etc. and abnormal flavour occur), the aerosol that i.e. present invention provides has more preferable air freshening effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (9)
1. the pure and fresh aerosol of aqueous-based air, it is characterized in that, being made up of the raw material of following weight percent content: Mentholum 0.1%-0.5%, thymol 0.1%-0.5%, castor oil hydrogenated 1.0%-1.5%, cosolvent 1.0%-1.5%, essence 0.5%-0.8%, corrosion inhibiter 0.2%-0.5% and propellant 20%-25%, surplus is deionized water.
The pure and fresh aerosol of aqueous-based air the most according to claim 1, it is characterized in that, being made up of the raw material of following weight percent content: Mentholum 0.2%, thymol 0.2%, castor oil hydrogenated 1.0%, cosolvent 1.0%, essence 0.6%, corrosion inhibiter 0.4% and propellant 20%, surplus is deionized water.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that one or more in ethanol, propandiol butyl ether, dipropylene glycol methyl ether and hexylene glycol of described cosolvent.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that described cosolvent is ethanol.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that one or more in ring ethylamine, sodium benzoate, sodium nitrite, ammonium benzoate and sodium molybdate of described corrosion inhibiter.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that one or more in dimethyl ether, propane, normal butane and iso-butane of described propellant.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that described propellant is dimethyl ether.
The pure and fresh aerosol of aqueous-based air the most according to claim 1 and 2, it is characterised in that described castor oil hydrogenated be numbered AA220.
9. the preparation method of the pure and fresh aerosol of aqueous-based air as described in any one of claim 1-8, it is characterised in that said method comprising the steps of:
(1) Mentholum, thymol and essence addition cosolvent will dissolve by proportioning, then add castor oil hydrogenated by proportioning, after mixing, obtain transparency emulsion；
(2) by proportioning, corrosion inhibiter is joined in deionized water, after mixing, obtain clear solution；
(3) after the clear solution that transparency emulsion step (1) obtained by proportioning obtains with step (2) mixes, then aerosol is made by proportioning addition propellant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610479680.9A CN105999342A (en) | 2016-06-28 | 2016-06-28 | Water-based air freshening aerosol and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610479680.9A CN105999342A (en) | 2016-06-28 | 2016-06-28 | Water-based air freshening aerosol and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105999342A true CN105999342A (en) | 2016-10-12 |
Family
ID=57084338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610479680.9A Pending CN105999342A (en) | 2016-06-28 | 2016-06-28 | Water-based air freshening aerosol and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105999342A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107008134A (en) * | 2017-04-07 | 2017-08-04 | 南京列格环保工程有限公司 | A kind of indoor air purification agent and preparation method thereof |
| CN107281524A (en) * | 2017-05-18 | 2017-10-24 | 佛山市顺德区香江精细化工实业有限公司 | A kind of butt freshener and preparation method thereof |
| CN107875051A (en) * | 2017-11-08 | 2018-04-06 | 成都彩虹电器（集团）中南有限公司 | A kind of pet nursing agent and preparation method thereof |
| CN107873701A (en) * | 2017-11-08 | 2018-04-06 | 成都彩虹电器（集团）中南有限公司 | A kind of aerosol for expelling parasite, sterilizing and mite killing and preparation method thereof |
| CN109679503A (en) * | 2018-12-28 | 2019-04-26 | 中山市天图精细化工有限公司 | Pet cake solidifies aerosol |
| CN111296495A (en) * | 2020-03-24 | 2020-06-19 | 广州市华晟健康产业有限公司 | Portable degerming and mite-killing spray applied to vehicles |
| CN111296438A (en) * | 2020-03-24 | 2020-06-19 | 广州市华晟健康产业有限公司 | Spray for removing bacteria and mites for household use |
| CN111420102A (en) * | 2019-01-10 | 2020-07-17 | 广东阜和实业有限公司 | Binary packaged non-combustible air freshener and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102973974A (en) * | 2012-12-31 | 2013-03-20 | 青岛信锐德科技有限公司 | Air freshening preparation, and preparation method and application thereof |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
| CN105214120A (en) * | 2015-11-03 | 2016-01-06 | 重庆市涣颜环保科技股份有限公司 | One Plant Extracts air purifying preparation and preparation method thereof |
-
2016
- 2016-06-28 CN CN201610479680.9A patent/CN105999342A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102973974A (en) * | 2012-12-31 | 2013-03-20 | 青岛信锐德科技有限公司 | Air freshening preparation, and preparation method and application thereof |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
| CN105214120A (en) * | 2015-11-03 | 2016-01-06 | 重庆市涣颜环保科技股份有限公司 | One Plant Extracts air purifying preparation and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107008134A (en) * | 2017-04-07 | 2017-08-04 | 南京列格环保工程有限公司 | A kind of indoor air purification agent and preparation method thereof |
| CN107281524A (en) * | 2017-05-18 | 2017-10-24 | 佛山市顺德区香江精细化工实业有限公司 | A kind of butt freshener and preparation method thereof |
| CN107875051A (en) * | 2017-11-08 | 2018-04-06 | 成都彩虹电器（集团）中南有限公司 | A kind of pet nursing agent and preparation method thereof |
| CN107873701A (en) * | 2017-11-08 | 2018-04-06 | 成都彩虹电器（集团）中南有限公司 | A kind of aerosol for expelling parasite, sterilizing and mite killing and preparation method thereof |
| CN109679503A (en) * | 2018-12-28 | 2019-04-26 | 中山市天图精细化工有限公司 | Pet cake solidifies aerosol |
| CN109679503B (en) * | 2018-12-28 | 2021-01-08 | 中山市天图精细化工有限公司 | Pet cake curing aerosol |
| CN111420102A (en) * | 2019-01-10 | 2020-07-17 | 广东阜和实业有限公司 | Binary packaged non-combustible air freshener and preparation method thereof |
| CN111296495A (en) * | 2020-03-24 | 2020-06-19 | 广州市华晟健康产业有限公司 | Portable degerming and mite-killing spray applied to vehicles |
| CN111296438A (en) * | 2020-03-24 | 2020-06-19 | 广州市华晟健康产业有限公司 | Spray for removing bacteria and mites for household use |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105999342A (en) | Water-based air freshening aerosol and preparation method thereof | |
| CA2942484C (en) | Persistent sanitizer composition | |
| CN108522554A (en) | A kind of compound and preparation method thereof to eliminate the unusual smell except formaldehyde plant extraction liquid | |
| CN103732225A (en) | Antimicrobial compositions | |
| CN101711883A (en) | Aerosol air purification freshener and preparation method thereof | |
| CN106310906A (en) | Indoor air deodorant having sterilizing function and preparation method thereof | |
| CN108324983A (en) | A kind of air freshener and preparation method thereof | |
| CN106729860A (en) | A kind of environment-friendly high-efficiency deodorant and preparation method thereof | |
| CN111318152A (en) | Plant extract deodorant | |
| CN105854056A (en) | Air freshener with sterilization function, and preparation method thereof | |
| CN107519517A (en) | A kind of natural air freshener and preparation method thereof | |
| CN105396166A (en) | Liquid air freshener | |
| CN101954107A (en) | Solid aromatic sleep aid and preparation method thereof | |
| US20030108582A1 (en) | Insect repellent comprising essential volatile oils and use thereof | |
| KR101772091B1 (en) | Antibacterial fragrances composition and method for manufacturing antibacterial fragrances using the same | |
| JP6017120B2 (en) | Solid volatilization preparation and composition used therefor | |
| CN107625982A (en) | A kind of air freshener | |
| JP5346461B2 (en) | Small animal repellent | |
| KR101898060B1 (en) | Natural aroma essential oil water soluble composition for humidifier disinfectant and the method of manufaturing the same | |
| KR101995022B1 (en) | Functional air freshener composition | |
| JP6086757B2 (en) | Aerosol insecticide | |
| CN1968672A (en) | Cosmetic sprays | |
| JP5405621B2 (en) | Fragrance composition | |
| WO2018174136A1 (en) | Fragrance composition, and disinfecting and deodorizing solution and disinfecting and deodorizing method each utilizing same | |
| CN109526950B (en) | Persistent degerming agent, preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |
|
| RJ01 | Rejection of invention patent application after publication |